JP2006523595A - 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 - Google Patents
水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 Download PDFInfo
- Publication number
- JP2006523595A JP2006523595A JP2006505545A JP2006505545A JP2006523595A JP 2006523595 A JP2006523595 A JP 2006523595A JP 2006505545 A JP2006505545 A JP 2006505545A JP 2006505545 A JP2006505545 A JP 2006505545A JP 2006523595 A JP2006523595 A JP 2006523595A
- Authority
- JP
- Japan
- Prior art keywords
- steam
- reaction
- product
- gas
- passage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00309—Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
【解決手段】天然ガス・水蒸気用容器入口2;熱ガス状媒体用容器入口3;水蒸気改質生成物含有ガス状生成物用容器出口4;及び水蒸気改質触媒床8を含む反応器空間7;を有する、水蒸気改質反応を行うための反応容器であって、該反応器空間の入口は該天然ガス及び水蒸気入口に流動可能に接続し、該空間の出口端は該ガス状生成物出口と流動可能に接続すると共に、該触媒床内には、触媒床中の反応剤流に対し向流で熱ガス状混合物を通過させるための通路9を、該熱ガス状媒体用容器入口に流動可能に接続して設けた該反応容器。
Description
本発明は、天然ガス供給原料から出発して、水蒸気改質反応を行うための反応容器に向けたものである。また本発明は、部分酸化反応及び吸熱水蒸気改質反応を行うことにより、炭素質原料から一酸化水素及び水素を含有する混合物を製造する方法にも向けたものである。
EP−A−168892には、少なくとも1つのパイプ内に配置した固定床中で吸熱水蒸気反応を行う方法が記載されている。パイプ内の温度は800〜950℃で、この温度は、部分酸化反応の熱生成物ガスの少なくとも一部に対しパイプ沿いに道筋を定めることにより維持される。この文献による合成ガスの部分酸化と吸熱製造とを組合わせた方法では、(部分酸化法に比べて)合成ガスの収率が向上し、H2/CO比が増大し、得られる合成ガス生成物1m3当りの酸素使用量が低下し、またCO及びH2を含有するガス混合物の製造プラントの資本コストが低下する。
この目的は以下の反応器により達成される。
天然ガス及び水蒸気用の容器入口;熱ガス状媒体用の容器入口;水蒸気改質生成物含有ガス状生成物用の容器出口;及び水蒸気改質触媒床を含む反応器空間;を有する、水蒸気改質反応を行うための反応容器であって、該反応器空間の入口は該天然ガス及び水蒸気入口に流動可能に接続し、該空間の出口端は該ガス状生成物出口と流動可能に接続すると共に、該触媒床内には、触媒床中の反応剤流に対し向流で熱ガス状混合物を通過させるための通路を、該熱ガス状媒体用容器入口に流動可能に接続して設けた該反応容器。
(a)炭素質供給原料を部分酸化して、水素と一酸化炭素との第一ガス状混合物を得る工程、及び
(b)炭素質供給原料を、1つ以上の改質触媒含有管を備えた管状反応器を有する対流式水蒸気改質器で接触水蒸気改質する工程、
を行うことにより、炭素質供給原料から水素及び一酸化炭素を含有するガスを製造する方法であって、水蒸気改質反応に必要な熱は該水蒸気改質器の反応管と、該管状反応管内に軸沿いに配置され、工程(a)の流出流が該水蒸気改質器管内のガスに対し向流で流れる通路との対流式熱交換により供給される該製造方法にも向けたものである。
前記方法の工程(b)は、本発明の反応容器で行うことが好ましい。
図1は、触媒床を反応容器のシェル側に配置した本発明反応容器の可能な実施態様を示す。
図2は、触媒床が1つ以上の反応管中にある本発明の水蒸気改質反応器を示す。図2a、2b、2cは、図2の反応器の詳細及び好ましい実施態様を示す。
図3は、2つの別々のガス出口を設けた図2の反応器を示す。
図4は、図3の反応容器と部分酸化反応容器との組合わせを示す。
図5は、図4の装置、フィッシャー・トロプシュ合成法及び該合成法の下流の幾つかの単位操作を含む統合方法を示す。
出願人は、熱ガス媒体を長い通路に通すと、CSR反応器の熱交換表面に煤が付着しないか、或いは付着しても少なくとも従来技術の設計に比べて非常に少ないガス速度条件が得られることを見い出した。この長い通路は、ガスがいわゆる自浄能力を有する特定の速度で流れるように、設計することが好ましい。設計能力でのガス速度は、好ましくは10m/秒より速く、更に好ましくは30m/秒より速い。ガスの最高速度は、好ましくは100m/秒未満、更に好ましくは60m/秒未満である。更に、堆積が起これば、このような堆積物は一回の操業停止で従来の導管内部浄化法により容易に除去できるという利点もある。浄化法の例はピギング(pigging)及び水噴射である。前記反応器及びその好ましい実施態様の別の利点を以下に説明する。
管及び該管の延長物は、次の種類:錬管、遠心注型管又は焼結金属管の1種であることが好ましい。
水蒸気改質反応(a)炭素質供給原料を部分酸化して、水素と一酸化炭素との第一ガス状混合物を得る工程、及び
(b)炭素質供給原料を、1つ以上の改質触媒含有管を備えた管状反応器を有する対流式水蒸気改質器で接触水蒸気改質する工程、
を行うことにより、炭素質供給原料から水素及び一酸化炭素を含有するガスを製造する方法であって、水蒸気改質反応に必要な熱は、該水蒸気改質器の反応管と、該管状反応管内に軸沿いに配置され、工程(a)の流出流が該水蒸気改質器管内のガスに対し向流で流れる通路との対流式熱交換により供給される該製造方法にも向けたものである。
工程(a)の部分酸化は、例えばOil and Gas Journal,1971年9月号85〜90頁のShell Gasification Processについて記載の周知の原理に従って行ってよい。部分酸化法の例を記載する文献は、EP−A−291111、WO−A−9722547、WO−A−9639354及びWO−A−9603345である。これらの方法では、原料は、好ましくは触媒の不存在下、部分酸化条件下で酸素含有ガスと接触させる。
工程(a)での部分酸化反応のガス状生成物は、1100〜1500℃の温度及び1.5〜2.6、好ましくは1.6〜2.2のH2/COモル比を有することが好ましい。
工程(b)で得られた一酸化炭素と水素との混合物(水蒸気改質生成物)は、工程(a)で得られた生成物ガスと直接組合わせてもよい。この組合わせは、図1及び図3で例示するような反応器中で行ってよい。或いは工程(a)及び(b)で生成物ガスは、別個の流れとしても得られるし、また任意に所望の比率で組合わせてもよい。
