JP2006506518A - 新規な干渉顔料 - Google Patents
新規な干渉顔料 Download PDFInfo
- Publication number
- JP2006506518A JP2006506518A JP2005506658A JP2005506658A JP2006506518A JP 2006506518 A JP2006506518 A JP 2006506518A JP 2005506658 A JP2005506658 A JP 2005506658A JP 2005506658 A JP2005506658 A JP 2005506658A JP 2006506518 A JP2006506518 A JP 2006506518A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- sio
- metal
- tio
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0051—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
- C09C1/0054—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index one layer consisting of at least one sub-stoichiometric inorganic compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0051—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
- C09C1/0057—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer
- C09C1/0072—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer consisting of a carbonaceous material, e.g. carbon black, graphite, SWNT, MWNT incorporated within an inorganic material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
- C09C1/642—Aluminium treated with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/62—L* (lightness axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/63—Optical properties, e.g. expressed in CIELAB-values a* (red-green axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/65—Chroma (C*)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
- C09C2200/1058—Interference pigments characterized by the core material the core consisting of a metal comprising a protective coating on the metallic layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/301—Thickness of the core
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/302—Thickness of a layer with high refractive material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/303—Thickness of a layer with low refractive material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/304—Thickness of intermediate layers adjacent to the core, e.g. metallic layers, protective layers, rutilisation enhancing layers or reflective layers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/20—PVD, CVD methods or coating in a gas-phase using a fluidized bed
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Paints Or Removers (AREA)
Abstract
Description
(A)場合によっては、金属からなる層、
(B)層(A)が存在する場合、層(A)と層(C)との間に位置する、金属、ケイ素(Si)及び酸素(O)からなる少なくとも一つの層、及び
(C)場合によっては、層(B)の上の、SiOz(0.70≦z≦2.0)からなる層
を含む顔料に関する。層(B)は、
(A)金属からなる層、及び
(C)金属層上の、SiOy(0.70≦y≦1.80)からなる層
を含む顔料を、非酸化性雰囲気中、600℃を超える温度で焼成することによって得られる。
(A1)金属、特にアルミニウムからなる層、
(B)層(A1)と層(A2)との間に配設された、金属、Si及びOからなる層、及び
(A2)金属、特にアルミニウムからなる層、又は
(A1)金属、特にアルミニウムからなる層、
(B1)層(A1)と層(C)との間に配設された、金属、Si及びOからなる層、
(C)SiOyからなる層、
(B2)層(C)と層(A2)との間に配設された、金属、Si及びOからなる層、及び
(A2)金属、特にアルミニウムからなる層
を得ることができる。
(C1)SiOyからなる層、
(B)層(C1)と層(C2)との間に配設された、金属、Si及びOからなる層、及び
(C2)SiOyからなる層
を含む。
(C1)SiOzからなる層、
(B)層(C1)と層(C2)との間に配設された、金属、Si及びOからなる層、及び
(C2)SiOzからなる層
を含む顔料を得ることもできる。
(C1)SiOzからなる層、
(B1)層(C1)と層(A)との間に配設された、金属、Si及びOからなる層、
(A)金属、特にアルミニウムからなる層、
(B2)層(A)と層(C2)との間に配設された、金属、Si及びOからなる層、
及び
(C2)SiOzからなる層
を含む。
(D1)高い屈折率の材料、特にTiO2の層、
(C1)SiOzからなる層、
(B)層(C1)と層(C2)との間に配設された、金属、Si及びOからなる層、
(C2)SiOzからなる層、及び
(D2)高い屈折率の材料、特にTiO2の層
