FI74990B - Paerlglanspigment. - Google Patents
Paerlglanspigment. Download PDFInfo
- Publication number
- FI74990B FI74990B FI833387A FI833387A FI74990B FI 74990 B FI74990 B FI 74990B FI 833387 A FI833387 A FI 833387A FI 833387 A FI833387 A FI 833387A FI 74990 B FI74990 B FI 74990B
- Authority
- FI
- Finland
- Prior art keywords
- pigment
- chromium
- pigments
- mica
- surface layer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/301—Thickness of the core
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/40—Interference pigments comprising an outermost surface coating
- C09C2200/401—Inorganic protective coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/10—Wet methods, e.g. co-precipitation
- C09C2220/106—Wet methods, e.g. co-precipitation comprising only a drying or calcination step of the finally coated pigment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Claims (10)
1. Pärlglanspigment med förbättrad väderleksstabili-5 tet pä basis av med metalloxider överdragna glimmerfjäll, vilka försetts med ett stabiliserande, kromhaltig ytskikt, kännetecknat därav, att ytskiktet bestär av en kombination av metallsalt, varvid järn och/eller mangan i form av hydroxid, karbonat eller fosfat och krom i form 10 av hydroxid, karbonat, fosfat eller som metakrylkromklorid utfälls pä utgängspigmenten.
2. Pärlglanspigment enligt patentkravet 1, kännetecknat därav, att ytskiktet utgör 0,1 - 10% av pigmentvikten. 15
3. Pärlglanspigment enligt patentkravet 1 eller 2, kännetecknat därav, att andelen kromförening 1 ytskiktet utgör ca. 20-80 vikt%.
4. Pärlglanspigment enligt nägot av patentkraven 1-3, kännetecknat därav, att metallerna före- 20 ligger i form av fosfater.
5. Pärlglanspigment enligt nägot av patentkraven 1-3, kännetecknat därav, att järn och/eller mangan föreligger i form av fosfat och krom i form av meta-krylatkromklorid. 25
6. Förfarande för framställning av pärlglanspigmen- ten enligt patentkravet 1, kännetecknat därav, att man i en vattenhaltig suspension av ett med metalloxider överdraget glimmerfjällpigment och vid ett pH mellan 2 och 8 tillsätter järn och/eller mangan samt krom i form 30 av saltlösningar och utfäller dessa pä glimmerfjällpigmen- ten, varefter pigmenten separeras och torkas.
7. Förfarande enligt patentkravet 6, kännetecknat därav, att pH-värdet i hög grad hälls kons-tant vid 4-7. 35
8. Förfarande enligt patentkravet 6 eller 7, kännetecknat därav, att utfällningen av metall-salten sker gemensamt.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3235017 | 1982-09-22 | ||
DE19823235017 DE3235017A1 (de) | 1982-09-22 | 1982-09-22 | Perlglanzpigmente |
Publications (4)
Publication Number | Publication Date |
---|---|
FI833387A0 FI833387A0 (fi) | 1983-09-21 |
FI833387A FI833387A (fi) | 1984-03-23 |
FI74990B true FI74990B (fi) | 1987-12-31 |
FI74990C FI74990C (sv) | 1988-04-11 |
Family
ID=6173817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI833387A FI74990C (sv) | 1982-09-22 | 1983-09-21 | Pärlglanspigment. |
Country Status (17)
Country | Link |
---|---|
US (1) | US4482389A (sv) |
EP (1) | EP0104516B1 (sv) |
JP (1) | JPS5978265A (sv) |
KR (1) | KR910004813B1 (sv) |
AR (1) | AR245948A1 (sv) |
AU (1) | AU562638B2 (sv) |
BR (1) | BR8305166A (sv) |
CA (1) | CA1203953A (sv) |
