JP2001270969A5 - - Google Patents
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- JP2001270969A5 JP2001270969A5 JP2001037120A JP2001037120A JP2001270969A5 JP 2001270969 A5 JP2001270969 A5 JP 2001270969A5 JP 2001037120 A JP2001037120 A JP 2001037120A JP 2001037120 A JP2001037120 A JP 2001037120A JP 2001270969 A5 JP2001270969 A5 JP 2001270969A5
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- JP
- Japan
- Prior art keywords
- polymer
- pctfe
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- mol
- ectfe
- Prior art date
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- 239000000203 mixture Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 15
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 13
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 13
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 12
- 239000000178 monomer Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000000701 coagulant Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- -1 fluoroalkyl vinyl ethers Chemical class 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YFZCNXJOYHYIGC-UHFFFAOYSA-N (2,2,2-trichloroacetyl) 2,2,2-trichloroethaneperoxoate Chemical compound ClC(Cl)(Cl)C(=O)OOC(=O)C(Cl)(Cl)Cl YFZCNXJOYHYIGC-UHFFFAOYSA-N 0.000 description 1
- MSTZXMFWGUDAOI-UHFFFAOYSA-N (2,2-dichloro-2-fluoroacetyl) 2,2-dichloro-2-fluoroethaneperoxoate Chemical compound FC(Cl)(Cl)C(=O)OOC(=O)C(F)(Cl)Cl MSTZXMFWGUDAOI-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical group [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- FYOWZTWVYZOZSI-UHFFFAOYSA-N thiourea dioxide Chemical compound NC(=N)S(O)=O FYOWZTWVYZOZSI-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2000A000248 | 2000-02-15 | ||
| IT2000MI000248A IT1317834B1 (it) | 2000-02-15 | 2000-02-15 | Fluoropolimeri termoplastici. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001270969A JP2001270969A (ja) | 2001-10-02 |
| JP2001270969A5 true JP2001270969A5 (https=) | 2008-03-27 |
Family
ID=11444015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001037120A Pending JP2001270969A (ja) | 2000-02-15 | 2001-02-14 | 熱可塑性フルオロポリマー |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6569946B2 (https=) |
| EP (1) | EP1130056B1 (https=) |
| JP (1) | JP2001270969A (https=) |
| CA (1) | CA2337453C (https=) |
| DE (1) | DE60122041T2 (https=) |
| IT (1) | IT1317834B1 (https=) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1318709B1 (it) | 2000-09-27 | 2003-08-27 | Ausimont Spa | Composizioni termoplastiche di fluoropolimeri. |
| ITMI20030642A1 (it) * | 2003-04-01 | 2004-10-02 | Solvay Solexis Spa | Composizioni termoprocessabili a base di ctfe |
| US7449111B2 (en) * | 2003-07-30 | 2008-11-11 | Arkema Inc. | Resins containing ionic or ionizable groups with small domain sizes and improved conductivity |
| EP2277675B1 (en) | 2003-08-19 | 2012-04-04 | Solvay Specialty Polymers USA, LLC. | Impact-modified polyamide hollow body |
| CN1308361C (zh) * | 2004-08-09 | 2007-04-04 | 大连振邦氟涂料股份有限公司 | 乙烯－三氟氯乙烯共聚物的制备方法 |
| EP1741729B1 (en) * | 2005-07-07 | 2008-03-12 | Solvay Solexis S.p.A. | Polymerization process |
| WO2008079937A2 (en) * | 2006-12-20 | 2008-07-03 | Honeywell International Inc. | Polymer processing simplification |
| JP5211497B2 (ja) * | 2007-02-02 | 2013-06-12 | ダイキン工業株式会社 | フッ素樹脂組成物及びフッ素樹脂成形体 |
| WO2008153718A1 (en) * | 2007-05-29 | 2008-12-18 | Cdi Seals, Inc. | One-piece blow-molded container with rigid fitment |
| HUE034359T2 (en) * | 2012-12-21 | 2018-02-28 | Solvay Specialty Polymers It | Hydrophilic fluoropolymer |
| US20180022970A1 (en) | 2015-02-11 | 2018-01-25 | Solvay Specialty Polymers Italy S.P.A. | Novel thermoprocessable fluoropolymer |
| SG11201810282SA (en) | 2016-07-04 | 2019-01-30 | Agc Inc | Film and method for its production |
| RU2752168C2 (ru) | 2016-10-05 | 2021-07-23 | Денка Компани Лимитед | Смоляная композиция и мембранная структура, содержащая смоляную композицию |
| CN110669302A (zh) | 2018-07-02 | 2020-01-10 | 清华大学 | 含氟树脂组合物及其制造方法 |
| EP3950806A4 (en) | 2019-03-29 | 2022-05-25 | Denka Company Limited | RESIN COMPOSITION, MOLDING USING SAID RESIN COMPOSITION AND FILM STRUCTURE, BUILDING STRUCTURE AND ADHESIVE MOLDING USING SAID RESIN COMPOSITION OR SAID MOLDING |
| CN113444330B (zh) * | 2021-06-28 | 2023-01-24 | 浙江巨化技术中心有限公司 | 一种聚三氟氯乙烯树脂组合物 |
