JP2004536915A5 - - Google Patents
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- Publication number
- JP2004536915A5 JP2004536915A5 JP2003515572A JP2003515572A JP2004536915A5 JP 2004536915 A5 JP2004536915 A5 JP 2004536915A5 JP 2003515572 A JP2003515572 A JP 2003515572A JP 2003515572 A JP2003515572 A JP 2003515572A JP 2004536915 A5 JP2004536915 A5 JP 2004536915A5
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- diene
- reaction system
- acrylonitrile
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 18
- 238000006243 chemical reaction Methods 0.000 claims 16
- 150000001993 dienes Chemical class 0.000 claims 16
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 13
- 229920000578 graft copolymer Polymers 0.000 claims 12
- 238000000034 method Methods 0.000 claims 12
- 239000000178 monomer Substances 0.000 claims 9
- 229920000642 polymer Polymers 0.000 claims 7
- 239000012986 chain transfer agent Substances 0.000 claims 6
- 239000007788 liquid Substances 0.000 claims 6
- 239000011541 reaction mixture Substances 0.000 claims 6
- 229920003244 diene elastomer Polymers 0.000 claims 5
- 229920000126 latex Polymers 0.000 claims 5
- 239000004816 latex Substances 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 5
- 239000000839 emulsion Substances 0.000 claims 4
- 239000003999 initiator Substances 0.000 claims 4
- 230000000379 polymerizing effect Effects 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- 239000005062 Polybutadiene Substances 0.000 claims 2
- 238000010923 batch production Methods 0.000 claims 2
- 229920002857 polybutadiene Polymers 0.000 claims 2
- 230000002194 synthesizing effect Effects 0.000 claims 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims 1
- -1 alkyl mercaptan Chemical compound 0.000 claims 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 238000010556 emulsion polymerization method Methods 0.000 claims 1
- 239000005060 rubber Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30744501P | 2001-07-24 | 2001-07-24 | |
| US10/200,877 US6784253B2 (en) | 2001-07-24 | 2002-07-23 | Enhanced polymerization process |
| PCT/US2002/023674 WO2003010214A1 (en) | 2001-07-24 | 2002-07-24 | Enhanced polymerization process |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008267855A Division JP5378749B2 (ja) | 2001-07-24 | 2008-10-16 | 改良重合法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004536915A JP2004536915A (ja) | 2004-12-09 |
| JP2004536915A5 true JP2004536915A5 (https=) | 2006-01-05 |
| JP4458843B2 JP4458843B2 (ja) | 2010-04-28 |
Family
ID=26896191
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003515572A Expired - Fee Related JP4458843B2 (ja) | 2001-07-24 | 2002-07-24 | 改良重合法 |
| JP2008267855A Expired - Fee Related JP5378749B2 (ja) | 2001-07-24 | 2008-10-16 | 改良重合法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008267855A Expired - Fee Related JP5378749B2 (ja) | 2001-07-24 | 2008-10-16 | 改良重合法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6784253B2 (https=) |
| EP (1) | EP1414873B1 (https=) |
| JP (2) | JP4458843B2 (https=) |
| CN (1) | CN100471883C (https=) |