このような再循環流に存在する二酸化炭素の一部又は全部は、工程(a)に供給する前に再循環流から任意に分離する。二酸化炭素の一部は、好適には工程(a)に供給してよい。
水蒸気改質生成物(55)中の水素対COモル比は、2を超え、好ましくは3を超え、通常、6以下である。水素回収ユニット(61)は、周知の膜分離ユニット、圧力スイング吸収機(PSA)又は膜ユニットとPSAとの組合わせでよい。
図2の水蒸気改質反応器に水蒸気対炭素比0.75で天然ガス及び水蒸気を供給する。部分酸化反応器の熱流出流もこの反応器に27経由で供給する。第1表にマスフロー、温度及び得られた生成物流を示す。
図2のCSR反応器の原料中の水蒸気対炭素比を1とした他は例1を繰り返す。
本例では反応管の流出流は、図4(ライン55)に示すように、まず部分酸化反応器に供給した。反応器51には触媒床53は存在しなかった。
2 天然ガス及び水蒸気用の容器入口
3 熱ガス状媒体用の容器入口
4 ガス状改質生成物用の容器出口
5 上部管シート
6 下部管シート
7 反応器空間
8 水蒸気改質触媒床
9 通路
10 管シート
11 空間
12 容器出口
13 空間
15 開口部
20 反応容器
21 反応管
22 水蒸気改質触媒床
23 通路又は導管
24 壁
26 天然ガス及び水蒸気用の容器入口
26’ 開口部
26’’ 蓋
27 熱ガス状媒体用容器入口
28 ガス状生成物と熱ガス状媒体との混合物用の容器出口
29 管シート又は開口部
29’ 矢印方向
30 空間
31 管シート
32 空間又は管シート
a、b、c 状態
33 空間
34 開口部
35 開口部
36 空間
38 熱ガス状媒体用容器入口
39 水蒸気改質生成物用容器出口
40 管シート
41 管シート
42 容器出口
43 天然ガス及び水蒸気用の容器入口
44 反応容器
45 ガス収集空間
46 入口空間
50 炭素質原料
50’ 酸素含有ガス
51 部分酸化反応器
52 バーナー
54 ガス状再循環流
55 生成物ガス又は水蒸気改質生成物
60 水蒸気改質生成物の一部
61 水素回収ユニット
62 水素
63 最終合成ガス生成物
64 フィッシャー・トロプシュ合成法ユニット
65 炭化水素生成物
66 水素化転化ユニット又は水素化処理ユニット
Claims (16)
- 天然ガス及び水蒸気用の容器入口;熱ガス状媒体用の容器入口;水蒸気改質生成物含有ガス状生成物用の容器出口;及び水蒸気改質触媒床を含む反応器空間;を有する、水蒸気改質反応を行うための反応容器であって、該反応器空間の入口は該天然ガス及び水蒸気入口に流動可能に接続し、該空間の出口端は該ガス状生成物出口と流動可能に接続すると共に、該触媒床内には、触媒床中の反応剤流に対し向流で熱ガス状混合物を通過させるための通路を、該熱ガス状媒体用容器入口に流動可能に接続して設けた該反応容器。
- 前記反応器空間は水蒸気改質触媒床を充填した1つ以上の反応管により規定されると共に、該反応管は反応管軸に平行に走行する1つ以上の通路を有する請求項1に記載の反応容器。
- 前記反応管から出る水蒸気改質生成物、前記熱ガス状媒体用容器入口から入る容器熱ガス状媒体は共に、使用時、熱ガス状媒体と水蒸気改質生成物との混合物が前記通路を通るように、該通路の入口と流動可能に連絡している請求項2に記載の反応容器。
- 前記通路が金属合金製の管であり、該合金は、鉄を0から7重量%以下、アルミニウムを0〜5重量%、珪素を0から5重量%以下、クロムを20から50重量%以下、及びニッケルを35重量%以上で、かつ合計を100%にバランスさせる量、含む請求項1〜3のいずれか1項に記載の反応容器。
- (a)炭素質供給原料を部分酸化して、水素と一酸化炭素との第一ガス状混合物を得る工程、及び
(b)炭素質供給原料を、1つ以上の改質触媒含有管を備えた管状反応器を有する対流式水蒸気改質器で接触水蒸気改質する工程、
を行うことにより、炭素質供給原料から水素及び一酸化炭素を含有するガスを製造する方法であって、水蒸気改質反応に必要な熱は、該水蒸気改質器の反応管と、該管状反応管内に軸沿いに配置され、工程(a)の流出流が該水蒸気改質器管内のガスに対し向流で流れる通路との対流式熱交換により供給される該製造方法。 - 前記通路内のガス速度が10〜60m/秒である請求項5に記載の製造方法。
- 工程(b)で得られた水蒸気改質生成物の0〜60重量%及び工程(a)の流出流が前記通路を流れる請求項5又は6に記載の製造方法。
- 前記工程(a)と工程(b)とを組合せた合成ガス生成物のH2/COモル比が1.5〜3、好ましくは1.9〜2.3である請求項5〜7のいずれか1項に記載の製造方法。
- 工程(b)の原料の水蒸気対炭素のモル比が0.5〜0.9である請求項5〜8のいずれか1項に記載の製造方法。
- 前記改質触媒が(a)酸化物支持体材料及び(b)Pt、Ni、Pd及びCoよりなる群の金属の少なくとも1種、好ましくは白金を0.1〜7.0重量%含むコーティングを含有し、該支持体材料は(i)該コーティングの適用前に約670℃以下の温度で焼成したZrO2を80重量%以上、(ii)Y、La、Al、Ca、Ce及びSiよりなる群から選ばれた少なくとも1種の酸化物、好ましくはLa2O3を0.5〜10モル%含有する請求項9に記載の製造方法。
- 工程(b)において前記通路の金属壁表面の温度が1100℃未満に維持される請求項5〜10のいずれか1項に記載の製造方法。
- 工程(b)の水蒸気改質生成物が工程(a)に供給される請求項5〜11のいずれか1項に記載の製造方法。
- 工程(b)の水蒸気改質生成物が、上端にバーナーを備え、上半部の温度が800〜1050℃である部分酸化反応容器の該上半部に供給される請求項12に記載の製造方法。
- 工程(b)の水蒸気改質生成物と工程(a)の部分酸化反応生成物との混合物に対し、自熱式改質工程(c)を施す請求項12又は13に記載の製造方法。
- 工程(b)の流出流から水素が回収されるる請求項5〜14のいずれか1項に記載の製造方法。
- 工程(b)が請求項1〜4のいずれか1項に記載の反応容器中で行われる請求項5〜14のいずれか1項に記載の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03076114 | 2003-04-15 | ||
PCT/EP2004/050499 WO2004092060A1 (en) | 2003-04-15 | 2004-04-13 | Reactor for performing a steam reforming reaction and a process to prepare synthesis gas |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006523595A true JP2006523595A (ja) | 2006-10-19 |
JP2006523595A5 JP2006523595A5 (ja) | 2007-06-14 |
Family
