CA1228867A - Methanol carbonylation process - Google Patents

Methanol carbonylation process

Info

Publication number
CA1228867A
CA1228867A CA000479440A CA479440A CA1228867A CA 1228867 A CA1228867 A CA 1228867A CA 000479440 A CA000479440 A CA 000479440A CA 479440 A CA479440 A CA 479440A CA 1228867 A CA1228867 A CA 1228867A
Authority
CA
Canada
Prior art keywords
iodide
water
acetic acid
reaction medium
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000479440A
Other languages
English (en)
French (fr)
Inventor
G. Paull Torrence
Brad L. Smith
Adolfo Aguilo
James S. Alder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27085322&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1228867(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Celanese Corp filed Critical Celanese Corp
Application granted granted Critical
Publication of CA1228867A publication Critical patent/CA1228867A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CA000479440A 1984-05-03 1985-04-18 Methanol carbonylation process Expired CA1228867A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US60673084A 1984-05-03 1984-05-03
US606,730 1984-05-03
US69952585A 1985-02-08 1985-02-08
US699,525 1985-02-08

Publications (1)

Publication Number Publication Date
CA1228867A true CA1228867A (en) 1987-11-03

Family

ID=27085322

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000479440A Expired CA1228867A (en) 1984-05-03 1985-04-18 Methanol carbonylation process

Country Status (12)

Country Link
EP (1) EP0161874B2 (es)
JP (1) JPH0723337B2 (es)
KR (1) KR920005954B1 (es)
AU (1) AU579627B2 (es)
BR (1) BR8502121A (es)
CA (1) CA1228867A (es)
DE (1) DE3573109D1 (es)
ES (3) ES8700648A1 (es)
HK (1) HK51992A (es)
NO (1) NO161734C (es)
NZ (1) NZ211959A (es)
SG (1) SG50292G (es)

Families Citing this family (68)