| AT (1) | ATE416202T1 (https=) |
| DE (1) | DE60230152D1 (https=) |
| WO (1) | WO2003010214A1 (https=) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313506C (zh) * | 2004-08-04 | 2007-05-02 | 中国石油天然气集团公司 | 一种附聚后聚丁二烯胶乳与苯乙烯和丙烯腈的聚合方法 |
| US20070173619A1 (en) * | 2005-05-23 | 2007-07-26 | Yu Claire Q | Low gloss thermoplastic articles |
| US8084550B2 (en) * | 2005-05-23 | 2011-12-27 | Sabic Innovative Plastics Ip B.V. | Low gloss thermoplastic composition |
| KR101126016B1 (ko) * | 2005-10-04 | 2012-03-19 | 주식회사 엘지화학 | 잔류 단량체 함량이 낮은 그라프트 고무 라텍스의 제조방법 |
| KR101098683B1 (ko) | 2006-12-22 | 2011-12-23 | 주식회사 엘지화학 | 중합전환율이 높은 아크릴로 니트릴-부타디엔-스티렌계공중합 라텍스 분말의 제조방법 |
| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| EP2308906A1 (en) * | 2009-10-07 | 2011-04-13 | Styron Europe GmbH | Impact-modified monovinylidene aromatic polymer having low rubber crosslinking |
| CN102199253B (zh) * | 2010-03-26 | 2013-02-13 | 中国石油天然气股份有限公司 | 一种abs树脂的双峰乳液接枝制备方法 |
| DE102010031338A1 (de) * | 2010-07-14 | 2012-01-19 | Wacker Chemie Ag | Teilkontinuierliches Verfahren zur Emulsionspolymerisation |
| KR101385907B1 (ko) * | 2011-04-12 | 2014-04-15 | 주식회사 엘지화학 | 중합 생산성이 개선된 폴리부타디엔 라텍스 제조방법 |
| US9193874B2 (en) | 2012-07-16 | 2015-11-24 | Empire Technology Development Llc | Self-renewing hydrophilic organic coatings |
| US9023962B2 (en) * | 2012-08-20 | 2015-05-05 | Honeywell International Inc. | Synthesis of high molecular weight poly(2,3,3,3-tetrafluoropropene) |
| CN104837920A (zh) | 2012-11-19 | 2015-08-12 | 惠普发展公司，有限责任合伙企业 | 用于三维(3d)打印的组合物 |
| US9321867B2 (en) * | 2012-12-21 | 2016-04-26 | Honeywell International Inc. | Synthesis of 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers |
| US8906995B2 (en) | 2013-03-15 | 2014-12-09 | Sabic Global Technologies B.V. | Polymer compositions, method of manufacture, and articles formed therefrom |
| US9493670B2 (en) | 2013-04-18 | 2016-11-15 | Empire Technology Development Llc | Coatings that provide hydrophilic surface |
| CA2923011A1 (en) | 2013-10-14 | 2015-04-23 | Halliburton Energy Services, Inc. | Treatment fluids containing polysaccharides with friction reducing grafts thereon |
| CN104693636B (zh) * | 2013-12-06 | 2017-07-14 | 中国石油天然气股份有限公司 | 一种具有提高abs接枝共聚物转化率的聚合方法 |
| EP3137524B1 (de) * | 2014-04-30 | 2018-08-01 | INEOS Styrolution Group GmbH | Thermoplastische formmassen mit optimiertem restmonomeranteil |
| CN105601769A (zh) * | 2016-03-03 | 2016-05-25 | 天津大沽化工股份有限公司 | 一种改善abs树脂基色的接枝胶乳凝聚方法 |
| CN111148766B (zh) | 2017-10-13 | 2022-02-01 | Sabic环球技术有限责任公司 | 生产弹性体附聚组合物的方法 |
| WO2019073042A1 (en) | 2017-10-13 | 2019-04-18 | Sabic Global Technologies B.V. | METHOD FOR PRODUCING ELASTOMERIC AGGLOMERATE COMPOSITION, ELASTOMERIC AGGLOMERATE COMPOSITION AND USE THEREOF |
| JP7009284B2 (ja) * | 2018-03-30 | 2022-01-25 | 株式会社カネカ | グラフト共重合体の製造方法、及び塩化ビニル系樹脂組成物の製造方法 |
| CN109796550B (zh) * | 2019-01-08 | 2021-09-03 | 同济大学 | 一种低分子量液体橡胶的制备方法 |
| EP3680266B1 (en) * | 2019-01-09 | 2025-08-27 | Trinseo Europe GmbH | Influence of vinylidene substituted aromatic monomers on nitrile migration |