ID=33185905
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006505545A Pending JP2006523595A (ja) | 2003-04-15 | 2004-04-13 | 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 |
JP2006505546A Pending JP2006523596A (ja) | 2003-04-15 | 2004-04-13 | 水素、及び水素と一酸化炭素との混合物の製造方法 |
JP2006505550A Pending JP2006523598A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
JP2006505548A Pending JP2006523597A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006505546A Pending JP2006523596A (ja) | 2003-04-15 | 2004-04-13 | 水素、及び水素と一酸化炭素との混合物の製造方法 |
JP2006505550A Pending JP2006523598A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
JP2006505548A Pending JP2006523597A (ja) | 2003-04-15 | 2004-04-13 | 合成ガスの製造方法 |
Country Status (6)
Country | Link |
---|---|
US (5) | US20080028680A1 (ja) |
EP (4) | EP1622829A1 (ja) |
JP (4) | JP2006523595A (ja) |
KR (1) | KR20050120719A (ja) |
CN (4) | CN1774391A (ja) |
WO (4) | WO2004092060A1 (ja) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7642294B2 (en) | 2004-10-08 | 2010-01-05 | Shell Oil Company | Process to prepare lower olefins from a carbon containing feedstock |
WO2006045744A1 (en) * | 2004-10-20 | 2006-05-04 | Shell Internationale Research Maatschappij B.V. | Process for steam and/or co2 reforming of a hydrocarbonaceous feedstock |
FR2877939B1 (fr) * | 2004-11-16 | 2007-02-02 | Air Liquide | Procede et installation pour la production combinee d'hydrogene et de dioxyde de carbone |
KR101127688B1 (ko) * | 2004-12-07 | 2012-03-23 | 에스케이이노베이션 주식회사 | 원통형 소형 개질 장치 |
DE102005021500A1 (de) * | 2005-05-10 | 2006-11-16 | Uhde Gmbh | Verfahren zur Aufheizung eines Dampf-/Erdgasgemisches im Bereich eines Gassammelrohres nach einem Primärreformer |
US7485767B2 (en) | 2005-06-29 | 2009-02-03 | Exxonmobil Chemical Patents Inc. | Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids |
EP1938406A4 (en) | 2005-08-25 | 2010-04-21 | Ceramatec Inc | ELECTROCHEMICAL CELL FOR PRODUCING SYNTHESIS GAS USING ATMOSPHERIC AIR AND WATER |
EP1991639B1 (en) | 2006-03-07 | 2015-04-22 | Shell Internationale Research Maatschappij B.V. | Process to prepare a fischer-tropsch synthesis product |
FR2898518B1 (fr) * | 2006-03-17 | 2009-01-16 | Inst Francais Du Petrole | Reacteur echangeur a combustion interne pour reaction endothermique en lit fixe |
US7772292B2 (en) | 2006-05-31 | 2010-08-10 | Exxonmobil Chemical Patents Inc. | Synthesis gas production and use |
EP2049437A2 (en) | 2006-07-11 | 2009-04-22 | Shell Internationale Research Maatschappij B.V. | Process to prepare a synthesis gas |
AU2007290757B2 (en) * | 2006-08-25 | 2011-05-26 | Exxonmobil Chemical Patents Inc. | Production of aromatics from methane |
EP1916233A1 (en) * | 2006-10-20 | 2008-04-30 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
US7695708B2 (en) * | 2007-03-26 | 2010-04-13 | Air Products And Chemicals, Inc. | Catalytic steam reforming with recycle |
WO2008123337A1 (ja) * | 2007-03-29 | 2008-10-16 | Nippon Oil Corporation | 水素製造および二酸化炭素回収方法ならびに装置 |
US9212059B2 (en) * | 2007-12-13 | 2015-12-15 | Gyco, Inc. | Method and apparatus for improving the efficiency of an SMR process for producing syngas while reducing the CO2 in a gaseous stream |
