ES8707487A1 - Un procedimiento mejorado para obtener acido acetico (como divisional de la solicitud de patente de invencion no. 542.724 presentada el 30-4-85) - Google Patents
Un procedimiento mejorado para obtener acido acetico (como divisional de la solicitud de patente de invencion no. 542.724 presentada el 30-4-85)Info
- Publication number
- ES8707487A1 ES8707487A1 ES551313A ES551313A ES8707487A1 ES 8707487 A1 ES8707487 A1 ES 8707487A1 ES 551313 A ES551313 A ES 551313A ES 551313 A ES551313 A ES 551313A ES 8707487 A1 ES8707487 A1 ES 8707487A1
- Authority
- ES
- Spain
- Prior art keywords
- iodide
- reaction medium
- water content
- catalyst
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE ACIDO ACETICO. CONSISTE EN HACER REACCIONAR METANOL CON MONOXIDO DE CARBONO EN UN MEDIO LIQUIDO DE REACCION QUE CONTIENE UN CATALIZADOR DE RODIO EN CONCENTRACION CATALITICAMENTE EFICAZ. EL MEDIO LIQUIDO ESTA FORMADO POR AGUA, ACIDO ACETICO, YODURO DE METILO Y ACETATO DE METILO. MIENTRAS DURA LA REACCION SE MANTIENE EN EL MEDIO DE REACCION, ALREDEDOR DE UN 1 A UN 4% EN PESO DE AGUA, ENTRE UN 10 Y UN 20% EN PESO DE YODURO DE LITIO, ENTRE UN 2 A UN 5% EN PASO DE ACETATO DE METILO, Y ENTRE UN 14 Y UN 16% EN PESO DE YODURO DE METILO, SIENDO EL RESTO ESENCIALMENTE ACIDO ACETICO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60673084A | 1984-05-03 | 1984-05-03 | |
US69952585A | 1985-02-08 | 1985-02-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8707487A1 true ES8707487A1 (es) | 1987-08-01 |
ES551313A0 ES551313A0 (es) | 1987-08-01 |
Family
ID=27085322
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES542724A Expired ES8700648A1 (es) | 1984-05-03 | 1985-04-30 | Un procedimiento mejorado para obtener acido acetico. |
ES551312A Expired ES8707486A1 (es) | 1984-05-03 | 1986-01-28 | Un procedimiento mejorado para obtener acido acetico (como divisional de la solicitud de patente de invencion no. 542.724 presentada el 30-4-85) |
ES551313A Expired ES8707487A1 (es) | 1984-05-03 | 1986-01-28 | Un procedimiento mejorado para obtener acido acetico (como divisional de la solicitud de patente de invencion no. 542.724 presentada el 30-4-85) |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES542724A Expired ES8700648A1 (es) | 1984-05-03 | 1985-04-30 | Un procedimiento mejorado para obtener acido acetico. |
ES551312A Expired ES8707486A1 (es) | 1984-05-03 | 1986-01-28 | Un procedimiento mejorado para obtener acido acetico (como divisional de la solicitud de patente de invencion no. 542.724 presentada el 30-4-85) |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0161874B2 (es) |
JP (1) | JPH0723337B2 (es) |
KR (1) | KR920005954B1 (es) |
AU (1) | AU579627B2 (es) |
BR (1) | BR8502121A (es) |
CA (1) | CA1228867A (es) |
DE (1) | DE3573109D1 (es) |
ES (3) | ES8700648A1 (es) |
HK (1) | HK51992A (es) |
NO (1) | NO161734C (es) |
NZ (1) | NZ211959A (es) |
SG (1) | SG50292G (es) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4628041A (en) * | 1986-02-10 | 1986-12-09 | Celanese Corporation | Rhodium and iodine recovery method |
CA1299195C (en) * | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
US4894477A (en) * | 1986-10-14 | 1990-01-16 | Hoechst Celanese Corporation | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