CS (1) | CS244430B2 (sv) |
DE (2) | DE3235017A1 (sv) |
ES (1) | ES525800A0 (sv) |
FI (1) | FI74990C (sv) |
HU (1) | HU193655B (sv) |
IN (1) | IN160815B (sv) |
MX (1) | MX155769A (sv) |
PL (1) | PL136638B2 (sv) |
ZA (1) | ZA837029B (sv) |
Families Citing this family (121)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3528256A1 (de) * | 1985-08-07 | 1987-02-19 | Merck Patent Gmbh | Eisenoxidbeschichtete perlglanzpigmente |
DE3617430A1 (de) * | 1986-05-23 | 1987-11-26 | Merck Patent Gmbh | Perlglanzpigmente |
US5223034A (en) * | 1988-05-19 | 1993-06-29 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Weather-resistant, pearlescent pigment and process for producing the same in the presence of hypophosphite |
CA1329867C (en) * | 1988-07-20 | 1994-05-31 | Hiroshi Ito | Pigment |
JP2508816B2 (ja) * | 1988-09-19 | 1996-06-19 | トヨタ自動車株式会社 | 顔料の製造方法 |
US5270352A (en) * | 1989-07-05 | 1993-12-14 | Basf Corporation | Surface-modified micaceous particulates having improved dispersibility in aqueous media |
US5308394A (en) * | 1990-04-05 | 1994-05-03 | Toyota Jidosha Kabushiki Kaisha | Pigment and process for producing the same |
US5119871A (en) * | 1990-04-06 | 1992-06-09 | The B. F. Goodrich Company | Opacified pearlescent multilayer louver for vertical blinds |
US5022700A (en) * | 1990-07-19 | 1991-06-11 | Auto Wrap, Inc. | Mounting system for an automobile cover |
DE4120921A1 (de) | 1991-06-25 | 1993-01-07 | Merck Patent Gmbh | Oberflaechenmodifizierte plaettchenfoermige substrate mit verbessertem absetz- und aufruehrverhalten |
DE4140296A1 (de) * | 1991-12-06 | 1993-06-09 | Merck Patent Gmbh, 6100 Darmstadt, De | Leitfaehige plaettchenfoermige pigmente |
US5273576A (en) * | 1992-10-19 | 1993-12-28 | Mearl Corporation | Intensely colored pearlescent pigments |
DE4321005A1 (de) | 1993-06-24 | 1995-01-05 | Merck Patent Gmbh | Perlglanzpigment für Wasserlacksysteme |
DE4443048A1 (de) | 1994-12-05 | 1996-06-13 | Merck Patent Gmbh | Effektpulverlacke |
US5693134A (en) | 1994-12-29 | 1997-12-02 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Gray interference pigment and process for producing the same |
DE19522397A1 (de) * | 1995-06-23 | 1997-01-02 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
JP3643144B2 (ja) * | 1995-08-04 | 2005-04-27 | メルク株式会社 | 新規な真珠光沢顔料およびその製造方法 |
DE19639783A1 (de) * | 1996-09-27 | 1998-04-02 | Merck Patent Gmbh | Modifizierte Perlglanzpigmente für Wasserlacksysteme |
US6107244A (en) * | 1997-10-15 | 2000-08-22 | Nashua Corporation | Verification methods employing thermally--imageable substrates |
US6139615A (en) * | 1998-02-27 | 2000-10-31 | Engelhard Corporation | Pearlescent pigments containing ferrites |
DE10046152A1 (de) | 2000-09-15 | 2002-03-28 | Merck Patent Gmbh | Pigmentpräparation in Granulatform |
DE19951871A1 (de) | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
DE19951869A1 (de) | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
KR20020093904A (ko) | 2000-04-11 | 2002-12-16 | 메르크 파텐트 게엠베하 | 각도 선택적인 투과 또는 반사 특성 및/또는 흡수 특성을갖는 투명 매질 |
US6451102B1 (en) | 2000-05-04 | 2002-09-17 | Merck Patent Gmbh | Pigment modification improving handling characteristics |
