FR2592158A1 - Composition indiquant la temperature de maniere reversible. - Google Patents

Composition indiquant la temperature de maniere reversible.

Info

Publication number
FR2592158A1
FR2592158A1 FR8519140A FR8519140A FR2592158A1 FR 2592158 A1 FR2592158 A1 FR 2592158A1 FR 8519140 A FR8519140 A FR 8519140A FR 8519140 A FR8519140 A FR 8519140A FR 2592158 A1 FR2592158 A1 FR 2592158A1
Authority
FR
France
Prior art keywords
carboxylic acids
esters
metal salts
aliphatic carboxylic
degrees
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8519140A
Other languages
English (en)
Other versions
FR2592158B1 (fr
Inventor
Tsutomu Kito
Norikazu Nakasuji
Takashi Kataoka
Hiroshi Inagaki
Yutaka Shibahashi
Nobuaki Matsunami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pilot Ink Co Ltd
Original Assignee
Pilot Ink Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP59131535A priority Critical patent/JPS619488A/ja
Priority to DE3545813A priority patent/DE3545813C2/de
Priority to US06/812,572 priority patent/US4732810A/en
Application filed by Pilot Ink Co Ltd filed Critical Pilot Ink Co Ltd
Priority to GB08531817A priority patent/GB2184450A/en
Priority to FR8519140A priority patent/FR2592158B1/fr
Publication of FR2592158A1 publication Critical patent/FR2592158A1/fr
Application granted granted Critical
Publication of FR2592158B1 publication Critical patent/FR2592158B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K11/00—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
    • G01K11/12—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in colour, translucency or reflectance
    • G01K11/16—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in colour, translucency or reflectance of organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/305—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers with reversible electron-donor electron-acceptor compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S252/00—Compositions
    • Y10S252/962—Temperature or thermal history
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2984—Microcapsule with fluid core [includes liposome]

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Color Printing (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

La composition comprend : (A) un composé chromatique organique donneur d'électrons choisi parmi les diarylphtalides, les indolylphtalides, les polyarylcarbinols, les leuco-auramines, les acryl-auramines, les arylauramines, les lactames de Rhodamine B, les indoles, les spiropyrannes et les fluoranes ; (B) un composé choisi parmi les composés phénoliques en C6-C49, les sels métalliques des composés phénoliques, les acides carboxyliques aromatiques en C7-C12, les acides carboxyliques aliphatiques en C2-C5, les sels métalliques d'acides carboxyliques en C2-C22, les esters phosphoriques acides en C1-C44, les sels métalliques des esters phosphoriques acides et les triazoles en C2-C24 ; et (C) un composant ester ; lesdits composants (A), (B) et (C) étant présents dans une gamme de proportions de 1:0,1 à 50:1 à 800 et étant sous la forme d'un mélange fondu homogène, ledit composant (C) étant choisi parmi les composés suivants ayant une valeur DELTA T (degrés C) = point de fusion - point de trouble dans la gamme de 3 degrés C ou moins : les esters d'alkyles ramifiés et les esters d'alkylaryles d'acides carboxyliques aliphatiques saturés à chaîne droite et les esters d'alkyles d'acides carboxyliques aliphatiques ayant dans leur chaîne carbonée une ou des doubles liaisons, un groupe alkyle ramifié, un groupe hydroxy, un groupe carbonyle ou un atome d'halogène. (CF DESSIN DANS BOPI)
FR8519140A 1984-06-26 1985-12-24 Composition indiquant la temperature de maniere reversible. Expired - Lifetime FR2592158B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP59131535A JPS619488A (ja) 1984-06-26 1984-06-26 可逆性感熱示温組成物
DE3545813A DE3545813C2 (de) 1984-06-26 1985-12-23 Reversible Temperaturanzeigezusammensetzung
US06/812,572 US4732810A (en) 1984-06-26 1985-12-23 Reversible temperature-indicating composition
GB08531817A GB2184450A (en) 1984-06-26 1985-12-24 Reversible temperature-indicating compositions
FR8519140A FR2592158B1 (fr) 1984-06-26 1985-12-24 Composition indiquant la temperature de maniere reversible.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP59131535A JPS619488A (ja) 1984-06-26 1984-06-26 可逆性感熱示温組成物
FR8519140A FR2592158B1 (fr) 1984-06-26 1985-12-24 Composition indiquant la temperature de maniere reversible.