GB8904125D0 (en) * | 1989-02-23 | 1989-04-05 | British Petroleum Co Plc | Process for preparing carboxylic acids |
US5442107A (en) * | 1989-04-06 | 1995-08-15 | Bp Chemicals Limited | Preparing carboxylic acids |
EP0391680B1 (en) * | 1989-04-06 | 1994-06-15 | BP Chemicals Limited | Process for preparing carboxylic acids |
GB9021454D0 (en) * | 1990-10-03 | 1990-11-14 | Bp Chem Int Ltd | Process |
AU8790391A (en) | 1990-11-19 | 1992-05-21 | Hoechst Celanese Corporation | Removal of carbonyl impurities from a carbonylation process stream |
GB9106298D0 (en) * | 1991-03-25 | 1991-05-08 | Bp Chem Int Ltd | Process |
GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
US5281359A (en) * | 1992-08-31 | 1994-01-25 | Hoechst Celanese Corporation | Polymeric carbonylation catalyst system |
GB9305902D0 (en) * | 1993-03-22 | 1993-05-12 | Bp Chem Int Ltd | Process |
US5352415A (en) * | 1993-09-29 | 1994-10-04 | Hoechst Celanese Corporation | Control system for acetic acid manufacturing process |
JP3308392B2 (ja) | 1994-06-02 | 2002-07-29 | ダイセル化学工業株式会社 | カルボニル化反応方法 |
US5599976A (en) * | 1995-04-07 | 1997-02-04 | Hoechst Celanese Corporation | Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process |
US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
US5783731A (en) * | 1995-09-11 | 1998-07-21 | Hoechst Celanese Corporation | Removal of carbonyl impurities from a carbonylation process stream |
AU702225B2 (en) * | 1995-10-27 | 1999-02-18 | Hoechst Celanese Corporation | Process for improving productivity of a carbonylation catalyst solution by removing corrosion metals |
US6339171B1 (en) | 1996-10-18 | 2002-01-15 | Celanese International Corporation | Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream |
IN192600B (es) * | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
GB9625335D0 (en) * | 1996-12-05 | 1997-01-22 | Bp Chem Int Ltd | Process |
US6066762A (en) * | 1996-12-30 | 2000-05-23 | Chiyoda Corporation | Process for the production of carbonyl compound |
ES2216385T3 (es) | 1998-08-06 | 2004-10-16 | Haldor Topsoe A/S | Proceso de destilacion reactiva de acido acetico basado en la carbonilacion de dme/metanol. |
GB9825424D0 (en) * | 1998-11-19 | 1999-01-13 | Bp Chem Int Ltd | Process |
US6323364B1 (en) | 1999-08-31 | 2001-11-27 | Celanese International Corporation | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
FR2826960B1 (fr) * | 2001-07-03 | 2005-10-21 | Acetex Chimie | Procede de controle d'une production d'acide acetique et/ou d'acetate de methyle en continu |
GB0213485D0 (en) * | 2002-06-12 | 2002-07-24 | Bp Chem Int Ltd | Process |
US7005541B2 (en) * | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
US7271293B2 (en) | 2004-03-02 | 2007-09-18 | Celanese International Corporation | Control method for process of removing permanganate reducing compounds from methanol carbonylation process |
US7223883B2 (en) | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
US7223886B2 (en) | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
JP4657632B2 (ja) * | 2004-05-27 | 2011-03-23 | ダイセル化学工業株式会社 | カルボン酸の製造方法 |
GB0427821D0 (en) * | 2004-12-17 | 2005-01-19 | Bp Chem Int Ltd | Catalyst and process |
JP5075336B2 (ja) | 2004-12-20 | 2012-11-21 | 株式会社ダイセル | 酢酸の製造方法 |
JP4526381B2 (ja) | 2004-12-27 | 2010-08-18 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