DE10034972A1 (de) | 2000-07-19 | 2002-01-31 | Merck Patent Gmbh | Verfahren zur Herstellung eines Pulverlacks, ein Pulverlack sowie die Verwendung von Effektpigmenten |
DE10054981A1 (de) | 2000-11-06 | 2002-05-16 | Merck Patent Gmbh | Nachbeschichtung von Perlglanzpigmenten mit hydrophoben Kupplungsreagenzien |
DE10054980C2 (de) * | 2000-11-06 | 2003-02-06 | Merck Patent Gmbh | Stabilisierung von Perlglanzpigmenten |
DE10128489A1 (de) | 2001-06-12 | 2002-12-19 | Merck Patent Gmbh | Mehrschichtige Glanzpigmente |
DE10128488A1 (de) | 2001-06-12 | 2002-12-19 | Merck Patent Gmbh | Optische Multischichtsysteme |
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DE102008025277A1 (de) | 2008-05-27 | 2009-12-03 | Merck Patent Gmbh | Glaszusammensetzung |
DE102008050924A1 (de) | 2008-10-10 | 2010-04-15 | Merck Patent Gmbh | Pigmente |
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EP2493987B1 (en) | 2009-10-28 | 2014-07-09 | Basf Se | Pigments with improved sparkling effect |
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DE102013012023A1 (de) | 2013-07-19 | 2015-01-22 | Merck Patent Gmbh | Pigmentgemisch |
DE102014003975A1 (de) | 2014-03-20 | 2015-10-08 | Merck Patent Gmbh | Effektpigmente |
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DE102015013400A1 (de) | 2015-10-19 | 2017-04-20 | Merck Patent Gmbh | Pigment/Fritten-Gemisch |
DE102016000054A1 (de) | 2016-01-05 | 2017-07-06 | Merck Patent Gmbh | Oberflächenfärbung von Lebensmitteln |
KR20170099369A (ko) | 2016-02-23 | 2017-08-31 | 메르크 파텐트 게엠베하 | 효과 안료 |
DE102016004164A1 (de) | 2016-04-11 | 2017-10-12 | Merck Patent Gmbh | Pigmentgemisch |
DE102017002554A1 (de) | 2017-03-17 | 2018-09-20 | Merck Patent Gmbh | Effektpigmente |
WO2018167109A1 (en) | 2017-03-17 | 2018-09-20 | Merck Patent Gmbh | Interference pigments |
DE102017011800A1 (de) | 2017-12-20 | 2019-06-27 | Merck Patent Gmbh | Effektpigmente |
EP3503214A1 (en) | 2017-12-22 | 2019-06-26 | Merck Patent GmbH | Solar cells |
EP3517579B1 (de) | 2018-01-23 | 2022-10-26 | Merck Patent GmbH | Pigmentgemisch enthaltend rote, blaue und grüne interferenzpigmente |
KR20200125971A (ko) | 2018-04-04 | 2020-11-05 | 알타나 아게 | 착색된 헥토라이트 및 코팅된 착색된 헥토라이트를 기재로 하는 효과 안료 및 그의 제조 |
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EP3564200A1 (en) | 2018-05-04 | 2019-11-06 | Merck Patent GmbH | Ceramic colours |
EP3564202A1 (en) | 2018-05-04 | 2019-11-06 | Merck Patent GmbH | Ceramic colours |
TW202045631A (zh) | 2019-03-15 | 2020-12-16 | 德商麥克專利有限公司 | 帶藍色之深黑色效果顏料 |
DE102019003072A1 (de) | 2019-04-30 | 2020-11-05 | Merck Patent Gmbh | Effektpigmente |
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TW202124596A (zh) | 2019-09-20 | 2021-07-01 | 德商麥克專利有限公司 | 顏料 |
DE102019006869A1 (de) | 2019-10-02 | 2021-04-08 | Merck Patent Gmbh | Interferenzpigmente |
CN115279590A (zh) | 2020-03-16 | 2022-11-01 | 默克专利股份有限公司 | 有色效应颜料用于增强有色聚合物的红外吸收能力的用途 |
EP3967491A1 (en) | 2020-09-15 | 2022-03-16 | Röhm GmbH | Heat reflective foils with improved mechanical properties and a high weathering resistance |
EP3974395A1 (de) | 2020-09-25 | 2022-03-30 | Merck Patent GmbH | Pigment/fritten-gemisch |
CN113948597A (zh) | 2021-04-30 | 2022-01-18 | 默克专利股份有限公司 | 制备彩色太阳能电池的方法 |
JP2024531179A (ja) | 2021-08-12 | 2024-08-29 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | エフェクト顔料と散乱添加剤とを含有する層 |