Publications (2)

Publication Number Publication Date
FR2592158A1 true FR2592158A1 (fr) 1987-06-26
FR2592158B1 FR2592158B1 (fr) 1992-07-31

Family

ID=37872284

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8519140A Expired - Lifetime FR2592158B1 (fr) 1984-06-26 1985-12-24 Composition indiquant la temperature de maniere reversible.

Country Status (5)

Country Link
US (1) US4732810A (fr)
JP (1) JPS619488A (fr)
DE (1) DE3545813C2 (fr)
FR (1) FR2592158B1 (fr)
GB (1) GB2184450A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1894747A2 (fr) * 2006-08-30 2008-03-05 Toyo Tire Rubber Co., Ltd. Pneumatique doté d'une partie changeant de couleur sensible à la température
FR2923906A1 (fr) * 2007-11-19 2009-05-22 Fagorbrandt Sas Soc Par Action Accessoire de conservation d'aliments destine a etre introduit dans une enceinte d'un appareil de congelation constitue d'un materiau thermochromique.

Families Citing this family (72)

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US4895827A (en) * 1987-12-04 1990-01-23 Appleton Papers Inc. Thermally-responsive record material
US4820683A (en) * 1987-12-04 1989-04-11 Appleton Papers Inc. Thermally-responsive record material
JPH02126126A (ja) * 1988-11-02 1990-05-15 Stanley Electric Co Ltd 温度分布調査方法
DE4020740A1 (de) * 1990-05-29 1991-12-05 Merck Patent Gmbh Verfahren zur herstellung mikroverkapselter fluessigkristalle
JP3751028B2 (ja) * 1992-02-28 2006-03-01 三菱製紙株式会社 蓄熱材用マイクロカプセル
JP3134108B2 (ja) * 1992-10-26 2001-02-13 パイロットインキ株式会社 熱変色性遮光性組成物及びこれを用いた積層体及び前記積層体を用いた内部隠顕立体物
US5441418A (en) * 1993-05-20 1995-08-15 Binney & Smith Inc. Thermochromic drawing device
DE69407154T2 (de) * 1993-12-24 1998-03-26 Pilot Ink Co Ltd Thermochrome Farbzusammensetzung mit Gedächtniseffekt
US5514635A (en) * 1993-12-29 1996-05-07 Optum Corporation Thermal writing surface and method for making the same
US5868821A (en) * 1996-01-31 1999-02-09 Richo Company, Ltd. Thermally reversible color forming composition and thermally reversible recording medium using the thermally reversible color forming composition
CA2235295A1 (fr) * 1997-04-23 1998-10-23 The Pilot Ink Co., Ltd. Compositions thermochromes reversibles
JP3917269B2 (ja) * 1997-10-07 2007-05-23 パイロットインキ株式会社 可逆熱変色性組成物
EP0919604B1 (fr) 1997-10-31 2004-01-02 The Pilot Ink Co., Ltd. Matériau de changement de couleur
US6294502B1 (en) 1998-05-22 2001-09-25 Bayer Aktiengesellschaft Thermally-responsive record material
US6753047B1 (en) 1999-06-10 2004-06-22 Ppg Industries Ohio, Inc. Electrodes for liquid crystal cells
CA2318700A1 (fr) 1999-09-17 2001-03-17 Katsuyuki Fujita Pigments microencapsules thermochromiques
CA2324637A1 (fr) 1999-10-29 2001-04-29 Nobuaki Matsunami Solide a construction thermochromique visible/invisible reversible incorporee
JP4303396B2 (ja) * 2000-04-13 2009-07-29 パイロットインキ株式会社 可逆熱変色性紫外線硬化型インキ及びそれを用いた可逆熱変色性積層体
US6554447B1 (en) 2000-04-14 2003-04-29 S. C. Johnson & Son, Inc. Candle product decorated with heat-shrinkable film and related method
JP2002012787A (ja) * 2000-04-28 2002-01-15 Pilot Ink Co Ltd 可逆熱変色性マイクロカプセル顔料
JP2002129055A (ja) * 2000-10-31 2002-05-09 Pilot Ink Co Ltd 可逆熱変色性マイクロカプセル顔料
JP2002234260A (ja) 2000-12-04 2002-08-20 Pilot Ink Co Ltd 可逆熱変色透光性積層体
JP2002234119A (ja) 2000-12-04 2002-08-20 Pilot Ink Co Ltd 可逆熱変色遮光性−透光性積層体
EP1221500A1 (fr) * 2001-01-04 2002-07-10 The Pilot Ink Co., Ltd. Fibres synthétiques acryliques thermochromiques, articles produits à partir de celles-ci et procédé pour leur fabrication
US6444313B1 (en) * 2001-01-05 2002-09-03 The Pilot Ink Co., Ltd. Thermochromic acrylic synthetic fiber, its processed article, and process for producing thermochromic acrylic synthetic fiber
DE10110019C1 (de) * 2001-03-01 2002-07-25 Spelsberg Guenther Gmbh Co Kg Gehäuse mit Temperaturwarnung
JP2002369978A (ja) 2001-04-13 2002-12-24 Pilot Ink Co Ltd 水変色性印刷物及びそれを用いた水変色性玩具
JP3910877B2 (ja) 2001-11-22 2007-04-25 パイロットインキ株式会社 感温変色性複合繊維
WO2003065856A2 (fr) * 2002-02-06 2003-08-14 University Of Akron Temoin de temperature faisant intervenir des materiaux thermochromiques
DE60336556D1 (de) * 2002-06-28 2011-05-12 Rhode Island Education Thermochrome indikatormaterialien mit kontrollierter reversibilität
US7011425B2 (en) * 2003-08-01 2006-03-14 S.C. Johnson & Son, Inc. Luminary product
US20050104035A1 (en) * 2003-11-13 2005-05-19 Christopher Eaddy Intelligent label for informing consumers of product quality criteria
