JP2001519849A - 発泡性組成物および乾燥発泡性顆粒 - Google Patents
発泡性組成物および乾燥発泡性顆粒Info
- Publication number
- JP2001519849A JP2001519849A JP54366798A JP54366798A JP2001519849A JP 2001519849 A JP2001519849 A JP 2001519849A JP 54366798 A JP54366798 A JP 54366798A JP 54366798 A JP54366798 A JP 54366798A JP 2001519849 A JP2001519849 A JP 2001519849A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- weight
- composition
- granules
- dry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
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- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
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- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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- A23L2/40—Effervescence-generating compositions
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- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
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- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
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- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
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- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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- C11D7/26—Organic compounds containing oxygen
- C11D7/268—Carbohydrates or derivatives thereof
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- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3227—Ethers thereof
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
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Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 酸、炭酸塩供給源、好ましくは炭酸塩および/または重炭酸塩、および 所望により結合剤を含んでなり、前記酸、炭酸塩供給源および所望により結合剤 が物理的に非常に接近していることを特徴とする、乾燥発泡性顆粒。 2. 直径が0.001〜7mm)好ましくは2mm未満である、請求項1に記載 の顆粒。 3. かさ密度が500g/l〜1200g/l、好ましくは700g/1〜110 0g/lである、請求項1または2に記載の顆粒。 4. 顆粒全体の0.1〜99重量%、好ましくは3〜75重量%、より好ま しくは5〜60重量%、最も好ましくは15〜50重量%の酸または酸の混合物 を含んでなるが、ただし、クエン酸が存在する場合、クエン酸の量は好ましくは 顆粒全体の20重量%未満である、請求項1〜3のいずれか1項に記載の顆粒。 5. 酸が、モノまたはポリカルボン酸またはそれらの混合物、好ましくはク エン酸、アジピン酸、グルタル酸、3ケトグルタル酸、シトラマル酸、酒石酸、 マレイン酸、フマル酸、リンゴ酸、コハク酸および/またはマロン酸であり、そ れらの酸形態、それらの塩(一、二、三塩)形態、それらの無水物および/また はそれらの水和した形態にある、請求項1〜4のいずれか1項に記載の顆粒。 6. 顆粒全体の0.1〜99重量%、好ましくは30〜95重量%、より好 ましくは45〜85重量%、最も好ましくは50〜80重量%の炭酸塩および/ または重炭酸塩を含んでなる、請求項1〜5のいずれか1項に記載の顆粒。 7. 顆粒全体の50重量%まで、好ましくは35重量%まで、より好ましく は20重量%までの結合剤または結合剤の混合物を含んでなる、請求項1〜6の いずれか1項に記載の顆粒。 8. 結合剤が、セルロース誘導体、カルボキシメチルセルロース、および単 独重合体状または共重合体状ポリカルボン酸およびそれらの塩、C6〜C20アル キルおよびアルキルアリールスルホネートおよびサルフェート、アルコール1モ ルあたりエチレンオキシド5〜100モルを含むC10〜C20アルコールエトキシ レート、平均分子量12000〜700000のポリビニルピロリドン、平均分 子量600〜10000のポリエチレングリコール、無水マレイン酸とエチレン 、メチルビニルエーテル、メタクリル酸またはアクリル酸の共重合体、C10−C 20モノおよびジグリセロールエーテル、C10〜C20脂肪酸およびそれらの混合物 および好ましくはC8〜C20アルキルベンゼンスルホネートからなる群から選択 される、請求項1〜7のいずれか1項に記載の顆粒。 9. 請求項1〜8のいずれか1項に記載の乾燥発泡性顆粒の製造方法であっ て、 −先ず酸、炭酸塩供給源および所望により結合剤を混合して混合物を形成する工 程、 −次いでこの混合物を凝集工程、好ましくは加圧凝集工程、にかけ、凝集混合物 を形成する工程、および −最後に、造粒工程で凝集混合物を造粒する工程 を含んでなることを特徴とする方法。 10. 前記加圧凝集工程にかけた乾燥発泡性顆粒のかさ密度が、酸および重 炭酸塩および/または炭酸塩、および所望により結合剤、を含んでなる形成され た混合物の、前記加圧凝集工程にかける前のかさ密度と比較して、200g/lま で、好ましくは10g/l〜150g/lに増加している、請求項9に記載の方法。 