GB1567101A - Production of multiple zinc/containing electro-coatings - Google Patents
Production of multiple zinc/containing electro-coatings Download PDFInfo
- Publication number
- GB1567101A GB1567101A GB512/78A GB51278A GB1567101A GB 1567101 A GB1567101 A GB 1567101A GB 512/78 A GB512/78 A GB 512/78A GB 51278 A GB51278 A GB 51278A GB 1567101 A GB1567101 A GB 1567101A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zinc
- nickel
- layer
- iron
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 79
- 229910052725 zinc Inorganic materials 0.000 title claims description 79
- 239000011701 zinc Substances 0.000 title claims description 79
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000004070 electrodeposition Methods 0.000 title description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 96
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 70
- 229910052759 nickel Inorganic materials 0.000 claims description 50
- 229910045601 alloy Inorganic materials 0.000 claims description 39
- 239000000956 alloy Substances 0.000 claims description 39
- 238000000576 coating method Methods 0.000 claims description 39
- 229910052742 iron Inorganic materials 0.000 claims description 35
- 238000005275 alloying Methods 0.000 claims description 31
- 238000013019 agitation Methods 0.000 claims description 29
- 239000011248 coating agent Substances 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000000758 substrate Substances 0.000 claims description 27
- 230000007797 corrosion Effects 0.000 claims description 26
- 238000005260 corrosion Methods 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 25
- 239000010941 cobalt Substances 0.000 claims description 23
- 229910017052 cobalt Inorganic materials 0.000 claims description 23
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 23
- 239000010959 steel Substances 0.000 claims description 18
- 229910000831 Steel Inorganic materials 0.000 claims description 16
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 15
- 238000009713 electroplating Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 230000035515 penetration Effects 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 7
- 230000001939 inductive effect Effects 0.000 claims description 6
- 230000006872 improvement Effects 0.000 claims description 5
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 3
- 230000006866 deterioration Effects 0.000 claims description 3
- 238000010422 painting Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 2
- 239000011253 protective coating Substances 0.000 claims description 2
- 230000002311 subsequent effect Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 14
- 229910007567 Zn-Ni Inorganic materials 0.000 description 11
- 229910007614 Zn—Ni Inorganic materials 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 8
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 5
- 239000011686 zinc sulphate Substances 0.000 description 5
- 235000009529 zinc sulphate Nutrition 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 229940005574 sodium gluconate Drugs 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 229910007564 Zn—Co Inorganic materials 0.000 description 1
- HSSJULAPNNGXFW-UHFFFAOYSA-N [Co].[Zn] Chemical compound [Co].[Zn] HSSJULAPNNGXFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75898277A | 1977-01-13 | 1977-01-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1567101A true GB1567101A (en) | 1980-05-08 |
Family
ID=25053916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB512/78A Expired GB1567101A (en) | 1977-01-13 | 1978-01-06 | Production of multiple zinc/containing electro-coatings |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5389835A (enrdf_load_stackoverflow) |
| CA (1) | CA1117894A (enrdf_load_stackoverflow) |
| DE (1) | DE2800258C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2377460A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1567101A (enrdf_load_stackoverflow) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3226239A1 (de) * | 1981-07-14 | 1983-05-26 | Kobe Steel, Ltd., Kobe, Hyogo | Doppelschichtiges elektroplattiertes stahlblech mit korrosionswiderstand nach dem anstreichen und einem guten nasshaftvermoegen des anstrichfilms |
| GB2116588A (en) * | 1982-01-29 | 1983-09-28 | Occidental Chem Co | Electroplated zinc-cobalt alloy |
| DE3414048A1 (de) * | 1984-04-13 | 1985-10-17 | Nisshin Steel Co., Ltd., Tokio/Tokyo | Verfahren zum herstellen von mit einer zink-nickel-legierung galvanisierten stahlteilen |
| GB2161499A (en) * | 1984-07-06 | 1986-01-15 | Phenix Works Sa | Hot-galvanized steel product for phosphating |
| GB2185757A (en) * | 1986-01-27 | 1987-07-29 | John Edwin Thorpe | Dendritic surface treatment of metal layers |
| GB2230537A (en) * | 1989-03-28 | 1990-10-24 | Usui Kokusai Sangyo Kk | Corrosion resistant multilayer plating |
| CN119753681A (zh) * | 2025-02-24 | 2025-04-04 | 江东金具设备有限公司 | 一种抗磨蚀层及其制备方法 |
