JP2006045489A5 - - Google Patents
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- JP2006045489A5 JP2006045489A5 JP2005004044A JP2005004044A JP2006045489A5 JP 2006045489 A5 JP2006045489 A5 JP 2006045489A5 JP 2005004044 A JP2005004044 A JP 2005004044A JP 2005004044 A JP2005004044 A JP 2005004044A JP 2006045489 A5 JP2006045489 A5 JP 2006045489A5
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- JP
- Japan
- Prior art keywords
- group
- acid
- weight
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- polyoxymethylene
- Prior art date
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- -1 polyoxymethylene Polymers 0.000 claims description 130
- 229920002866 paraformaldehyde Polymers 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 36
- 239000011342 resin composition Substances 0.000 claims description 30
- 229920000642 polymer Polymers 0.000 claims description 29
- 239000011780 sodium chloride Substances 0.000 claims description 27
- WTEOIRVLGSZEPR-UHFFFAOYSA-N Boron trifluoride Chemical group FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 20
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 150000004665 fatty acids Chemical class 0.000 claims description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims description 14
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 14
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 239000006096 absorbing agent Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 9
- 125000003277 amino group Chemical group 0.000 claims description 9
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 9
- KQBSGRWMSNFIPG-UHFFFAOYSA-N trioxane Chemical compound C1COOOC1 KQBSGRWMSNFIPG-UHFFFAOYSA-N 0.000 claims description 9
- UTTHLMXOSUFZCQ-UHFFFAOYSA-N benzene-1,3-dicarbohydrazide Chemical compound NNC(=O)C1=CC=CC(C(=O)NN)=C1 UTTHLMXOSUFZCQ-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 claims description 8
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 125000004185 ester group Chemical group 0.000 claims description 6
- 125000005704 oxymethylene group Chemical group [H]C([H])([*:2])O[*:1] 0.000 claims description 6
- 239000002685 polymerization catalyst Substances 0.000 claims description 6
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 5
- IBVAQQYNSHJXBV-UHFFFAOYSA-N Adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 150000004292 cyclic ethers Chemical class 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 4
- 125000004430 oxygen atoms Chemical group O* 0.000 claims description 4
- 125000004434 sulfur atoms Chemical group 0.000 claims description 4
- XEVRDFDBXJMZFG-UHFFFAOYSA-N Carbohydrazide Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000003078 antioxidant Effects 0.000 claims description 3
- GRGBENNNGZARRZ-UHFFFAOYSA-N dodecanedihydrazide Chemical compound NNC(=O)CCCCCCCCCCC(=O)NN GRGBENNNGZARRZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- MVJKXJPDBTXECY-UHFFFAOYSA-N trifluoroborane;hydrate Chemical compound O.FB(F)F MVJKXJPDBTXECY-UHFFFAOYSA-N 0.000 claims description 3
- 230000000379 polymerizing Effects 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 62
- 239000002253 acid Substances 0.000 description 30
- 238000000465 moulding Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 14
- 238000001746 injection moulding Methods 0.000 description 13
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 12
- 229920000877 Melamine resin Polymers 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 229940005581 Sodium Lactate Drugs 0.000 description 7
- NGSFWBMYFKHRBD-UHFFFAOYSA-M Sodium lactate Chemical compound [Na+].CC(O)C([O-])=O NGSFWBMYFKHRBD-UHFFFAOYSA-M 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000001540 sodium lactate Substances 0.000 description 7
- 235000011088 sodium lactate Nutrition 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000920 calcium hydroxide Substances 0.000 description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 5