(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を含む有色(干渉)顔料に関する。
a)(可動)支持体に分離剤を蒸着させて分離剤層を製造する工程、
b)分離剤層にSiOy(0.70≦y≦1.80)層を蒸着させる工程、
c)SiOy層にAl層を蒸着させる工程、
d)Al層にSiOy層を蒸着させる工程、
e)分離剤層を溶媒に溶解させる工程、及び
f)溶媒からSiOyを分離する工程
を含む方法(EP−B−990715)によって調製される。
変形(1):非酸化性雰囲気中で焼成し(→層(B))、酸素の存在で焼成し(SiOz→SiO2)、場合によっては、得られた顔料をTiO2でコーティングする(TiO2/SiOz/コア/SiOz/TiO2)。この場合、コアは、層(B)又は層(B)/層(A)/層(B)である。
TiO2コーティングされた金属小板を、非酸化性ガス雰囲気中600℃を超える、好ましくは700〜1100℃の範囲の温度で10分を超える時間、好ましくは数時間焼成する。焼成は、非酸化性ガス雰囲気、たとえばAr及び/又はHe、好ましくはAr中、場合によっては減圧、好ましくは700Torr(0.9333 105N/m2)未満の圧で実施する。
上記のように、SiOyコーティングされた金属小板をTiO2でコーティングしたのち、非酸化性雰囲気中で焼成する。このようにして、層(B)の他に、TiO2/SiOyの焼成によって形成されるさらなる層(E)が製造される。TiO2/SiOyを非酸化性雰囲気中で焼成することが、屈折率の変化を生じさせる中間層を製造すると推測される。しかし、中間層が連続層ではなく、むしろTiO2とSiOyとの界面の個々の領域だけが、屈折率の変化を生じさせる転換を受けるという可能性を排除することはできない。さらに、屈折率の変化はSiOyによるTiO2の還元のせいであると推測される。したがって、本発明の原理は、屈折率の変化を生じさせる中間層をSiOyによるTiO2の還元によって製造することに基づく。
TiO2+SiOy→SiOy+a+TiO2-a
実施例1
真空チャンバ中、約10-2Pa未満の圧力で、金属支持体に厚さ約50nmのNaCl層を蒸着させた。次いで、同じ圧力で、以下の層:SiO、Al及びSiOを順に付着させて、金属支持体上に以下の層構造:
SiO(270nm)/Al(40nm)/SiO(270nm)
を有するフィルムを形成した。
真空チャンバ中、約10-2Pa未満の圧力で、ガラス支持体に以下の層:TiO2(50nm)、SiO(270nm)、Al(50nm)、SiO(270nm)及びTiO2(50nm)を順に昇華させた。一方の試料を参考試料(RS)として使用し、他方の試料(S)をアルゴン雰囲気中700℃で0.5時間加熱した。
Claims (12)
- (A)場合によっては、金属からなる層、
(B)層(A)が存在する場合、層(A)と層(C)との間に位置する、金属、ケイ素(Si)及び酸素(O)からなる少なくとも一つの層、及び
(C)場合によっては、層(B)の上の、SiOzからなる層
(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を含む顔料。 - (B)金属、ケイ素(Si)及び酸素(O)からなる少なくとも一つの層、及び
(C)層(B)の上の、SiOzからなる少なくとも一つの層
(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を含む、請求項1記載の顔料。 - (C1)SiOzからなる層、
(B)層(C1)と層(C2)との間に位置する、金属、ケイ素(Si)及び酸素(O)からなる少なくとも一つの層、
(C2)層(B)の上の、SiOzからなる少なくとも一つの層
(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を含む、請求項1又は2記載の顔料。 - (D)高い屈折率を有する材料、特にTiO2、非晶質炭素、ダイヤモンド様炭素又は炭化ケイ素のさらなる層を含む、請求項3記載の顔料。
- (D1)高い屈折率を有する材料、特にTiO2の層、
(C1)SiOzからなる層、
(B)層(C1)と層(C2)との間に位置する、金属、ケイ素(Si)及び酸素(O)からなる少なくとも一つの層、
(C2)SiOzからなる層、及び
(D2)高い屈折率を有する材料、特にTiO2の層
(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を含む、請求項4記載の顔料。 - 金属が、Ag、Al、Cu、Cr、Mo、Ni、Ti又はそれらの合金から選択され、特にアルミニウムである、請求項1〜5のいずれか記載の顔料。
- 以下の層構造:TiO2/SiOz/コア/SiOz/TiO2、SiC/SiOz/コア/SiOz/SiC又はC/SiOz/コア/SiOz/C
(コアは、層(B)又は層(B)/層(A)/層(B)で形成され、層(B)は、面平行な面に存在し、層(A)の側面には存在せず、SiOz層は、面平行な面だけに存在し、側面には存在せず、TiO2層は全面に適用され、0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)
を有する、請求項3記載の顔料。 - (A)金属からなる少なくとも一つの層、及び(C)SiOz(0.70≦z≦2.0、特に1.1≦z≦2.0)からなる少なくとも一つの層を含む面平行な構造(フレーク)を非酸化性雰囲気中で焼成し、場合によっては、得られたフレークをさらなる層でコーティングすることによって得られる顔料。
- (A)金属、特にアルミニウムからなる層、及び(C)SiOz(0.70≦z≦2.0、特に1.10≦z≦2.0、とりわけ1.40≦z≦2.0)からなる少なくとも一つの層を含む面平行な構造。
- インクジェット印刷における、織物を染色するための、コーティング、塗料、印刷インク、プラスチック、化粧品、セラミックス及びガラス用のうわぐすりを着色するための、請求項1〜8のいずれか記載の顔料の使用。
- 請求項1〜8のいずれか記載の顔料を含む組成物。
- 請求項1〜8のいずれか記載の顔料を含む化粧品調製物、塗料、印刷インク又はコーティング。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02405978.4 | 2002-11-13 | ||
EP02405978 | 2002-11-13 | ||
EP03405026 | 2003-01-23 | ||
EP03405026.0 | 2003-01-23 | ||
PCT/EP2003/050777 WO2004044060A1 (en) | 2002-11-13 | 2003-11-03 | Novel interference pigments |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006506518A true JP2006506518A (ja) | 2006-02-23 |
JP2006506518A5 JP2006506518A5 (ja) | 2006-12-14 |
JP4777066B2 JP4777066B2 (ja) | 2011-09-21 |
Family
