JP2004521740A5 - - Google Patents
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- Publication number
- JP2004521740A5 JP2004521740A5 JP2003508963A JP2003508963A JP2004521740A5 JP 2004521740 A5 JP2004521740 A5 JP 2004521740A5 JP 2003508963 A JP2003508963 A JP 2003508963A JP 2003508963 A JP2003508963 A JP 2003508963A JP 2004521740 A5 JP2004521740 A5 JP 2004521740A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- chiral
- producing
- hydrogen atom
- salen catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 26
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 claims 21
- 238000004519 manufacturing process Methods 0.000 claims 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 15
- 150000001875 compounds Chemical class 0.000 claims 13
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 10
- 239000000126 substance Substances 0.000 claims 8
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 7
- 150000002118 epoxides Chemical class 0.000 claims 6
- 125000003277 amino group Chemical group 0.000 claims 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 3
- 125000003172 aldehyde group Chemical group 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 125000004185 ester group Chemical group 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 125000000623 heterocyclic group Chemical group 0.000 claims 3
- 125000000468 ketone group Chemical group 0.000 claims 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 3
- -1 phosphoryl group Chemical group 0.000 claims 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 3
- 150000000180 1,2-diols Chemical class 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 claims 2
- 125000003368 amide group Chemical group 0.000 claims 2
- 125000000392 cycloalkenyl group Chemical group 0.000 claims 2
- 125000001033 ether group Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000000879 imine group Chemical group 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- 125000000854 selenoether group Chemical group 0.000 claims 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims 2
- 125000000101 thioether group Chemical group 0.000 claims 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- SFXNZFATUMWBHR-UHFFFAOYSA-N 2-morpholin-4-yl-2-pyridin-3-ylacetonitrile Chemical compound C=1C=CN=CC=1C(C#N)N1CCOCC1 SFXNZFATUMWBHR-UHFFFAOYSA-N 0.000 claims 1
- LVZGQWKTUCVPBQ-UHFFFAOYSA-N acetic acid;trifluoroborane Chemical compound CC(O)=O.FB(F)F LVZGQWKTUCVPBQ-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical class FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 125000002837 carbocyclic group Chemical group 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- JDVIRCVIXCMTPU-UHFFFAOYSA-N ethanamine;trifluoroborane Chemical compound CCN.FB(F)F JDVIRCVIXCMTPU-UHFFFAOYSA-N 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- JBXYCUKPDAAYAS-UHFFFAOYSA-N methanol;trifluoroborane Chemical compound OC.FB(F)F JBXYCUKPDAAYAS-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- BRWZPVRDOUWXKE-UHFFFAOYSA-N methylsulfanylmethane;trifluoroborane Chemical compound CSC.FB(F)F BRWZPVRDOUWXKE-UHFFFAOYSA-N 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- CHNLPLHJUPMEOI-UHFFFAOYSA-N oxolane;trifluoroborane Chemical compound FB(F)F.C1CCOC1 CHNLPLHJUPMEOI-UHFFFAOYSA-N 0.000 claims 1
- VENBJVSTINLYEU-UHFFFAOYSA-N phenol;trifluoroborane Chemical compound FB(F)F.OC1=CC=CC=C1 VENBJVSTINLYEU-UHFFFAOYSA-N 0.000 claims 1
- LKWKIVHUCKVYOA-UHFFFAOYSA-N phosphoric acid;trifluoroborane Chemical compound FB(F)F.OP(O)(O)=O LKWKIVHUCKVYOA-UHFFFAOYSA-N 0.000 claims 1
- 125000003367 polycyclic group Chemical group 0.000 claims 1
- RQPQOULISUUGNY-UHFFFAOYSA-N propan-1-ol;trifluoroborane Chemical compound CCCO.FB(F)F RQPQOULISUUGNY-UHFFFAOYSA-N 0.000 claims 1
- MJCYPBSRKLJZTB-UHFFFAOYSA-N trifluoroborane;dihydrate Chemical compound O.O.FB(F)F MJCYPBSRKLJZTB-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20010037081 | 2001-06-27 | ||