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US4628041A (en) * 1986-02-10 1986-12-09 Celanese Corporation Rhodium and iodine recovery method
CA1299195C (en) * 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
US4894477A (en) * 1986-10-14 1990-01-16 Hoechst Celanese Corporation Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid
GB8904125D0 (en) * 1989-02-23 1989-04-05 British Petroleum Co Plc Process for preparing carboxylic acids
ES2055322T3 (es) * 1989-04-06 1994-08-16 Bp Chem Int Ltd Proceso para preparar acidos carboxilicos.
US5442107A (en) * 1989-04-06 1995-08-15 Bp Chemicals Limited Preparing carboxylic acids
GB9021454D0 (en) * 1990-10-03 1990-11-14 Bp Chem Int Ltd Process
AU8790391A (en) 1990-11-19 1992-05-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
GB9106298D0 (en) * 1991-03-25 1991-05-08 Bp Chem Int Ltd Process
GB9211671D0 (en) * 1992-06-02 1992-07-15 Bp Chem Int Ltd Process
US5281359A (en) * 1992-08-31 1994-01-25 Hoechst Celanese Corporation Polymeric carbonylation catalyst system
GB9305902D0 (en) * 1993-03-22 1993-05-12 Bp Chem Int Ltd Process
US5352415A (en) * 1993-09-29 1994-10-04 Hoechst Celanese Corporation Control system for acetic acid manufacturing process
JP3308392B2 (ja) 1994-06-02 2002-07-29 ダイセル化学工業株式会社 カルボニル化反応方法
US5599976A (en) * 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
US5783731A (en) * 1995-09-11 1998-07-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
KR100462697B1 (ko) * 1995-10-27 2005-02-28 씨엔에이 홀딩즈 인코포레이티드 부식금속을제거하여카보닐화촉매용액의생산성을증진시키는방법
US6339171B1 (en) 1996-10-18 2002-01-15 Celanese International Corporation Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream
IN192600B (es) * 1996-10-18 2004-05-08 Hoechst Celanese Corp
GB9625335D0 (en) * 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
US6066762A (en) * 1996-12-30 2000-05-23 Chiyoda Corporation Process for the production of carbonyl compound
EP0978501B9 (en) 1998-08-06 2004-10-06 Haldor Topsoe A/S Acetic acid reactive distillation process based on dme/methanol carbonylation
GB9825424D0 (en) * 1998-11-19 1999-01-13 Bp Chem Int Ltd Process
US6323364B1 (en) * 1999-08-31 2001-11-27 Celanese International Corporation Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile
FR2826960B1 (fr) * 2001-07-03 2005-10-21 Acetex Chimie Procede de controle d'une production d'acide acetique et/ou d'acetate de methyle en continu
GB0213485D0 (en) * 2002-06-12 2002-07-24 Bp Chem Int Ltd Process
US7005541B2 (en) * 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US7271293B2 (en) 2004-03-02 2007-09-18 Celanese International Corporation Control method for process of removing permanganate reducing compounds from methanol carbonylation process
US7223886B2 (en) 2004-03-02 2007-05-29 Celanese International Corporation Removal of permanganate reducing compounds from methanol carbonylation process stream
US7223883B2 (en) 2004-03-02 2007-05-29 Celanese International Corporation Removal of permanganate reducing compounds from methanol carbonylation process stream
JP4657632B2 (ja) * 2004-05-27 2011-03-23 ダイセル化学工業株式会社 カルボン酸の製造方法
GB0427821D0 (en) * 2004-12-17 2005-01-19 Bp Chem Int Ltd Catalyst and process
JP5075336B2 (ja) 2004-12-20 2012-11-21 株式会社ダイセル 酢酸の製造方法
JP4526381B2 (ja) * 2004-12-27 2010-08-18 ダイセル化学工業株式会社 酢酸の製造方法
US7053241B1 (en) 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
US7855306B2 (en) 2005-04-28 2010-12-21 Celanese International Corporation Process for the production of acetic acid
TWI465424B (zh) 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
JP5486299B2 (ja) 2006-04-14 2014-05-07 セラニーズ・インターナショナル・コーポレーション 標的ストリーム中のアルデヒド濃度の低減法
ES2401129T3 (es) 2006-12-19 2013-04-17 F. Hoffmann-La Roche Ag Derivados de heteroaril-pirrolidinil- y -piperidinil-cetona
US7989659B2 (en) * 2007-05-17 2011-08-02 Celanese International Corporation Method and apparatus for making acetic acid with improved light ends column productivity
US7619113B2 (en) * 2007-09-27 2009-11-17 Celanese International Corporation Method and apparatus for making acetic acid with improved purification
US7902397B2 (en) * 2007-10-11 2011-03-08 Celanese International Corporation Method and apparatus for making acetic acid with improved productivity
EP2093209A1 (en) 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
US7884237B2 (en) 2008-11-07 2011-02-08 Celanese International Corp. Methanol carbonylation with improved aldehyde removal
US8455685B2 (en) 2009-07-07 2013-06-04 Celanese International Corporation Acetic anhydride production by way of carbonylation with enhanced reaction and flashing
US8168822B2 (en) 2009-07-07 2012-05-01 Celanese International Corporation Acetic acid production by way of carbonylation with enhanced reaction and flashing
JP5837576B2 (ja) 2010-05-18 2015-12-24 セラニーズ・インターナショナル・コーポレーション 過マンガン酸塩還元性化合物を除去することによって酢酸流を精製する方法
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
US8952196B2 (en) * 2011-05-05 2015-02-10 Celanese International Corporation Removal of aromatics from carbonylation process
SG11201403174RA (en) * 2011-12-16 2014-09-26 Celanese Int Corp Production of acetic acid with enhanced catalyst stability
US20140121403A1 (en) 2012-10-31 2014-05-01 Celanese International Corporation Integrated Process for the Production of Acrylic Acids and Acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
EP3201165B1 (en) 2014-10-02 2019-08-21 Celanese International Corporation Process for producing acetic acid
US9458078B2 (en) 2014-11-14 2016-10-04 Celanese International Corporation Processes for producing acetic acid from a reaction medium having low ethyl iodide content
KR102439539B1 (ko) 2014-11-14 2022-09-01 셀라니즈 인터내셔날 코포레이션 리튬 화합물을 도입하는 것에 의한 아세트산을 제조하기 위한 방법
WO2016122728A1 (en) 2015-01-30 2016-08-04 Celanese International Corporation Processes for producing acetic acid
US9487464B2 (en) 2015-01-30 2016-11-08 Celanese International Corporation Processes for producing acetic acid
US9561994B2 (en) 2015-01-30 2017-02-07 Celanese International Corporation Processes for producing acetic acid
RS59401B1 (sr) 2015-01-30 2019-11-29 Celanese Int Corp Postupci proizvodnje sirćetne kiseline
US9505696B2 (en) 2015-02-04 2016-11-29 Celanese International Corporation Process to control HI concentration in residuum stream
US10413840B2 (en) 2015-02-04 2019-09-17 Celanese International Coporation Process to control HI concentration in residuum stream
US9512056B2 (en) 2015-02-04 2016-12-06 Celanese International Corporation Process to control HI concentration in residuum stream
US9957216B2 (en) 2015-11-13 2018-05-01 Celanese International Corporation Processes for producing acetic acid
US9908835B2 (en) 2015-11-13 2018-03-06 Celanese International Corporation Processes for purifying acetic and hydrating anhydride
GB202005016D0 (en) 2020-04-06 2020-05-20 Bp Chem Int Ltd Process for producing acetic acid
GB202014657D0 (en) 2020-09-17 2020-11-04 Bp Chem Int Ltd Processes and apparatuses for treating offgas in an acetic acid production unit
GB202015835D0 (en) 2020-10-06 2020-11-18 Bp Chem Int Ltd Processes and apparatuses for distillation of an acetic acid and propionic acid-containing stream in an acetic acid production unit