| CN119900060A (zh) * | 2025-03-18 | 2025-04-29 | 江东金具设备有限公司 | 一种抗磨蚀复合层及其制备方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4329402A (en) * | 1978-09-27 | 1982-05-11 | Whyco Chromium Co., Inc. | Micro-throwing alloy undercoatings and method for improving corrosion resistance |
| JPS5573888A (en) * | 1978-11-22 | 1980-06-03 | Nippon Kokan Kk <Nkk> | High corrosion resistant zinc-electroplated steel sheet with coating and non-coating |
| JPS55110792A (en) * | 1979-02-15 | 1980-08-26 | Sumitomo Metal Ind Ltd | Surface treated steel plate |
| JPS56119790A (en) * | 1980-02-22 | 1981-09-19 | Nippon Kokan Kk <Nkk> | Production of high-corrosive zinc-electroplated steel sheet |
| US4268364A (en) * | 1980-03-18 | 1981-05-19 | Inco Research & Development Center Inc. | Nickel-zinc alloy deposition from a sulfamate bath |
| JPS5751283A (en) * | 1980-09-12 | 1982-03-26 | Nippon Steel Corp | Electroplating method for zinc-iron alloy |
| JPS58204196A (ja) * | 1982-05-25 | 1983-11-28 | Nisshin Steel Co Ltd | 加工部耐食性に優れた電気亜鉛合金めつき鋼板の製造法 |
| DE3227755A1 (de) * | 1982-07-24 | 1984-04-12 | Hoesch Werke Ag, 4600 Dortmund | Verfahren zur herstellung von elektrolytisch legierverzinktem stahlblech |
| JPS6052592A (ja) * | 1983-09-02 | 1985-03-25 | Nisshin Steel Co Ltd | Ｚｎ−Ｎｉ系合金電気めっき鋼板の製造方法 |
| JPS60211096A (ja) * | 1984-04-03 | 1985-10-23 | Kawasaki Steel Corp | 高耐食性表面処理鋼板 |
| GB2212816B (en) * | 1987-11-26 | 1992-04-08 | Nippon Steel Corp | Zn-ni based composite electroplated material and multi-layer composite plated material |
| DE102006035233A1 (de) * | 2006-07-26 | 2008-01-31 | Mahle International Gmbh | Galvanische Oberflächenbeschichtung eines Bauteils |
| CN104005063A (zh) * | 2014-06-11 | 2014-08-27 | 沈阳飞机工业（集团）有限公司 | 一种钢制件电镀锌镍合金的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR453605A (fr) * | 1913-01-25 | 1913-06-12 | Sherard | Procédé pour protéger le fer contre la corrosion |
| BE470874A (enrdf_load_stackoverflow) * | 1940-12-21 | |||
| GB763065A (en) * | 1953-07-06 | 1956-12-05 | British Coated Sheets Ltd | Improvements in or relating to plated ferrous metallic materials and articles and the plating thereof |
| US2989446A (en) * | 1956-10-29 | 1961-06-20 | Rockwell Standard Co | Electroplating |
| US2994126A (en) * | 1957-10-29 | 1961-08-01 | Porter Co Inc H K | Ferrous metal body with alloyed zinc coating |
| US3064337A (en) * | 1958-05-19 | 1962-11-20 | Rockwell Standard Co | Composite metal article |
| GB1229932A (enrdf_load_stackoverflow) * | 1967-07-24 | 1971-04-28 | ||
| US3791801A (en) * | 1971-07-23 | 1974-02-12 | Toyo Kohan Co Ltd | Electroplated steel sheet |
| JPS51112437A (en) * | 1975-03-28 | 1976-10-04 | Nippon Kokan Kk | Electrogalvanized steel plate having excellent net corrosion resistance and property to be treated and method of fabricating the same |
-
1978
- 1978-01-04 CA CA000294313A patent/CA1117894A/en not_active Expired
- 1978-01-04 DE DE2800258A patent/DE2800258C2/de not_active Expired
- 1978-01-06 GB GB512/78A patent/GB1567101A/en not_active Expired
- 1978-01-11 FR FR7800676A patent/FR2377460A1/fr active Granted
- 1978-01-11 JP JP183078A patent/JPS5389835A/ja active Granted
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3226239A1 (de) * | 1981-07-14 | 1983-05-26 | Kobe Steel, Ltd., Kobe, Hyogo | Doppelschichtiges elektroplattiertes stahlblech mit korrosionswiderstand nach dem anstreichen und einem guten nasshaftvermoegen des anstrichfilms |
| GB2116588A (en) * | 1982-01-29 | 1983-09-28 | Occidental Chem Co | Electroplated zinc-cobalt alloy |
| DE3414048A1 (de) * | 1984-04-13 | 1985-10-17 | Nisshin Steel Co., Ltd., Tokio/Tokyo | Verfahren zum herstellen von mit einer zink-nickel-legierung galvanisierten stahlteilen |
| GB2161499A (en) * | 1984-07-06 | 1986-01-15 | Phenix Works Sa | Hot-galvanized steel product for phosphating |
| US4670354A (en) * | 1984-07-06 | 1987-06-02 | Phenix Works | Hot-galvanized steel product, notably intended to be phosphated, and method for preparing such a product |
| GB2185757A (en) * | 1986-01-27 | 1987-07-29 | John Edwin Thorpe | Dendritic surface treatment of metal layers |
| GB2185757B (en) * | 1986-01-27 | 1989-11-01 | John Edwin Thorpe | Dendritic surface treatment of copper layers |
| GB2230537A (en) * | 1989-03-28 | 1990-10-24 | Usui Kokusai Sangyo Kk | Corrosion resistant multilayer plating |
| GB2230537B (en) * | 1989-03-28 | 1993-12-08 | Usui Kokusai Sangyo Kk | Heat and corrosion resistant plating |
| CN119753681A (zh) * | 2025-02-24 | 2025-04-04 | 江东金具设备有限公司 | 一种抗磨蚀层及其制备方法 |
| CN119900060A (zh) * | 2025-03-18 | 2025-04-29 | 江东金具设备有限公司 | 一种抗磨蚀复合层及其制备方法 |
| CN119900060B (zh) * | 2025-03-18 | 2025-07-15 | 江东金具设备有限公司 | 一种抗磨蚀复合层及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5756557B2 (enrdf_load_stackoverflow) | 1982-11-30 |
| DE2800258A1 (de) | 1978-07-20 |
| JPS5389835A (en) | 1978-08-08 |
| DE2800258C2 (de) | 1982-11-11 |
| FR2377460B1 (enrdf_load_stackoverflow) | 1982-06-25 |
| CA1117894A (en) | 1982-02-09 |
| FR2377460A1 (fr) | 1978-08-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |