HRP20191099T1 - Poliamidni pripravci - Google Patents

Poliamidni pripravci Download PDF

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HRP20191099T1
HRP20191099T1 HRP20191099TT HRP20191099T HRP20191099T1 HR P20191099 T1 HRP20191099 T1 HR P20191099T1 HR P20191099T T HRP20191099T T HR P20191099TT HR P20191099 T HRP20191099 T HR P20191099T HR P20191099 T1 HRP20191099 T1 HR P20191099T1
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HRP20191099TT
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Matthias Bienmüller
Jochen Endtner
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Lanxess Deutschland Gmbh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/18—Feeding the material into the injection moulding apparatus, i.e. feeding the non-plastified material into the injection unit
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/04—Extrusion blow-moulding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34928—Salts
    • C—CHEMISTRY; METALLURGY
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
    • B29K2309/08—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/08—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0016—Non-flammable or resistant to heat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
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    • C08K2201/004—Additives being defined by their length
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (16)

1. Pripravci koji sadrže A) najlon-6 ili najlon-6,6, B) najmanje jedan kvarcni prah koji ima d95 u rasponu od 5 do 250 µm određeno laserskom difraktometrijom, C) usitnjena duga staklena vlakna početne duljine u rasponu od 1 do 50 mm, i D) melamin cijanurat.
2. Pripravci prema zahtjevu 1, naznačeni time što oni sadrže A) 5% do 96.9 težinskih % najlona-6 ili najlona-6,6, B) 1% do 60 težinskih % najmanje jednog kvarcnog praha koji ima d95 u rasponu od 5 do 250 µm određeno laserskom difraktometrijom, C) 2% do 8 težinskih % usitnjenih dugih staklenih vlakana početne duljine u rasponu od 1 do 50 mm, i D) 0.1% do 40 težinskih % melamin cijanurata, uz uvjet da je zbroj svih težinskih postotaka uvijek 100.
3. Pripravci prema zahtjevu 1 ili 2, naznačeni time što oni, pored komponenata A), B), C) i D), sadrže također E) 0.01% do 30 težinskih %, u odnosu na ukupni pripravak, titanijevog dioksida, u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
4. Pripravci prema bilo kojem od zahtjeva 1 do 3, naznačeni time što oni, pored komponenata A) do E) ili umjesto E), sadrže također F) 0.01% do 5 težinskih %, u odnosu na ukupni pripravak, najmanje jednog sredstva za podmazivanje i/ili sredstva za odvajanje iz kalupa, u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
5. Pripravci prema bilo kojem od zahtjeva 1 do 4, naznačeni time što, oni pored komponenata A) do F) ili umjesto E) i/ili F), sadrže također G) 0.01% do 10 težinskih %, u odnosu na ukupni pripravak, najmanje jednog laserskog apsorbera odabranog iz skupine koja sadrži antimonov trioksid, kositrov oksid, kositrov ortofosfat, barijev titanat, aluminijev oksid, bakrov hidroksifosfat, bakrov ortofosfat, kalijev bakrov difosfat, bakrov hidroksid, antimonov kositrov oksid, bizmutov trioksid i antrakinon, u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
6. Pripravci prema bilo kojem od zahtjeva 1 do 5, naznačeni time što, oni pored komponenata A) do G) ili umjesto E) i/ili F) i/ili G), sadrže također H) 0.01% do 60 težinskih %, u odnosu na ukupni pripravak, najmanje jednog daljnjeg usporivača gorenja osim melamin cijanurata, u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
7. Pripravci prema zahtjevu 6, naznačeni time što se upotrebljavaju usporivači gorenja bez halogena i/ili bez fosfora.
8. Pripravci prema bilo kojem od zahtjeva 1 do 7, naznačeni time što, oni pored komponenata A) do H) ili umjesto E) i/ili F) i/ili G) i/ili H), sadrže također komponentu K) 0.01% do 50 težinskih %, u odnosu na ukupni pripravak, najmanje jednog punila osim komponenata B) i C), u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
9. Pripravci prema bilo kojem od zahtjeva 1 do 8, naznačeni time što, oni pored komponenata A) do K) ili umjesto komponenata E) i/ili F) i/ili G) i/ili H) i/ili K), sadrže također L) 0.01% do 20 težinskih %, u odnosu na ukupni pripravak, najmanje jedan dodatni aditiv osim komponenata D) do K), u kojem se slučaju razine ostalih komponenti smanjuju do te mjere da je ukupni zbroj svih težinskih postotaka uvijek 100.
10. Pripravci prema bilo kojem od zahtjeva 1 do 9, naznačeni time što se kao komponenta B) koriste mljeveni kvarci prirodnog podrijetla.
11. Pripravci prema zahtjevu 10, naznačeni time što kvarcni prah ima srednju veličinu čestica (d50) u rasponu od 2 µm do 50 µm, određeno laserskom difraktometrijom.
12. Proizvodi, naznačeni time što sadrže pripravak prema bilo kojem od zahtjeva 1 do 11.
13. Uporaba pripravaka prema bilo kojem od zahtjeva 1 do 12 kao pripravaka za oblikovanje u injekcijskom prešanju, uključujući posebne postupke GIT (tehnologija ubrizgavanja plina), WIT (tehnologija ubrizgavanja vode) i PIT (tehnologija ubrizgavanja projektila), u postupcima ekstruzije uključujući i ekstrudiranje profila, ili u injekcijskom puhanju, postupcima 3D ekstruzije injekcijskim puhanjem ili postupcima usisnog injekcijskog puhanja.
14. Postupak za proizvodnju proizvoda, naznačen time što se sljedeće komponente: A) najlon-6 ili najlon-6,6, B) najmanje jedno kvarcno brašno koje ima d95 u rasponu od 5 do 250 µm određeno laserskom difraktometrijom, C) usitnjena duga staklena vlakna početne duljine u rasponu od 1 do 50 mm, i D) melamin cijanurat prvo miješaju u najmanje jednom uređaju za miješanje i navedena smjesa, koja je tada u obliku pripravka za oblikovanje, se ili dovodi kroz najmanje jedan izlaz alata za miješanje u izravnu daljnju obradu ili se ispušta kao nit i reže na pelete željene duljine pomoću granulatora, i pripravci u obliku pripravka za oblikovanje ili peleta se podvrgavaju procesu oblikovanja.
15. Postupak prema zahtjevu 14, naznačen time što su postupci oblikovanja injekcijsko prešanje, uključujući posebne postupke GIT (tehnologija ubrizgavanja plina), WIT (tehnologija ubrizgavanja vode) i PIT (tehnologija ubrizgavanja projektila), postupke ekstruzije, uključujući ekstrudiranje profila, injekcijsko puhanje, postupke 3D ekstruzije injekcijskim puhanjem ili postupke usisnog injekcijskog puhanja.
16. Uporaba kvarcnog brašna dobivenog iz prirodnog kvarca u kombinaciji sa staklenim vlaknima, melamin cijanuratom i po izboru titanijevim dioksidom za poboljšanje svojstava vezanih uz otpornost na toplinu, usporavanje plamena pri ispitivanju žicom prema IEC60695-2-12 i karakteristike izotropnog skupljanja pripravaka bazirane na PA 6 ili PA 66.
HRP20191099TT 2014-10-31 2019-06-18 Poliamidni pripravci HRP20191099T1 (hr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201420008607 DE202014008607U1 (de) 2014-10-31 2014-10-31 Polyamidzusammensetzungen
EP15188081.2A EP3015500B1 (de) 2014-10-31 2015-10-02 Polyamidzusammensetzungen

