FR2386513A1 - Procede pour la preparation d'esters d'acide oxalique - Google Patents

Procede pour la preparation d'esters d'acide oxalique

Info

Publication number
FR2386513A1
FR2386513A1 FR7810270A FR7810270A FR2386513A1 FR 2386513 A1 FR2386513 A1 FR 2386513A1 FR 7810270 A FR7810270 A FR 7810270A FR 7810270 A FR7810270 A FR 7810270A FR 2386513 A1 FR2386513 A1 FR 2386513A1
Authority
FR
France
Prior art keywords
preparation
acid esters
oxalic acid
compound
acidic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7810270A
Other languages
English (en)
Other versions
FR2386513B1 (fr
Inventor
Ugo Romano
Franco Rivetti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of FR2386513A1 publication Critical patent/FR2386513A1/fr
Application granted granted Critical
Publication of FR2386513B1 publication Critical patent/FR2386513B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/36—Oxalic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Steroid Compounds (AREA)

Abstract

Ce procédé consite à faire réagir l'oxyde de carbone sous pression avec l'alcool approprié en utilisant un système catalytique très particulier. Celui-ci est un système binaire dans lequel le constituant principal est un complexe du palladium et le co-catalyseur est un composé, de préférence un composé organique de nature acide, meme faiblement acide.
FR7810270A 1977-04-07 1978-04-06 Procede pour la preparation d'esters d'acide oxalique Granted FR2386513A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT22209/77A IT1078033B (it) 1977-04-07 1977-04-07 Processo per la preparazione di esteri dell'acido ossalico

Publications (2)

Publication Number Publication Date
FR2386513A1 true FR2386513A1 (fr) 1978-11-03
FR2386513B1 FR2386513B1 (fr) 1980-07-11

Family

ID=11193068

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7810270A Granted FR2386513A1 (fr) 1977-04-07 1978-04-06 Procede pour la preparation d'esters d'acide oxalique

Country Status (37)

Country Link
US (1) US4230881A (fr)
JP (1) JPS53124215A (fr)
AR (1) AR222793A1 (fr)
AT (1) AT356638B (fr)
AU (1) AU518170B2 (fr)
BE (1) BE865812A (fr)
BG (1) BG28568A3 (fr)
BR (1) BR7802216A (fr)
CA (1) CA1112662A (fr)
CH (1) CH633516A5 (fr)
CS (1) CS207595B2 (fr)
DD (1) DD135719A5 (fr)
DE (1) DE2814708C2 (fr)
DK (1) DK153978A (fr)
EG (1) EG13299A (fr)
ES (1) ES469431A1 (fr)
FR (1) FR2386513A1 (fr)
GB (1) GB1583336A (fr)
GR (1) GR63768B (fr)
HU (1) HU180935B (fr)
IE (1) IE46767B1 (fr)
IL (1) IL54417A (fr)
IN (1) IN148036B (fr)
IT (1) IT1078033B (fr)
LU (1) LU79397A1 (fr)
MW (1) MW1178A1 (fr)
MX (1) MX147280A (fr)
NL (1) NL7803646A (fr)
NO (1) NO781207L (fr)
PL (1) PL118175B1 (fr)
PT (1) PT67875B (fr)
RO (1) RO75614A (fr)
SE (1) SE7803853L (fr)
SU (1) SU831070A3 (fr)
TR (1) TR19773A (fr)
YU (1) YU81278A (fr)
ZA (1) ZA781866B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4614832A (en) * 1979-12-17 1986-09-30 Chevron Research Company Dialkyl oxalates from carbon monoxide and an alcohol
JPS5867647A (ja) * 1981-10-15 1983-04-22 Ube Ind Ltd マロン酸ジエステルの製造法
US4523029A (en) * 1982-06-15 1985-06-11 Chevron Research Company Oxidative carbonylation of alcohols to produce dialkyl oxalates
US4454342A (en) * 1982-07-13 1984-06-12 Atlantic Richfield Company Preparation of dialkyl oxalates using a heterogeneous Pd-V-P catalyst for the oxidative carbonylation of alcohols
US4447638A (en) * 1982-08-02 1984-05-08 Atlantic Richfield Company Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system
US4447639A (en) * 1982-08-06 1984-05-08 Atlantic Richfield Company Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst
US4451666A (en) * 1982-08-06 1984-05-29 Atlantic Richfield Company Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst
DE3342291A1 (de) * 1983-11-23 1985-05-30 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
US4554374A (en) * 1984-08-27 1985-11-19 Texaco Inc. Process for dicarbonylation of simple olefins
US4552976A (en) * 1984-08-27 1985-11-12 Texaco Inc. Process for oxidative dicarbonylation of butadiene
DE3513255A1 (de) * 1985-04-13 1986-10-23 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
US4629807A (en) * 1986-02-06 1986-12-16 Texaco Inc. Selective synthesis of aliphatic dicarboxylic acid esters using palladium-phosphine or palladium-arsine catalysts
RU2493238C1 (ru) * 2012-09-26 2013-09-20 Государственное унитарное предприятие "Институт нефтехимпереработки Республики Башкортостан" (ГУП "ИНХП РБ") Способ получения эфирной присадки к глубоко гидроочищенному дизельному топливу
RU2659069C1 (ru) * 2014-06-05 2018-06-28 Шанхай Учжэн Инжиниринг Текнолоджи Ко., Лтд Способ и система устройств для получения диметилоксалата карбонилированием промышленного синтез-газа при средневысоком и высоком давлении и получения этиленгликоля гидрированием диметилоксалата
CN105330542A (zh) * 2014-07-03 2016-02-17 中国石油化工股份有限公司 草酸二甲酯的生产方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3994960A (en) * 1974-04-05 1976-11-30 Ube Industries, Ltd. Process for preparing dialkyl oxalates
US4005128A (en) * 1975-04-02 1977-01-25 Atlantic Richfield Company Process for the preparation of oxalate esters
US4005129A (en) * 1975-06-04 1977-01-25 Atlantic Richfield Company Process for the oxidative carbonylation of alcohols and method for the reoxidation of reduced copper salts produced by the oxidation carbonylation
JPS5315313A (en) * 1976-07-27 1978-02-13 Ube Ind Ltd Production of oxalic acid diesters

