JP2005510437A5 - - Google Patents
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- JP2005510437A5 JP2005510437A5 JP2003547304A JP2003547304A JP2005510437A5 JP 2005510437 A5 JP2005510437 A5 JP 2005510437A5 JP 2003547304 A JP2003547304 A JP 2003547304A JP 2003547304 A JP2003547304 A JP 2003547304A JP 2005510437 A5 JP2005510437 A5 JP 2005510437A5
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- JP
- Japan
- Prior art keywords
- water
- group
- oxidized hydrocarbon
- metal
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004215 Carbon black (E152) Substances 0.000 claims 15
- 150000002430 hydrocarbons Chemical class 0.000 claims 15
- 229910052751 metal Inorganic materials 0.000 claims 15
- 239000002184 metal Substances 0.000 claims 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 11
- 239000003054 catalyst Substances 0.000 claims 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 150000002739 metals Chemical class 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 4
- 229910045601 alloy Inorganic materials 0.000 claims 3
- 239000000956 alloy Substances 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 239000000377 silicon dioxide Substances 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 125000004432 carbon atoms Chemical group C* 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 229920001223 polyethylene glycol Polymers 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000011780 sodium chloride Substances 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052723 transition metal Inorganic materials 0.000 claims 2
- 150000003624 transition metals Chemical class 0.000 claims 2
- GZCGUPFRVQAUEE-UHFFFAOYSA-N 2,3,4,5,6-pentahydroxyhexanal Chemical compound OCC(O)C(O)C(O)C(O)C=O GZCGUPFRVQAUEE-UHFFFAOYSA-N 0.000 claims 1
- 229910052582 BN Inorganic materials 0.000 claims 1
- MNQZXJOMYWMBOU-UHFFFAOYSA-N Glyceraldehyde Chemical compound OCC(O)C=O MNQZXJOMYWMBOU-UHFFFAOYSA-N 0.000 claims 1
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N Glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N N#B Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N Rhenium Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 239000005092 Ruthenium Substances 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 1
- 239000002041 carbon nanotube Substances 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical group CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- 150000002574 ketohexoses Chemical class 0.000 claims 1
- 150000002581 ketopentoses Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- TWXTWZIUMCFMSG-UHFFFAOYSA-N nitride(3-) Chemical compound [N-3] TWXTWZIUMCFMSG-UHFFFAOYSA-N 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000002407 reforming Methods 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Claims (21)
- 金属含有触媒存在下、水と、少なくとも二つの炭素原子を有する水溶性酸化炭化水素とを反応することを有し、
前記触媒は、ＶＩＩＩＢ族遷移金属、該金属の合金及びこれらの混合物からなる群から選択された金属を有することを特徴とする、水素の生成方法。 - 凝縮相リフォーミングによる水素の生成方法であって：
前記凝縮相において、金属含有触媒の存在下、水と水溶性酸化炭化水素とを反応することを有し、
前記触媒は、ＶＩＩＩＢ族遷移金属、該金属の合金及びこれらの混合物からなる群から選択された金属を有することを特徴とする方法。 - 前記水と前記酸化炭化水素とは、約１００℃以上約４５０℃以上の温度にて、且つ、前記水と前記酸化炭化水素とがガス状である圧力にて、反応されることを特徴とする請求項１に記載の方法。
- 前記水と前記酸化炭化水素とは、約４００℃未満の温度にて、且つ、前記水と前記酸化炭化水素とが凝縮液体である圧力にて、反応されることを特徴とする請求項１又は２に記載の方法。
