JP2006150185A - 水素化分解触媒組成物 - Google Patents
水素化分解触媒組成物 Download PDFInfo
- Publication number
- JP2006150185A JP2006150185A JP2004341939A JP2004341939A JP2006150185A JP 2006150185 A JP2006150185 A JP 2006150185A JP 2004341939 A JP2004341939 A JP 2004341939A JP 2004341939 A JP2004341939 A JP 2004341939A JP 2006150185 A JP2006150185 A JP 2006150185A
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- JP
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- Prior art keywords
- pore
- aluminum
- pores
- zeolite
- type zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003054 catalyst Substances 0.000 title claims abstract description 59
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 239000011148 porous material Substances 0.000 claims abstract description 153
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 125
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 122
- 239000010457 zeolite Substances 0.000 claims abstract description 122
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 57
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 56
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 abstract description 36
- 230000000694 effects Effects 0.000 abstract description 26
- 229930195733 hydrocarbon Natural products 0.000 abstract description 26
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 26
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 25
- 238000005336 cracking Methods 0.000 abstract description 9
- 229910052987 metal hydride Inorganic materials 0.000 abstract description 6
- 150000004681 metal hydrides Chemical class 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000011973 solid acid Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 9
- 239000000725 suspension Substances 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 7
- 238000001116 aluminium-27 magic angle spinning nuclear magnetic resonance spectrum Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 5
- 235000011130 ammonium sulphate Nutrition 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910001361 White metal Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000012013 faujasite Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000010969 white metal Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
Images
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- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004341939A JP2006150185A (ja) | 2004-11-26 | 2004-11-26 | 水素化分解触媒組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004341939A JP2006150185A (ja) | 2004-11-26 | 2004-11-26 | 水素化分解触媒組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006150185A true JP2006150185A (ja) | 2006-06-15 |
| JP2006150185A5 JP2006150185A5 (https=) | 2007-11-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004341939A Pending JP2006150185A (ja) | 2004-11-26 | 2004-11-26 | 水素化分解触媒組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2006150185A (https=) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032232A1 (ja) * | 2005-09-12 | 2007-03-22 | Petroleum Energy Center | 炭化水素の水素化処理用触媒組成物および水素化処理方法 |
| JP2007313409A (ja) * | 2006-05-24 | 2007-12-06 | Petroleum Energy Center | 水素化分解触媒組成物およびその製造方法 |
| JP2011102390A (ja) * | 2009-11-10 | 2011-05-26 | IFP Energies Nouvelles | 塩基処理により改変されたゼオライトを用いる水素化分解方法 |
| JP2012140287A (ja) * | 2010-12-28 | 2012-07-26 | Jgc Catalysts & Chemicals Ltd | 新規なフォージャサイト型ゼオライトおよびその製造方法、ならびに該フォージャサイト型ゼオライトを含む炭化水素接触分解用触媒 |
| TWI478872B (zh) * | 2008-09-18 | 2015-04-01 | Exxonmobil Res & Eng Co | 超介孔性ｙ沸石 |
| CN115916403A (zh) * | 2020-06-30 | 2023-04-04 | 株式会社科特拉 | 排气净化用催化剂 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01258743A (ja) * | 1987-06-11 | 1989-10-16 | Mobil Oil Corp | ゼオライトの活性化法 |
| JPH05329375A (ja) * | 1990-06-04 | 1993-12-14 | Texaco Dev Corp | 新規なゼオライト及びその製造方法 |
| JP2001170489A (ja) * | 1999-12-16 | 2001-06-26 | Natl Inst Of Advanced Industrial Science & Technology Meti | 芳香族炭化水素の水素化触媒組成物 |
| JP2002255537A (ja) * | 2001-02-22 | 2002-09-11 | National Institute Of Advanced Industrial & Technology | 固体酸触媒 |
| JP2003093883A (ja) * | 2001-09-26 | 2003-04-02 | Nippon Oil Corp | 水素化処理触媒 |
| JP2003095643A (ja) * | 2001-09-26 | 2003-04-03 | Nippon Oil Corp | 超安定ｙ型ゼオライト |
-
2004
- 2004-11-26 JP JP2004341939A patent/JP2006150185A/ja active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01258743A (ja) * | 1987-06-11 | 1989-10-16 | Mobil Oil Corp | ゼオライトの活性化法 |
| JPH05329375A (ja) * | 1990-06-04 | 1993-12-14 | Texaco Dev Corp | 新規なゼオライト及びその製造方法 |
| JP2001170489A (ja) * | 1999-12-16 | 2001-06-26 | Natl Inst Of Advanced Industrial Science & Technology Meti | 芳香族炭化水素の水素化触媒組成物 |
| JP2002255537A (ja) * | 2001-02-22 | 2002-09-11 | National Institute Of Advanced Industrial & Technology | 固体酸触媒 |
| JP2003093883A (ja) * | 2001-09-26 | 2003-04-02 | Nippon Oil Corp | 水素化処理触媒 |
| JP2003095643A (ja) * | 2001-09-26 | 2003-04-03 | Nippon Oil Corp | 超安定ｙ型ゼオライト |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032232A1 (ja) * | 2005-09-12 | 2007-03-22 | Petroleum Energy Center | 炭化水素の水素化処理用触媒組成物および水素化処理方法 |
| JP5100388B2 (ja) * | 2005-09-12 | 2012-12-19 | 一般財団法人石油エネルギー技術センター | 炭化水素の水素化処理用触媒組成物および水素化処理方法 |
| JP2007313409A (ja) * | 2006-05-24 | 2007-12-06 | Petroleum Energy Center | 水素化分解触媒組成物およびその製造方法 |
| TWI478872B (zh) * | 2008-09-18 | 2015-04-01 | Exxonmobil Res & Eng Co | 超介孔性ｙ沸石 |
| JP2011102390A (ja) * | 2009-11-10 | 2011-05-26 | IFP Energies Nouvelles | 塩基処理により改変されたゼオライトを用いる水素化分解方法 |
| JP2012140287A (ja) * | 2010-12-28 | 2012-07-26 | Jgc Catalysts & Chemicals Ltd | 新規なフォージャサイト型ゼオライトおよびその製造方法、ならびに該フォージャサイト型ゼオライトを含む炭化水素接触分解用触媒 |
| CN115916403A (zh) * | 2020-06-30 | 2023-04-04 | 株式会社科特拉 | 排气净化用催化剂 |
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