US20050177215A1 (en) * 2004-02-11 2005-08-11 Rosenberg Steven L. Method and device for lower extremity cryo-thermo therapy
US7513682B2 (en) * 2004-05-11 2009-04-07 Hewlett-Packard Development Company, L.P. Temperature monitoring system
JP4754224B2 (ja) * 2005-01-25 2011-08-24 パイロットインキ株式会社 可逆熱変色性組成物及びそれを内包した可逆熱変色性マイクロカプセル顔料
US7335624B2 (en) * 2005-01-27 2008-02-26 The Pilot Ink Co., Ltd. Reversible thermochromic display article
JP5415671B2 (ja) 2006-01-27 2014-02-12 パイロットインキ株式会社 摩擦体及びそれを備えた筆記具、筆記具セット
US7465693B2 (en) * 2006-09-13 2008-12-16 Flint Trading, Inc. Thermochromatic temperature marking for outdoor surfaces
CA2664623A1 (fr) * 2006-09-27 2008-04-03 Luvgear Inc. Dispositif et procede pour identifier un changement dans une condition predeterminee
JP2008120059A (ja) 2006-10-17 2008-05-29 Pilot Ink Co Ltd 筆記具、筆記具セット
JP2008155624A (ja) 2006-11-29 2008-07-10 Pilot Ink Co Ltd 摩擦体及びそれを用いた筆記具、筆記具セット
US20080145940A1 (en) * 2006-12-18 2008-06-19 3M Innovative Properties Company Chemical indicator test strip
US20080145948A1 (en) * 2006-12-18 2008-06-19 3M Innovative Properties Company Chemical indicator test strip
US20090153837A1 (en) * 2007-12-17 2009-06-18 Bwt Property, Inc. Optical power monitor based on thermo-chromic material
US8986915B2 (en) 2009-02-16 2015-03-24 Toshiba Tec Kabushiki Kaisha Toner, method for producing the same, cartridge storing the same, process cartridge, and image forming apparatus
US8252496B2 (en) 2009-02-16 2012-08-28 Toshiba Tec Kabushiki Kaisha Developing agent and method for producing the same
US20100304142A1 (en) * 2009-05-27 2010-12-02 Toshiba Tec Kabushiki Kaisha Color erasable recording material and method for producing the same
JP5511259B2 (ja) 2009-08-18 2014-06-04 パイロットインキ株式会社 可逆熱変色性水性インキ組成物及びそれを用いた筆記具、筆記具セット
JP5557542B2 (ja) * 2010-02-04 2014-07-23 パイロットインキ株式会社 摩擦具及びそれを備えた筆記具
JP5129397B2 (ja) * 2010-03-31 2013-01-30 日油技研工業株式会社 温度管理インジケータ及びそれが付された構造物
DE102011006362A1 (de) * 2011-03-29 2012-10-04 Evonik Goldschmidt Gmbh Isopentylester zur Verwendung in kosmetischen, dermatologischen oder pharmazeutischen Kompositionen
US8652996B2 (en) 2011-12-31 2014-02-18 Sanford, L.P. Irreversible thermochromic pigment capsules
US8664156B2 (en) 2011-12-31 2014-03-04 Sanford, L.P. Irreversible thermochromic ink compositions
US8709973B2 (en) 2011-12-31 2014-04-29 Sanford, L.P. Irreversible thermochromic ink compositions
FR2986324A1 (fr) * 2012-01-30 2013-08-02 Gem Innov Indicateur de respect d'une plage de temperature
US8865621B2 (en) 2012-08-06 2014-10-21 Sanford, L.P. Irreversible color changing ink compositions
EP3346245A4 (fr) * 2015-09-03 2019-06-05 Hitachi, Ltd. Indicateur d'historique des températures
US10983013B2 (en) * 2015-10-21 2021-04-20 Hitachi, Ltd. Temperature sensing body
JP6771208B2 (ja) * 2016-07-07 2020-10-21 平岡織染株式会社 可撓性調光シート
JP6771211B2 (ja) * 2016-07-15 2020-10-21 平岡織染株式会社 可撓性調光シート
DE102016214617B4 (de) 2016-08-05 2022-06-23 Stabilo International Gmbh Löschbare Tinte, deren Verwendung und Tintenpatrone die mit der löschbaren Tinte befült ist
DE202016004825U1 (de) 2016-08-05 2017-11-07 Stabilo International Gmbh Löschbare Tinte und ihre Verwendung
DE202016005058U1 (de) 2016-08-17 2017-11-19 Stabilo International Gmbh Löschbare Tinte und ihre Verwendung
JP7262228B2 (ja) 2016-12-19 2023-04-21 株式会社パイロットコーポレーション 摩擦体並びに筆記具及び筆記セット
EP3702419B1 (fr) 2017-10-23 2023-09-20 Kabushiki Kaisha Pilot Corporation (also trading as Pilot Corporation) Composition d'encre aqueuse thermochromique réversible et instrument d'écriture l'utilisant
US11313730B2 (en) * 2018-03-14 2022-04-26 Temptime Corporation Descending and ascending temperature indicators utilizing deep eutectics
CN109229912B (zh) * 2018-07-23 2020-09-04 企鹅兰登（北京）文化发展有限公司 一种可逆感温变化内容的印刷品及其包装容器
KR20220160547A (ko) 2020-03-31 2022-12-06 가부시키가이샤 파이롯트 코포레이숀 열변색성 필기구
WO2022065228A1 (fr) 2020-09-28 2022-03-31 パイロットインキ株式会社 Composition thermochromique réversible et pigment en microcapsule thermochromique réversible encapsulant ladite composition
WO2022065229A1 (fr) 2020-09-28 2022-03-31 パイロットインキ株式会社 Composition thermochromique réversible, et pigment thermochromique réversible en microcapsule la contenant
JP7510901B2 (ja) 2021-03-19 2024-07-04 東芝テック株式会社 画像形成装置
CN117355577A (zh) 2021-05-31 2024-01-05 株式会社百乐 书写工具用墨液组合物和收容书写工具用墨液组合物而成的书写工具

