JP2006523598A - 合成ガスの製造方法 - Google Patents
合成ガスの製造方法 Download PDFInfo
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- JP2006523598A JP2006523598A JP2006505550A JP2006505550A JP2006523598A JP 2006523598 A JP2006523598 A JP 2006523598A JP 2006505550 A JP2006505550 A JP 2006505550A JP 2006505550 A JP2006505550 A JP 2006505550A JP 2006523598 A JP2006523598 A JP 2006523598A
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- reactor
- steam
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- partial oxidation
- carbon
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- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000007789 gas Substances 0.000 claims abstract description 48
- 239000003054 catalyst Substances 0.000 claims abstract description 29
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 28
- 230000003647 oxidation Effects 0.000 claims abstract description 23
- 238000000629 steam reforming Methods 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000002407 reforming Methods 0.000 claims abstract description 7
- 239000008246 gaseous mixture Substances 0.000 claims abstract description 4
- 229910002090 carbon oxide Inorganic materials 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 43
- 238000002303 thermal reforming Methods 0.000 claims 1
- 238000001833 catalytic reforming Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 44
- 230000015572 biosynthetic process Effects 0.000 description 26
- 238000003786 synthesis reaction Methods 0.000 description 26
- 229930195733 hydrocarbon Natural products 0.000 description 22
- 150000002430 hydrocarbons Chemical class 0.000 description 22
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000003345 natural gas Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000006315 carbonylation Effects 0.000 description 1
- 238000005810 carbonylation reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- B01J8/067—Heating or cooling the reactor
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- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
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| EP03076114 | 2003-04-15 | ||
| PCT/EP2004/050504 WO2004092063A1 (en) | 2003-04-15 | 2004-04-13 | Process to prepare synthesis gas |
Publications (1)
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|---|---|
| JP2006523598A true JP2006523598A (ja) | 2006-10-19 |
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| JP2006505548A Pending JP2006523597A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
| JP2006505545A Pending JP2006523595A (ja) | 2003-04-15 | 2004-04-13 | 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 |
| JP2006505546A Pending JP2006523596A (ja) | 2003-04-15 | 2004-04-13 | 水素、及び水素と一酸化炭素との混合物の製造方法 |
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| JP2006505548A Pending JP2006523597A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
| JP2006505545A Pending JP2006523595A (ja) | 2003-04-15 | 2004-04-13 | 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 |
| JP2006505546A Pending JP2006523596A (ja) | 2003-04-15 | 2004-04-13 | 水素、及び水素と一酸化炭素との混合物の製造方法 |
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| US (5) | US7462209B2 (enExample) |
| EP (4) | EP1613552A1 (enExample) |
| JP (4) | JP2006523598A (enExample) |
| KR (1) | KR20050120719A (enExample) |
| CN (4) | CN1774393A (enExample) |
| WO (4) | WO2004092061A1 (enExample) |
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|---|---|---|---|---|
| JP2006160602A (ja) * | 2004-12-07 | 2006-06-22 | Sk Corp | 小型円筒状改質装置 |
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| JPS61222903A (ja) * | 1985-03-05 | 1986-10-03 | インペリアル・ケミカル・インダストリーズ・ピーエルシー | 水素及び炭素酸化物類を含むガス流の製造方法及びそのための装置 |
| JPH01501224A (ja) * | 1986-09-15 | 1989-04-27 | エル・ウント・ツエ・シユタインミユラア・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 水蒸気によってガス状の炭化水素を触媒分解するための改質器、およびそのための1次改質器と2次改質器を備えた設備 |
| JPH04215837A (ja) * | 1990-02-02 | 1992-08-06 | Haldor Topsoe As | 熱交換を改質するプロセスと反応系 |
| JPH0948601A (ja) * | 1995-07-31 | 1997-02-18 | Texaco Dev Corp | 部分酸化装置ガス供給システムの熱含量連続制御方法 |
| JPH11510431A (ja) * | 1995-08-07 | 1999-09-14 | インペリアル ケミカル インダストリーズ パブリック リミティド カンパニー | 熱交換装置及び方法 |
| JP2003520747A (ja) * | 2000-01-25 | 2003-07-08 | インペリアル・ケミカル・インダストリーズ・ピーエルシー | スチーム改質装置 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006160602A (ja) * | 2004-12-07 | 2006-06-22 | Sk Corp | 小型円筒状改質装置 |
Also Published As
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|---|---|
| CN100381353C (zh) | 2008-04-16 |
| CN1832900A (zh) | 2006-09-13 |
| US20080028680A1 (en) | 2008-02-07 |
| JP2006523597A (ja) | 2006-10-19 |
| JP2006523596A (ja) | 2006-10-19 |
| EP1622828A1 (en) | 2006-02-08 |
| US7462209B2 (en) | 2008-12-09 |
| CN1774392A (zh) | 2006-05-17 |
| US20090126272A1 (en) | 2009-05-21 |
| US20060260194A1 (en) | 2006-11-23 |
| WO2004092061A1 (en) | 2004-10-28 |
| WO2004092063A1 (en) | 2004-10-28 |
| JP2006523595A (ja) | 2006-10-19 |
| EP1622827A1 (en) | 2006-02-08 |
| EP1613552A1 (en) | 2006-01-11 |
| KR20050120719A (ko) | 2005-12-22 |
| EP1622829A1 (en) | 2006-02-08 |
| US7550635B2 (en) | 2009-06-23 |
| WO2004092060A1 (en) | 2004-10-28 |
| US8986631B2 (en) | 2015-03-24 |
| US20060191201A1 (en) | 2006-08-31 |
| CN1774391A (zh) | 2006-05-17 |
| WO2004092062A1 (en) | 2004-10-28 |
| US20070140954A1 (en) | 2007-06-21 |
| CN1774393A (zh) | 2006-05-17 |
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