HUP9901881A2 - Eljárás karbonilező katalizátoroldat hatékonyságának javítására, valamint metanol javított karbinilezésére - Google Patents
Eljárás karbonilező katalizátoroldat hatékonyságának javítására, valamint metanol javított karbinilezéséreInfo
- Publication number
- HUP9901881A2 HUP9901881A2 HU9901881A HUP9901881A HUP9901881A2 HU P9901881 A2 HUP9901881 A2 HU P9901881A2 HU 9901881 A HU9901881 A HU 9901881A HU P9901881 A HUP9901881 A HU P9901881A HU P9901881 A2 HUP9901881 A2 HU P9901881A2
- Authority
- HU
- Hungary
- Prior art keywords
- carbonylation
- catalyst solution
- improved
- metal impurities
- methanol
- Prior art date
Links
- 230000006315 carbonylation Effects 0.000 title abstract 5
- 238000005810 carbonylation reaction Methods 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000012535 impurity Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 238000000855 fermentation Methods 0.000 abstract 1
- 230000004151 fermentation Effects 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
A találmány szerinti, kis víztartalmú reakcióközegben használt,ródiűmőt, alkálifémet és kőrrődált fémszennyeződéseket tartalmazókarbőnilezőkatalizátőr-őldat hatékőnyságának javítására szőlgálóeljárás sőrán a karbőnilezőkatalizátőr-őldatőt iőncserélő gyantával ésvízzel érintkeztetik, ahől az érintkeztetés sőrán a katalizátőrőldatvíztartalmát a 0,25-50 tömeg% tartőmányban tartják, majd csökkentettmennyiségű fémszennyeződéseket tartalmazó katalizátőrőldatőt nyernekki. A találmány tárgyköréhez tartőzik tővábbá eljárás metanől javítőttkarbőnilezésére ecetsavvá, amelynek sőrán a kőrrődáltfémszennyeződéseket eltávőlítják. ŕ
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US54960995A | 1995-10-27 | 1995-10-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP9901881A2 true HUP9901881A2 (hu) | 1999-09-28 |
HUP9901881A3 HUP9901881A3 (en) | 1999-12-28 |
Family
ID=24193714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU9901881A HUP9901881A3 (en) | 1995-10-27 | 1996-10-16 | Process for improving productivity of a carbonylation catalyst solution and improved carbonylation of methanol |
Country Status (27)
Country | Link |
---|---|
US (1) | US5731252A (hu) |
EP (1) | EP0920407B1 (hu) |
JP (1) | JP3955326B2 (hu) |
KR (1) | KR100462697B1 (hu) |
CN (1) | CN1092179C (hu) |
AR (1) | AR004107A1 (hu) |
AT (1) | ATE229493T1 (hu) |
AU (1) | AU702225B2 (hu) |
BR (1) | BR9611164A (hu) |
CA (1) | CA2234853C (hu) |
CZ (1) | CZ297265B6 (hu) |
DE (1) | DE69625385T2 (hu) |
ES (1) | ES2185809T3 (hu) |
HU (1) | HUP9901881A3 (hu) |
IN (1) | IN189249B (hu) |
MY (1) | MY112995A (hu) |
NO (1) | NO309858B1 (hu) |
NZ (1) | NZ321758A (hu) |
PL (1) | PL185073B1 (hu) |
RU (1) | RU2156656C2 (hu) |
SA (1) | SA96170479B1 (hu) |
TR (1) | TR199800738T2 (hu) |
TW (1) | TW419393B (hu) |
UA (1) | UA48988C2 (hu) |
WO (1) | WO1997015544A1 (hu) |
YU (1) | YU49355B (hu) |
ZA (1) | ZA968942B (hu) |
Families Citing this family (61)
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GB0410289D0 (en) | 2004-05-07 | 2004-06-09 | Bp Chem Int Ltd | Process |
US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
US7790920B2 (en) * | 2008-09-11 | 2010-09-07 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US9024083B2 (en) | 2010-07-09 | 2015-05-05 | Celanese International Corporation | Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed |
WO2012148509A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
US8378141B2 (en) | 2010-08-16 | 2013-02-19 | Celanese International Corporation | Process and system for supplying vapor from drying column to light ends column |
US8530696B2 (en) | 2010-09-24 | 2013-09-10 | Celanese International Corporation | Pump around reactor for production of acetic acid |
