JP2004528180A5 - - Google Patents

Info

Publication number

JP2004528180A5

JP2004528180A5 JP2003501595A JP2003501595A JP2004528180A5 JP 2004528180 A5 JP2004528180 A5 JP 2004528180A5 JP 2003501595 A JP2003501595 A JP 2003501595A JP 2003501595 A JP2003501595 A JP 2003501595A JP 2004528180 A5 JP2004528180 A5 JP 2004528180A5

Authority

JP

Japan

Prior art keywords

catalyst

anionic clay

destabilization

mixture

phosphate

Prior art date

2002-05-28

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Links

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• 238000000034 method Methods 0.000 claims 19
• 239000000203 mixture Substances 0.000 claims 13
• 125000000129 anionic group Chemical group 0.000 claims 10
• 239000003054 catalyst Substances 0.000 claims 10
• 239000004927 clay Substances 0.000 claims 10
• 230000001687 destabilization Effects 0.000 claims 6
• 239000012018 catalyst precursor Substances 0.000 claims 5
• 229910021536 Zeolite Inorganic materials 0.000 claims 4
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 4
• 239000010457 zeolite Substances 0.000 claims 4
• GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 3
• 229910052782 aluminium Inorganic materials 0.000 claims 3
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
• 229910017604 nitric acid Inorganic materials 0.000 claims 3
• 239000003002 pH adjusting agent Substances 0.000 claims 3
• 238000001694 spray drying Methods 0.000 claims 3
• 229910019142 PO4 Inorganic materials 0.000 claims 2
• RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims 2
• 229910001593 boehmite Inorganic materials 0.000 claims 2
• MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims 2
• 238000010335 hydrothermal treatment Methods 0.000 claims 2
• FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims 2
• 239000010452 phosphate Substances 0.000 claims 2
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
• RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 2
• NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 2
• VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims 1
• 239000004254 Ammonium phosphate Substances 0.000 claims 1
• 239000005696 Diammonium phosphate Substances 0.000 claims 1
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
• 239000004115 Sodium Silicate Substances 0.000 claims 1
• 239000002253 acid Substances 0.000 claims 1
• ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims 1
• 239000000908 ammonium hydroxide Substances 0.000 claims 1
• 229910000148 ammonium phosphate Inorganic materials 0.000 claims 1
• 235000019289 ammonium phosphates Nutrition 0.000 claims 1
• 239000012736 aqueous medium Substances 0.000 claims 1
• GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims 1
• 229910000388 diammonium phosphate Inorganic materials 0.000 claims 1
• 235000019838 diammonium phosphate Nutrition 0.000 claims 1
• 229910001701 hydrotalcite Inorganic materials 0.000 claims 1
• 229960001545 hydrotalcite Drugs 0.000 claims 1
• 239000000395 magnesium oxide Substances 0.000 claims 1
• CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
• AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
• 238000004519 manufacturing process Methods 0.000 claims 1
• 239000000463 material Substances 0.000 claims 1
• 239000002245 particle Substances 0.000 claims 1
• 235000019353 potassium silicate Nutrition 0.000 claims 1
• 239000002243 precursor Substances 0.000 claims 1
• 239000011734 sodium Substances 0.000 claims 1
• 229910052708 sodium Inorganic materials 0.000 claims 1
• 229910001388 sodium aluminate Inorganic materials 0.000 claims 1
• 239000001488 sodium phosphate Substances 0.000 claims 1
• 229910000162 sodium phosphate Inorganic materials 0.000 claims 1
• 229910052911 sodium silicate Inorganic materials 0.000 claims 1
• RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1