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US (2) US9969866B2 (hr)
EP (1) EP3015500B1 (hr)
JP (1) JP6096861B2 (hr)
KR (1) KR102357765B1 (hr)
CN (1) CN105566896B (hr)
DE (1) DE202014008607U1 (hr)
ES (1) ES2726678T3 (hr)
HR (1) HRP20191099T1 (hr)
HU (1) HUE045024T2 (hr)
PL (1) PL3015500T3 (hr)
TR (1) TR201908741T4 (hr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2924067A1 (de) 2014-03-26 2015-09-30 LANXESS Deutschland GmbH Polyamidzusammensetzungen
EP2924065A1 (de) 2014-03-26 2015-09-30 LANXESS Deutschland GmbH Polyamidzusammensetzungen
DE202014008607U1 (de) * 2014-10-31 2014-11-24 Lanxess Deutschland Gmbh Polyamidzusammensetzungen
CN104672896B (zh) * 2015-02-09 2018-03-27 杭州鸿雁电器有限公司 一种耐高温型断路器外壳
EP3135707A1 (de) * 2015-08-26 2017-03-01 LANXESS Deutschland GmbH Polyamidzusammensetzungen
WO2018069055A1 (de) 2016-10-13 2018-04-19 Basf Se Flammgeschützte polyamide
CN106633847A (zh) * 2016-11-16 2017-05-10 马鞍山市华能电力线路器材有限责任公司 一种自清洁型塑料电力金具复合材料及其制作方法
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