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US3451338A (en) * 1964-05-11 1969-06-24 Ncr Co Thermographic recording system
FR2090862A5 (fr) * 1970-04-28 1972-01-14 Fuji Photo Film Co Ltd
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1894747A2 (fr) * 2006-08-30 2008-03-05 Toyo Tire Rubber Co., Ltd. Pneumatique doté d'une partie changeant de couleur sensible à la température
EP1894747A3 (fr) * 2006-08-30 2009-07-01 Toyo Tire Rubber Co., Ltd. Pneumatique doté d'une partie changeant de couleur sensible à la température
FR2923906A1 (fr) * 2007-11-19 2009-05-22 Fagorbrandt Sas Soc Par Action Accessoire de conservation d'aliments destine a etre introduit dans une enceinte d'un appareil de congelation constitue d'un materiau thermochromique.

Also Published As

Publication number Publication date
DE3545813A1 (de) 1987-06-25
FR2592158B1 (fr) 1992-07-31
US4732810A (en) 1988-03-22
GB2184450A (en) 1987-06-24
DE3545813C2 (de) 1994-02-24
JPH0129398B2 (fr) 1989-06-09
JPS619488A (ja) 1986-01-17
GB8531817D0 (en) 1986-02-05
GB2184450B (fr) 1989-10-18

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