HUE027182T2 - Katalizátor és egy, a katalizátort alkalmazó gázfázisú eljárás - Google Patents

Katalizátor és egy, a katalizátort alkalmazó gázfázisú eljárás Download PDF

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Publication number
HUE027182T2
HUE027182T2 HUE04818425A HUE04818425A HUE027182T2 HU E027182 T2 HUE027182 T2 HU E027182T2 HU E04818425 A HUE04818425 A HU E04818425A HU E04818425 A HUE04818425 A HU E04818425A HU E027182 T2 HUE027182 T2 HU E027182T2
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HU
Hungary
Prior art keywords
catalyst
alumina
titanium
gas phase
copper
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Application number
HUE04818425A
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English (en)
Inventor
Michel Strebelle
Andre Petitjean
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Solvay
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Application filed by Solvay filed Critical Solvay
Publication of HUE027182T2 publication Critical patent/HUE027182T2/hu

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (7)

  1. Szabodaäins sgveypnnmk f. Katalizátor, amely áktiv elemekei, költik ahant'ouas-o sodra deponál; rezet îarralmaz, ahol az slumi-nium-ojck? egy kilogramm akmdnkinvoxkim számiiva legalább 0.1)1 g mám îattslmaz fém fontsábim kifejelve, és az aiumimmn-oídd adagos r-ás/vvshe-ámséróje 5-200 μη, azzal jellemezve, Hogy a;·: eiumkmsm-oxid ahum-mum-hldm kaiemálásábói keletkezeti, és azzal jellemesve. hogy a mán az nhmknkuri-hhk.it előállításának egytk lépésében lek'hozzáadva*
  2. 2. A? i.
  3. Igénypont szerint- katalizátor, azzal jellemezve. hogy az akammem-osid egy kilogramm aks-mmium-oxkka sxásnitva legfeljebb 15 g mám tartalmaz, fém formájában kifejezve. 5 Az 1 vagy 5. igénypont szem·! kstabzátor, azzal jelkotezve. hogy as. almnmüsm-oxid egy kilogramm simmnkim-oxídra számítva legalább 9,0.5 g titánt r&tiáhnaz, lém tormájában kifejezve,
  4. 4. Az t-3. igénypontok bármelyike szerlral katalizátor, az sál jdkmezve. hogy as aiorniniunv-mod c-.gy kilogramm akmlsium-oxldra számává legfeljebb 5 g titánt táttalmaz, fém fámájában kifejezve.
  5. 5 Az 1-4. igénypontok bármelyike szerinti katalizátor, azzal jellemezve, hogy a résen kívül sáriaknak legalább egy ttsastk aktív elemei is. amely a következők közül van kiválasztva: alkálifémek, alkálishkiiémch, mkatöidíémfá; és a kövadmzőkMí állá fémek csoportja: ntténlum, rêdiorn., palládium., osmium, iridium., platóm és arany
  6. , 6 Az 1-5, igény pool ok bármelyike szerifai katalizátor, azzal jellemezve, hogy a fezen kívüli aktív eleső vagy elemek a következők közéi vatgoaks kiválási va; alkálifémek, alkáli földfémek és ritkaföldfémek.
  7. 7 Az. i-6 igénypontok bármelyike vzerin-s katalizátor, azzal Jellemezve, hogy az aknv elemek a k<f-vétkezők: sóz, m.agnezmm é» legalább egy alkálifém. $> Egy kilogramm almnvk'nma-oxidra számítva, fém tormájában kitetszve legalább 0,05 g titánt tartalmazó, 4-209 μην átlagos resze^vke-átméröjü ahnnmiunvor-bd alkalmazása aki Is- elemeket, köztük rezet tariaima-zo katalizátor hordozójaként. azzal jellemezve, hogy az aiuminmto-oxH- asmnmmm-hidfás kalcinálásábói kelek kezeit, es azzal jellemezve, hogy a után az föuntmmm-hidrát előállításnak egyik lépésében lett hozzáadva. 9 kijárás. .amely magában foglal egy gá?.fazjsú reakesöL azzal jellemezve, hogy s gázfázisú reakc-é }-?. igénypontok bármelyike-szerinti katalizátorral van katalizálva, lö. A 9. igénypont. szerkői eljárás, azzal jeiissnezve, hogy a gázElzisá reakció szénMdíjögén ozkMeíos reakciója, 11. A 9. vagy 10. igényponti szerinti eljárás, azanl jellemezve, hogy a gázfázisú tüskeid !~4 szésnarnntóf tariaimaző szénhidrogén oxikíérozásí reakciója, 12. A $-11. igénypontok bármelyike szerinti eljárás, azzal Jellemezve, hogy a gázfázisú makóié etilén oxikiérozási reakciója I »2-dtklóretánná.
HUE04818425A 2003-11-14 2004-11-12 Katalizátor és egy, a katalizátort alkalmazó gázfázisú eljárás HUE027182T2 (hu)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0313370A FR2862238B1 (fr) 2003-11-14 2003-11-14 Catalyseur a base d'alumine contenant du titane et procede en phase gazeuse utilisant un tel catalyseur
US53958304P 2004-01-29 2004-01-29