ID=32313855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005506658A Expired - Fee Related JP4777066B2 (ja) | 2002-11-13 | 2003-11-03 | 新規な干渉顔料 |
Country Status (9)
Country | Link |
---|---|
US (1) | US7452597B2 (ja) |
EP (1) | EP1570008A1 (ja) |
JP (1) | JP4777066B2 (ja) |
KR (1) | KR20050075396A (ja) |
AU (1) | AU2003301972A1 (ja) |
CA (1) | CA2495007A1 (ja) |
MX (1) | MXPA05002425A (ja) |
RU (1) | RU2005118747A (ja) |
WO (1) | WO2004044060A1 (ja) |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009042763A (ja) * | 2007-08-12 | 2009-02-26 | Toyota Motor Engineering & Manufacturing North America Inc | 狭い帯域の全方向性反射体および構造色としてのそれらの使用 |
US9063291B2 (en) | 2007-08-12 | 2015-06-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional reflector |
US9229140B2 (en) | 2007-08-12 | 2016-01-05 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional UV-IR reflector |
JP2016536406A (ja) * | 2013-08-02 | 2016-11-24 | シュレンク メタリック ピグメンツ ゲーエムベーハー | 厚さ1nm〜50nmの基板薄片をベースとする金属光沢顔料 |
US9612369B2 (en) | 2007-08-12 | 2017-04-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Red omnidirectional structural color made from metal and dielectric layers |
JPWO2016006664A1 (ja) * | 2014-07-10 | 2017-04-27 | 日本ペイントホールディングス株式会社 | 赤外反射性顔料及び赤外反射性塗料組成物 |
US9658375B2 (en) | 2012-08-10 | 2017-05-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with combination metal absorber and dielectric absorber layers |
US9664832B2 (en) | 2012-08-10 | 2017-05-30 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with combination semiconductor absorber and dielectric absorber layers |
US9678260B2 (en) | 2012-08-10 | 2017-06-13 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with semiconductor absorber layer |
US9739917B2 (en) | 2007-08-12 | 2017-08-22 | Toyota Motor Engineering & Manufacturing North America, Inc. | Red omnidirectional structural color made from metal and dielectric layers |
US9810824B2 (en) | 2015-01-28 | 2017-11-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural colors |
JP2018514611A (ja) * | 2015-04-15 | 2018-06-07 | シュレンク メタリック ピグメンツ ゲーエムベーハー | 一体式構造の基材を基礎とするパール光輝顔料、該パール光輝顔料の製造方法、及びそのようなパール光輝顔料の使用 |
US10048415B2 (en) | 2007-08-12 | 2018-08-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-dichroic omnidirectional structural color |
US10563065B2 (en) | 2017-01-10 | 2020-02-18 | Schlenk Metallic Pigments Gmbh | Pearlescent pigments obtained by wet oxidation |
JP2020079368A (ja) * | 2018-11-14 | 2020-05-28 | トヨタ自動車株式会社 | 光輝性顔料およびその製造方法 |
US10690823B2 (en) | 2007-08-12 | 2020-06-23 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
US10788608B2 (en) | 2007-08-12 | 2020-09-29 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures |
US10870740B2 (en) | 2007-08-12 | 2020-12-22 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures and protective coatings thereon |
US11726239B2 (en) | 2014-04-01 | 2023-08-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-color shifting multilayer structures |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7517404B2 (en) * | 2002-10-16 | 2009-04-14 | Ciba Specialty Chemicals Corporation | Interference pigments on the basis of silicon oxides |
JP2005287377A (ja) * | 2004-03-31 | 2005-10-20 | Cbc Kk | 鳥獣類忌避器具及び方法 |
WO2005107456A2 (en) * | 2004-05-12 | 2005-11-17 | Ciba Specialty Chemicals Holding Inc. | Antimicrobial silicon oxide flakes |
EP1784355A2 (en) * | 2004-07-26 | 2007-05-16 | CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement | Reactive silicon suboxide flakes |
DE602005026820D1 (de) | 2004-08-23 | 2011-04-21 | Basf Se | Verfahren zur herstellung von blättchenförmigen pi0) |
JP4686538B2 (ja) * | 2005-02-23 | 2011-05-25 | 株式会社東芝 | 放射線遮蔽シート |
JP5234960B2 (ja) * | 2005-06-22 | 2013-07-10 | チバ ホールディング インコーポレーテッド | ガラスフレークに基づく干渉顔料 |
US7559985B2 (en) * | 2005-12-15 | 2009-07-14 | Axalto Sa | Ink suitable for printing smart card and process for producing a printed smart card with such an ink |
JP2011506700A (ja) * | 2007-12-19 | 2011-03-03 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 導電性コアを有する濃色および/または光学可変性の顔料 |
US8454861B2 (en) * | 2007-12-19 | 2013-06-04 | Merck Patent Gmbh | Optically variable pigments of high electrical conductivity |
US20120028865A1 (en) | 2010-07-28 | 2012-02-02 | Sudhin Datta | Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers |
KR101821431B1 (ko) * | 2010-02-04 | 2018-01-23 | 바스프 에스이 | 개선된 스파클링 효과를 갖는 안료 조성물 |
EP2354189A1 (en) * | 2010-02-09 | 2011-08-10 | Silberline Manufacturing Co., Inc. | Black metallic effect pigments |
US20110192320A1 (en) * | 2010-02-09 | 2011-08-11 | Silberline Manufacturing Company, Inc. | Black metallic effect pigments |
US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
EP3058021B1 (de) * | 2013-10-14 | 2019-09-04 | Eckart GmbH | Kunststoffzusammensetzung umfassend wenigstens ein metallpigment, verfahren zur herstellung und verwendung |
JP2016020968A (ja) * | 2014-07-14 | 2016-02-04 | 富士ゼロックス株式会社 | 静電荷像現像用トナー及びその製造方法、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置並びに画像形成方法 |
US11493672B2 (en) * | 2017-03-01 | 2022-11-08 | Viavi Solutions Inc. | Lamellar particles with functional coating |
EP3617277B1 (en) * | 2017-04-27 | 2021-03-24 | Nippon Sheet Glass Company, Limited | Lustrous pigment having electromagnetic wave-transmitting characteristics, composition containing this pigment, and coated body |
US10998638B2 (en) * | 2019-01-31 | 2021-05-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Nickel-chromium particles and multilayer structures comprising nickel chromium core layers |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000517374A (ja) * | 1996-05-09 | 2000-12-26 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉性顔料 |
WO2001029137A1 (en) * | 1999-10-20 | 2001-04-26 | Flex Products, Inc. | Color shifting carbon-containing interference pigments |
JP2002179947A (ja) * | 2000-12-11 | 2002-06-26 | Nittetsu Mining Co Ltd | 粉体、その製造方法および色材組成物 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL135722C (ja) | 1961-06-28 | |||
US3438796A (en) * | 1967-02-02 | 1969-04-15 | Du Pont | Aluminum-silica-aluminum flake pigments |
DE2009566C2 (de) | 1970-02-28 | 1972-06-15 | Merck Patent Gmbh | Verfahren zur Herstellung von Titandioxid- bzw. Titandioxidaquatüberzügen |
CA964403A (en) | 1971-03-26 | 1975-03-18 | Howard R. Linton | Nacreous pigments of improved luster and process for their manufacture |
CA957108A (en) | 1971-03-30 | 1974-11-05 | E. I. Du Pont De Nemours And Company | Pigments treated with methacrylatochromic chloride for improved humidity resistance |