11. 前記加圧凝集工程がローラー圧縮工程であり、その際、形成された混 合物が圧縮ロール間に加圧下で押し込まれ、その様にして得られた、圧縮された 混合物(シート/フレーク)が乾燥発泡性顆粒に造粒され、所望により篩にかけ られる、請求項9または10に記載の方法。 12. 酸および炭酸塩供給源を含む発泡性材料を含んでなり、酸および炭酸 塩供給源が顆粒中に存在する、および/または酸および炭酸塩供給源が組成物中 に分離されて存在する顆粒状組成物であって、沸騰係数(EI)が少なくとも1 0であり、沸騰係数(EI)が、 (式中、Lは、pKaが6以下である酸の酸性基の数であり、Sは3√(25℃ における、酸の水に対する溶解度g/リットル)であり、Mは酸の分子量であり、 NCinterは、組成物中に分離されて存在する炭酸塩供給源と酸の接触点の1mm3 の密度であり、NCintra粒中の酸の重量画分)×(該顆粒中の炭酸塩供給源の 重量画分)×12である) であることを特徴とする顆粒状組成物。 13. 顆粒が、請求項1〜8のいずれか1項に記載の乾燥発泡性顆粒を含ん でなる、請求項12に記載の顆粒状組成物。 14. 乾燥発泡性顆粒および他の洗剤成分を含んでなり、請求項1〜8のい ずれか1項に記載の乾燥発泡性顆粒を先ず形成し、次いで乾燥発泡性顆粒を他の 洗剤成分に加える工程を含んでなる方法により得られる、請求項12または13 に記載の顆粒状組成物。 15. 組成物全体の0.1〜99重量%、好ましくは2〜50重量%、より 好ましくは3〜25重量%、最も好ましくは4〜15重量%の乾燥発泡性顆粒を 含んでなる、請求項12〜14のいずれか1項に記載の顆粒状組成物。 16. 酸素漂白剤、好ましくはアルカリ金属の過炭酸塩および/または過ホ ウ酸塩、を組成物全体の80重量%まで、好ましくは2〜45重量%、より好ま しくは10〜40重量%の量で、および好ましくは漂白活性剤を組成物全体の3 0重量%までの量で含んでなる、請求項12〜15のいずれか1項に記載の顆 粒状組成物。 17. 組成物全体の50重量%まで、好ましくは1〜30重量%、より好ま しくは5〜20重量%の量の、好ましくは非イオン系界面活性剤を含んでなる、 少なくとも1種の界面活性剤または界面活性剤の混合物を含んでなる、請求項1 2〜16のいずれか1項に記載の顆粒状組成物。 18. 乾燥発泡性粒子および乾燥添加された酸、好ましくはクエン酸または リンゴ酸、および/または乾燥添加された炭酸塩供給源を含んでなる、請求項1 2〜18のいずれか1項に記載の顆粒状組成物。 19. 押出し物または錠剤の形態である、請求項12〜19のいずれか1項 に記載の顆粒状組成物。 20. 布地の浸漬方法であって、水および有効量の、請求項12〜19のい ずれか1項に記載の顆粒状洗剤組成物を含んでなる浸漬液に前記布地を効果的な 時間浸漬し、次いで前記浸漬液から取り出すことを特徴とする方法。 21. 酸素漂白剤、好ましくは過炭酸塩および/または過ホウ酸塩、を含ん でなる顆粒状組成物中における、この組成物の貯蔵時における熱的安定性を改良 するための、請求項1〜8のいずれか1項に記載の乾燥発泡性顆粒の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP97870048A EP0872544A1 (en) | 1997-04-14 | 1997-04-14 | Dry effervescent granules and granular compositions comprising the same |
EP97870048.2 | 1997-04-14 | ||
PCT/IB1998/000562 WO1998046716A1 (en) | 1997-04-14 | 1998-04-14 | Effervescent compositions and dry effervescent granules |
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JP2001519849A true JP2001519849A (ja) | 2001-10-23 |
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JP54366798A Ceased JP2001519849A (ja) | 1997-04-14 | 1998-04-14 | 発泡性組成物および乾燥発泡性顆粒 |
Country Status (19)
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US (1) | US6440926B1 (ja) |
EP (3) | EP0872544A1 (ja) |
JP (1) | JP2001519849A (ja) |
KR (1) | KR100360135B1 (ja) |
CN (1) | CN1259991A (ja) |
AR (1) | AR011715A1 (ja) |
AT (1) | ATE232556T1 (ja) |
AU (1) | AU745174B2 (ja) |
BR (1) | BR9808894A (ja) |
CA (1) | CA2284755C (ja) |
DE (1) | DE69811357T2 (ja) |
EG (1) | EG21246A (ja) |
ES (1) | ES2187941T3 (ja) |
HU (1) | HUP0000936A3 (ja) |
ID (1) | ID27458A (ja) |
MA (1) | MA24523A1 (ja) |
TR (1) | TR199902535T2 (ja) |
WO (1) | WO1998046716A1 (ja) |
ZA (3) | ZA983120B (ja) |
Cited By (4)
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JP2009500490A (ja) * | 2005-06-29 | 2009-01-08 | ザ プロクター アンド ギャンブル カンパニー | 手洗いにより汚れた皿を洗浄するための発泡性製品の使用 |
JP2014005367A (ja) * | 2012-06-25 | 2014-01-16 | Lion Corp | 粒状洗浄剤 |
JP2018527307A (ja) * | 2015-06-30 | 2018-09-20 | アモーレパシフィック コーポレーション | 速崩壊型顆粒丸毛髪洗浄用組成物 |
JP2018532502A (ja) * | 2015-10-30 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | 直接的泡沫洗浄生成物を含む、食器を洗浄する方法 |
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-
1998