US8877963B2 (en) | 2010-09-28 | 2014-11-04 | Celanese International Corporation | Production of acetic acid with high conversion rate |
US8394988B2 (en) | 2010-09-28 | 2013-03-12 | Celanese International Corporation | Production of acetic acid with high conversion rate |
US8461379B2 (en) | 2010-10-12 | 2013-06-11 | Celanese International Corporation | Production of acetic acid comprising feeding at least one reactant to a recycle stream |
US8637698B2 (en) | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
US8563773B2 (en) | 2010-12-16 | 2013-10-22 | Celanese International Corporation | Eductor-based reactor and pump around loops for production of acetic acid |
CN103298860B (zh) | 2010-12-30 | 2016-03-30 | 国际人造丝公司 | 乙酸产物流的纯化 |
US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
US8884081B2 (en) | 2011-04-26 | 2014-11-11 | Celanese International Corporation | Integrated process for producing acetic acid and alcohol |
US8686199B2 (en) | 2011-04-26 | 2014-04-01 | Celanese International Corporation | Process for reducing the concentration of acetic acid in a crude alcohol product |
US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
US8697908B2 (en) | 2011-05-05 | 2014-04-15 | Celanese International Corporation | Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants |
US8952196B2 (en) | 2011-05-05 | 2015-02-10 | Celanese International Corporation | Removal of aromatics from carbonylation process |
KR20140028072A (ko) | 2011-05-13 | 2014-03-07 | 노보머, 인코포레이티드 | 촉매적 카르보닐화 촉매 및 방법 |
US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
US9663437B2 (en) | 2011-09-13 | 2017-05-30 | Celanese International Corporation | Production of acetic acid with high conversion rate |
US8614359B2 (en) | 2011-11-09 | 2013-12-24 | Celanese International Corporation | Integrated acid and alcohol production process |
US8686201B2 (en) | 2011-11-09 | 2014-04-01 | Celanese International Corporation | Integrated acid and alcohol production process having flashing to recover acid production catalyst |
SG192556A1 (en) | 2012-02-08 | 2013-09-30 | Celanese Int Corp | Production of acetic acid with high conversion rate |
US10858329B2 (en) | 2014-05-05 | 2020-12-08 | Novomer, Inc. | Catalyst recycle methods |
US10597294B2 (en) | 2014-05-30 | 2020-03-24 | Novomer, Inc. | Integrated methods for chemical synthesis |
JP6670011B2 (ja) | 2014-07-25 | 2020-03-18 | ノボマー, インコーポレイテッド | 金属錯体の合成およびその使用 |
RS59574B1 (sr) | 2014-10-02 | 2019-12-31 | Celanese Int Corp | Proces za proizvodnju sirćetne kiseline |
US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
ES2833013T3 (es) * | 2014-11-14 | 2021-06-14 | Celanese Int Corp | Procesos para mejorar el rendimiento del ácido acético mediante la eliminación de hierro |
US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
SG11201706008YA (en) | 2015-01-30 | 2017-08-30 | Celanese Int Corp | Processes for producing acetic acid |
US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
WO2016122727A1 (en) | 2015-01-30 | 2016-08-04 | Celanese International Corporation | Processes for producing acetic acid |
US9540302B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
US9512056B2 (en) | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
MA41510A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de production d'acide acrylique |
WO2016130998A1 (en) | 2015-02-13 | 2016-08-18 | Novomer, Inc. | Continuous carbonylation processes |
MA41513A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de distillation pour la production d'acide acrylique |
MA41514A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédés intégrés de synthèse chimique |
US9540303B2 (en) * | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
RS63644B1 (sr) | 2015-10-02 | 2022-10-31 | Celanese Int Corp | Postupak za proizvodnju sirćetne kiseline recikliranjem vode |