Publications (1)

Publication Number Publication Date
HUE027182T2 true HUE027182T2 (hu) 2016-10-28

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Country Link
US (1) US7612244B2 (hu)
EP (2) EP1687084B2 (hu)
JP (1) JP2007511343A (hu)
KR (1) KR101132588B1 (hu)
CN (1) CN1882386B (hu)
AR (1) AR047040A1 (hu)
BR (1) BRPI0416468A (hu)
CA (1) CA2545199A1 (hu)
EA (1) EA011661B1 (hu)
EG (1) EG24286A (hu)
ES (1) ES2566333T5 (hu)
FR (1) FR2862238B1 (hu)
HU (1) HUE027182T2 (hu)
IN (1) IN2006CH01650A (hu)
MX (1) MX264869B (hu)
MY (1) MY178953A (hu)
NO (1) NO20062379L (hu)
PL (1) PL1687084T5 (hu)
TW (2) TWI359695B (hu)
UA (1) UA99090C2 (hu)
WO (1) WO2005046866A2 (hu)

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CA2545199A1 (en) 2005-05-26
JP2007511343A (ja) 2007-05-10
BRPI0416468A (pt) 2007-03-06
EA011661B1 (ru) 2009-04-28
TWI359695B (en) 2012-03-11
MX264869B (en) 2009-03-04
EG24286A (en) 2009-01-05
FR2862238A1 (fr) 2005-05-20
EP2883608A3 (en) 2015-09-09
MY178953A (en) 2020-10-24
EP1687084B2 (en) 2022-03-09
TWI365765B (en) 2012-06-11
EP2883608B1 (en) 2017-08-02
WO2005046866A3 (en) 2005-07-28
CN1882386A (zh) 2006-12-20
FR2862238B1 (fr) 2006-11-17
WO2005046866A2 (en) 2005-05-26
TW200526318A (en) 2005-08-16
CN1882386B (zh) 2011-06-08
ES2566333T5 (es) 2022-05-03
US20070142682A1 (en) 2007-06-21
NO20062379L (no) 2006-05-24
KR101132588B1 (ko) 2012-04-06
US7612244B2 (en) 2009-11-03
EA200600962A1 (ru) 2006-10-27
UA99090C2 (ru) 2012-07-25
MXPA06005401A (es) 2006-07-19
PL1687084T5 (pl) 2023-04-24
PL1687084T3 (pl) 2016-06-30
EP1687084A2 (en) 2006-08-09
AR047040A1 (es) 2006-01-04
EP2883608A2 (en) 2015-06-17
IN2006CH01650A (hu) 2007-06-08
TW200638988A (en) 2006-11-16
EP1687084B1 (en) 2016-01-20
KR20060131750A (ko) 2006-12-20
ES2566333T3 (es) 2016-04-12

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