CN105061887A - 无卤阻燃聚丙烯材料及其制备方法 - Google Patents
无卤阻燃聚丙烯材料及其制备方法 Download PDFInfo
- Publication number
- CN105061887A CN105061887A CN201510422261.7A CN201510422261A CN105061887A CN 105061887 A CN105061887 A CN 105061887A CN 201510422261 A CN201510422261 A CN 201510422261A CN 105061887 A CN105061887 A CN 105061887A
- Authority
- CN
- China
- Prior art keywords
- halogen
- polypropylene material
- flame
- retardant
- free anti
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 54
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 40
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 22
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 10
- 239000001177 diphosphate Substances 0.000 claims description 7
- 235000011180 diphosphates Nutrition 0.000 claims description 7
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 7
- NQQWFVUVBGSGQN-UHFFFAOYSA-N phosphoric acid;piperazine Chemical compound OP(O)(O)=O.C1CNCCN1 NQQWFVUVBGSGQN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920002943 EPDM rubber Polymers 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 2
- MWFNQNPDUTULBC-UHFFFAOYSA-N phosphono dihydrogen phosphate;piperazine Chemical compound C1CNCCN1.OP(O)(=O)OP(O)(O)=O MWFNQNPDUTULBC-UHFFFAOYSA-N 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- PYLQXBCYFPDGBI-UHFFFAOYSA-N Nc1nc(N)nc(N)n1.OCC(CO)(CO)COP(O)(=O)OP(O)(O)=O Chemical compound Nc1nc(N)nc(N)n1.OCC(CO)(CO)COP(O)(=O)OP(O)(O)=O PYLQXBCYFPDGBI-UHFFFAOYSA-N 0.000 abstract 2
- 229910017059 organic montmorillonite Inorganic materials 0.000 abstract 2
- 238000003795 desorption Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000009156 water cure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92209—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510422261.7A CN105061887B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料及其制备方法 |
CN201710265390.9A CN107216542B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510422261.7A CN105061887B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料及其制备方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710265390.9A Division CN107216542B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105061887A true CN105061887A (zh) | 2015-11-18 |
CN105061887B CN105061887B (zh) | 2017-06-13 |
Family
ID=54491425
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510422261.7A Active CN105061887B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料及其制备方法 |
CN201710265390.9A Active CN107216542B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710265390.9A Active CN107216542B (zh) | 2015-07-17 | 2015-07-17 | 无卤阻燃聚丙烯材料 |
Country Status (1)
Country | Link |
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CN (2) | CN105061887B (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106084484A (zh) * | 2016-08-18 | 2016-11-09 | 刘世超 | 冰箱内板用抗老化塑料 |
CN107266786A (zh) * | 2017-07-11 | 2017-10-20 | 江苏理工学院 | 一种聚丙烯无卤阻燃母粒及其制备方法 |
CN107513209A (zh) * | 2016-06-16 | 2017-12-26 | 汉达精密电子(昆山)有限公司 | 无卤阻燃聚丙烯树脂组合物及其成型品 |
CN109867897A (zh) * | 2017-12-01 | 2019-06-11 | 中国石油化工股份有限公司 | 无卤阻燃epdm/pp热塑性弹性体材料及其应用 |
CN110157096A (zh) * | 2019-05-16 | 2019-08-23 | 江苏理工学院 | 一种环保型抗静电阻燃聚丙烯材料及其制备方法 |
CN112266541A (zh) * | 2020-10-16 | 2021-01-26 | 张雪飞 | 一种氮磷阻燃聚丙烯材料及其制备方法 |
CN114015187A (zh) * | 2021-11-24 | 2022-02-08 | 江苏尚艾新材料科技有限公司 | 一种汽车内饰用无卤阻燃聚丙烯材料及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115160692B (zh) * | 2022-07-14 | 2023-11-17 | 江苏金发科技新材料有限公司 | 一种无卤阻燃可吸塑聚丙烯合金材料及其制备方法与应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1847301A (zh) * | 2006-05-11 | 2006-10-18 | 宁波福天工程塑料有限公司 | 一种环保无卤阻燃聚丙烯材料 |
CN103554657A (zh) * | 2013-10-18 | 2014-02-05 | 浙江工业大学之江学院工业研究院 | 一种无卤阻燃聚丙烯复合电缆料及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102304250B (zh) * | 2011-09-07 | 2014-04-09 | 上海日之升新技术发展有限公司 | 高熔指无卤阻燃聚丙烯及其制备方法 |
CN104059278A (zh) * | 2014-06-30 | 2014-09-24 | 成都硕屋科技有限公司 | 一种耐水解不迁移无卤阻燃聚烯烃组合物及其制备方法 |
CN104119610A (zh) * | 2014-07-04 | 2014-10-29 | 广东聚石化学股份有限公司 | 一种v0级无卤阻燃增强聚丙烯复合材料及其制备方法 |
CN104559154B (zh) * | 2014-12-29 | 2017-04-12 | 江苏理工学院 | 环保型阻燃pa6材料及其制备方法 |
-
2015
- 2015-07-17 CN CN201510422261.7A patent/CN105061887B/zh active Active
- 2015-07-17 CN CN201710265390.9A patent/CN107216542B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1847301A (zh) * | 2006-05-11 | 2006-10-18 | 宁波福天工程塑料有限公司 | 一种环保无卤阻燃聚丙烯材料 |
CN103554657A (zh) * | 2013-10-18 | 2014-02-05 | 浙江工业大学之江学院工业研究院 | 一种无卤阻燃聚丙烯复合电缆料及其制备方法 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107513209A (zh) * | 2016-06-16 | 2017-12-26 | 汉达精密电子(昆山)有限公司 | 无卤阻燃聚丙烯树脂组合物及其成型品 |
CN106084484A (zh) * | 2016-08-18 | 2016-11-09 | 刘世超 | 冰箱内板用抗老化塑料 |
CN107266786A (zh) * | 2017-07-11 | 2017-10-20 | 江苏理工学院 | 一种聚丙烯无卤阻燃母粒及其制备方法 |
CN109867897A (zh) * | 2017-12-01 | 2019-06-11 | 中国石油化工股份有限公司 | 无卤阻燃epdm/pp热塑性弹性体材料及其应用 |
CN109867897B (zh) * | 2017-12-01 | 2021-07-02 | 中国石油化工股份有限公司 | 无卤阻燃epdm/pp热塑性弹性体材料及其应用 |
CN110157096A (zh) * | 2019-05-16 | 2019-08-23 | 江苏理工学院 | 一种环保型抗静电阻燃聚丙烯材料及其制备方法 |
CN110157096B (zh) * | 2019-05-16 | 2021-10-19 | 江苏理工学院 | 一种环保型抗静电阻燃聚丙烯材料及其制备方法 |
CN112266541A (zh) * | 2020-10-16 | 2021-01-26 | 张雪飞 | 一种氮磷阻燃聚丙烯材料及其制备方法 |
CN114015187A (zh) * | 2021-11-24 | 2022-02-08 | 江苏尚艾新材料科技有限公司 | 一种汽车内饰用无卤阻燃聚丙烯材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN107216542A (zh) | 2017-09-29 |
CN105061887B (zh) | 2017-06-13 |
CN107216542B (zh) | 2020-01-10 |
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