US7988948B2 (en) * | 2008-03-17 | 2011-08-02 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming method with limited steam export |
US7850944B2 (en) * | 2008-03-17 | 2010-12-14 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming method with limited steam export |
US8105402B1 (en) * | 2008-07-30 | 2012-01-31 | Bossard Peter R | Micro-channel steam reformer and system for extracting ultra-pure hydrogen gas from a hydrocarbon fuel |
WO2010022096A2 (en) * | 2008-08-18 | 2010-02-25 | Syngest, Inc. | Method for converting biomass into synthesis gas using a pressurized multi-stage progressively expanding fluidized bed gasifier followed by an oxyblown autothermal reformer to reduce methane and tars |
BRPI0904285B1 (pt) * | 2009-10-30 | 2019-09-10 | Petroleo Brasileiro Sa Petrobras | dispositivo para resfriamento e distribuição de cargas mistas sobre leitos fixos de catalisador |
CN101721957B (zh) * | 2009-12-03 | 2011-08-31 | 太原理工大学 | 一种连续炭催化ch4-co2重整反应器 |
US9611437B2 (en) * | 2010-01-12 | 2017-04-04 | Lummus Technology Inc. | Producing low methane syngas from a two-stage gasifier |
US9227844B2 (en) * | 2010-01-19 | 2016-01-05 | Haldor Topsoe A/S | Heat exchange reformer with double-tubes for reforming hydrocarbons |
WO2011106895A1 (en) * | 2010-03-01 | 2011-09-09 | Plasco Energy Group Inc. | Carbon conversion system with integrated processing zones |
US9321641B1 (en) | 2011-02-11 | 2016-04-26 | Emerging Fuels Technology, Inc. | Process to convert natural gas into liquid fuels and chemicals |
US9034208B1 (en) | 2011-02-11 | 2015-05-19 | Emerging Fuels Technology, Inc. | Process to convert natural gas into liquid fuels and chemicals |
EP2740322B1 (en) | 2011-08-04 | 2018-05-02 | Stephen Lee Cunningham | Plasma arc furnace and applications |
EP2607301A1 (de) * | 2011-12-20 | 2013-06-26 | Karl-Heinz Tetzlaff | Vorrichtung und Verfahren zur Erdgasreformierung |
JP6002249B2 (ja) * | 2012-02-06 | 2016-10-05 | ヘルビオ ソシエテ アノニム ハイドロジェン アンド エナジー プロダクション システムズ | 水素生成のための触媒燃焼式熱統合型改質器 |
EP2671842A1 (en) * | 2012-06-06 | 2013-12-11 | Ammonia Casale S.A. | A process for gas-heated reforming of a hydrocarbon source and a related plant |
CN104736472A (zh) * | 2012-09-26 | 2015-06-24 | 埃讷肯公司 | 合成气分离与重整方法 |
US9452931B2 (en) * | 2012-11-15 | 2016-09-27 | Phillips 66 Company | Process scheme for catalytic production of renewable hydrogen from oxygenate feedstocks |
EP2801550A1 (en) * | 2013-05-10 | 2014-11-12 | Ammonia Casale S.A. | A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio |
CA2869645A1 (en) * | 2013-11-04 | 2015-05-04 | Me Resource Corp | Method and apparatus for producing chemicals from a methane-containing gas |
DE102014004264A1 (de) * | 2014-03-14 | 2015-09-17 | Universität Stuttgart | Wärmeintegrierte Hochtemperatur-Reaktoren für die autotherme partielle Oxidation |
EP3140601A4 (en) | 2014-05-09 | 2017-11-08 | Stephen Lee Cunningham | Arc furnace smeltering system & method |
WO2016016257A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated sct-cpo/pox process for producing synthesis gas |
