GR900100537A - Βελτιωμένη χλωρίωση 6-εστέρος ζακχαρόζης. - Google Patents
Βελτιωμένη χλωρίωση 6-εστέρος ζακχαρόζης.Info
- Publication number
- GR900100537A GR900100537A GR900100537A GR900100537A GR900100537A GR 900100537 A GR900100537 A GR 900100537A GR 900100537 A GR900100537 A GR 900100537A GR 900100537 A GR900100537 A GR 900100537A GR 900100537 A GR900100537 A GR 900100537A
- Authority
- GR
- Greece
- Prior art keywords
- ester
- sucrose
- produce
- reaction mixture
- product
- Prior art date
Links
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title abstract 4
- 229960004793 sucrose Drugs 0.000 abstract 5
- 229930006000 Sucrose Natural products 0.000 abstract 4
- 239000005720 sucrose Substances 0.000 abstract 4
- 239000011541 reaction mixture Substances 0.000 abstract 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- 241000193830 Bacillus <bacterium> Species 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000003511 tertiary amides Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
- C07H5/02—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Μια μέ?οδος δια την χλωρίωση των 6-εστέρων της σακχαρόζης προς παραγωγή 6-εστέρων 6',4,1' -τριχλωριο σακχαρόζης η οποία περιλαμβάνει τας βα?μίδας: (α) Προσ?ήκη τουλάχιστον 67 μοριακών ισοδυνάμων ενός χλωριδίου οξέος εις ένα μίγμα αντιδράσεως που περιέχει ένα 6- εστέρα σακχαρόζης και μια τριτοταγή αμίδη προς σχηματισμό κατ' αρχάς ενός άλατος χλωριούχου χλωριοφορμιμινίου το οποίο εν συνεχεία σχηματίζει ένα σύμπλοκο με τις υδροξυλομάδες του 6-εστέρος της σακχαρόζης. (β) υποβολή του μίγματος αντιδράσεως του προιόντος της βα?μίδος (α) εις ηυξημένη ?ερμοκρασία όχι μεγαλυτέρα των περίπου 85 βα?μών Κελσίου επί χρονικό διάστημα επαρκές ώστε να παραχ?εί ένα μίγμα χλωριωμένων προιόντων 6-εστέρος σακχαρόζης που αποτελείται κυρίως από 6-εστέρα 6'- χλωριοσακχαρόζη, 6-εστέρα 4,6'-διχλωριοσακχαρόζης και 6- εστέρα 1',6'-διχλωριοσακχαρόζης και (γ) υποβολή του μίγματος αντιδράσεως του προιόντος της βα?μίδος (β) εις ηυξημένη ?ερμοκρασία όχι μεγαλυτέρα των περίπου 125 βα?μών Κελσίου επί χρονικό διάστημα επαρκές δια να παραχ?εί ένα χλωριωμένο προιόν που αποτελείται κυρίως από 6-εστέρα της 1',4,6'-τριχλωριοσακχαρόζης. ω
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/382,147 US4980463A (en) | 1989-07-18 | 1989-07-18 | Sucrose-6-ester chlorination |
Publications (2)
Publication Number | Publication Date |
---|---|
GR900100537A true GR900100537A (el) | 1991-12-10 |
GR1002037B GR1002037B (en) | 1995-10-31 |
Family
ID=23507711
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GR900100537A GR1002037B (en) | 1989-07-18 | 1990-07-12 | Improvents relating to the sacharose 6-estere chlorization |
Country Status (26)
Country | Link |
---|---|
US (1) | US4980463A (el) |
EP (1) | EP0409549B1 (el) |
JP (1) | JP3183506B2 (el) |
KR (1) | KR0144344B1 (el) |
AR (1) | AR247401A1 (el) |
AT (1) | ATE133175T1 (el) |
AU (1) | AU625908B2 (el) |
CA (1) | CA2021632C (el) |
DE (1) | DE69024868T2 (el) |
DK (1) | DK0409549T3 (el) |
ES (1) | ES2088973T3 (el) |
FI (1) | FI95802C (el) |
GR (1) | GR1002037B (el) |
IE (1) | IE69961B1 (el) |
IL (1) | IL94994A (el) |