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1953905A (en) * 1931-06-20 1934-04-03 Atmospheric Nitrogen Corp Preparation of acetic acid
SE364255B (es) * 1967-04-05 1974-02-18 Monsanto Co
US3769329A (en) * 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
US4356320A (en) * 1976-11-08 1982-10-26 The Halcon Sd Group, Inc. Preparation of carboxylic acids
JPS5466614A (en) * 1977-11-01 1979-05-29 Mitsubishi Gas Chem Co Inc Preparation of carboxylic acid or its ester
FR2440349A1 (fr) * 1978-10-31 1980-05-30 Rhone Poulenc Ind Procede de preparation de l'acide acetique ou de ses melanges avec l'acetate de methyle
US4241219A (en) * 1979-07-30 1980-12-23 Halcon Research And Development Corp. Treatment of carbonylation effluent
US4374070A (en) * 1980-11-21 1983-02-15 Eastman Kodak Company Preparation of acetic anhydride
JPS57134436A (en) * 1980-12-29 1982-08-19 Monsanto Co Stabilization of carbonylation catalyst
DE3377125D1 (en) * 1982-03-30 1988-07-28 Shell Int Research A process for carbonylating methanol to acetic acid and/or methyl acetate
JPS6054334A (ja) * 1983-09-02 1985-03-28 Daicel Chem Ind Ltd カルボン酸の製造法
CA1231965A (en) * 1983-12-02 1988-01-26 David J. Schreck Synergistic production of carboxylic acids from alcohols

Also Published As

Publication number Publication date
JPH0723337B2 (ja) 1995-03-15
ES551313A0 (es) 1987-08-01
ES8707486A1 (es) 1987-08-01
HK51992A (en) 1992-07-24
NO161734C (no) 1989-09-20
KR850008482A (ko) 1985-12-18
JPS60239434A (ja) 1985-11-28
ES542724A0 (es) 1986-10-16
NO161734B (no) 1989-06-12
DE3573109D1 (en) 1989-10-26
AU4195285A (en) 1985-11-07
ES8700648A1 (es) 1986-10-16
ES551312A0 (es) 1987-08-01
NZ211959A (en) 1987-08-31
EP0161874B1 (en) 1989-09-20
EP0161874A1 (en) 1985-11-21
EP0161874B2 (en) 1992-07-01
AU579627B2 (en) 1988-12-01
NO851759L (no) 1985-11-04
BR8502121A (pt) 1986-01-07
ES8707487A1 (es) 1987-08-01
KR920005954B1 (ko) 1992-07-25
SG50292G (en) 1993-02-19

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Legal Events

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