WO2016016251A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated sct-cpo/sr process for producing synthesis gas |
US9840413B2 (en) | 2015-05-18 | 2017-12-12 | Energyield Llc | Integrated reformer and syngas separator |
US9843062B2 (en) | 2016-03-23 | 2017-12-12 | Energyield Llc | Vortex tube reformer for hydrogen production, separation, and integrated use |
FR3040313B1 (fr) * | 2015-08-24 | 2017-08-25 | Air Liquide | Echangeur-reacteur integrant les reactions de vaporeformage et de gaz a l'eau pour la production d'hydrogene |
DE102016212757A1 (de) * | 2016-07-13 | 2018-01-18 | Thyssenkrupp Ag | Kompakter Methanolreformer für ein Unterseeboot |
CN106082127B (zh) * | 2016-08-25 | 2018-09-11 | 晋城市阿邦迪能源有限公司 | 选择性氧化净化co的甲醇重整反应器 |
CN106145036B (zh) * | 2016-08-25 | 2018-12-04 | 晋城市阿邦迪能源有限公司 | 甲烷化反应净化co的甲醇重整反应器 |
EP3296255A1 (de) * | 2016-09-14 | 2018-03-21 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt |
DK3532430T3 (da) * | 2016-10-25 | 2020-07-27 | Technip France | Katalysatorrør til reformering |
EA039539B1 (ru) | 2016-11-09 | 2022-02-08 | 8 Риверз Кэпитл, Ллк | Способ выработки энергии с интегрированным производством водорода |
GB201813431D0 (en) * | 2018-08-17 | 2018-10-03 | Weedon Geoffrey Gerald | Process & apparatus for steam reforming |
IT201900008280A1 (it) * | 2019-06-06 | 2020-12-06 | Amec Foster Wheeler Italiana S R L | Reattore, in particolare reattore di reforming con vapore, e suo uso in un processo di reforming con vapore |
AU2020292848A1 (en) | 2019-06-13 | 2022-02-03 | 8 Rivers Capital, Llc | Power production with cogeneration of further products |
IT201900013239A1 (it) * | 2019-07-29 | 2021-01-29 | Milano Politecnico | Impianto per la produzione di syngas a partire da polimeri plastici di recupero pretrattati |
GB2593179B (en) * | 2020-03-17 | 2022-04-27 | Nordic Electrofuel As | Production of hydrocarbons |
CN112573482B (zh) * | 2020-12-10 | 2022-07-08 | 洛阳沃达节能科技有限公司 | 一种制氢装置的制氢管以及制氢装置 |
WO2023089571A1 (en) | 2021-11-18 | 2023-05-25 | 8 Rivers Capital, Llc | Method for hydrogen production |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59107901A (ja) * | 1982-11-30 | 1984-06-22 | ウ−デ・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング | 水素および酸化炭素を含有するプロダクトガスを製造する装置 |
JPS62210047A (ja) * | 1986-03-10 | 1987-09-16 | Toyo Eng Corp | 反応用装置 |
JPH01501224A (ja) * | 1986-09-15 | 1989-04-27 | エル・ウント・ツエ・シユタインミユラア・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 水蒸気によってガス状の炭化水素を触媒分解するための改質器、およびそのための1次改質器と2次改質器を備えた設備 |
JPH01261201A (ja) * | 1988-04-12 | 1989-10-18 | Mitsubishi Gas Chem Co Inc | 炭化水素改質反応器 |
JPH03245833A (ja) * | 1991-01-25 | 1991-11-01 | Hitachi Ltd | 触媒反応装置 |
JPH11106204A (ja) * | 1997-10-01 | 1999-04-20 | Sanyo Electric Co Ltd | 水素製造装置及び水素製造方法 |
JP2001206702A (ja) * | 2000-01-26 | 2001-07-31 | Nissan Motor Co Ltd | 燃料改質装置および燃料電池システム |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2324172A (en) * | 1940-10-31 | 1943-07-13 | Standard Oil Co | Processing well fluids |
GB1093943A (en) * | 1963-10-07 | 1967-12-06 | Ici Ltd | Reforming hydrocarbons |