DE2244298C3 (de) | 1972-09-09 | 1975-06-19 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente und Verfahren zu ihrer Herstellung |
DE2313331C2 (de) | 1973-03-17 | 1986-11-13 | Merck Patent Gmbh, 6100 Darmstadt | Eisenoxidhaltige Glimmerschuppenpigmente |
DE2746174C3 (de) | 1977-10-14 | 1980-11-06 | Lindauer Dornier Gesellschaft Mbh, 8990 Lindau | Vorrichtung zum Überführen einer nicht eigensteifen, instabilen Warenbahn (z.B. Papier, Textilien, Fließstoffe u.a.) von einer Behandlungsmaschine zu einem vor einer Spannrahmenkette eines Breitspannrahmens angeordneten Zwischenförderer |
FR2405888A2 (fr) | 1977-10-14 | 1979-05-11 | Egretier Et Co Sa | Dispositif de cuve tournante a auto-vidange |
DE3030056A1 (de) | 1980-08-08 | 1982-03-25 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mit metalloxiden beschichteten schuppenfoermigen glimmerpigmenten |
DE3237264A1 (de) | 1982-10-08 | 1984-04-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mit metalloxid beschichteten effektpigmenten |
DE3813335A1 (de) | 1988-04-21 | 1989-11-02 | Basf Ag | Metalloxidbeschichtete aluminiumpigmente |
DE4140900A1 (de) | 1991-12-12 | 1993-06-17 | Basf Ag | Als carrier fuer die elektrophotographie geeignete teilchen |
US5540769A (en) * | 1992-03-26 | 1996-07-30 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Platelet-like colored pigments and process for producing the same |
DE4236332A1 (de) | 1992-10-28 | 1994-05-05 | Basf Ag | Wasserbeständige Metallpigmente durch Gasphasenpassivierung |
DE4403678A1 (de) | 1994-02-07 | 1995-08-10 | Basf Ag | Metalloxid- und metallbeschichtete Carrier für die Elektrophotographie |
ATE168713T1 (de) | 1994-02-21 | 1998-08-15 | Basf Ag | Mehrfach beschichtete metallische glanzpigmente |
DE4414079A1 (de) | 1994-04-22 | 1995-10-26 | Basf Ag | Zweifach gasphasenpassivierte Metallpigmente |
US5877895A (en) | 1995-03-20 | 1999-03-02 | Catalina Coatings, Inc. | Multicolor interference coating |
DE19516181A1 (de) | 1995-05-03 | 1996-11-07 | Basf Ag | Goniochromatische Glanzpigmente mit Aluminiumbeschichtung |
DE59704636D1 (de) * | 1996-04-25 | 2001-10-25 | Ciba Sc Holding Ag | Farbige Glanzpigmente |
EP0984043A1 (en) | 1998-08-31 | 2000-03-08 | Sicpa Holding S.A. | Optically variable pigments providing a colour shift between two distinct colours, coating composition comprising the same, method for producing the same and substrate coated with the coating composition |
US6150022A (en) * | 1998-12-07 | 2000-11-21 | Flex Products, Inc. | Bright metal flake based pigments |
WO2000069975A1 (en) | 1999-05-14 | 2000-11-23 | Flex Products, Inc. | Bright aluminum pigment |
US6586098B1 (en) * | 2000-07-27 | 2003-07-01 | Flex Products, Inc. | Composite reflective flake based pigments comprising reflector layers on bothside of a support layer |
US6569529B1 (en) | 2000-10-10 | 2003-05-27 | Flex Product, Inc. | Titanium-containing interference pigments and foils with color shifting properties |
US7157116B2 (en) * | 2001-05-21 | 2007-01-02 | Ciba Specialty Chemicals Corporation | Method for the production of plane-parallel platelets by using organic separating agents |