US7053241B1 (en) | 2005-02-24 | 2006-05-30 | Celanese International Corporation | Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer |
US7855306B2 (en) | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
TWI465424B (zh) | 2006-03-21 | 2014-12-21 | Bp Chem Int Ltd | 製造醋酸的方法 |
CN104529701A (zh) | 2006-04-14 | 2015-04-22 | 塞拉尼斯国际公司 | 降低目标流中的醛浓度的方法 |
EP2684871B1 (en) | 2006-12-19 | 2016-05-04 | F. Hoffmann-La Roche AG | Heteroaryl pyrrolidinyl and piperidinyl ketone derivatives |
US7989659B2 (en) * | 2007-05-17 | 2011-08-02 | Celanese International Corporation | Method and apparatus for making acetic acid with improved light ends column productivity |
US7619113B2 (en) * | 2007-09-27 | 2009-11-17 | Celanese International Corporation | Method and apparatus for making acetic acid with improved purification |
US7902397B2 (en) * | 2007-10-11 | 2011-03-08 | Celanese International Corporation | Method and apparatus for making acetic acid with improved productivity |
EP2093209A1 (en) | 2008-02-19 | 2009-08-26 | BP Chemicals Limited | Process for the production of acetic acid |
US7884237B2 (en) | 2008-11-07 | 2011-02-08 | Celanese International Corp. | Methanol carbonylation with improved aldehyde removal |
US8168822B2 (en) | 2009-07-07 | 2012-05-01 | Celanese International Corporation | Acetic acid production by way of carbonylation with enhanced reaction and flashing |
US8455685B2 (en) | 2009-07-07 | 2013-06-04 | Celanese International Corporation | Acetic anhydride production by way of carbonylation with enhanced reaction and flashing |
CN105111067B (zh) | 2010-05-18 | 2018-02-06 | 国际人造丝公司 | 通过除去高锰酸盐还原化合物纯化乙酸物流的方法 |
DE102010040921A1 (de) | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure |
US8952196B2 (en) * | 2011-05-05 | 2015-02-10 | Celanese International Corporation | Removal of aromatics from carbonylation process |
BR112014014610A2 (pt) * | 2011-12-16 | 2017-06-13 | Celanese Int Corp | produção de ácido acético com estabilidade de catalisador aprimorada |
US20140121403A1 (en) | 2012-10-31 | 2014-05-01 | Celanese International Corporation | Integrated Process for the Production of Acrylic Acids and Acrylates |
US9120743B2 (en) | 2013-06-27 | 2015-09-01 | Celanese International Corporation | Integrated process for the production of acrylic acids and acrylates |
CN106715379B (zh) | 2014-10-02 | 2020-05-19 | 国际人造丝公司 | 用于生产乙酸的方法 |
RS60539B1 (sr) | 2014-11-14 | 2020-08-31 | Celanese Int Corp | Postupci za proizvodnju sirćetne kiseline iz reakcionog medijuma koji ima nizak sadržaj etil jodida |
SG10201802742TA (en) * | 2014-11-14 | 2018-05-30 | Celanese Int Corp | Process for producing acetic acid by introducing a lithium compound |
CN107207391B (zh) | 2015-01-30 | 2020-11-06 | 国际人造丝公司 | 生产乙酸的方法 |
US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
MY181742A (en) | 2015-01-30 | 2021-01-06 | Celanese Int Corp | Processes for producing acetic acid |
US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
US9512056B2 (en) | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
GB202005016D0 (en) | 2020-04-06 | 2020-05-20 | Bp Chem Int Ltd | Process for producing acetic acid |
GB202014657D0 (en) | 2020-09-17 | 2020-11-04 | Bp Chem Int Ltd | Processes and apparatuses for treating offgas in an acetic acid production unit |