MX (1) | MX164442B (el) |
NO (1) | NO175532C (el) |
NZ (1) | NZ234468A (el) |
PE (1) | PE21591A1 (el) |
PH (1) | PH26799A (el) |
PT (1) | PT94719B (el) |
RU (1) | RU1836377C (el) |
TR (1) | TR28705A (el) |
TW (1) | TW219939B (el) |
YU (1) | YU47948B (el) |
ZA (1) | ZA905615B (el) |
Families Citing this family (89)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5136031A (en) * | 1990-07-09 | 1992-08-04 | Tate & Lyle Public Limited Company | Chlorination of sugars |
US5470969A (en) * | 1990-08-27 | 1995-11-28 | Mcneil-Ppc, Inc. | Catalyzed sucrose-6-ester process |
GB9110931D0 (en) * | 1991-05-21 | 1991-07-10 | Tate & Lyle Plc | Process for the preparation of sucrose 6-esters |
US5298611A (en) * | 1993-03-12 | 1994-03-29 | Mcneil-Ppc, Inc. | Sucralose pentaester production |
WO1996001832A1 (en) | 1994-07-11 | 1996-01-25 | The United States Of America, Represented By The Secretary Of The Department Of Agriculture | Chemically synthesized sugar esters for the control of soft-bodied arthropods |
US6608039B1 (en) | 1994-07-11 | 2003-08-19 | The United States Of America As Represented By The Secretary Of Agriculture | Chemically synthesized sugar esters for the control of soft-bodied arthropods |
US5498709A (en) * | 1994-10-17 | 1996-03-12 | Mcneil-Ppc, Inc. | Production of sucralose without intermediate isolation of crystalline sucralose-6-ester |
KR100405203B1 (ko) * | 1996-05-23 | 2004-02-14 | 비앤티엔지니어링(주) | 암거배수로관 |
CA2280784A1 (en) * | 1997-02-13 | 1998-08-20 | Mcneil-Ppc, Inc. | Chromatographic purification of chlorinated sucrose |
WO1999060006A1 (en) * | 1998-05-15 | 1999-11-25 | Zhbankov Rostislav G | Method of preparation 4,1´,6´-trichloro-4,1´,6´-trideoxygalactosucrose |
DE19924770A1 (de) * | 1999-05-29 | 2000-12-21 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von Polyetherpolyolen aus Polysacchariden und deren Verwendung für die Herstellung von PUR-Schäumen |
US6500973B2 (en) | 2000-06-02 | 2002-12-31 | Eastman Chemical Company | Extractive solution crystallization of chemical compounds |
ATE387457T1 (de) * | 2000-08-25 | 2008-03-15 | Eastman Chem Co | Verfahren zur herstellung von disaccharid und trisaccharid c6-c12 fettsäure-estern mit hohem alpha gehalt und materialien davon |
US6667397B2 (en) * | 2000-08-25 | 2003-12-23 | Eastman Chemical Company | Methods of preparing disaccharide and trisaccharide C6-C12 fatty acid esters with high alpha content and materials therefrom |
CA2429228C (en) | 2000-11-17 | 2008-08-26 | Mcneil-Ppc, Inc. | Improved sucralose composition and process for the crystallization thereof |
US7049435B2 (en) | 2002-03-08 | 2006-05-23 | Tate & Lyle Public Limited Company | Extractive methods for purifying sucralose |
US6998480B2 (en) | 2002-03-08 | 2006-02-14 | Tate & Lyle Public Limited Company | Process for improving sucralose purity and yield |
US20040170735A2 (en) * | 2002-04-05 | 2004-09-02 | Mcneil-Ppc, Inc. | Methods and compositions for altering the sweetness delivery profile of sucralose |
US6890581B2 (en) * | 2002-04-05 | 2005-05-10 | Tate & Lyle Public Limited Company | Methods for buffer stabilized aqueous deacylation |
