ES462969A1 - Procedimiento para producir metacrilonitrilo. - Google Patents
Procedimiento para producir metacrilonitrilo.Info
- Publication number
- ES462969A1 ES462969A1 ES462969A ES462969A ES462969A1 ES 462969 A1 ES462969 A1 ES 462969A1 ES 462969 A ES462969 A ES 462969A ES 462969 A ES462969 A ES 462969A ES 462969 A1 ES462969 A1 ES 462969A1
- Authority
- ES
- Spain
- Prior art keywords
- containing compounds
- preparation
- tertiary
- tertiary butyl
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para producir metacrilonitrilo por oxidación con amoniaco de un compuesto que contiene butilo terciario, elegido del grupo que consta de alcohol butílico terciario, éter alcohol-terc-butílico en el que el grupo alcohilo contiene de 1 a 4 átomos de carbono, dímero de isobutileno, trímero de isobutileno, o mezclas de dímero de isobutileno y/o trímero de isobutileno con isobutileno, en presencia de amoniaco, oxígeno molecular, y opcionalmente en presencia de vapor de agua, a una termperatura elelvada, y en presencia de un catalizador que tiene la fórmula AaCcFeeBiFDdMogOx, donde A es un metal alcalino bario, estroncio, talio, indio, plata, cobre o una mezcla de ellos, C es níquel, cobalto, magnesio, cinc, manganeso, cadmio, calcio o mezclas de ellos, D es fósforo, antiomonio, germanio, cromo, torio, estaño, niobio, praseodimio, wolframio, boro, zirconio, cerio, arsénico o mezclas de ellos y donde a es un número de 0 a 3, c es un número de 0,001 a 12, d es un número de 0a 3, e y f son, cada uno, un número de 0,01 a 12, g es 12, y x es el número de oxígenos requerido para satisfacer los requisitos de valencia de los otros elementos presentes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/711,014 US4065507A (en) | 1976-08-02 | 1976-08-02 | Preparation of methacrylic derivatives from tertiary butyl-containing compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
ES462969A1 true ES462969A1 (es) | 1978-06-16 |
Family
ID=24856442
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES461227A Expired ES461227A1 (es) | 1976-08-02 | 1977-08-01 | Un procedimiento para preparar metacroleina. |
ES462969A Expired ES462969A1 (es) | 1976-08-02 | 1977-10-06 | Procedimiento para producir metacrilonitrilo. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES461227A Expired ES461227A1 (es) | 1976-08-02 | 1977-08-01 | Un procedimiento para preparar metacroleina. |
Country Status (19)
Country | Link |
---|---|
US (1) | US4065507A (es) |
JP (1) | JPS5318508A (es) |
AT (1) | AT358002B (es) |
BE (1) | BE857324A (es) |
BR (1) | BR7704883A (es) |
CA (1) | CA1113498A (es) |
CH (2) | CH635056A5 (es) |
CS (2) | CS194845B2 (es) |
DD (2) | DD132860A5 (es) |
DE (1) | DE2732952C2 (es) |
ES (2) | ES461227A1 (es) |
FR (1) | FR2360545A1 (es) |
GB (1) | GB1564459A (es) |
IT (1) | IT1085664B (es) |
MX (1) | MX147440A (es) |
NL (1) | NL7708493A (es) |
NO (1) | NO772723L (es) |
PT (1) | PT66875B (es) |
YU (1) | YU190277A (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4111984A (en) * | 1973-06-11 | 1978-09-05 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, and unsaturated fatty acids |
CA1133505A (en) * | 1977-07-28 | 1982-10-12 | Andrew T. Guttmann | Process for the oxidation of olefins |
IL55073A (en) * | 1977-07-28 | 1982-01-31 | Standard Oil Co | Catalysts for the oxidation and ammoxidation of olefins |
US4230640A (en) * | 1977-11-01 | 1980-10-28 | Halcon International, Inc. | Process for the preparation of acrolein and methacrolein |
JPS584691B2 (ja) * | 1977-11-07 | 1983-01-27 | 宇部興産株式会社 | メタクロレインの製造方法 |
GB2033775B (en) * | 1978-10-13 | 1983-02-09 | Asahi Chemical Ind | Catalysts and process for the production of methacrolein catalysts |
US4230639A (en) * | 1979-01-19 | 1980-10-28 | Halcon International, Inc. | Process for the preparation of methacrolein |
US4280928A (en) * | 1979-10-12 | 1981-07-28 | Rohm And Haas Company | Catalyst compositions and their use for the preparation of methacrolein |
US4358622A (en) * | 1979-10-12 | 1982-11-09 | Rohm And Haas Company | Preparation of methacrolein and methacrylonitrile from tert-butyl alkanoates |
US4306090A (en) * | 1979-10-12 | 1981-12-15 | Rohm And Haas Company | Catalyst compositions and their use for the preparation of methacrolein |
JPS56166140A (en) * | 1980-05-24 | 1981-12-21 | Asahi Chem Ind Co Ltd | Preparation of methacrolein |
US4446328A (en) * | 1980-05-19 | 1984-05-01 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing methacrolein |
JPS5728012A (en) * | 1980-07-25 | 1982-02-15 | Mitsubishi Gas Chem Co Inc | Preparation of tertiary olefin |