US3549335A (en) * | 1965-10-22 | 1970-12-22 | Braun & Co C F | Autothermal reactor |
CN87100591A (zh) * | 1983-06-09 | 1988-07-20 | 联合碳化公司 | 用于烃类一次及二次催化水蒸汽转化的联合方法及设备 |
US4650651A (en) * | 1983-06-09 | 1987-03-17 | Union Carbide Corporation | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
DE3345088A1 (de) * | 1983-12-13 | 1985-06-13 | Linde Ag, 6200 Wiesbaden | Verfahren zur erzeugung von synthesegas |
GB2163449B (en) | 1984-07-18 | 1988-06-02 | Shell Int Research | Production of gas mixtures containing hydrogen and carbon monoxide |
NL8403144A (nl) * | 1984-10-16 | 1986-05-16 | Stamicarbon | Werkwijze voor het bereiden van een synthesegas. |
EP0194067B2 (en) | 1985-03-05 | 1994-05-11 | Imperial Chemical Industries Plc | Steam reforming hydrocarbons |
GB8711156D0 (en) | 1987-05-12 | 1987-06-17 | Shell Int Research | Partial oxidation of hydrocarbon-containing fuel |
JP2625443B2 (ja) * | 1987-09-25 | 1997-07-02 | 三菱瓦斯化学株式会社 | 固定触媒層反応器 |
US4943672A (en) * | 1987-12-18 | 1990-07-24 | Exxon Research And Engineering Company | Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403) |
US5059299A (en) * | 1987-12-18 | 1991-10-22 | Exxon Research And Engineering Company | Method for isomerizing wax to lube base oils |
DE3813863A1 (de) * | 1988-04-23 | 1989-11-02 | Uhde Gmbh | Einrichtung zur aufnahme von katalysatoren, insbesondere bei der erzeugung von synthesegas |
DK167864B1 (da) * | 1990-02-02 | 1993-12-27 | Topsoe Haldor As | Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling |
US5029299A (en) | 1990-05-09 | 1991-07-02 | Altec Lansing Corporation | Power amplifier with current limiting means |
US5245110A (en) | 1991-09-19 | 1993-09-14 | Starchem, Inc. | Process for producing and utilizing an oxygen enriched gas |
GB9203375D0 (en) * | 1992-02-18 | 1992-04-01 | Davy Mckee London | Process |
US5254318A (en) * | 1992-07-20 | 1993-10-19 | Stone & Webster Engineering Corporation | Lined reformer tubes for high pressure reformer reactors |
PL175047B1 (pl) | 1993-04-22 | 1998-10-30 | Kti Group Bv | Sposób wytwarzania katalizatora do procesu wytwarzania gazu syntezowego |
EP0668342B1 (en) | 1994-02-08 | 1999-08-04 | Shell Internationale Researchmaatschappij B.V. | Lubricating base oil preparation process |
MY115440A (en) | 1994-07-22 | 2003-06-30 | Shell Int Research | A process for the manufacture of synthesis gas by partial oxidation of a gaseous hydrocarbon-containing fuel using a multi-orifice (co-annular)burner |
EG20966A (en) | 1995-06-06 | 2000-07-30 | Shell Int Research | A method for flame stabilization in a process for preparing synthesis gas |
JP3734859B2 (ja) * | 1995-07-31 | 2006-01-11 | テキサコ・デベロップメント・コーポレーション | 部分酸化装置ガス供給システムの熱含量連続制御方法 |
GB9516125D0 (en) * | 1995-08-07 | 1995-10-04 | Ici Plc | Heat exchange apparatus and process |
EP0776959B1 (en) | 1995-11-28 | 2004-10-06 | Shell Internationale Researchmaatschappij B.V. | Process for producing lubricating base oils |
US5931978A (en) | 1995-12-18 | 1999-08-03 | Shell Oil Company | Process for preparing synthesis gas |
US6090989A (en) | 1997-10-20 | 2000-07-18 | Mobil Oil Corporation | Isoparaffinic lube basestock compositions |