- 239000008116 calcium stearate Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 description 4
- 150000004692 metal hydroxides Chemical class 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 3
- QRXWMOHMRWLFEY-UHFFFAOYSA-N Isoniazid Chemical class NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 3
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N N-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
- 239000002530 phenolic antioxidant Substances 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- 229940116351 sebacate Drugs 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- UCMIRNVEIXFBKS-UHFFFAOYSA-N β-Alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 3
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 2
- AOZXEVSFVUNQFZ-UHFFFAOYSA-N 2-N,4-N-dibutyl-6-chloro-2-N,4-N-bis(1,2,2,6,6-pentamethylpiperidin-4-yl)-1,3,5-triazine-2,4-diamine Chemical compound N=1C(Cl)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 AOZXEVSFVUNQFZ-UHFFFAOYSA-N 0.000 description 2
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 2
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 2
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 2
- DBXBTMSZEOQQDU-UHFFFAOYSA-N 3-Hydroxyisobutyric acid Chemical compound OCC(C)C(O)=O DBXBTMSZEOQQDU-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N Benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- MCXJNPSSNVLIFK-UHFFFAOYSA-N C=C.CCCCCCCCCCCCCCCCCC[N-]CCCCCCCCCCCCCCCCCC Chemical compound C=C.CCCCCCCCCCCCCCCCCC[N-]CCCCCCCCCCCCCCCCCC MCXJNPSSNVLIFK-UHFFFAOYSA-N 0.000 description 2
- 229960005069 Calcium Drugs 0.000 description 2
- NKDDWNXOKDWJAK-UHFFFAOYSA-N Dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 2
- 229920002456 HOTAIR Polymers 0.000 description 2
- ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N Malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 2
- 150000001339 alkali metal compounds Chemical class 0.000 description 2
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229960004106 citric acid Drugs 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 229940099690 malic acid Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 229960001367 tartaric acid Drugs 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- LVRFTAZAXQPQHI-RXMQYKEDSA-N (R)-2-hydroxy-4-methylpentanoic acid Chemical compound CC(C)C[C@@H](O)C(O)=O LVRFTAZAXQPQHI-RXMQYKEDSA-N 0.000 description 1
- BZCOSCNPHJNQBP-UPHRSURJSA-N (Z)-2,3-dihydroxybut-2-enedioic acid Chemical compound OC(=O)C(\O)=C(\O)C(O)=O BZCOSCNPHJNQBP-UPHRSURJSA-N 0.000 description 1
- PJFQKDBQOXFCAI-UHFFFAOYSA-N 1,2-dihydroxyethane-1,1,2-tricarboxylic acid Chemical compound OC(=O)C(O)C(O)(C(O)=O)C(O)=O PJFQKDBQOXFCAI-UHFFFAOYSA-N 0.000 description 1
- STEYNUVPFMIUOY-UHFFFAOYSA-N 1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 1
- QLAFGHVZDNLIDW-UHFFFAOYSA-N 1-[3-(benzotriazol-2-yl)-5-(3-methylbutyl)phenyl]-3-methylbutan-2-ol Chemical compound CC(C)CCC1=CC(CC(O)C(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1 QLAFGHVZDNLIDW-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- VGVLFMIJNWWPBR-UHFFFAOYSA-N 2,2,3-trihydroxypentanedioic acid Chemical compound OC(=O)CC(O)C(O)(O)C(O)=O VGVLFMIJNWWPBR-UHFFFAOYSA-N 0.000 description 1
- LGRBMDDGJHFADD-UHFFFAOYSA-N 2,2,6,6-tetramethyl-4$l^{6},8,9-trithiabicyclo[5.2.0]non-1(7)-ene 4,4-dioxide Chemical compound CC1(C)CS(=O)(=O)CC(C)(C)C2=C1SS2 LGRBMDDGJHFADD-UHFFFAOYSA-N 0.000 description 1
- HVDFUVLFCQSGAK-UHFFFAOYSA-N 2,2-dihydroxy-3-oxobutanoic acid Chemical compound CC(=O)C(O)(O)C(O)=O HVDFUVLFCQSGAK-UHFFFAOYSA-N 0.000 description 1
- HOULBXUZSSMBID-UHFFFAOYSA-N 2,3,3-trihydroxy-2-methylpropanoic acid Chemical compound OC(O)C(O)(C)C(O)=O HOULBXUZSSMBID-UHFFFAOYSA-N 0.000 description 1
- CPLWWXZZFYHPJY-UHFFFAOYSA-N 2,3-dihydroxy-2,3-dimethylbutanedioic acid Chemical compound OC(=O)C(O)(C)C(C)(O)C(O)=O CPLWWXZZFYHPJY-UHFFFAOYSA-N 0.000 description 1