US4443383A (en) * | 1981-03-19 | 1984-04-17 | Rohm And Haas Company | Preparation of methacrolein and methacrylonitrile from tert-butyl alkanoates |
US4558154A (en) * | 1981-04-27 | 1985-12-10 | Atlantic Richfield Company | Oxidation of isobutylene oxide to methacrylic acid and methacrolein |
US4537998A (en) * | 1981-04-27 | 1985-08-27 | Atlantic Richfield Company | Process for the oxidation of isobutylene oxide to methacrolein |
US4474997A (en) * | 1982-07-06 | 1984-10-02 | E. I. Du Pont De Nemours And Company | Oxidation process and catalyst therefor |
JPS6122040A (ja) * | 1984-07-10 | 1986-01-30 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
JPH07116070B2 (ja) * | 1987-08-26 | 1995-12-13 | 株式会社日本触媒 | メチルタ−シャリ−ブチルエ−テルからメタクロレインおよびメタクリル酸の製法 |
JP2520279B2 (ja) * | 1988-03-03 | 1996-07-31 | 日東化学工業株式会社 | アクリロニトリルの製造方法 |
US7851397B2 (en) | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
US7649112B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
US7732367B2 (en) | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
US7649111B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1018799A (fr) * | 1949-03-25 | 1953-01-13 | Distillers Co Yeast Ltd | Nouveaux composés organiques oxygénés |
US3470239A (en) * | 1968-06-07 | 1969-09-30 | Halcon International Inc | Process for preparing methacrylic acid and its esters from isobutane |
US3642930A (en) * | 1968-12-30 | 1972-02-15 | Standard Oil Co Ohio | Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor |
BE755422A (fr) * | 1969-09-08 | 1971-03-01 | Inst Francais Du Petrole | Fabrication de catalyseurs du type molybdate de fer utilisablesnotamment pour l'oxydation catalytique des alcools en |
JPS5112603B1 (es) * | 1971-05-26 | 1976-04-21 | ||
US3972920A (en) * | 1973-06-11 | 1976-08-03 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes |
JPS5163112A (en) * | 1974-11-27 | 1976-06-01 | Nippon Kayaku Kk | Metakuroreinno seizoho |
GB1490683A (en) * | 1975-03-12 | 1977-11-02 | Mitsubishi Rayon Co | Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene |
JPS5939413B2 (ja) * | 1975-04-08 | 1984-09-22 | 三菱レイヨン株式会社 | メタクロレインとメタクリル酸の製造方法 |
-
1976
- 1976-08-02 US US05/711,014 patent/US4065507A/en not_active Expired - Lifetime
-
1977
- 1977-07-15 CA CA282,896A patent/CA1113498A/en not_active Expired
- 1977-07-21 DE DE2732952A patent/DE2732952C2/de not_active Expired
- 1977-07-25 GB GB31076/77A patent/GB1564459A/en not_active Expired
- 1977-07-26 BR BR7704883A patent/BR7704883A/pt unknown
- 1977-07-27 JP JP9024177A patent/JPS5318508A/ja active Pending
- 1977-07-28 AT AT555377A patent/AT358002B/de not_active IP Right Cessation
- 1977-07-29 FR FR7723447A patent/FR2360545A1/fr active Pending
- 1977-07-29 DD DD7700200356A patent/DD132860A5/xx unknown
- 1977-07-29 CS CS782906A patent/CS194845B2/cs unknown
- 1977-07-29 DD DD77207071A patent/DD137582A5/xx unknown
- 1977-07-29 CS CS775036A patent/CS194814B2/cs unknown
- 1977-07-29 CH CH942877A patent/CH635056A5/de not_active IP Right Cessation
- 1977-07-29 BE BE179784A patent/BE857324A/xx not_active IP Right Cessation
- 1977-08-01 NO NO772723A patent/NO772723L/no unknown
- 1977-08-01 MX MX170061A patent/MX147440A/es unknown
- 1977-08-01 IT IT26381/77A patent/IT1085664B/it active
- 1977-08-01 ES ES461227A patent/ES461227A1/es not_active Expired
- 1977-08-01 NL NL7708493A patent/NL7708493A/xx not_active Application Discontinuation
- 1977-08-01 PT PT66875A patent/PT66875B/pt unknown
- 1977-08-02 YU YU01902/77A patent/YU190277A/xx unknown
- 1977-10-06 ES ES462969A patent/ES462969A1/es not_active Expired
-
1982
- 1982-02-18 CH CH103082A patent/CH635315A5/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE2732952C2 (de) | 1987-02-12 |
GB1564459A (en) | 1980-04-10 |
NL7708493A (nl) | 1978-02-06 |
YU190277A (en) | 1983-01-21 |
CS194814B2 (en) | 1979-12-31 |
FR2360545A1 (fr) | 1978-03-03 |
JPS5318508A (en) | 1978-02-20 |
DE2732952A1 (de) | 1978-02-09 |
CH635056A5 (de) | 1983-03-15 |
CA1113498A (en) | 1981-12-01 |
BE857324A (fr) | 1977-11-14 |
ES461227A1 (es) | 1978-12-01 |
MX147440A (es) | 1982-12-03 |
IT1085664B (it) | 1985-05-28 |
CS194845B2 (en) | 1979-12-31 |
CH635315A5 (de) | 1983-03-31 |
DD137582A5 (de) | 1979-09-12 |
US4065507A (en) | 1977-12-27 |
AT358002B (de) | 1980-08-11 |
DD132860A5 (de) | 1978-11-15 |
ATA555377A (de) | 1980-01-15 |
PT66875B (en) | 1979-01-23 |
PT66875A (en) | 1977-09-01 |
BR7704883A (pt) | 1978-06-13 |
NO772723L (no) | 1978-02-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19971103 |