US9957216B2 (en) * | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
US10807935B2 (en) | 2018-11-02 | 2020-10-20 | Celanese International Corporation | Process for continuous acetic acid production |
CN110078612B (zh) * | 2019-06-06 | 2021-09-07 | 上海华谊(集团)公司 | 催化剂循环液的纯化方法 |
US20230127564A1 (en) | 2020-04-01 | 2023-04-27 | Celanese International Corporation | Processes for removing and/or reducing permanganate reducing compounds and alkyl iodides |
KR20230019135A (ko) | 2020-06-03 | 2023-02-07 | 셀라니즈 인터내셔날 코포레이션 | 공정 스트림으로부터 아세탈의 제거 |
MX2022015384A (es) | 2020-06-03 | 2023-01-16 | Celanese Int Corp | Proceso para la produccion de acido acetico mediante la eliminacion de compuestos reductores de permanganato. |
WO2021247854A1 (en) | 2020-06-03 | 2021-12-09 | Celanese International Corporation | Production and purification of acetic acid |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3769329A (en) * | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
US4007130A (en) * | 1975-12-29 | 1977-02-08 | Monsanto Company | Catalyst regeneration method |
US4792620A (en) * | 1983-10-14 | 1988-12-20 | Bp Chemicals Limited | Carbonylation catalysts |
CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
US5001259A (en) * | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
US4894477A (en) * | 1986-10-14 | 1990-01-16 | Hoechst Celanese Corporation | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
DE4034501A1 (de) * | 1990-10-30 | 1992-05-07 | Hoechst Ag | Verfahren zur entfernung metallischer korrosionsprodukte aus wasserfrei betriebenen carbonylierungsreaktionen |
GB9305902D0 (en) * | 1993-03-22 | 1993-05-12 | Bp Chem Int Ltd | Process |
-
1996
- 1996-10-16 AU AU75169/96A patent/AU702225B2/en not_active Ceased
- 1996-10-16 JP JP51665097A patent/JP3955326B2/ja not_active Expired - Lifetime
- 1996-10-16 IN IN1828CA1996 patent/IN189249B/en unknown
- 1996-10-16 RU RU98110138/04A patent/RU2156656C2/ru not_active IP Right Cessation
- 1996-10-16 CN CN96197834A patent/CN1092179C/zh not_active Expired - Fee Related
- 1996-10-16 CZ CZ0127998A patent/CZ297265B6/cs not_active IP Right Cessation
- 1996-10-16 KR KR10-1998-0703005A patent/KR100462697B1/ko not_active IP Right Cessation
- 1996-10-16 EP EP96937688A patent/EP0920407B1/en not_active Expired - Lifetime
- 1996-10-16 HU HU9901881A patent/HUP9901881A3/hu unknown
- 1996-10-16 CA CA002234853A patent/CA2234853C/en not_active Expired - Fee Related
- 1996-10-16 UA UA98042072A patent/UA48988C2/uk unknown
- 1996-10-16 NZ NZ321758A patent/NZ321758A/xx not_active IP Right Cessation
- 1996-10-16 ES ES96937688T patent/ES2185809T3/es not_active Expired - Lifetime
- 1996-10-16 WO PCT/US1996/016516 patent/WO1997015544A1/en active IP Right Grant
- 1996-10-16 DE DE69625385T patent/DE69625385T2/de not_active Expired - Lifetime
- 1996-10-16 PL PL96326360A patent/PL185073B1/pl not_active IP Right Cessation
- 1996-10-16 TR TR1998/00738T patent/TR199800738T2/xx unknown
- 1996-10-16 BR BR9611164A patent/BR9611164A/pt not_active IP Right Cessation
- 1996-10-16 AT AT96937688T patent/ATE229493T1/de active
- 1996-10-24 ZA ZA9608942A patent/ZA968942B/xx unknown
- 1996-10-25 YU YU56496A patent/YU49355B/sh unknown
- 1996-10-25 AR ARP960104911A patent/AR004107A1/es unknown
- 1996-10-25 MY MYPI96004456A patent/MY112995A/en unknown
- 1996-10-29 TW TW085113196A patent/TW419393B/zh not_active IP Right Cessation
- 1996-12-08 SA SA96170479A patent/SA96170479B1/ar unknown
-
1997
- 1997-01-21 US US08/786,016 patent/US5731252A/en not_active Expired - Lifetime
-
1998
- 1998-04-27 NO NO981887A patent/NO309858B1/no not_active IP Right Cessation
Also Published As
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