- 前記水と前記酸化炭化水素とは、約４．０以上約１０．０以下のｐＨで反応されることを特徴とする請求項１乃至４のいずれか一項に記載の方法。
- 前記触媒は、ニッケル、パラジウム、白金、ルテニウム、ロジウム及びイリジウム、これらの合金並びにこれらの混合物からなる群から選択された金属を有することを特徴とする請求項１乃至５のいずれか一項に記載の方法。
- 前記触媒は、ＩＢ族金属、ＩＩＢ族金属、ＶＩＩＢ族金属、ＩＶＡ族金属及びＶＡ族金属からなる群から選択された金属で、さらに合金化又は混合されていることを特徴とする請求項１乃至６のいずれか一項に記載の方法。
- 前記金属は、銅、亜鉛、レニウム、ゲルマニウム、スズ及びビスマスからなる群から選択された金属で、さらに合金化又は混合されていることを特徴とする請求項１乃至７のいずれか一項に記載の方法。
- 前記触媒は支持体に接着されていることを特徴とする請求項１乃至８のいずれか一項に記載の方法。
- 前記支持体は、シリカ、アルミナ、ジルコニア、チタニア、セリア、炭素、シリカ−アルミナ、シリカナイトライド及びホウ素ナイトライド並びにこれらの混合物からなる群から選択されていることを特徴とする請求項９に記載の方法。
- 前記支持体は、水素及び水酸基からなる群から選択された表面残基を除去するように表面改質されていることを特徴とする請求項９又は１０に記載の方法。
- 前記支持体は、シラン、アルカリ化合物及びアルカリ土類化合物からなる群から選択されたモディファイヤーで処理することにより改質されていることを特徴とする請求項９乃至１１のいずれか一項に記載の方法。
- 前記支持体は、トリメチルエトキシシランで改質されたシリカであることを特徴とする請求項９乃至１２のいずれか一項に記載の方法。
- 前記支持体は、ゼオライト、カーボンナノチューブ、炭素フルーラン及びナノ多孔性支持体からなる群から選択されていることを特徴とする請求項９乃至１３のいずれか一項に記載の方法。
- 前記水と前記酸化炭化水素とは、約４００℃未満の温度にて、且つ、前記水と前記酸化炭化水素とが凝縮液体である圧力にて、反応されることを特徴とし、当該方法は、アルカリ又はアルカリ土類金属の水溶性塩の存在下、前記水と前記水溶性酸化炭化水素とを反応することをさらに有することを特徴とする請求項１乃至２及び４乃至１４のいずれか一項に記載の方法。
- 前記水溶性塩は、アルカリ若しくはアルカリ土類金属の、水酸化物、炭酸塩、硝酸塩及び塩化物からなる群から選択されていることを特徴とする請求項１５に記載の方法。
- 前記水溶性酸化炭化水素は、酸素に対する炭素の比率が１：１であることを特徴とする請求項１乃至１６のいずれか一項に記載の方法。
- 前記水溶性酸化炭化水素は、２以上１２以下の炭素数を有することを特徴とする請求項１乃至１７のいずれか一項に記載の方法。
- 前記水溶性酸化炭化水素は、メタノール、エタンジオール、エタンジオン、グリセロール、グリセルアルデヒド、アルドテトロース、アルドペントース、アルドヘキソース、ケトテトロース、ケトペントース、ケトヘキソース及びアルジトールからなる群から選択されていることを特徴とする請求項１乃至１８のいずれか一項に記載の方法。
- 前記水溶性酸化炭化水素は、アルドヘキソース及び該アルドヘキソースに対応するアルジトールからなる群から選択されていることを特徴とする請求項１乃至１９のいずれか一項に記載の方法。
- 前記水と前記酸化炭化水素とは、約３００℃未満の温度にて反応されることを特徴とする請求項１乃至２０のいずれか一項に記載の方法。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/998,552 | 2001-11-29 | ||
| US09/998,552 US6699457B2 (en) | 2001-11-29 | 2001-11-29 | Low-temperature hydrogen production from oxygenated hydrocarbons |
| PCT/US2002/038180 WO2003045841A1 (en) | 2001-11-29 | 2002-11-27 | Low-temperature hydrogen production from oxygenated hydrocarbons |
| US10/306,258 US6964757B2 (en) | 2001-11-29 | 2002-11-27 | Low-temperature hydrogen production from oxygenated hydrocarbons |
| US10/306,258 | 2002-11-27 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008131365A Division JP5322497B2 (ja) | 2001-11-29 | 2008-05-19 | 酸化炭化水素からの低温水素生成 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005510437A JP2005510437A (ja) | 2005-04-21 |
| JP2005510437A5 true JP2005510437A5 (ja) | 2005-12-22 |
| JP5081368B2 JP5081368B2 (ja) | 2012-11-28 |
Family
ID=31981071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003547304A Expired - Lifetime JP5081368B2 (ja) | 2001-11-29 | 2002-11-27 | 酸化炭化水素からの低温水素生成 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7618612B2 (ja) |
| EP (1) | EP1458645A4 (ja) |
| JP (1) | JP5081368B2 (ja) |
| CN (1) | CN100415637C (ja) |
| AU (1) | AU2002364703B2 (ja) |
| BR (1) | BR0214560A (ja) |
| CA (1) | CA2467443C (ja) |
| NZ (1) | NZ533175A (ja) |
| WO (1) | WO2003045841A1 (ja) |
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- 2002-11-27 EP EP02804080A patent/EP1458645A4/en not_active Ceased
- 2002-11-27 JP JP2003547304A patent/JP5081368B2/ja not_active Expired - Lifetime
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- 2002-11-27 BR BR0214560-0A patent/BR0214560A/pt active IP Right Grant
- 2002-11-27 AU AU2002364703A patent/AU2002364703B2/en not_active Expired
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