JP2006510449A - 植込み型医療装置用の硬化可能な媒質 - Google Patents
植込み型医療装置用の硬化可能な媒質 Download PDFInfo
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- JP2006510449A JP2006510449A JP2004563576A JP2004563576A JP2006510449A JP 2006510449 A JP2006510449 A JP 2006510449A JP 2004563576 A JP2004563576 A JP 2004563576A JP 2004563576 A JP2004563576 A JP 2004563576A JP 2006510449 A JP2006510449 A JP 2006510449A
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- diepoxide resin
- orthopedic
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- bisphenol
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Abstract
Description
H2N−(R−NH)X−R−NH2
ここで、Rの各々は、約2乃至10、好ましくは、2乃至5の炭素原子の枝分れ又は非枝分れ鎖から独立的に選ばれ、xは0、1、2である。好ましい実施の形態において、Rはアルキル、好ましくは直線鎖状であり、全てのR基は同一である。幾つかの実施の形態において、第二の部分は、ピペラジン系アミンのようなシクロアルキルアミンとアルキルアミンとの混合体を備えている。
フォミュ
レーション 成分 量(重量%)
VL14M
部分1 ビスフェノールAのジグリシジルエーテル 46.75%
グリシジルエーテルのブタンジオール 20.00%
部分2 n−アミノエチルピペラジン
ノニル/フェノール 28.34%
1,3 ジアミノプロパン 4.91%
VL18
部分1 ビスフェノールAのジグリシジルエーテル 49.12%
グリシジルエーテルのブタンジオール 21.05%
部分2 n−アミノエチルピペラジン
ノニル/フェノール 21.05%
1,3 ジアミノプロパン 8.78%
VL18−3
部分1 ビスフェノールAのジグリシジルエーテル 51.47%
グリシジルエーテルのブタンジオール 22.06%
部分2 n−アミノエチルピペラジン
ノニル/フェノール 22.06%
ジエチレントリアミン 4.41%
VL18−4
部分1 ビスフェノールAのジグリシジルエーテル 51.09%
グリシジルエーテルのブタンジオール 21.90%
部分2 n−アミノエチルピペラジン
ノニル/フェノール 21.90%
トリエチレンテトラアミン 5.11%
VL18−12
部分1 ビスフェノールAのジグリシジルエーテル 49.82%
グリシジルエーテルのブタンジオール 21.35%
部分2 n−アミノエチルピペラジン
ノニル/フェノール 24.20%
トリエチレンテトラアミン 4.63%
図49は、バルーン400を除去した、カテーテルの末端の拡大図である。最内管は注入管430である。その内部の管腔は注入管腔432である。注入管腔432はカテーテルの基端における注入ポートまで基端方向に伸びている。注入管430は吸引管434内に同軸状に配置されている。注入管430の外面と吸引管434の内面との間の環状空間は吸引管腔436を画成する。吸引管腔436はカテーテルの基端にて吸引ポートと連通している。
図52には、カテーテルの挿入を容易にし得るよう使用した補強ワイヤー520の1つの実施の形態が示される。補強ワイヤー520は、基端及び末端を有する細長い可撓性の本体を備えている。ハンドル522がその基端に設けられている。線の長さは、挿入中、カテーテルを支持するのに十分であり、このため、本明細書にて説明したカテーテルの寸法に依存して変更することができる。寸法は、また所期のカテーテルの拡張管腔の内径にも基づく。1つの実施の形態において、線は、ステンレス鋼又はその他の材料とすることができる1.27mm(0.050インチ)ODの線又は管を備えている。PTFEのような潤滑性被覆を設けることもできる。末端領域524内にて一層の可撓性を実現するため、線又は管はテーパー付き領域528の全体を通じてテーパーを付け、末端方向により小さいODとなるようにしてもよい。コイルばね526をテーパー付き領域528の周りにて同心状に保持し且つ、末端の先端530に採り付けることができる。このことは、ガイドワイヤーが末端方向に可撓性を増すようにすることを許容する。
Claims (44)
- 現所にて形成される整形外科用装置であって、
内部にキャビティを画成する外壁と、前記キャビティ内の整形外科用装置を形成する硬化可能な媒質とを含み、該硬化可能な媒質は、約90分以内にて約45℃以下の温度で実質的に硬化する樹脂及び硬化剤の混合体を含み、
装置が患者の体内に配置される間、硬化可能な媒質が硬化し、現所にて形成される整形外科用装置を形成する、現所にて形成される整形外科用装置。 - 前記硬化可能な媒質はエポキシ樹脂を含む請求項1の現所にて形成される整形外科用装置。
- 前記エポキシ樹脂は、重量比にて合計約65乃至75%のジエポキシド樹脂と、重量比にて合計約25乃至35%の1つ又はより多くのアミンキュアリング剤とを含む、請求項2の現所にて形成される整形外科用装置。
- 前記エポキシ樹脂は、重量比にて合計約45乃至52%の芳香族ジエポキシド樹脂と、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂と、重量比にて約20乃至29%のジアルキルアミンと、約4乃至9%のシクロアルキルアミンとを含む請求項2の現所にて形成される整形外科用装置。
