HRP20110950T1 - Adhezivno sredstvo za primjenu na sanitarni objekt - Google Patents

Adhezivno sredstvo za primjenu na sanitarni objekt Download PDF

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HRP20110950T1
HRP20110950T1 HR20110950T HRP20110950T HRP20110950T1 HR P20110950 T1 HRP20110950 T1 HR P20110950T1 HR 20110950 T HR20110950 T HR 20110950T HR P20110950 T HRP20110950 T HR P20110950T HR P20110950 T1 HRP20110950 T1 HR P20110950T1
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Leipold Joachim
Jaeschke Edgar
Fritz Matthias
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Buck-Chemie Gmbh
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Priority claimed from DE102008012092A external-priority patent/DE102008012092A1/de
Priority claimed from DE200810051173 external-priority patent/DE102008051173A1/de
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Abstract

Sredstvo za sanitarno područje, koje sredstvo se može primijeniti izravno na sanitarni objekt, tamo prianja i može biti isprano samo nakon relativno velikog broja radnji ispiranja, gdje sredstvo sadrži punila iz skupine surfaktanata i također adhezijski promotor, naznačeno time da je adhezijski promotor odabran iz skupine koju čine derivati polialkilena koji sadrže lance polialkilena sa nasumično smještenim funkcionalnim skupinama, ili iz skupine kopolimera iz skupine monoalkilestera poli/metil viniletera/karboksilnih anhidrida, homopolimera olefina i kopolimera dva ili više olefina koji su djelomično oksidirani ili dodatno funkcionalizirani preko cijepljenih molekula, te iz skupine polialkilenimina, također u alkoksiliranom obliku, polieter amina (alkoksiliranih amina) i poliglicerol polieter alkilkarboksilne kiseline, a viskoznost sredstva je najmanje 30 Pas, mjereno korištenjem viskozimetra Haake, sistem ploča/ploča, promjer ploče 10 mm, uz gradijent smicanja od 2.62 s-1 i 20°C a sredstvo je tako ljepljivo da može poslužiti za učvršćivanje sredstava u obliku pločice u WC školjku, pri čemu koncentracija surfaktanata u slučaju adhezijskog promotora iz skupine polialkilenimina je između 7 i 60% težinski. Patent sadrži još 28 patentnih zahtjeva.

Claims (29)