US20040086605A1 (en) * | 2002-10-30 | 2004-05-06 | Sox Thomas E. | Composition for delivering a high intensity sweetener |
US6943248B2 (en) | 2003-04-30 | 2005-09-13 | Tate & Lyle Public Limited Company | Crystalline form of sucralose, and method for producing it |
CN1176094C (zh) * | 2003-05-23 | 2004-11-17 | 广东省食品工业研究所 | 一种三氯蔗糖的合成方法 |
WO2005087020A1 (en) * | 2004-03-05 | 2005-09-22 | Richmond Chemical Corporation | High-intensity sweetener-polyol compositions |
MXPA06010665A (es) * | 2004-03-19 | 2007-03-28 | Pharmed Medicare Pvt Ltd | Un proceso mejorado para producir sacarosa clorada. |
US20050214425A1 (en) * | 2004-03-23 | 2005-09-29 | Roma Vazirani | Sugar substitute prepared with nutritive and high-intensity sweeteners |
GB2437442B (en) * | 2004-12-10 | 2010-03-31 | Pharmed Medicare Pvt Ltd | Improved process for purification of 6 acetyl 4,1',6' trichlorogalactosucrose and 4,1'6' trichlorogalactosucrose by chromatography on silanized silica gel |
US20080051574A1 (en) * | 2004-12-10 | 2008-02-28 | Rakesh Ratnam | Control of Ph By Direct Addition of Carbonates and Bicarbonates During Concentration of Organics Solvent Extracts of 6-Acetyl-4,1',6' Trichlorogalactosucrose and 4,1',6' trichlorogalactosucrose |
WO2006061855A2 (en) * | 2004-12-10 | 2006-06-15 | Pharmed Medicare Private Limited | Salts assisted selective extraction of 6-acetyl-4.1', 6' trichlorogalactosucrose and 4, 1 ', 6' trichlorogalactosucrose from aqueous reaction mixture |
WO2006072965A2 (en) * | 2005-01-03 | 2006-07-13 | Pharmed Medicare Private Limited | Sucrose-6-ester chlorination by co-addition of chlorination reagent. |
US20060188629A1 (en) * | 2005-01-21 | 2006-08-24 | Greg Liesen | Method for the purification of sucralose |
US20080163867A1 (en) * | 2005-02-22 | 2008-07-10 | Molecular Separation Process in Various Steps of Process for Production of Chlorinated Sugars, Their Precursors and Derivatives | |
US20060205936A1 (en) * | 2005-03-14 | 2006-09-14 | Sl Laboratories, Llc | Chlorination of Sucrose-6-esters |
US20060247180A1 (en) * | 2005-04-29 | 2006-11-02 | Bergey James L | Purgative composition and uses thereof |
CN101484437A (zh) * | 2005-05-04 | 2009-07-15 | V.B.医疗保险私人有限公司 | 从双(三氯甲基)碳酸酯合成用于氯化反应的Vilsmeier-Haack试剂 |
US20090131653A1 (en) * | 2005-05-04 | 2009-05-21 | Pharmed Medicare Private Limited | Generation of Phosphorus Oxychloride as by-Product from Phosphorus Pentachloride and DMF and its Use for Chlorination Reaction by Converting Into Vilsmeier-Haack Reagent |
US20060276639A1 (en) * | 2005-06-01 | 2006-12-07 | Healthy Brands, Llc | Conversion of sucralose-6-ester to sucralose |
US20100190975A1 (en) * | 2005-06-01 | 2010-07-29 | Pharmed Medicare Private Limited | Method for purification of chlorinated sucrose derivatives by solvent extraction |
CN101268091A (zh) * | 2005-09-22 | 2008-09-17 | 法马德医疗保险私人有限公司 | 从无水氯化反应物料制备6-o-酰基氯化蔗糖的新型方法 |
US20070100139A1 (en) * | 2005-10-31 | 2007-05-03 | Healthy Brands, Llc | Methods for chlorinating sucrose-6-ester |
US7741477B2 (en) * | 2006-01-10 | 2010-06-22 | Alembic Limited | Process for purification of sucralose |