| CN114085338B (zh) * | 2020-08-24 | 2024-01-30 | 中国石油天然气股份有限公司 | 聚合物胶乳凝聚粒子及其制备方法 |
| EP4225819B1 (en) | 2020-10-08 | 2024-12-04 | INEOS Styrolution Group GmbH | Preparation of diene polymer latex of high gel content and controlled cross linking |
| EP4457251A1 (en) * | 2021-12-27 | 2024-11-06 | SABIC Global Technologies B.V. | Process of manufacturing graft polymer compositions |
| KR20250036840A (ko) | 2022-07-15 | 2025-03-14 | 이네오스 스티롤루션 그룹 게엠베하 | 변색이 감소된 asa 또는 abs 그라프트 코폴리머를 생산하는 방법 |
| CN117756993A (zh) * | 2023-07-27 | 2024-03-26 | 万华化学集团股份有限公司 | 一种低黄度指数丙烯腈-丁二烯-苯乙烯接枝共聚物的制备方法及abs胶粉 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2430562A (en) | 1944-02-23 | 1947-11-11 | Goodrich Co B F | Polymerization of butadiene-1,3 hydrocarbons |
| US4003871A (en) | 1975-01-08 | 1977-01-18 | Celanese Corporation | High solids styrene-butadiene emulsions |
| US3991136A (en) | 1975-04-02 | 1976-11-09 | Monsanto Company | Method of producing ABS polyblends having a low residual monomer content |
| GB1594863A (en) | 1978-03-03 | 1981-08-05 | Int Synthetic Rubber | Emulsion polymerisation process |
| US4145494A (en) | 1978-05-10 | 1979-03-20 | The General Tire & Rubber Company | Aqueous free radical emulsion polymerization |
| US4272425A (en) | 1979-10-26 | 1981-06-09 | The B. F. Goodrich Company | Treating dispersions of acrylonitrile polymers |
| DE3327190A1 (de) | 1983-07-28 | 1985-02-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur behandlung von (co)polymerisatdispersionen |
| IT1190360B (it) | 1985-05-24 | 1988-02-16 | Enichem Polimeri | Processo per la preparazione di polibutadiene aggraffato con stirolo ed acrilonitrile avente bassissimo contenuto finale di monomeri residui non reagiti |
| JP2555294B2 (ja) * | 1989-06-30 | 1996-11-20 | 日本合成ゴム株式会社 | 紙塗被組成物 |
| US5414045A (en) * | 1993-12-10 | 1995-05-09 | General Electric Company | Grafting, phase-inversion and cross-linking controlled multi-stage bulk process for making ABS graft copolymers |
| US6384129B1 (en) | 1995-08-30 | 2002-05-07 | General Electric Company | Semi-batch emulsion process for making diene rubber latex, rubber latex made thereby, and graft copolymer made therefrom |
| JPH1017602A (ja) * | 1996-07-05 | 1998-01-20 | Oji Paper Co Ltd | 共重合体ラテックスの製造方法および印刷用塗被紙 |
| JP3502791B2 (ja) * | 1999-06-29 | 2004-03-02 | 日本エイアンドエル株式会社 | オフセット印刷用紙被覆用共重合体ラテックスおよび該ラテックスを含有するオフセット印刷用紙被覆用組成物 |
-
2002
- 2002-07-23 US US10/200,877 patent/US6784253B2/en not_active Expired - Lifetime
- 2002-07-24 EP EP02763348A patent/EP1414873B1/en not_active Expired - Lifetime
- 2002-07-24 WO PCT/US2002/023674 patent/WO2003010214A1/en not_active Ceased
- 2002-07-24 DE DE60230152T patent/DE60230152D1/de not_active Expired - Lifetime
- 2002-07-24 CN CNB02818646XA patent/CN100471883C/zh not_active Expired - Lifetime
- 2002-07-24 JP JP2003515572A patent/JP4458843B2/ja not_active Expired - Fee Related
- 2002-07-24 AT AT02763348T patent/ATE416202T1/de not_active IP Right Cessation
-
2008
- 2008-10-16 JP JP2008267855A patent/JP5378749B2/ja not_active Expired - Fee Related
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