- 前記芳香族ジエポキシド樹脂は、ビスフェノールAのジグリシジルエーテル又はビスフェノールFのジグリシジルエーテルを含む請求項4の現所にて形成される整形外科用装置。
- 前記脂肪族ジエポキシド樹脂は、1つ以上のグリシジルエーテルのアルカンジオールを含む請求項4の現所にて形成される整形外科用装置。
- 前記ジアルキルアミンは、H2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である請求項4の現所にて形成される整形外科用装置。
- 前記シクロアルキルアミンは、N−アミノアルキルピペラジンである、請求項4の現所にて形成される整形外科用装置。
- 前記芳香族ジエポキシド樹脂は、ビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む請求項4の現所にて形成される整形外科用装置。
- 前記硬化可能な媒質は、少なくとも45.359kg(100lbs)の静止圧縮曲げ値(ASTM F1717)を有する硬化した形態に硬化する請求項1の現所にて形成される整形外科用装置。
- 拡張可能な部材を有する送込みカテーテルと、
拡張可能な部材内に収容された硬化可能な媒質であって、約90分以内にて少なくとも40.823kg(90lbs)の静止圧縮曲げ値(ASTM F1717)を有する硬化した形態に硬化するエポキシを含む前記硬化可能な媒質と、
入口を有する少なくとも2つのアンカーと、を含み、
前記拡張可能な部材は、前記少なくとも2つのアンカーの前記入口を通って伸びる、骨固定装置。 - 前記エポキシ樹脂は、重量比にて合計約45乃至52%の芳香族ジエポキシド樹脂と、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂と、重量比にて約20乃至29%のジアルキルアミンと、約4乃至9%のシクロアルキルアミンとを含む請求項11の骨固定装置。
- 前記芳香族ジエポキシド樹脂は、ビスフェノールAのジグリシジルエーテル又はビスフェノールFのジグリシジルエーテルを含む請求項12の骨固定装置。
- 前記脂肪族ジエポキシド樹脂は、1つ以上のグリシジルエーテルのアルカンジオールを含む請求項12の骨固定装置。
- 前記ジアルキルアミンは、H2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である請求項13の骨固定装置。
- 前記シクロアルキルアミンは、N−アミノアルキルピペラジンである請求項15の骨固定装置。
- 前記芳香族ジエポキシド樹脂は、ビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む請求項12の骨固定装置。
- 前記硬化可能な媒質は、約45℃以下の温度にて硬化する請求項11の骨固定装置。
- 前記硬化可能な媒質は、12時間以内に少なくとも68.039kg(150lbs)の静止圧縮曲げ値(ASTM F1717)を有する請求項11の骨固定装置。
- 末端及び基端を有し、中央管腔を形成する細長い可撓性の管状本体と、
少なくとも1つのポートを備える管状本体の基端におけるマニホルドと、
基端、末端及び内部を有し、管状本体の末端に除去可能に取り付けられた拡張可能な部材と、
該拡張可能な部材を拡張させる硬化可能な媒質であって、重量比にて約45乃至52%の芳香族ジエポキシド樹脂と、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂と、重量比にて約20乃至29%のジアルキルアミンと、約4乃至9%のシクロアルキルアミンとを含む硬化可能な媒質と、
拡張可能な部材の基端に設けられた弁と、を含む整形外科用固定装置。 - 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテル又はビスフェノールFのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂は1つ以上のグリシジルエーテルのアルカンジオールを含み、シクロアルキルアミンはN−アミノアルキルピペラジンであり、ジアルキルアミンはH2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である請求項20の整形外科用固定装置。
- 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む請求項21の整形外科用固定装置。
- 前記硬化可能な媒質は、硬化したとき、少なくとも45.359kg(100lbs)の静止圧縮曲げ値(ASTM F1717)を有する請求項20の整形外科用固定装置。
- 前記媒質は、約90分以内に実質的に硬化する請求項20の整形外科用固定装置。
- 前記媒質は、約45℃以下の温度にて硬化する請求項20の整形外科用固定装置。
- 患者の身体内の治療箇所に整形外科用装置を形成する方法であって、
チャンバを画成する外壁を患者の体内の治療箇所に配置するステップと、
硬化可能な媒質をチャンバ内に導入するステップとを含み、
硬化可能な媒質は、約90分以内に液体の形態から少なくとも40.823kg(90lbs)の静止圧縮曲げ値(ASTM F1717)を有する硬化した形態に硬化するものである整形外科用装置を形成する方法。 - 前記配置するステップは、外壁を2つの骨アンカーの間に配置するステップを含む請求項26の整形外科用装置を形成する方法。
- 前記硬化可能な媒質は、重量比にて合計約45乃至52%の芳香族ジエポキシド樹脂と、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂と、重量比にて約20乃至29%のジアルキルアミンと、約4乃至9%のシクロアルキルアミンとを含む請求項26の方法。