- SUDDXMSROFLAQH-UHFFFAOYSA-N 2,3-dihydroxy-2-methylbutanedioic acid Chemical compound OC(=O)C(O)(C)C(O)C(O)=O SUDDXMSROFLAQH-UHFFFAOYSA-N 0.000 description 1
- DGADNPLBVRLJGD-UHFFFAOYSA-N 2,3-dihydroxy-2-methylpropanoic acid Chemical compound OCC(O)(C)C(O)=O DGADNPLBVRLJGD-UHFFFAOYSA-N 0.000 description 1
- LOUGYXZSURQALL-UHFFFAOYSA-N 2,3-dihydroxybutanoic acid Chemical compound CC(O)C(O)C(O)=O LOUGYXZSURQALL-UHFFFAOYSA-N 0.000 description 1
- BGCSUUSPRCDKBQ-UHFFFAOYSA-N 2,4,8,10-tetraoxaspiro[5.5]undecane Chemical compound C1OCOCC21COCOC2 BGCSUUSPRCDKBQ-UHFFFAOYSA-N 0.000 description 1
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 description 1
- GWNIBSQWAZQIEJ-UHFFFAOYSA-N 2-(1-hydroxypropyl)propanedioic acid Chemical compound CCC(O)C(C(O)=O)C(O)=O GWNIBSQWAZQIEJ-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-methylphenol Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 1
- PPVBGPLECSKJDX-UHFFFAOYSA-N 2-(hydroxymethyl)propanedioic acid Chemical compound OCC(C(O)=O)C(O)=O PPVBGPLECSKJDX-UHFFFAOYSA-N 0.000 description 1
- LXVSANCQXSSLPA-UHFFFAOYSA-N 2-Ethyl-2-Hydroxybutyric acid Chemical compound CCC(O)(CC)C(O)=O LXVSANCQXSSLPA-UHFFFAOYSA-N 0.000 description 1
- AFENDNXGAFYKQO-UHFFFAOYSA-N 2-Hydroxybutyric acid Chemical compound CCC(O)C(O)=O AFENDNXGAFYKQO-UHFFFAOYSA-N 0.000 description 1
- JZUMVFMLJGSMRF-UHFFFAOYSA-N 2-Methyladipic acid Chemical compound OC(=O)C(C)CCCC(O)=O JZUMVFMLJGSMRF-UHFFFAOYSA-N 0.000 description 1
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical compound OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 1
- YDGNKNPOBSPHSQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propanedioic acid Chemical compound CCC(CO)(C(O)=O)C(O)=O YDGNKNPOBSPHSQ-UHFFFAOYSA-N 0.000 description 1
- WNVYLFYOHRMKGV-UHFFFAOYSA-N 2-ethyl-2-hydroxypropanedioic acid Chemical compound CCC(O)(C(O)=O)C(O)=O WNVYLFYOHRMKGV-UHFFFAOYSA-N 0.000 description 1
- QKBMDPMOFLQDLM-UHFFFAOYSA-N 2-hydroxy-2,3,3-trimethylbutanedioic acid Chemical compound OC(=O)C(C)(C)C(C)(O)C(O)=O QKBMDPMOFLQDLM-UHFFFAOYSA-N 0.000 description 1
- CWMPKCMFWTVVMX-UHFFFAOYSA-N 2-hydroxy-2,4-dimethylpentanoic acid Chemical compound CC(C)CC(C)(O)C(O)=O CWMPKCMFWTVVMX-UHFFFAOYSA-N 0.000 description 1
- KXEISHUBUXWXGY-UHFFFAOYSA-N 2-hydroxy-2-(1-hydroxyethyl)-3-methylbutanoic acid Chemical compound CC(C)C(O)(C(C)O)C(O)=O KXEISHUBUXWXGY-UHFFFAOYSA-N 0.000 description 1
- MBIQENSCDNJOIY-UHFFFAOYSA-N 2-hydroxy-2-methylbutyric acid Chemical compound CCC(C)(O)C(O)=O MBIQENSCDNJOIY-UHFFFAOYSA-N 0.000 description 1
- HNQAXDPWMQIKEE-UHFFFAOYSA-N 2-hydroxy-2-methylhexanoic acid Chemical compound CCCCC(C)(O)C(O)=O HNQAXDPWMQIKEE-UHFFFAOYSA-N 0.000 description 1
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| CN100365061C (zh) * | 2006-05-24 | 2008-01-30 | 云南云天化股份有限公司 | 聚甲醛胺处理热稳定化的方法 |
| JP5085061B2 (ja) * | 2006-06-30 | 2012-11-28 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| EP2267075B1 (de) | 2008-10-28 | 2014-01-22 | Asahi Kasei Chemicals Corporation | Polyacetalharzzusammensetzung und verfahren zu ihrer herstellung |
| TW201037028A (en) | 2009-04-14 | 2010-10-16 | Fdc Lees Chemical Industry Co | Motified polyacetal with high thermal stability |
| JP5616102B2 (ja) * | 2010-04-08 | 2014-10-29 | 旭化成ケミカルズ株式会社 | 自動車内装・機構部品 |
| JP5610613B2 (ja) * | 2010-04-27 | 2014-10-22 | 旭化成ケミカルズ株式会社 | ポリアセタール樹脂組成物及びその成形体 |
| JP5610569B2 (ja) * | 2010-04-27 | 2014-10-22 | 旭化成ケミカルズ株式会社 | ポリアセタール樹脂製自動車内装用意匠部品 |
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| JP2003286386A (ja) * | 2002-03-28 | 2003-10-10 | Toray Ind Inc | ポリオキシメチレン樹脂組成物の製造方法およびその方法で得られた樹脂組成物 |
| US20070073007A1 (en) * | 2003-11-07 | 2007-03-29 | Hatsuhiko Harashina | Polyacetal resin composition and molded article thereof |
| JP4982043B2 (ja) * | 2003-11-10 | 2012-07-25 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
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2005
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