| KR1020020035467A KR100368002B1 (en) | 2001-06-27 | 2002-06-24 | Chiral salen catalyst and process for preparing chiral compounds from racemic epoxy compounds using the same |
| PCT/KR2002/001219 WO2003002582A1 (en) | 2001-06-27 | 2002-06-26 | New chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004521740A JP2004521740A (ja) | 2004-07-22 |
| JP2004521740A5 true JP2004521740A5 (enExample) | 2005-02-17 |
| JP3968076B2 JP3968076B2 (ja) | 2007-08-29 |
Family
ID=26639176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003508963A Expired - Fee Related JP3968076B2 (ja) | 2001-06-27 | 2002-06-26 | 新しいキラルサレン化合物、キラルサレン触媒及びこれを利用したラセミックエポキシ化合物からキラル化合物を製造する方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6884750B2 (enExample) |
| EP (1) | EP1292602B1 (enExample) |
| JP (1) | JP3968076B2 (enExample) |
| CN (1) | CN1233648C (enExample) |
| AT (1) | ATE263626T1 (enExample) |
| AU (1) | AU2002345388A1 (enExample) |
| DE (1) | DE60200346T2 (enExample) |
| ES (1) | ES2217245T3 (enExample) |
| WO (1) | WO2003002582A1 (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100838139B1 (ko) | 2001-04-18 | 2008-06-13 | 스미또모 가가꾸 가부시끼가이샤 | 착물 촉매, 착물 촉매의 제조방법, 및 착물 촉매를 사용한알콜 유도체의 제조방법 |
| DE10130229A1 (de) * | 2001-06-22 | 2003-01-02 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
| US6639087B2 (en) * | 2001-08-22 | 2003-10-28 | Rhodia Pharma Solutions Inc. | Kinetic resolution method |
| UA79300C2 (en) * | 2002-08-12 | 2007-06-11 | Janssen Pharmaceutica Nv | N-aryl piperidine substituted biphenylcarboxamides as inhibitors of apolipoprotein b secretion |
| ATE338050T1 (de) * | 2003-02-12 | 2006-09-15 | Saltigo Gmbh | Verfahren zur asymmetrischen hydrierung von ketocarbonsäureestern |
| EP1469006A3 (de) * | 2003-02-12 | 2005-03-16 | Bayer Chemicals AG | Verfahren zur Reduktion von Ketocarbonsäureestern |
| PE20050483A1 (es) | 2003-10-31 | 2005-08-25 | Arena Pharm Inc | Derivados de tetrazol de formula (i), sus composiciones farmaceuticas y procesos para producir composiciones farmaceuticas |
| US7304172B2 (en) * | 2004-10-08 | 2007-12-04 | Cornell Research Foundation, Inc. | Polycarbonates made using highly selective catalysts |
| PE20060949A1 (es) | 2004-12-23 | 2006-10-11 | Arena Pharm Inc | Derivados fusionados de pirazol como agonistas del receptor de niacina |
| WO2006099162A2 (en) * | 2005-03-14 | 2006-09-21 | Georgia Tech Research Corporation | Polymeric salen compounds and methods thereof |
| US7728179B2 (en) * | 2006-02-01 | 2010-06-01 | Sumitomo Chemical Company, Limited | Method for producing optically active alcohol compound |
| US7906667B2 (en) | 2006-02-01 | 2011-03-15 | Sumitomo Chemical Company, Limited | Method for producing optically active alcohol compound |
| US20090286968A1 (en) * | 2008-04-25 | 2009-11-19 | Auburn University | 2-Quinoxalinol Salen Compounds and Uses Thereof |
| US20110087001A1 (en) | 2008-05-09 | 2011-04-14 | Cornell University | Polymers of ethylene oxide and carbon dioxide |
| CN101328264B (zh) * | 2008-07-10 | 2010-12-15 | 浙江大学 | 用离子液体支载催化剂制备聚碳酸酯的方法 |
| KR102128706B1 (ko) | 2008-08-22 | 2020-07-02 | 사우디 아람코 테크놀로지스 컴퍼니 | 촉매 및 중합체 합성방법 |
| CN103333330A (zh) | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| BRPI0919237B1 (pt) | 2008-09-17 | 2019-08-13 | Novomer Inc | método de remoção de um catalisador de um produto de uma reação de polimerização de policarbonato alifático e método de purificação de um produto de reação de polimerização de policarbonato alifático |
| WO2010062703A1 (en) | 2008-11-01 | 2010-06-03 | Novomer, Inc. | Polycarbonate block copolymers |
| JP5766716B2 (ja) | 2009-12-24 | 2015-08-19 | ノボマー， インコーポレイテッド | 多環式グアニジン化合物の合成のための方法 |
| EP2616513B1 (en) | 2010-09-14 | 2019-11-06 | Saudi Aramco Technologies Company | Catalysts and methods for polymer synthesis |
| CN101967165B (zh) * | 2010-09-21 | 2012-09-05 | 中国科学院上海有机化学研究所 | 桥链双希夫碱-钴络合物及其合成方法和用途 |
| US8859822B2 (en) | 2010-09-22 | 2014-10-14 | Novomer, Inc. | Synthesis of substituted salicylaldehyde derivatives |
| KR102055540B1 (ko) | 2011-05-09 | 2019-12-13 | 사우디 아람코 테크놀로지스 컴퍼니 | 고분자 조성물 및 방법 |