WO1999034917A1 (en) | 1997-12-30 | 1999-07-15 | Shell Internationale Research Maatschappij B.V. | Cobalt based fisher-tropsch catalyst |
DK173742B1 (da) * | 1998-09-01 | 2001-08-27 | Topsoe Haldor As | Fremgangsmåde og reaktorsystem til fremstilling af syntesegas |
EP0983964A3 (de) | 1998-09-04 | 2000-07-26 | Linde Aktiengesellschaft | Verfahren und Primärreformer zur Erzeugung von Synthesegas |
DE60019935T2 (de) | 1999-07-26 | 2006-02-16 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung eines grundschmieröls |
US6284217B1 (en) * | 1999-08-17 | 2001-09-04 | Battelle Memorial Institute | Method and catalyst structure for steam reforming of a hydrocarbon |
DE19953641A1 (de) | 1999-11-09 | 2001-06-07 | Metallgesellschaft Ag | Verfahren zur katalytischen Dehydrierung von Kohlenwasserstoffen im Röhrenreaktor |
GB9927817D0 (en) | 1999-11-26 | 2000-01-26 | Ici Plc | Steam reforming apparatus |
GB0001540D0 (en) * | 2000-01-25 | 2000-03-15 | Gratwick Christopher | Stream reforming |
US6521143B1 (en) | 2000-04-13 | 2003-02-18 | Air Products And Chemicals, Inc. | Co-production of carbon monoxide-rich syngas wth high purity hydrogen |
US6892225B1 (en) * | 2000-07-19 | 2005-05-10 | Fusionone, Inc. | Agent system for a secure remote access system |
AR032930A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Procedimiento para preparar un aceite de base lubricante y gas oil |
MY137259A (en) | 2001-03-05 | 2009-01-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil. |
AR032941A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones |
MY136087A (en) * | 2001-10-22 | 2008-08-29 | Shell Int Research | Process to reduce the temperature of a hydrogen and carbon monoxide containing gas and heat exchanger for use in said process |
-
2004
- 2004-04-13 US US10/552,551 patent/US20080028680A1/en not_active Abandoned
- 2004-04-13 JP JP2006505545A patent/JP2006523595A/ja active Pending
- 2004-04-13 US US10/552,553 patent/US7462209B2/en not_active Expired - Fee Related
- 2004-04-13 US US10/552,854 patent/US7550635B2/en not_active Expired - Fee Related
- 2004-04-13 CN CNA2004800100803A patent/CN1774391A/zh active Pending
- 2004-04-13 CN CNA2004800100790A patent/CN1832900A/zh active Pending
- 2004-04-13 WO PCT/EP2004/050499 patent/WO2004092060A1/en active Search and Examination
- 2004-04-13 JP JP2006505546A patent/JP2006523596A/ja active Pending
- 2004-04-13 JP JP2006505550A patent/JP2006523598A/ja active Pending
- 2004-04-13 KR KR1020057019714A patent/KR20050120719A/ko not_active Application Discontinuation
- 2004-04-13 WO PCT/EP2004/050504 patent/WO2004092063A1/en active Application Filing
- 2004-04-13 EP EP04727023A patent/EP1622829A1/en not_active Withdrawn
- 2004-04-13 EP EP04727021A patent/EP1613552A1/en not_active Withdrawn
- 2004-04-13 WO PCT/EP2004/050502 patent/WO2004092062A1/en active Application Filing
- 2004-04-13 CN CNA2004800100822A patent/CN1774393A/zh active Pending
- 2004-04-13 EP EP04727011A patent/EP1622827A1/en not_active Withdrawn
- 2004-04-13 WO PCT/EP2004/050500 patent/WO2004092061A1/en active Search and Examination
