JP2004300439A5 - - Google Patents
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- JP2004300439A5 JP2004300439A5 JP2004095709A JP2004095709A JP2004300439A5 JP 2004300439 A5 JP2004300439 A5 JP 2004300439A5 JP 2004095709 A JP2004095709 A JP 2004095709A JP 2004095709 A JP2004095709 A JP 2004095709A JP 2004300439 A5 JP2004300439 A5 JP 2004300439A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- reactor
- composition
- radical initiator
- polyether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims 48
- -1 siloxane moiety Chemical group 0.000 claims 29
- 150000003254 radicals Chemical class 0.000 claims 22
- 239000004094 surface-active agent Substances 0.000 claims 21
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 20
- 239000000203 mixture Substances 0.000 claims 20
- 239000000178 monomer Substances 0.000 claims 20
- 239000003999 initiator Substances 0.000 claims 18
- 229910052736 halogen Inorganic materials 0.000 claims 16
- 150000002367 halogens Chemical class 0.000 claims 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims 15
- 229920000570 polyether Polymers 0.000 claims 15
- 238000006116 polymerization reaction Methods 0.000 claims 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 8
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims 8
- 150000003839 salts Chemical class 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 7
- 239000012736 aqueous medium Substances 0.000 claims 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 6
- 229920000867 polyelectrolyte Polymers 0.000 claims 6
- 229920001296 polysiloxane Polymers 0.000 claims 6
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical group O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- 239000012986 chain transfer agent Substances 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 4
- 125000000600 disaccharide group Chemical group 0.000 claims 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 4
- 239000011261 inert gas Substances 0.000 claims 4
- 150000002772 monosaccharides Chemical group 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- 229920001281 polyalkylene Polymers 0.000 claims 4
- 150000003077 polyols Chemical group 0.000 claims 4
- 238000010926 purge Methods 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 claims 3
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 claims 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 3
- 239000008367 deionised water Substances 0.000 claims 3
- 229910021641 deionized water Inorganic materials 0.000 claims 3
- 150000002978 peroxides Chemical group 0.000 claims 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 3
- XLOFNXVVMRAGLZ-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2-trifluoroethene Chemical compound FC(F)=C.FC=C(F)F XLOFNXVVMRAGLZ-UHFFFAOYSA-N 0.000 claims 2
- ABADUMLIAZCWJD-UHFFFAOYSA-N 1,3-dioxole Chemical class C1OC=CO1 ABADUMLIAZCWJD-UHFFFAOYSA-N 0.000 claims 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- XVKFQTALPDUTNS-UHFFFAOYSA-N 2-chloro-1,3,4,4,5,6,6,7,8,8,8-undecafluoro-3-(trifluoromethyl)oct-1-ene Chemical compound FC(C(F)(F)F)C(C(C(C(C(F)(F)F)(C(=CF)Cl)F)(F)F)F)(F)F XVKFQTALPDUTNS-UHFFFAOYSA-N 0.000 claims 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- 229920002125 Sokalan® Polymers 0.000 claims 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 2
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 2
- 239000002519 antifouling agent Substances 0.000 claims 2
- 229960003237 betaine Drugs 0.000 claims 2
- 229920001400 block copolymer Polymers 0.000 claims 2
- 239000000872 buffer Substances 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- 229940008099 dimethicone Drugs 0.000 claims 2
- MWYMHZINPCTWSB-UHFFFAOYSA-N dimethylsilyloxy-dimethyl-trimethylsilyloxysilane Chemical class C[SiH](C)O[Si](C)(C)O[Si](C)(C)C MWYMHZINPCTWSB-UHFFFAOYSA-N 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 230000002209 hydrophobic effect Effects 0.000 claims 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 claims 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 2
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 claims 2
- 229920000058 polyacrylate Polymers 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 239000001294 propane Substances 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical group [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims 2
- DAVCAHWKKDIRLY-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)OC=C DAVCAHWKKDIRLY-UHFFFAOYSA-N 0.000 claims 1
- YKWORVRLPTZONH-UHFFFAOYSA-N 1-ethenoxy-1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propane Chemical compound FC(F)(F)C(F)(F)C(F)(F)OC(F)(C(F)(F)F)C(F)(F)OC=C YKWORVRLPTZONH-UHFFFAOYSA-N 0.000 claims 1
- HFNSTEOEZJBXIF-UHFFFAOYSA-N 2,2,4,5-tetrafluoro-1,3-dioxole Chemical compound FC1=C(F)OC(F)(F)O1 HFNSTEOEZJBXIF-UHFFFAOYSA-N 0.000 claims 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 claims 1
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000008351 acetate buffer Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 claims 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims 1
- 239000006172 buffering agent Substances 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- CSJWOWRPMBXQLD-UHFFFAOYSA-N perfluoromethylvinylether group Chemical group FC(=C(C(F)(F)F)F)OC(=C(F)C(F)(F)F)F CSJWOWRPMBXQLD-UHFFFAOYSA-N 0.000 claims 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims 1
- 239000008363 phosphate buffer Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 claims 1
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 claims 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims 1
- 229940029284 trichlorofluoromethane Drugs 0.000 claims 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/401,499 US6841616B2 (en) | 2003-03-28 | 2003-03-28 | Polymerization of halogen-containing monomers using siloxane surfactant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004300439A JP2004300439A (ja) | 2004-10-28 |