US20100228020A1 (en) * | 2006-02-28 | 2010-09-09 | V.B Medicare Pvt. Ltd | Novel Chlorination Reagent and a Novel Process for Chlorination of Sugars Using Thionyl Chloride |
CN100418976C (zh) * | 2006-04-03 | 2008-09-17 | 广州科宏食品添加物有限公司 | 一种三氯蔗糖的制备方法 |
CN100402541C (zh) * | 2006-06-15 | 2008-07-16 | 浙江工业大学 | 一种三氯蔗糖-6-乙酯的合成方法 |
CN101092438A (zh) * | 2006-06-22 | 2007-12-26 | 南京莱因医药科技有限公司 | 6-o-苯甲酰三氯半乳型蔗糖四乙酯的制备方法 |
JP2009542625A (ja) * | 2006-07-06 | 2009-12-03 | アレムビック・リミテッド | 高純度スクラロースの改良製造法 |
CN100420697C (zh) * | 2006-08-30 | 2008-09-24 | 河北苏科瑞科技有限公司 | 一种制备蔗糖-6-有机酸酯的方法 |
US8258291B2 (en) * | 2006-10-25 | 2012-09-04 | Mamtek International Limited | Process for the preparation of sucralose by the chlorination of sugar with triphosgene (BTC) |
US20080103295A1 (en) * | 2006-10-25 | 2008-05-01 | David Losan Ho | Process for the preparation of sucrose-6-ester by esterification in the presence of solid superacid catalyst |
GB0702857D0 (en) * | 2007-01-19 | 2007-03-28 | Tate & Lyle Plc | Improved sucralose production method |
US20080227971A1 (en) * | 2007-01-19 | 2008-09-18 | Leinhos Duane A | Deacylation of sucralose-6-acylates |
CN101260127B (zh) * | 2007-03-06 | 2011-04-20 | 盐城捷康三氯蔗糖制造有限公司 | 由三氯蔗糖-6-乙酯脱乙酰基合成三氯蔗糖的方法 |
US20080300392A1 (en) * | 2007-06-04 | 2008-12-04 | Polymed Therapeutics, Inc. | Novel chlorination process for preparing sucralose |
US20080300401A1 (en) * | 2007-06-04 | 2008-12-04 | Polymed Therapeutics, Inc. | Novel chlorination process for preparing sucralose |
US8436156B2 (en) * | 2008-01-04 | 2013-05-07 | Tate & Lyle Technology Limited | Method for the production of sucralose |
US7932380B2 (en) * | 2008-03-06 | 2011-04-26 | Wanhe International (Group) Co. Ltd. | Process for the preparation of sucralose |
US8557976B2 (en) * | 2008-03-13 | 2013-10-15 | Tate & Lyle Technology Limited | Microbial consortia and methods for their use |
WO2009117317A1 (en) * | 2008-03-20 | 2009-09-24 | Tate & Lyle Technology Ltd | Removal of acids from tertiary amide solvents |
US8436157B2 (en) * | 2008-03-26 | 2013-05-07 | Tate & Lyle Technology Limited | Method for the production of sucralose |
US20090299055A1 (en) * | 2008-04-03 | 2009-12-03 | Tate & Lyle Technology Limited | Purification of Sucralose Containing Feed Streams for Sucralose Crystallization |
WO2009137193A2 (en) * | 2008-04-03 | 2009-11-12 | Tate & Lyte Technology Ltd | Effect of carbohydrate concentration on sucralose extraction efficiency |
US8497367B2 (en) * | 2008-04-03 | 2013-07-30 | Tate & Lyle Technology Limited | Sucralose purification process |
AR071134A1 (es) * | 2008-04-03 | 2010-05-26 | Tate & Lyle Technology Ltd | Cristalizacion de sucralosa a partir de chorros que contienen sucralosa |
WO2009124113A1 (en) * | 2008-04-03 | 2009-10-08 | Tate & Lyle Technology Ltd. | Extraction of less polar impurities from sucralose containing aqueous feed streams |
US7862744B2 (en) * | 2008-07-23 | 2011-01-04 | Mamtek International Limited | Methods and systems for preparing materials for sucralose production |
US20100022765A1 (en) * | 2008-07-23 | 2010-01-28 | David Losan Ho | Methods for extracting and purifying sucralose intermediate |
GB2468936B (en) | 2009-03-27 | 2011-09-07 | Mohamad Rami Radwan Jaber | Chlorination of sucrose-6-esters |