GB202015835D0 (en) | 2020-10-06 | 2020-11-18 | Bp Chem Int Ltd | Processes and apparatuses for distillation of an acetic acid and propionic acid-containing stream in an acetic acid production unit |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1953905A (en) * | 1931-06-20 | 1934-04-03 | Atmospheric Nitrogen Corp | Preparation of acetic acid |
SE364255B (es) * | 1967-04-05 | 1974-02-18 | Monsanto Co | |
US3769329A (en) * | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
US4356320A (en) * | 1976-11-08 | 1982-10-26 | The Halcon Sd Group, Inc. | Preparation of carboxylic acids |
JPS5466614A (en) * | 1977-11-01 | 1979-05-29 | Mitsubishi Gas Chem Co Inc | Preparation of carboxylic acid or its ester |
FR2440349A1 (fr) * | 1978-10-31 | 1980-05-30 | Rhone Poulenc Ind | Procede de preparation de l'acide acetique ou de ses melanges avec l'acetate de methyle |
US4241219A (en) * | 1979-07-30 | 1980-12-23 | Halcon Research And Development Corp. | Treatment of carbonylation effluent |
US4374070A (en) * | 1980-11-21 | 1983-02-15 | Eastman Kodak Company | Preparation of acetic anhydride |
JPS57134436A (en) * | 1980-12-29 | 1982-08-19 | Monsanto Co | Stabilization of carbonylation catalyst |
DE3377125D1 (en) * | 1982-03-30 | 1988-07-28 | Shell Int Research | A process for carbonylating methanol to acetic acid and/or methyl acetate |
JPS6054334A (ja) * | 1983-09-02 | 1985-03-28 | Daicel Chem Ind Ltd | カルボン酸の製造法 |
CA1231965A (en) * | 1983-12-02 | 1988-01-26 | David J. Schreck | Synergistic production of carboxylic acids from alcohols |
-
1985
- 1985-04-18 CA CA000479440A patent/CA1228867A/en not_active Expired
- 1985-04-30 ES ES542724A patent/ES8700648A1/es not_active Expired
- 1985-05-02 NZ NZ211959A patent/NZ211959A/en unknown
- 1985-05-02 EP EP85303127A patent/EP0161874B2/en not_active Expired - Lifetime
- 1985-05-02 KR KR1019850002987A patent/KR920005954B1/ko not_active IP Right Cessation
- 1985-05-02 NO NO851759A patent/NO161734C/no not_active IP Right Cessation
- 1985-05-02 JP JP60093953A patent/JPH0723337B2/ja not_active Expired - Lifetime
- 1985-05-02 DE DE8585303127T patent/DE3573109D1/de not_active Expired
- 1985-05-03 BR BR8502121A patent/BR8502121A/pt not_active IP Right Cessation
- 1985-05-03 AU AU41952/85A patent/AU579627B2/en not_active Expired
-
1986
- 1986-01-28 ES ES551312A patent/ES8707486A1/es not_active Expired
- 1986-01-28 ES ES551313A patent/ES8707487A1/es not_active Expired
-
1992
- 1992-05-05 SG SG502/92A patent/SG50292G/en unknown
- 1992-07-16 HK HK519/92A patent/HK51992A/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ES551312A0 (es) | 1987-08-01 |
AU579627B2 (en) | 1988-12-01 |
ES8700648A1 (es) | 1986-10-16 |
DE3573109D1 (en) | 1989-10-26 |
EP0161874A1 (en) | 1985-11-21 |
EP0161874B2 (en) | 1992-07-01 |
NO161734C (no) | 1989-09-20 |
JPS60239434A (ja) | 1985-11-28 |
HK51992A (en) | 1992-07-24 |
NZ211959A (en) | 1987-08-31 |
CA1228867A (en) | 1987-11-03 |
AU4195285A (en) | 1985-11-07 |
NO161734B (no) | 1989-06-12 |
KR850008482A (ko) | 1985-12-18 |
EP0161874B1 (en) | 1989-09-20 |
KR920005954B1 (ko) | 1992-07-25 |
ES551313A0 (es) | 1987-08-01 |
ES542724A0 (es) | 1986-10-16 |
JPH0723337B2 (ja) | 1995-03-15 |
NO851759L (no) | 1985-11-04 |
ES8707486A1 (es) | 1987-08-01 |
SG50292G (en) | 1993-02-19 |
BR8502121A (pt) | 1986-01-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20070611 |