| JP2004300439A5 true JP2004300439A5 (https=) | 2007-05-17 |
| JP4677197B2 JP4677197B2 (ja) | 2011-04-27 |
Family
ID=32825019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004095709A Expired - Lifetime JP4677197B2 (ja) | 2003-03-28 | 2004-03-29 | シロキサン界面活性剤を使用するハロゲン含有単量体の重合 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6841616B2 (https=) |
| EP (1) | EP1462461B1 (https=) |
| JP (1) | JP4677197B2 (https=) |
| CN (1) | CN1324056C (https=) |
| AT (1) | ATE386753T1 (https=) |
| DE (1) | DE602004011848T2 (https=) |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7279522B2 (en) | 2001-09-05 | 2007-10-09 | 3M Innovative Properties Company | Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant |
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| US8080621B2 (en) * | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US8338518B2 (en) * | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| GB0523853D0 (en) | 2005-11-24 | 2006-01-04 | 3M Innovative Properties Co | Fluorinated surfactants for use in making a fluoropolymer |
| GB0525978D0 (en) | 2005-12-21 | 2006-02-01 | 3M Innovative Properties Co | Fluorinated Surfactants For Making Fluoropolymers |
| US20080015304A1 (en) | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
| GB0514398D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant |
| US7671112B2 (en) | 2005-07-15 | 2010-03-02 | 3M Innovative Properties Company | Method of making fluoropolymer dispersion |
| US8124699B2 (en) * | 2005-08-08 | 2012-02-28 | Arkema Inc. | Polymerization of fluoropolymers using alkyl phosphonate surfactants |
| ES2611988T3 (es) | 2005-08-08 | 2017-05-11 | Arkema Inc. | Polimerización de fluoropolímeros usando tensioactivos no fluorados |
| US7728087B2 (en) * | 2005-12-23 | 2010-06-01 | 3M Innovative Properties Company | Fluoropolymer dispersion and method for making the same |
| US7754795B2 (en) | 2006-05-25 | 2010-07-13 | 3M Innovative Properties Company | Coating composition |
| US8119750B2 (en) | 2006-07-13 | 2012-02-21 | 3M Innovative Properties Company | Explosion taming surfactants for the production of perfluoropolymers |
| US7678859B2 (en) * | 2006-09-14 | 2010-03-16 | 3M Innovative Properties Company | Preparation and stabilization of fluoropolymer dispersions |
| JP5439186B2 (ja) * | 2006-11-09 | 2014-03-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合 |
| EP2079766B1 (en) | 2006-11-09 | 2011-05-18 | E.I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant |
| WO2008060462A1 (en) * | 2006-11-09 | 2008-05-22 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and siloxane surfactant |
| EP2188120A1 (en) * | 2007-08-21 | 2010-05-26 | Saint-Gobain Performance Plastics Corporation | Roofing sheet material |
| EP2274345B1 (en) | 2008-04-07 | 2017-01-04 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| US20090281241A1 (en) | 2008-05-09 | 2009-11-12 | E. I. Du Pont De Nemours And Company | Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts |
| US8058376B2 (en) * | 2008-12-23 | 2011-11-15 | E. I. Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ |
| US8835547B2 (en) | 2008-12-23 | 2014-09-16 | E I Du Pont De Nemours And Company | Fluoropolymer particles having a nucleus of fluorinated ionomer |
| WO2010075495A1 (en) | 2008-12-23 | 2010-07-01 | E. I. Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| US8436053B2 (en) * | 2008-12-23 | 2013-05-07 | E.I. Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| US8436054B2 (en) * | 2008-12-23 | 2013-05-07 | E I Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ |
| US8153738B2 (en) | 2008-12-23 | 2012-04-10 | E I Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| EP2284200A1 (en) | 2009-07-31 | 2011-02-16 | 3M Innovative Properties Company | Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them |
| RU2522749C2 (ru) * | 2009-07-31 | 2014-07-20 | Зм Инновейтив Пропертиз Компани | Соединения фторполимера, содержащие многоатомные соединения, и способы из производства |
| JP6109073B2 (ja) | 2010-11-09 | 2017-04-05 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
| WO2012064858A1 (en) | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization |
| EP3533811B1 (en) | 2010-11-09 | 2021-08-11 | The Chemours Company FC, LLC | Nucleation in aqueous polymerization of fluoromonomer |
| US20130122309A1 (en) * | 2011-11-14 | 2013-05-16 | Arkema Inc. | Polyvinylidene fluoride dispersion |
| KR101400558B1 (ko) * | 2011-12-07 | 2014-05-29 | (주)엘지하우시스 | 폼 테이프 기재 조성물, 이를 이용한 폼 테이프 및 이의 제조 방법 |
| EP2868674B1 (en) * | 2013-10-30 | 2019-11-20 | 3M Innovative Properties Company | Peroxide curable fluoropolymers obtainable by polymerization using non-fluorinated polyhydroxy emulsifiers |
| JP6622209B2 (ja) | 2013-11-26 | 2019-12-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用 |
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| US10774233B2 (en) | 2015-11-25 | 2020-09-15 | Arkema Inc. | Fluoropolymer compositions with improved mechanical dampening |
| KR102144304B1 (ko) * | 2016-07-06 | 2020-08-14 | 에이치피 인디고 비.브이. | 방출 층 |
| CN110997735B (zh) | 2017-08-10 | 2024-03-01 | 大金工业株式会社 | 精制聚四氟乙烯水性分散液的制造方法、改性聚四氟乙烯粉末的制造方法、聚四氟乙烯成型体的制造方法以及组合物 |
| RU2766151C2 (ru) | 2017-08-10 | 2022-02-08 | Дайкин Индастриз, Лтд. | Способ производства водной жидкой дисперсии очищенного политетрафторэтилена, способ производства модифицированного порошкообразного политетрафторэтилена, способ производства формованного тела из политетрафторэтилена и композиция |
| WO2019131633A1 (ja) | 2017-12-25 | 2019-07-04 | ダイキン工業株式会社 | ポリテトラフルオロエチレン粉末の製造方法 |
| WO2019172382A1 (ja) | 2018-03-07 | 2019-09-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
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