| WO2025089224A1 (ja) * | 2023-10-23 | 2025-05-01 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59103022A (ja) * | 1982-12-03 | 1984-06-14 | Daido Metal Kogyo Kk | 耐摩耗性にすぐれた軸受材料 |
| JPS59197411A (ja) | 1983-04-25 | 1984-11-09 | Daikin Ind Ltd | エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体 |
| EP0185242A3 (en) | 1984-12-20 | 1986-11-05 | Ausimont, U.S.A. | Copolymers of chlorotrifluoroethylene, ethylene and perfluoroalkylethylenes |
| JPS61152652A (ja) | 1984-12-27 | 1986-07-11 | Daikin Ind Ltd | 含フツ素ジアシルパ−オキサイドおよびその用途 |
| IT1189092B (it) | 1986-04-29 | 1988-01-28 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati |
| IT1204903B (it) | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
| JPS63179950A (ja) * | 1987-01-20 | 1988-07-23 | Nitto Electric Ind Co Ltd | フツ素系樹脂組成物 |
| JPH01292013A (ja) * | 1988-05-19 | 1989-11-24 | Central Glass Co Ltd | 軟質ふっ素樹脂の製造方法 |
| JPH02163148A (ja) * | 1988-09-15 | 1990-06-22 | Ausimont Usa Inc | 改良した安定化したハロ重合体組成物 |
| US5021516A (en) | 1989-06-26 | 1991-06-04 | E. I. Du Pont De Nemours And Company | Poly(perfluoroether)acyl peroxides |
| JP2910220B2 (ja) * | 1990-10-30 | 1999-06-23 | 大日本インキ化学工業株式会社 | フッ素樹脂水性分散体、その製造法、それを含有する樹脂組成物及びその組成物を被覆してなる物品 |
| EP0526216B1 (en) | 1991-08-01 | 1995-12-27 | Kureha Chemical Industry Co., Ltd. | Method of making vinylidene fluoride polymer |
| US5182342A (en) | 1992-02-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon solvents for fluoromonomer polymerization |
| JP3147489B2 (ja) * | 1992-04-22 | 2001-03-19 | ジェイエスアール株式会社 | 重合体粒子の水性分散体 |
| US5453477A (en) | 1992-05-01 | 1995-09-26 | Alliedsignal Inc. | Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite |
| JP3265678B2 (ja) * | 1993-02-12 | 2002-03-11 | ダイキン工業株式会社 | エチレンーテトラフルオロエチレン共重合体多孔膜の製造方法 |
| IT1263955B (it) | 1993-02-23 | 1996-09-05 | Ausimont Spa | Processo di (co) polimerizzazione radicalica di monomeri olefinici fluorurati |
| IT1265067B1 (it) | 1993-05-18 | 1996-10-30 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
| IT1266647B1 (it) | 1993-10-29 | 1997-01-09 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa |
| IT1271622B (it) | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
| IT1271621B (it) | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo per la preparazione di fluoropolimeri termoplastici contenenti idrogeno |
| IT1274711B (it) | 1994-08-04 | 1997-07-24 | Ausimont Spa | Processo per la preparazione di fluoropolimeri contenenti idrogeno tramite (co)polimerizzazione in sospensione |
| IT1272861B (it) | 1995-01-04 | 1997-07-01 | Ausimont Spa | Copolimeri dell'etilene con tetrafluoroetilene e/o clorotrifluoroetilene,aventi migliorate proprieta' meccaniche alle alte temperature |
| US5770819A (en) * | 1995-02-13 | 1998-06-23 | Raychem Corporation | Insulated wire or cable having foamed fluoropolymer insulation |
| IT1290426B1 (it) * | 1997-03-21 | 1998-12-03 | Ausimont Spa | Polimeri fluorurati termoprocessabili |
| IT1301451B1 (it) | 1998-06-04 | 2000-06-13 | Ausimont Spa | Copolimeri del clorotrifluoroetilene |
| CN1152894C (zh) * | 1998-07-07 | 2004-06-09 | 大金工业株式会社 | 含氟聚合物的制造方法 |
| JP2000290396A (ja) * | 1999-04-07 | 2000-10-17 | Toagosei Co Ltd | 含フッ素フィルム |
| ITMI991515A1 (it) | 1999-07-09 | 2001-01-09 | Ausimont Spa | Co polimeri peralogenati termoprocessabili del clorotrifluoroetilene |
| ITMI991514A1 (it) | 1999-07-09 | 2001-01-09 | Ausimont Spa | Co polimeri peralogenati termoprocessabili del clorotrifluoroetilene |
| ITMI991516A1 (it) | 1999-07-09 | 2001-01-09 | Ausimont Spa | Sintesi dei copolimeri peralogenati termoprocesabili del clorotrifluoroetilene |
| IT1317833B1 (it) * | 2000-02-15 | 2003-07-15 | Ausimont Spa | Polimeri fluorurati termoprocessabili. |
-
2000
- 2000-02-15 IT IT2000MI000248A patent/IT1317834B1/it active
-
2001
- 2001-01-26 DE DE60122041T patent/DE60122041T2/de not_active Expired - Lifetime
- 2001-01-26 EP EP01101785A patent/EP1130056B1/en not_active Expired - Lifetime
- 2001-02-13 US US09/781,210 patent/US6569946B2/en not_active Expired - Lifetime
- 2001-02-14 JP JP2001037120A patent/JP2001270969A/ja active Pending
- 2001-02-15 CA CA2337453A patent/CA2337453C/en not_active Expired - Fee Related
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