Also Published As

Publication number Publication date
ATA243378A (de) 1979-10-15
DK153978A (da) 1978-10-08
SU831070A3 (ru) 1981-05-15
US4230881A (en) 1980-10-28
SE7803853L (sv) 1978-10-08
BR7802216A (pt) 1979-01-02
AR222793A1 (es) 1981-06-30
GR63768B (en) 1979-12-15
IT1078033B (it) 1985-05-08
PT67875A (en) 1978-05-01
MW1178A1 (en) 1979-05-09
DE2814708A1 (de) 1978-10-19
IL54417A0 (en) 1978-07-31
PL205895A1 (pl) 1978-12-18
CS207595B2 (en) 1981-08-31
BG28568A3 (bg) 1980-05-15
JPS53124215A (en) 1978-10-30
CA1112662A (fr) 1981-11-17
NL7803646A (nl) 1978-10-10
YU81278A (en) 1982-06-30
MX147280A (es) 1982-11-04
IL54417A (en) 1981-09-13
IE780692L (en) 1978-10-07
AU3479278A (en) 1979-10-11
EG13299A (en) 1981-03-31
TR19773A (tr) 1979-11-30
BE865812A (fr) 1978-10-09
ES469431A1 (es) 1979-02-16
GB1583336A (en) 1981-01-28
FR2386513B1 (fr) 1980-07-11
AU518170B2 (en) 1981-09-17
IN148036B (fr) 1980-10-04
PL118175B1 (en) 1981-09-30
RO75614A (fr) 1980-11-30
LU79397A1 (fr) 1978-07-12
ZA781866B (en) 1979-03-28
HU180935B (en) 1983-05-30
AT356638B (de) 1980-05-12
IE46767B1 (en) 1983-09-21
CH633516A5 (it) 1982-12-15
NO781207L (no) 1978-10-10
PT67875B (en) 1979-11-14
DE2814708C2 (de) 1982-08-26
DD135719A5 (de) 1979-05-23

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Legal Events

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ST Notification of lapse