- 1998-04-13 EG EG40198A patent/EG21246A/xx active
- 1998-04-13 MA MA25031A patent/MA24523A1/fr unknown
- 1998-04-14 ZA ZA983120A patent/ZA983120B/xx unknown
- 1998-04-14 US US09/402,973 patent/US6440926B1/en not_active Expired - Fee Related
- 1998-04-14 AT AT98910946T patent/ATE232556T1/de not_active IP Right Cessation
- 1998-04-14 JP JP54366798A patent/JP2001519849A/ja not_active Ceased
- 1998-04-14 EP EP02017757A patent/EP1254950A3/en not_active Withdrawn
- 1998-04-14 WO PCT/IB1998/000562 patent/WO1998046716A1/en not_active Application Discontinuation
- 1998-04-14 KR KR1019997009464A patent/KR100360135B1/ko not_active IP Right Cessation
- 1998-04-14 DE DE69811357T patent/DE69811357T2/de not_active Expired - Fee Related
- 1998-04-14 AU AU65151/98A patent/AU745174B2/en not_active Ceased
- 1998-04-14 HU HU0000936A patent/HUP0000936A3/hu unknown
- 1998-04-14 ID IDW991212A patent/ID27458A/id unknown
- 1998-04-14 ZA ZA983121A patent/ZA983121B/xx unknown
- 1998-04-14 ES ES98910946T patent/ES2187941T3/es not_active Expired - Lifetime
- 1998-04-14 CA CA002284755A patent/CA2284755C/en not_active Expired - Fee Related
- 1998-04-14 EP EP98910946.7A patent/EP0975724B2/en not_active Expired - Lifetime
- 1998-04-14 AR ARP980101690A patent/AR011715A1/es active IP Right Grant
- 1998-04-14 CN CN98805964A patent/CN1259991A/zh active Pending
- 1998-04-14 BR BR9808894-7A patent/BR9808894A/pt not_active Application Discontinuation
- 1998-04-14 ZA ZA983124A patent/ZA983124B/xx unknown
- 1998-04-14 TR TR1999/02535T patent/TR199902535T2/xx unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2009500490A (ja) * | 2005-06-29 | 2009-01-08 | ザ プロクター アンド ギャンブル カンパニー | 手洗いにより汚れた皿を洗浄するための発泡性製品の使用 |
JP2014005367A (ja) * | 2012-06-25 | 2014-01-16 | Lion Corp | 粒状洗浄剤 |
JP2018527307A (ja) * | 2015-06-30 | 2018-09-20 | アモーレパシフィック コーポレーション | 速崩壊型顆粒丸毛髪洗浄用組成物 |
JP2018532502A (ja) * | 2015-10-30 | 2018-11-08 | ザ プロクター アンド ギャンブル カンパニー | 直接的泡沫洗浄生成物を含む、食器を洗浄する方法 |
Also Published As
Publication number | Publication date |
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ZA983120B (en) | 1999-05-17 |
EP0975724B1 (en) | 2003-02-12 |
KR100360135B1 (ko) | 2002-11-13 |
EP1254950A3 (en) | 2003-05-07 |
ES2187941T3 (es) | 2003-06-16 |
EG21246A (en) | 2001-04-30 |
MA24523A1 (fr) | 1998-12-31 |
EP0975724B2 (en) | 2014-11-26 |
DE69811357T2 (de) | 2003-11-27 |
ID27458A (id) | 2001-04-12 |
ZA983121B (en) | 1998-10-20 |
AU745174B2 (en) | 2002-03-14 |
DE69811357D1 (de) | 2003-03-20 |
CA2284755C (en) | 2007-06-19 |
EP0872544A1 (en) | 1998-10-21 |
CA2284755A1 (en) | 1998-10-22 |
BR9808894A (pt) | 2000-08-01 |
US6440926B1 (en) | 2002-08-27 |
TR199902535T2 (xx) | 2000-02-21 |
HUP0000936A2 (hu) | 2000-09-28 |
ATE232556T1 (de) | 2003-02-15 |
EP1254950A2 (en) | 2002-11-06 |
HUP0000936A3 (en) | 2001-11-28 |
AR011715A1 (es) | 2000-08-30 |
CN1259991A (zh) | 2000-07-12 |
AU6515198A (en) | 1998-11-11 |
ZA983124B (en) | 1999-06-28 |
WO1998046716A1 (en) | 1998-10-22 |
KR20010006377A (ko) | 2001-01-26 |
EP0975724A1 (en) | 2000-02-02 |
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