ITMI981134A1 - Oligomeri a blocchi contenenti 1-idrocarbilossi-2,2,6,6-tetrametil-4 piperidil gruppi come stabilizzanti per materiali organici - Google Patents

Info

Publication number

ITMI981134A1

ITMI981134A1 IT98MI001134A ITMI981134A ITMI981134A1 IT MI981134 A1 ITMI981134 A1 IT MI981134A1 IT 98MI001134 A IT98MI001134 A IT 98MI001134A IT MI981134 A ITMI981134 A IT MI981134A IT MI981134 A1 ITMI981134 A1 IT MI981134A1

Authority

IT

Italy

Prior art keywords

formula

substituted

c4alkyl

compound

unsubstituted

Prior art date

1997-05-27

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• -1 PIPERIDYL GROUPS Chemical group 0.000 title claims description 155
• 239000011368 organic material Substances 0.000 title claims description 16
• 239000003381 stabilizer Substances 0.000 title description 10
• 150000001875 compounds Chemical class 0.000 claims description 136
• 239000000203 mixture Substances 0.000 claims description 108
• 229910052739 hydrogen Inorganic materials 0.000 claims description 35
• 239000001257 hydrogen Substances 0.000 claims description 34
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 33
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 29
• 150000002431 hydrogen Chemical class 0.000 claims description 27
• 238000000034 method Methods 0.000 claims description 22
• 238000006243 chemical reaction Methods 0.000 claims description 18
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 18
• 239000004743 Polypropylene Substances 0.000 claims description 17
• 125000000217 alkyl group Chemical group 0.000 claims description 16
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 15
• 229920001155 polypropylene Polymers 0.000 claims description 13
• 239000003960 organic solvent Substances 0.000 claims description 12
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 12
• 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 11
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
• 150000007529 inorganic bases Chemical class 0.000 claims description 10
• 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 10
• 239000000463 material Substances 0.000 claims description 9
• 239000004698 Polyethylene Substances 0.000 claims description 8
• 125000004432 carbon atom Chemical group C* 0.000 claims description 8
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
• 229920000573 polyethylene Polymers 0.000 claims description 8
• 239000004215 Carbon black (E152) Substances 0.000 claims description 7
• 230000015556 catabolic process Effects 0.000 claims description 7
• 238000006731 degradation reaction Methods 0.000 claims description 7
• 229930195733 hydrocarbon Natural products 0.000 claims description 7
• 230000003647 oxidation Effects 0.000 claims description 7
• 238000007254 oxidation reaction Methods 0.000 claims description 7
• 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims description 6
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
• 229920001059 synthetic polymer Polymers 0.000 claims description 6
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 5
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
• 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims description 4
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
• 125000003545 alkoxy group Chemical group 0.000 claims description 3
• 125000002619 bicyclic group Chemical group 0.000 claims description 3
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• 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
• 238000004519 manufacturing process Methods 0.000 claims description 3
• 230000000087 stabilizing effect Effects 0.000 claims description 3
• 125000006645 (C3-C4) cycloalkyl group Chemical group 0.000 claims description 2
• 125000002947 alkylene group Chemical group 0.000 claims description 2
• JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical group CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 2
• 125000006526 (C1-C2) alkyl group Chemical group 0.000 claims 1
• 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
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• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
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• 238000003756 stirring Methods 0.000 description 6
• KMEUSKGEUADGET-UHFFFAOYSA-N 1-hydroxy-2,2,6,6-tetramethylpiperidin-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)N1O KMEUSKGEUADGET-UHFFFAOYSA-N 0.000 description 5
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• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
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