DE10128489A1 (de) * | 2001-06-12 | 2002-12-19 | Merck Patent Gmbh | Mehrschichtige Glanzpigmente |
KR100948245B1 (ko) | 2002-02-18 | 2010-03-19 | 시바 홀딩 인크 | 아산화규소, 이산화규소 및/또는 탄화규소의 평면 평행구조물의 제조방법, 이러한 방법으로 수득 가능한 평면평행 구조물 및 이의 용도 |
EP1517964A1 (en) * | 2002-06-18 | 2005-03-30 | Ciba SC Holding AG | Plane-parallel structures of silicon/silicon oxide |
US7517404B2 (en) * | 2002-10-16 | 2009-04-14 | Ciba Specialty Chemicals Corporation | Interference pigments on the basis of silicon oxides |
MXPA05007871A (es) * | 2003-01-23 | 2005-09-21 | Ciba Sc Holding Ag | Pigmentos en forma de plaquetas. |
-
2003
- 2003-11-03 US US10/531,483 patent/US7452597B2/en not_active Expired - Fee Related
- 2003-11-03 RU RU2005118747/15A patent/RU2005118747A/ru not_active Application Discontinuation
- 2003-11-03 MX MXPA05002425A patent/MXPA05002425A/es unknown
- 2003-11-03 AU AU2003301972A patent/AU2003301972A1/en not_active Abandoned
- 2003-11-03 KR KR1020057008514A patent/KR20050075396A/ko not_active Application Discontinuation
- 2003-11-03 EP EP03810993A patent/EP1570008A1/en not_active Withdrawn
- 2003-11-03 CA CA002495007A patent/CA2495007A1/en not_active Abandoned
- 2003-11-03 JP JP2005506658A patent/JP4777066B2/ja not_active Expired - Fee Related
- 2003-11-03 WO PCT/EP2003/050777 patent/WO2004044060A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000517374A (ja) * | 1996-05-09 | 2000-12-26 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉性顔料 |
WO2001029137A1 (en) * | 1999-10-20 | 2001-04-26 | Flex Products, Inc. | Color shifting carbon-containing interference pigments |
JP2002179947A (ja) * | 2000-12-11 | 2002-06-26 | Nittetsu Mining Co Ltd | 粉体、その製造方法および色材組成物 |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10690823B2 (en) | 2007-08-12 | 2020-06-23 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
US10788608B2 (en) | 2007-08-12 | 2020-09-29 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures |
US10048415B2 (en) | 2007-08-12 | 2018-08-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-dichroic omnidirectional structural color |
US11796724B2 (en) | 2007-08-12 | 2023-10-24 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
US10870740B2 (en) | 2007-08-12 | 2020-12-22 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures and protective coatings thereon |
US9063291B2 (en) | 2007-08-12 | 2015-06-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional reflector |
JP2009042763A (ja) * | 2007-08-12 | 2009-02-26 | Toyota Motor Engineering & Manufacturing North America Inc | 狭い帯域の全方向性反射体および構造色としてのそれらの使用 |
US9612369B2 (en) | 2007-08-12 | 2017-04-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Red omnidirectional structural color made from metal and dielectric layers |
US9229140B2 (en) | 2007-08-12 | 2016-01-05 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional UV-IR reflector |
US9739917B2 (en) | 2007-08-12 | 2017-08-22 | Toyota Motor Engineering & Manufacturing North America, Inc. | Red omnidirectional structural color made from metal and dielectric layers |
US9658375B2 (en) | 2012-08-10 | 2017-05-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with combination metal absorber and dielectric absorber layers |