1. Sredstvo za sanitarno područje, koje sredstvo se može primijeniti izravno na sanitarni objekt, tamo prianja i može biti isprano samo nakon relativno velikog broja radnji ispiranja, gdje sredstvo sadrži punila iz skupine surfaktanata i također adhezijski promotor, naznačeno time da je adhezijski promotor odabran iz skupine koju čine derivati polialkilena koji sadrže lance polialkilena sa nasumično smještenim funkcionalnim skupinama, ili iz skupine kopolimera iz skupine monoalkilestera poli/metil viniletera/karboksilnih anhidrida, homopolimera olefina i kopolimera dva ili više olefina koji su djelomično oksidirani ili dodatno funkcionalizirani preko cijepljenih molekula, te iz skupine polialkilenimina, također u alkoksiliranom obliku, polieter amina (alkoksiliranih amina) i poliglicerol polieter alkilkarboksilne kiseline, a viskoznost sredstva je najmanje 30 Pas, mjereno korištenjem viskozimetra Haake, sistem ploča/ploča, promjer ploče 10 mm, uz gradijent smicanja od 2.62 s-1 i 20°C a sredstvo je tako ljepljivo da može poslužiti za učvršćivanje sredstava u obliku pločice u WC školjku, pri čemu koncentracija surfaktanata u slučaju adhezijskog promotora iz skupine polialkilenimina je između 7 i 60% težinski.
2. Sredstvo prema zahtjevu 1, naznačeno time da polialkilenski lanci adhezijskih promotora iz skupine derivata polialkilena su iz skupine derivata polialkilena i poželjno su polibutadienski, poliizopropilenski i polipropilenski lanci.
3. Sredstvo prema zahtjevu 2, naznačeno time da su funkcionalne skupine anhidridi, tioli, epoksidi ili primarni amini.
4. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da su derivati polialkilena polimeri sa maleinskim anhidridnim skupinama nasumično vezanim na polibutadienski lanac i poželjno maleinski anhidridni adukt na 1,4-cis-polibutadienu.
5. Sredstvo prema zahtjevu 1, naznačeno time da su adhezijski promotori iz skupine homopolimera olefina i kopolimeri dva ili više olefina koji su djelomično oksidirani ili dodatno funkcionalizirani odabrani iz skupine koju čine polibutadienske gume, stiren-butadien blok polimeri i kopolimeri, poliizopreni, slučajni (blok) polimeri koji su dobiveni pomoću 1,3-adicije butadiena ili izoprena na stiren ili alfa-metilstiren, homopolimeri ili kopolimeri etilena i propilena, kao etilen-propilendien terpolimeri, etilen-etilen oksid kopolimeri, prirodna guma i norbornen polimeri kao što je polidiciklopentadien.
6. Sredstvo prema zahtjevu 1, naznačeno time da adhezijski promotori iz skupine polialkilenimina su homopolimerni polialkilenimini, posebice opće formule -(R-NH)n gdje R = alkil ili derivat alkila, n = 10-105 sa dvo- ili tro-dimenzijskim umrežavanjem na funkciji dušika.
7. Sredstvo prema zahtjevu 6, naznačeno time da polialkilenimini sadrže, kao alkilensku skupinu, etilen, metilen, propilen, butilen ili višu alkilensku skupinu.
8. Sredstvo prema zahtjevu 1, naznačeno time da polieter amini su alkoksilirani primarni i/ili sekundarni i/ili tercijarni alkil- ili arilamini.
9. Sredstvo prema zahtjevu 1, naznačeno time da polieter amini sadrže tri-, bi- i/ili monofunkcionalne primarne amine i kao polieterske skupine, polietilen oksid, mješavinu poli(etilen oksida/propilen oksida) ili polipropilenske oksidne skupine.
10. Sredstvo prema zahtjevu 1, naznačeno time da su poliglicerol polieter alkilkarboksilne kiseline odabrane iz skupine koju čine polietilen glikol-150 poligliceril-2 tristearat ili PEG-150 digliceril tristearat ili PEG-150 tetragliceril distearat.
11. Sredstvo prema jednom od zahtjeva 1 i 6 do 10, naznačeno time da je koncentracija promotora adhezije u sredstvu između 2% težinski i 60% težinski, poželjno između 7 i 50% težinski i naročito poželjno između 8% težinski i 40% težinski.
12. Sredstvo prema jednom od zahtjeva 1 do 5, naznačeno time da je koncentracija promotora adhezije u sredstvu između 15% težinski i 80% težinski, poželjno između 20 i 70% težinski i naročito poželjno između 30% težinski i 50% težinski.
13. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da su punila odabrana iz skupine koju čine zgušnjivači, mirisi, boje, soli, stabilizatori pjene, pojačivači pjenjenja, generatori pjene i polimerne prirodne tvari.