GB2469157B (en) | 2009-03-30 | 2011-07-06 | John Kerr | Process for removing dimethylamine during sucralose production |
GB2469158B (en) * | 2009-03-31 | 2011-09-28 | Peter J Seaberg | Base-assisted formation of tin-sucrose adducts |
GB2471348B (en) * | 2009-06-22 | 2011-12-14 | Tate & Lyle Technology Ltd | A method for producing sucralose-6-acylate |
GB2474311B (en) * | 2009-10-12 | 2012-10-17 | Tate & Lyle Technology Ltd | Low temperature, single solvent process for the production of sucrose-6-ester |
GB2474310B (en) | 2009-10-12 | 2012-02-29 | Tate & Lyle Technology Ltd | Process for the production of sucrose-6-ester |
ES2551585T3 (es) * | 2010-08-25 | 2015-11-20 | Davuluri, Ramamohan Rao | Procedimiento mejorado para la preparación de Sugammadex |
MX2013005560A (es) * | 2010-11-23 | 2013-08-26 | Lexington Pharmaceuticals Lab Llc | Cloracion de baja temperatura de carbohidratos. |
GB201110520D0 (en) | 2011-05-10 | 2011-08-03 | Tate & Lyle Technology Ltd | Extraction of carboxylic acids with tin compounds |
JP5679447B2 (ja) * | 2011-06-20 | 2015-03-04 | 第一工業製薬株式会社 | ショ糖ベンゾエート組成物の製造方法 |
US8884004B2 (en) | 2011-09-02 | 2014-11-11 | Divi's Laboratories, Ltd. | Process for the preparation of sucralose |
SG2013049648A (en) * | 2011-10-14 | 2014-12-30 | Lexington Pharmaceuticals Lab Llc | Chlorination of carbohydrates and carbohydrate derivatives |
CN102964396B (zh) * | 2012-10-26 | 2015-11-18 | 溧阳维信生物科技有限公司 | 一种三氯蔗糖-6-乙酯重结晶的方法 |
JP6109531B2 (ja) * | 2012-11-02 | 2017-04-05 | 第一工業製薬株式会社 | 溶媒の除去方法 |
CN103145772A (zh) * | 2013-03-26 | 2013-06-12 | 山东金城柯瑞化学有限公司 | 三氯蔗糖的制备方法 |
US10227367B2 (en) | 2013-12-16 | 2019-03-12 | Tate & Lyle Technology Limited | Chlorination of sucrose-6-esters |
WO2016020635A1 (en) | 2014-08-08 | 2016-02-11 | Tate & Lyle Technology Limited | Chlorination of sucrose-6-esters |
CN104387427A (zh) * | 2014-10-30 | 2015-03-04 | 安徽金禾实业股份有限公司 | 一种三氯蔗糖的生产方法 |
GB2536480B (en) | 2015-03-17 | 2019-09-04 | Tate & Lyle Tech Ltd | DMF Distillation |
CN105131050B (zh) * | 2015-07-22 | 2018-07-31 | 青岛科技大学 | 一种氯化剂的制备方法及其制备三氯蔗糖的方法 |
CN105859802B (zh) * | 2016-05-14 | 2019-02-12 | 广西科技大学 | 一种三氯蔗糖的结晶和纯化方法 |
GB2551591B (en) | 2016-06-23 | 2019-08-07 | Tate & Lyle Tech Ltd | Liquid-liquid extraction of DMF |
EP4206211A4 (en) | 2020-09-30 | 2023-10-11 | Anhui Jinhe Industrial Co., Ltd. | METHOD FOR PURIFYING SUCRALOSE |
CN113699196A (zh) * | 2021-08-17 | 2021-11-26 | 安徽金禾实业股份有限公司 | 一种蔗糖-6-乙酸酯的无水酶法催化合成方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0015757A1 (en) * | 1979-03-09 | 1980-09-17 | TATE & LYLE PATENT HOLDINGS LIMITED | Process for the preparation of chlorodeoxysugars |
EP0043649A1 (en) * | 1980-07-08 | 1982-01-13 | TATE & LYLE PUBLIC LIMITED COMPANY | Process for the preparation of 4, 1',6'-trichloro-4,1',6'-trideoxygalactosucrose (TGS) |
EP0130054A2 (en) * | 1983-06-21 | 1985-01-02 | TATE & LYLE PUBLIC LIMITED COMPANY | Novel Fructosyltransferase, process for the preparation of Fructosyl disaccharides, and a novel halosucrose |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4435440A (en) * | 1976-01-08 | 1984-03-06 | Tate & Lyle Limited | Sweeteners |