| CN102295579B (zh) * | 2011-06-22 | 2014-05-21 | 安庆金泉药业有限公司 | 一种(r)-4-氰基-3-羟基丁酸乙酯的合成工艺 |
| JP2014524965A (ja) | 2011-07-25 | 2014-09-25 | ノボマー， インコーポレイテッド | ポリウレタンに使用するための脂肪族ポリカーボネート |
| KR20200014932A (ko) | 2011-12-11 | 2020-02-11 | 사우디 아람코 테크놀로지스 컴퍼니 | 2가음이온성 반대이온을 갖는 살렌 착물 |
| CN102580777B (zh) * | 2011-12-19 | 2013-11-20 | 浙江大学 | 负载型salen锰配合物催化剂及其制备方法和应用 |
| ES2963032T3 (es) | 2011-12-20 | 2024-03-25 | Saudi Aramco Tech Co | Métodos para la síntesis de polímeros |
| CN103301882B (zh) * | 2012-03-16 | 2015-04-22 | 中国科学院大连化学物理研究所 | 一种用于拆分外消旋环氧烷烃的催化剂及其应用 |
| CN114774053A (zh) | 2012-04-16 | 2022-07-22 | 沙特阿美技术公司 | 粘合剂组合物和方法 |
| US9388277B2 (en) | 2012-05-24 | 2016-07-12 | Novomer, Inc. | Polycarbonate polyol compositions and methods |
| ES2761880T3 (es) | 2012-08-24 | 2020-05-21 | Saudi Aramco Tech Co | Complejos metálicos |
| ES2752043T3 (es) | 2012-11-07 | 2020-04-02 | Saudi Aramco Tech Co | Composiciones de espuma de poliuretano de gran resistencia y métodos |
| US10308759B2 (en) | 2014-04-03 | 2019-06-04 | Saudi Aramco Technologies Company | Aliphatic polycarbonate polyol compositions |
| CN104610263B (zh) * | 2014-09-17 | 2016-06-29 | 成都理工大学 | 手性咪唑啉酮-酚 |
| CN104356098A (zh) * | 2014-11-10 | 2015-02-18 | 舒兰市金马化工有限公司 | 一种手性环氧氯丙烷的制备方法 |
| CN104607250B (zh) * | 2015-02-02 | 2016-11-30 | 舒兰市金马化工有限公司 | 一种多面体低聚倍半硅氧烷树枝状大分子催化剂及其应用 |
| CN104804044A (zh) * | 2015-03-10 | 2015-07-29 | 沈阳化工大学 | Ru(II)-Salen金属配合物及其制备方法 |
| CN107226797B (zh) * | 2016-08-29 | 2019-05-17 | 沈阳金久奇科技有限公司 | 一种手性化合物2，2-二甲基-3-(环氧乙烷-2-基)丙酸甲酯的制备方法 |
| WO2019204553A1 (en) | 2018-04-18 | 2019-10-24 | Saudi Aramco Technologies Company | End-group isomerization of poly(alkylene carbonate) polymers |
| CN111097529B (zh) * | 2018-10-25 | 2023-05-02 | 中国石油化工股份有限公司 | 高性能纳米笼限域催化剂、制备方法及应用 |
| US11180609B2 (en) | 2018-08-02 | 2021-11-23 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
| MA53727A (fr) | 2018-09-24 | 2021-12-29 | Saudi Aramco Tech Co | Copolymères séquencés de polycarbonate et procédés associés |
| JP2024525422A (ja) | 2021-06-23 | 2024-07-12 | サウジ アラムコ テクノロジーズ カンパニー | ポリオール組成物及び方法 |
| CN117658953A (zh) * | 2023-12-04 | 2024-03-08 | 上海中化科技有限公司 | 手性环氧化合物、手性β-内酯及聚羟基脂肪酸酯的制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US566393A (en) * | 1896-08-25 | Andrew fyrberg | ||
| US5637739A (en) * | 1990-03-21 | 1997-06-10 | Research Corporation Technologies, Inc. | Chiral catalysts and catalytic epoxidation catalyzed thereby |
| DE4435158A1 (de) * | 1994-09-30 | 1996-04-04 | Degussa | Verfahren zur Herstellung von Salcomin |
| US5665890A (en) | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| US6262278B1 (en) * | 1995-03-14 | 2001-07-17 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| US6521561B1 (en) * | 1998-05-01 | 2003-02-18 | President And Fellows Of Harvard College | Main-group metal based asymmetric catalysts and applications thereof |
| AU5891201A (en) * | 2000-05-24 | 2001-12-03 | Rstech Co., Ltd. | Novel chiral salen catalysts, and a process for preparing chiral compounds from racemic epoxides for using them |
| US7205420B2 (en) * | 2002-06-13 | 2007-04-17 | Teva Pharmaceutical Industries Ltd. | Epimerization of analogs of vitamin D |
-
2002
- 2002-06-26 DE DE60200346T patent/DE60200346T2/de not_active Expired - Lifetime
- 2002-06-26 WO PCT/KR2002/001219 patent/WO2003002582A1/en not_active Ceased
- 2002-06-26 CN CN02802133.9A patent/CN1233648C/zh not_active Expired - Fee Related
- 2002-06-26 JP JP2003508963A patent/JP3968076B2/ja not_active Expired - Fee Related
- 2002-06-26 AU AU2002345388A patent/AU2002345388A1/en not_active Abandoned
- 2002-06-26 EP EP02743918A patent/EP1292602B1/en not_active Expired - Lifetime
- 2002-06-26 US US10/297,164 patent/US6884750B2/en not_active Expired - Lifetime
- 2002-06-26 ES ES02743918T patent/ES2217245T3/es not_active Expired - Lifetime
- 2002-06-26 AT AT02743918T patent/ATE263626T1/de not_active IP Right Cessation
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