- 請求項28の方法において、芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテル、又はビスフェノールFのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルの1以上のアルカンジオールを含み、シクロアルキルアミンはN−アミノアルキルピペラジンであり、ジアルキルアミンはH2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である、方法。
- 請求項28の方法において、芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む、方法。
- 前記硬化可能な媒質は約45℃以下の温度にて硬化する請求項26の方法。
- 前記硬化可能な媒質は12時間以内に少なくとも68.039kg(150lbs)の静止圧縮曲げ値(ASTM F1717)を有する請求項26の方法。
- 整形外科的骨折を安定化する方法であって、
入口を有する少なくとも2つのアンカーを骨内に挿入するステップと、
拡張可能なバルーンを含む整形外科用装置を骨まで送り込むステップと、
重量比にて約45乃至52%の芳香族ジエポキシド樹脂、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂、重量比にて約20乃至29%のジアルキルアミン、約4乃至9%のシクロアルキルアミンを含む硬化可能な媒質にて前記バルーンを拡張させるステップと、を含み、
前記整形外科用装置は、前記入口を通って伸び、前記拡張により前記アンカーが互いに固定されるようにする、整形外科的骨折を安定化する方法。 - 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテル又はビスフェノールFのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルの1つ以上のアルカンジオールを含み、シクロアルキルアミンはN−アミノアルキルピペラジンであり、ジアルキルアミンはH2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である請求項33の方法。
- 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む請求項33の方法。
- 前記硬化可能な媒質は、硬化したとき、少なくとも45.359kg(100lbs)の静止圧縮曲げ値(ASTM F1717)を有する請求項33の方法。
- 前記媒質は、約90分以内に実質的に硬化する請求項33の方法。
- 前記媒質は約45℃以下の温度にて硬化する請求項33の方法。
- 整形外科的骨折を安定化する方法において、
入口を有する少なくとも2つのアンカーを骨内に挿入するステップと、
拡張可能なバルーンを備える整形外科用装置を入口を通して送り込むステップと、
前記バルーンを液体の硬化可能な材料にて拡張させるステップと、を含み、
拡張させるステップは、前記アンカーを互いに固定し、硬化可能な材料は、約90分以内に約45℃以下の温度にて実質的に硬化する、整形外科的骨折を安定化する方法。 - 前記硬化可能な材料は、重量比にて合計約45乃至52%の芳香族ジエポキシド樹脂と、重量比にて約19乃至23%の脂肪族ジエポキシド樹脂と、重量比にて約20乃至29%のジアルキルアミンと、約4乃至9%のシクロアルキルアミンとを含む請求項39の方法。
- 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテル又はビスフェノールFのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルの1つ以上のアルカンジオールを含み、シクロアルキルアミンはN−アミノアルキルピペラジンであり、ジアルキルアミンはH2N−R−NH2の式に従うものであり、ここでRは枝分れ又は非枝分れC2−C10アルキル基である請求項40の方法。
- 前記芳香族ジエポキシド樹脂はビスフェノールAのジグリシジルエーテルを含み、脂肪族ジエポキシド樹脂はグリシジルエーテルのブタンジオールを含み、ジアルキルアミンは1,3−ジアミノプロパンを含み、シクロアルキルアミンはN−アミノエチルピペラジンを含む請求項40の方法。
- 前記硬化可能な媒質は、硬化したとき、少なくとも45.359kg(100lbs)の静止圧縮曲げ値(ASTM F1717)を有する請求項39の方法。
- 現所にて形成される医療装置であって、
内部にキャビティを画成する外壁と、
医療装置を形成するためのキャビティ内の硬化可能な媒質であって、約45℃以下の温度にて硬化する樹脂及び硬化剤の混合体を含み、硬化したとき、少なくとも68.039kg(150lbs)の静止圧縮曲げ値(ASTM F1717)を有する硬化可能な媒質と、を含み、
前記硬化可能な媒質は、装置が患者の身体内に配置される間に、硬化し、現所にて形成される医療装置を形成することを特徴とする現所にて形成される医療装置。
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US8801790B2 (en) | 2005-12-27 | 2014-08-12 | Warsaw Orthopedic, Inc. | Intervertebral disc augmentation and rehydration with superabsorbent polymers |
-
2002
- 2002-12-20 US US10/327,706 patent/US6875212B2/en not_active Expired - Lifetime
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2003
- 2003-12-16 CN CN200380109700A patent/CN100588374C/zh not_active Expired - Fee Related