14. Sredstvo prema zahtjevu 1, naznačeno time da je udjel surfaktanta u sredstvu do 80% težinski, poželjno 10 do 60% težinski i naročito poželjno 25 do 45% težinski.
15. Sredstvo prema jednom od zahtjeva 1 ili 14, naznačeno time da su surfaktanti praškasti ili vrlo pastasti.
16. Sredstvo prema jednom od zahtjeva 1 do 15, naznačeno time da su surfaktanti anionski surfaktanti i odabrani su iz skupine koju čine soli karboksilnih kiselina, polu-esteri sumporne kiseline, sulfonske kiseline, alkoholi relativno dugog-lanca i etoksilati masnih alkohola.
17. Sredstvo prema jednom od zahtjeva 1 ili 13 do 16, naznačeno time da su surfaktanti neionski surfaktanti i odabrani su iz skupine koju čine alkoholni etoksilati, alkil glikozidi, alkoksilirani alkil esteri masnih kiselina, amin oksidi i alkanolamidi.
18. Sredstvo prema zahtjevu 13, naznačeno time da sredstvo sadrži mirise ili mirisna ulja u koncentracijama između 0.25% težinski i 20% težinski, poželjno između 3% težinski i 15% težinski i naročito poželjno između 5% težinski i 10% težinski.
19. Sredstvo prema zahtjevu 13, naznačeno time da sredstvo sadrži do 90% težinski soli, posebice do 10% težinski, poželjno do 5% težinski, soli, poželjno iz skupine soli jakih kiselina alkalnih metala i alkalnih zemljanih metala ili mono-, di- i polikarboksilnih kiselina.
20. Sredstvo prema zahtjevu 13, naznačeno time da sredstvo sadrži (ko)zgušnjivače iz skupine bentonita, praškaste surfaktanate, ksantane, polibutadienske gume, poliizopropene, blok kopolimere, aril etoksilate ili alkil-aril etoksilate ili polimerne prirodne tvari.
21. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da je sredstvo topivo u vodi i/ili se može disperzirati u vodi privremeno se držeći adhezivnog sredstva.
22. Uporaba sredstva prema jednom od prethodnih zahtjeva, naznačena time da pripravci u obliku pločice koji se mogu učvrstiti su uobičajeni ulošci za toaletne školjke sa jednom ili više faza, ulošci za toaletne školjke sa mirisnom fazom, ulošci za toaletne školjke koji sadrže izbjeljivač, kompaktne tablete, vodotopive ili ne-vodotopive plastike koje sadrže aktivne sastojke, tablete za deodoriziranje, kruti gelovi za deodoriziranje, tablete za izbjeljivanje, tablete za uklanjanje kamenca ili tablete za intenzivno čišćenje.
23. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da sredstvo sadrži aditive za čišćenje i/ili za deodoriziranje i/ili za izbjeljivanje i/ili za bojenje.
24. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da je sredstvo slično masti, pasta i/ili slično kremi i dimenzijski je stabilno.
25. Sredstvo prema bilo kojem od prethodnih zahtjeva, naznačeno time da je površinska napetost sredstva između 50 i 65 mN/m, a posebice manje od 60 mN/m.
26. Komplet za čišćenje toaleta naznačen time da sadrži najmanje jedno sredstvo prema jednom od prethodnih zahtjeva i jednu ili više smjesa u obliku pločice iz skupine uložaka za toalete sa jednom ili više faza, uložaka za toalete sa mirisnom fazom, uložaka za toalete koji sadrže izbjeljivač, kompaktnih tableta, vodotopivih ili ne-vodotopivih plastika koje sadrže aktivne sastojke, tableta za deodoriziranje, krutih gelova za deodoriziranje, tableta za izbjeljivanje, tableta za uklanjanje kamenca ili tableta za intenzivno čišćenje.
27. Uporaba sredstva prema jednom od prethodnih zahtjeva kao hladnog ljepila u sanitarnom sektoru, naročito za učvršćivanje objekata u pisoarima, umivaonicima za pranje ruku bazena ili na pločicama, ili u kuhinjama, restoranima, klaonicama, prostorijama za pranje ili za primjenu na/u odvodima ili kanalima ili kao pasta za smještaj mamca za borbu protiv štetočina ili za učvršćivanje na prozore ili fasade.
28. Uporaba prema zahtjevu 27, naznačena time da masa sredstva koje se primjenjuje na objekt je 3 do 15% težinski od mase objekta.
29. Postupak za proizvodnju sredstva kako je zatraženo u jednom od prethodnih zahtjeva, naznačen time da se pojedinačne komponente miješaju zajedno na sobnoj temperaturi.
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