EP0010410B1 (en) * | 1978-10-18 | 1982-03-03 | TATE & LYLE PATENT HOLDINGS LIMITED | A method for the preparation of 2-chloro-2-deoxy saccharides and some 2-chloro-2-deoxy saccharides |
DE3062467D1 (en) * | 1979-12-20 | 1983-04-28 | Tate & Lyle Plc | Process for the preparation of 4,1',6'-trichloro-4,1',6'-trideoxy-galactosucrose |
US4291158A (en) * | 1980-01-28 | 1981-09-22 | Velsicol Chemical Corporation | Sucrose ester of 2-methoxy-3,6-dichlorobenzoic acid |
US4345933A (en) * | 1980-01-28 | 1982-08-24 | Velsicol Chemical Corporation | Sucrose ester of 2-methoxy-3,6-dichlorobenzoic acid |
DE3362086D1 (en) * | 1982-09-13 | 1986-03-20 | Tate & Lyle Plc | Sucrose derivatives |
GB8622345D0 (en) * | 1986-09-17 | 1986-10-22 | Tate & Lyle Plc | Sucrose derivatives |
-
1989
- 1989-07-18 US US07/382,147 patent/US4980463A/en not_active Expired - Lifetime
-
1990
- 1990-07-06 PH PH40800A patent/PH26799A/en unknown
- 1990-07-06 IL IL9499490A patent/IL94994A/en unknown
- 1990-07-11 NZ NZ234468A patent/NZ234468A/en unknown
- 1990-07-12 GR GR900100537A patent/GR1002037B/el not_active IP Right Cessation
- 1990-07-16 CA CA002021632A patent/CA2021632C/en not_active Expired - Lifetime
- 1990-07-16 PE PE1990172224A patent/PE21591A1/es not_active Application Discontinuation
- 1990-07-17 AT AT90307784T patent/ATE133175T1/de not_active IP Right Cessation
- 1990-07-17 DK DK90307784.0T patent/DK0409549T3/da active
- 1990-07-17 EP EP90307784A patent/EP0409549B1/en not_active Expired - Lifetime
- 1990-07-17 PT PT94719A patent/PT94719B/pt not_active IP Right Cessation
- 1990-07-17 JP JP18732890A patent/JP3183506B2/ja not_active Expired - Fee Related
- 1990-07-17 FI FI903603A patent/FI95802C/fi not_active IP Right Cessation
- 1990-07-17 DE DE69024868T patent/DE69024868T2/de not_active Expired - Lifetime
- 1990-07-17 RU SU4830726A patent/RU1836377C/ru active
- 1990-07-17 ES ES90307784T patent/ES2088973T3/es not_active Expired - Lifetime
- 1990-07-17 NO NO903190A patent/NO175532C/no not_active IP Right Cessation
- 1990-07-17 ZA ZA905615A patent/ZA905615B/xx unknown
- 1990-07-17 AU AU59069/90A patent/AU625908B2/en not_active Expired
- 1990-07-17 IE IE260390A patent/IE69961B1/en not_active IP Right Cessation
- 1990-07-17 AR AR90317395A patent/AR247401A1/es active
- 1990-07-18 YU YU141190A patent/YU47948B/sh unknown
- 1990-07-18 MX MX21634A patent/MX164442B/es unknown
- 1990-07-18 TR TR00678/90A patent/TR28705A/xx unknown
- 1990-07-18 KR KR1019900010857A patent/KR0144344B1/ko not_active IP Right Cessation
- 1990-07-26 TW TW079106171A patent/TW219939B/zh active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0015757A1 (en) * | 1979-03-09 | 1980-09-17 | TATE & LYLE PATENT HOLDINGS LIMITED | Process for the preparation of chlorodeoxysugars |
EP0043649A1 (en) * | 1980-07-08 | 1982-01-13 | TATE & LYLE PUBLIC LIMITED COMPANY | Process for the preparation of 4, 1',6'-trichloro-4,1',6'-trideoxygalactosucrose (TGS) |
EP0130054A2 (en) * | 1983-06-21 | 1985-01-02 | TATE & LYLE PUBLIC LIMITED COMPANY | Novel Fructosyltransferase, process for the preparation of Fructosyl disaccharides, and a novel halosucrose |