US9678260B2 (en) | 2012-08-10 | 2017-06-13 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with semiconductor absorber layer |
US9664832B2 (en) | 2012-08-10 | 2017-05-30 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural color with combination semiconductor absorber and dielectric absorber layers |
JP2016536406A (ja) * | 2013-08-02 | 2016-11-24 | シュレンク メタリック ピグメンツ ゲーエムベーハー | 厚さ1nm〜50nmの基板薄片をベースとする金属光沢顔料 |
US11236240B2 (en) | 2013-08-02 | 2022-02-01 | Schlenk Metallic Pigments Gmbh | Metallic luster pigments |
US10227494B2 (en) | 2013-08-02 | 2019-03-12 | Schlenk Metallic Pigments Gmbh | Metallic luster pigments |
JP2018188665A (ja) * | 2013-08-02 | 2018-11-29 | シュレンク メタリック ピグメンツ ゲーエムベーハー | 厚さ1nm〜50nmの基板薄片をベースとする金属光沢顔料 |
US11726239B2 (en) | 2014-04-01 | 2023-08-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-color shifting multilayer structures |
JPWO2016006664A1 (ja) * | 2014-07-10 | 2017-04-27 | 日本ペイントホールディングス株式会社 | 赤外反射性顔料及び赤外反射性塗料組成物 |
US10131790B2 (en) | 2014-07-10 | 2018-11-20 | Nippon Paint Holdings Co., Ltd. | Infrared-reflective pigment and infrared-reflective coating composition |
US9810824B2 (en) | 2015-01-28 | 2017-11-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Omnidirectional high chroma red structural colors |
US11214690B2 (en) | 2015-04-15 | 2022-01-04 | Schlenk Metallic Pigments Gmbh | Pearlescent pigments, process for producing them, and use of such pigments |
JP2018514611A (ja) * | 2015-04-15 | 2018-06-07 | シュレンク メタリック ピグメンツ ゲーエムベーハー | 一体式構造の基材を基礎とするパール光輝顔料、該パール光輝顔料の製造方法、及びそのようなパール光輝顔料の使用 |
US10563065B2 (en) | 2017-01-10 | 2020-02-18 | Schlenk Metallic Pigments Gmbh | Pearlescent pigments obtained by wet oxidation |
JP2020079368A (ja) * | 2018-11-14 | 2020-05-28 | トヨタ自動車株式会社 | 光輝性顔料およびその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
MXPA05002425A (es) | 2005-05-27 |
JP4777066B2 (ja) | 2011-09-21 |
EP1570008A1 (en) | 2005-09-07 |
KR20050075396A (ko) | 2005-07-20 |
RU2005118747A (ru) | 2006-01-27 |
CA2495007A1 (en) | 2004-05-27 |
AU2003301972A1 (en) | 2004-06-03 |
US20060099420A1 (en) | 2006-05-11 |
WO2004044060A1 (en) | 2004-05-27 |
US7452597B2 (en) | 2008-11-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4777066B2 (ja) | 新規な干渉顔料 | |
JP4511926B2 (ja) | ケイ素/酸化ケイ素の面平行な構造 | |
JP4476629B2 (ja) | 亜酸化ケイ素、二酸化ケイ素及び/又は炭化ケイ素の面平行な構造を製造する方法、当該方法によって得られる面平行な構造ならびにその使用 | |
JP4820549B2 (ja) | 還元顔料 | |
JP5234960B2 (ja) | ガラスフレークに基づく干渉顔料 | |
KR101015031B1 (ko) | 규소 산화물을 기본으로 하는 간섭 안료 | |
KR101057964B1 (ko) | 작은판 형상의 안료 | |
JP2006509088A (ja) | アルミニウムをベースとするフレーク状顔料 | |
JP2015052117A (ja) | パーライトフレークを基礎とする干渉顔料 | |
JP2010532808A5 (ja) | ||
JP2008511704A (ja) | アルミニウムおよびSiOz(z=0.7〜2.0)をベースとするフレーク状顔料を製造する方法 | |
JP2010525125A (ja) | 効果顔料のための強化金属酸化物フレーク | |
JP4620469B2 (ja) | 非対称層構造を有する光学的に可変性の顔料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061023 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20061023 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100824 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101102 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110628 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110629 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140708 Year of fee payment: 3 |
|
LAPS | Cancellation because of no payment of annual fees |