- 2004-04-13 EP EP04727022A patent/EP1622828A1/en not_active Withdrawn
- 2004-04-13 JP JP2006505548A patent/JP2006523597A/ja active Pending
- 2004-04-13 CN CNB2004800100818A patent/CN100381353C/zh not_active Expired - Fee Related
- 2004-04-13 US US10/553,164 patent/US20060260194A1/en not_active Abandoned
-
2008
- 2008-11-03 US US12/264,121 patent/US8986631B2/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59107901A (ja) * | 1982-11-30 | 1984-06-22 | ウ−デ・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング | 水素および酸化炭素を含有するプロダクトガスを製造する装置 |
JPS62210047A (ja) * | 1986-03-10 | 1987-09-16 | Toyo Eng Corp | 反応用装置 |
JPH01501224A (ja) * | 1986-09-15 | 1989-04-27 | エル・ウント・ツエ・シユタインミユラア・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 水蒸気によってガス状の炭化水素を触媒分解するための改質器、およびそのための1次改質器と2次改質器を備えた設備 |
JPH01261201A (ja) * | 1988-04-12 | 1989-10-18 | Mitsubishi Gas Chem Co Inc | 炭化水素改質反応器 |
JPH03245833A (ja) * | 1991-01-25 | 1991-11-01 | Hitachi Ltd | 触媒反応装置 |
JPH11106204A (ja) * | 1997-10-01 | 1999-04-20 | Sanyo Electric Co Ltd | 水素製造装置及び水素製造方法 |
JP2001206702A (ja) * | 2000-01-26 | 2001-07-31 | Nissan Motor Co Ltd | 燃料改質装置および燃料電池システム |
Also Published As
Publication number | Publication date |
---|---|
US20060191201A1 (en) | 2006-08-31 |
EP1622829A1 (en) | 2006-02-08 |
JP2006523596A (ja) | 2006-10-19 |
EP1622827A1 (en) | 2006-02-08 |
WO2004092061A1 (en) | 2004-10-28 |
US7462209B2 (en) | 2008-12-09 |
WO2004092063A1 (en) | 2004-10-28 |
EP1622828A1 (en) | 2006-02-08 |
US7550635B2 (en) | 2009-06-23 |
US20060260194A1 (en) | 2006-11-23 |
CN100381353C (zh) | 2008-04-16 |
US20080028680A1 (en) | 2008-02-07 |
WO2004092062A1 (en) | 2004-10-28 |
JP2006523597A (ja) | 2006-10-19 |
CN1832900A (zh) | 2006-09-13 |
US8986631B2 (en) | 2015-03-24 |
EP1613552A1 (en) | 2006-01-11 |
KR20050120719A (ko) | 2005-12-22 |
CN1774392A (zh) | 2006-05-17 |
US20070140954A1 (en) | 2007-06-21 |
US20090126272A1 (en) | 2009-05-21 |
CN1774391A (zh) | 2006-05-17 |
WO2004092060A1 (en) | 2004-10-28 |
JP2006523598A (ja) | 2006-10-19 |
CN1774393A (zh) | 2006-05-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2006523595A (ja) | 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法 | |
JP4745219B2 (ja) | 水素製造用の自己熱改質装置−改質交換器の配置 | |
JP4351010B2 (ja) | 合成ガスの製造方法 | |
US7717971B2 (en) | Process for the production of synthesis gas | |
CN103748033B (zh) | 重整烃的方法 | |
US9932229B2 (en) | Method and system for production of hydrogen rich gas mixtures | |
JP4700603B2 (ja) | 部分酸化改質器−改質交換器配列 | |
US20220169502A1 (en) | Production of synthesis gas and of methanol | |
WO2010133621A1 (en) | Process to prepare a mixture of carbon monoxide and hydrogen | |
WO2006045746A1 (en) | Process to prepare a mixture of carbon monoxide and hydrogen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070404 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070404 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20100226 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100713 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20100803 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20100825 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110118 |