Non-Patent Citations (3)
Title |
---|
ANGEW. CHEM. INTERNAT. EDIT., vol. 12, no. 10, 1973, pages 806-818; H.G. VIEHE et al.: "The chemistry of dichloromethylenammomium salts" * |
CLAIMS SEARCHED: ALL * |
J. CHEM. SOC., PERKIN I, 1976, pages 754-757; D.R. HEPBURN et al.: "Factors in the formation of isomerically and optically pure alkyl halides. Part XI. Vilsmeier reagents for the replacement of a hydroxy-group by chlorine or bromine" * |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GR900100537A (el) | Βελτιωμένη χλωρίωση 6-εστέρος ζακχαρόζης. | |
IT7821282A0 (it) | Processo per la concentrazione diprodotti alimentari liquidi e affini. | |
NO883670D0 (no) | Metode for direktebestemmelse av fysikalske egenskaper for hydrokarbonprodukter. | |
NO884015L (no) | Nukleinsyrefragment og anvendelse derav for paavisning av listeria bakterier. | |
ATE84791T1 (de) | Verfahren zur herstellung von 1,6-dichlor-1,6gb851021 | |
DE3880278T2 (de) | Ein verfahren zur verbesserung der geschmackseigenschaften von kartoffelprodukten. | |
DE3775401D1 (de) | Behandelte fleischprodukte, die ein konjac mannan-gel enthalten und verfahren zu deren herstellung. | |
DE3850736D1 (de) | Verfahren zur Herstellung von modifizierter, vorverkleisterter Maisstärke und das so erhaltene Produkt. | |
ES461693A1 (es) | Procedimiento de tratamiento de sangre y analogos para la fabricacion de productos alimenticios. | |
ATE24317T1 (de) | 4-methyl-6-phenyl-pyridazinderivate mit einer wirkung auf das zentrale nervensystem. | |
DE3167109D1 (en) | Sucrose-mutase, immobilized sucrose-mutase and use of this immobilized sucrose-mutase for the production of isomaltulose(6-o-alpha-d-glucopyranosido-d fructose) | |
ES2077561T3 (es) | Proceso para la modificacion de un tamiz molecular. | |
ATE40353T1 (de) | Verfahren zur herstellung von chlorierten pyridinderivaten und radikal initiatoren verwendet in diesem verfahren. | |
MD342G2 (ro) | Procedeu şi dispozitiv pentru stabilizarea configuraţiei produselor din aluat | |
KR860002446A (ko) | 2,4-디클로로-5-플루오로-벤조산의 제조방법 | |
IT1005592B (it) | Processo per la preparazione di 2.4.5 trichetoimidazulidine n.n sostituite modificate e contenen ti gruppi amidici e.o imidici | |
DK0426311T3 (da) | Fremgangsmåde til bearbejdning af krydderier og andet aromatisk spiseligt vegetabilsk stof | |
OA05590A (fr) | Procédé d'enrichissement en protéines de produits comestibles. | |
BR8001454A (pt) | Nitretos de fosforo polimericos, contendo hidroxila e halogenio, ativos, processo para sua producao, e sua aplicacao | |
Kariyil | Religion and Material Development | |
ATE100673T1 (de) | Verfahren zur herstellung von getrocknetem aromatisiertem fleisch. | |
IT1070500B (it) | Diamino 2..4 bromo 5 cloro 6 pirimidine utilizzabili come prodotti come tali e procedimento per la loro proparazione | |
KR890014382A (ko) | 조절된 비율의 고리상 올리고머를 갖는 폴리디클로로포스파젠 조성물의 제조방법 및 이 방법에 의해 얻어지는 조성물 | |
KR960037700A (ko) | 고순도 베타-사이클로덱스트린의 제조방법 | |
ES2034498T3 (es) | Procedimiento y aparato para expandir productos conteniendo almidon. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ML | Lapse due to non-payment of fees |