- 2003-12-16 EP EP03799917A patent/EP1589886A2/en not_active Withdrawn
- 2003-12-16 KR KR1020057011682A patent/KR100812901B1/ko not_active IP Right Cessation
- 2003-12-16 AU AU2003299633A patent/AU2003299633B2/en not_active Ceased
- 2003-12-16 WO PCT/US2003/039952 patent/WO2004058045A2/en active Application Filing
- 2003-12-16 CA CA002510731A patent/CA2510731A1/en not_active Abandoned
- 2003-12-16 JP JP2004563576A patent/JP4464282B2/ja not_active Expired - Fee Related
- 2003-12-16 KR KR1020067022098A patent/KR100778621B1/ko not_active IP Right Cessation
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- 2005-02-11 US US11/056,971 patent/US8337556B2/en active Active
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JP2013078599A (ja) * | 2006-04-26 | 2013-05-02 | Illuminoss Medical Inc | 骨に補強材を配送する装置および方法 |
JP2010514471A (ja) * | 2006-12-21 | 2010-05-06 | ウォーソー・オーソペディック・インコーポレーテッド | 生体内硬化性整形外科用インプラント装置 |
JP2010514470A (ja) * | 2006-12-21 | 2010-05-06 | ウォーソー・オーソペディック・インコーポレーテッド | 生体内配置後に硬化するように構成された硬化性整形外科用インプラント装置 |
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US11672553B2 (en) | 2007-06-22 | 2023-06-13 | Ekos Corporation | Method and apparatus for treatment of intracranial hemorrhages |
JP2012507342A (ja) * | 2008-10-31 | 2012-03-29 | イルミンオス・メディカル・インコーポレイテッド | 内部骨固定のためのシステムおよび方法 |
JP2013538097A (ja) * | 2010-08-27 | 2013-10-10 | イーコス・コーポレイシヨン | 頭蓋内出血の治療のための方法および装置関連出願本出願は、2010年8月27日付の米国仮特許出願第61/377,639号の優先権の利益を主張し、この米国特許仮出願の全内容が、ここでの言及によって本明細書に援用される。 |
US10888657B2 (en) | 2010-08-27 | 2021-01-12 | Ekos Corporation | Method and apparatus for treatment of intracranial hemorrhages |
US10656025B2 (en) | 2015-06-10 | 2020-05-19 | Ekos Corporation | Ultrasound catheter |
US11740138B2 (en) | 2015-06-10 | 2023-08-29 | Ekos Corporation | Ultrasound catheter |
Also Published As
Publication number | Publication date |
---|---|
WO2004058045A3 (en) | 2005-01-20 |
AU2003299633A1 (en) | 2004-07-22 |
KR20050088319A (ko) | 2005-09-05 |
AU2009200370A1 (en) | 2009-02-19 |
WO2004058045A2 (en) | 2004-07-15 |
US6875212B2 (en) | 2005-04-05 |
JP4464282B2 (ja) | 2010-05-19 |
KR20070020015A (ko) | 2007-02-16 |
EP1589886A2 (en) | 2005-11-02 |
KR100778621B1 (ko) | 2007-11-28 |
AU2003299633B2 (en) | 2008-12-04 |
CN1787785A (zh) | 2006-06-14 |
US20040006341A1 (en) | 2004-01-08 |
CA2510731A1 (en) | 2004-07-15 |
KR100812901B1 (ko) | 2008-03-11 |
AU2009200348A1 (en) | 2009-02-19 |
US20050149022A1 (en) | 2005-07-07 |
CN100588374C (zh) | 2010-02-10 |
US8337556B2 (en) | 2012-12-25 |
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