WO2023194420A1 (en) | 2022-04-08 | 2023-10-12 | Merck Patent Gmbh | Colored solar cell comprising effect pigments |
EP4389828A1 (de) | 2022-12-19 | 2024-06-26 | Merck Patent GmbH | Effektpigmente mit mindestens einer tio2-schichtt, in der das tio2 mit ti(3+) und fluorid dotiert ist |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3087829A (en) * | 1961-06-28 | 1963-04-30 | Du Pont | Micaceous pigment composition |
FR1326901A (fr) * | 1961-06-28 | 1963-05-10 | Du Pont | Nouvelles compositions de pigments |
US3087828A (en) * | 1961-06-28 | 1963-04-30 | Du Pont | Nacreous pigment compositions |
US3331699A (en) * | 1963-10-24 | 1967-07-18 | Du Pont | Nacreous glass flake pigment compositions |
US3342617A (en) * | 1965-08-12 | 1967-09-19 | Du Pont | Nacreous pigment compositions |
US3650790A (en) * | 1970-02-13 | 1972-03-21 | Du Pont | Nacreous mica pigment compositions |
US3832208A (en) * | 1972-03-09 | 1974-08-27 | Du Pont | Nacreous pigments treated with methacrylatochromic chloride for improved humidity resistance |
JPS5632842B2 (sv) * | 1972-09-18 | 1981-07-30 | ||
DE2313331C2 (de) * | 1973-03-17 | 1986-11-13 | Merck Patent Gmbh, 6100 Darmstadt | Eisenoxidhaltige Glimmerschuppenpigmente |
US4134776A (en) * | 1977-12-27 | 1979-01-16 | The Mearl Corporation | Exterior grade titanium dioxide coated mica |
-
1982
- 1982-09-22 DE DE19823235017 patent/DE3235017A1/de not_active Withdrawn
-
1983
- 1983-06-17 IN IN761/CAL/83A patent/IN160815B/en unknown
- 1983-09-08 DE DE8383108848T patent/DE3376118D1/de not_active Expired
- 1983-09-08 EP EP83108848A patent/EP0104516B1/de not_active Expired
- 1983-09-20 AR AR83294249A patent/AR245948A1/es active
- 1983-09-20 KR KR1019830004419A patent/KR910004813B1/ko not_active IP Right Cessation
- 1983-09-20 CS CS836849A patent/CS244430B2/cs unknown
- 1983-09-21 FI FI833387A patent/FI74990C/sv not_active IP Right Cessation
- 1983-09-21 MX MX198785A patent/MX155769A/es unknown
- 1983-09-21 HU HU833257A patent/HU193655B/hu not_active IP Right Cessation
- 1983-09-21 ZA ZA837029A patent/ZA837029B/xx unknown
- 1983-09-21 PL PL1983243840A patent/PL136638B2/xx unknown
- 1983-09-21 BR BR8305166A patent/BR8305166A/pt not_active IP Right Cessation
- 1983-09-21 ES ES525800A patent/ES525800A0/es active Granted
- 1983-09-22 US US06/534,869 patent/US4482389A/en not_active Expired - Lifetime
- 1983-09-22 AU AU19366/83A patent/AU562638B2/en not_active Ceased
- 1983-09-22 JP JP58174429A patent/JPS5978265A/ja active Granted
- 1983-09-22 CA CA000437290A patent/CA1203953A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FI833387A0 (fi) | 1983-09-21 |
US4482389A (en) | 1984-11-13 |
PL136638B2 (en) | 1986-03-31 |
ZA837029B (en) | 1984-12-24 |
FI833387A (fi) | 1984-03-23 |
KR840006185A (ko) | 1984-11-22 |
KR910004813B1 (ko) | 1991-07-13 |
DE3235017A1 (de) | 1984-03-22 |
CS244430B2 (en) | 1986-07-17 |
IN160815B (sv) | 1987-08-08 |
AR245948A1 (es) | 1994-03-30 |
JPH0541670B2 (sv) | 1993-06-24 |
DE3376118D1 (en) | 1988-05-05 |
FI74990C (sv) | 1988-04-11 |
ES8501428A1 (es) | 1984-11-16 |
EP0104516B1 (de) | 1988-03-30 |
HU193655B (en) | 1987-11-30 |
PL243840A2 (en) | 1984-09-10 |
EP0104516A1 (de) | 1984-04-04 |
BR8305166A (pt) | 1984-05-02 |
MX155769A (es) | 1988-04-25 |
CS684983A2 (en) | 1985-09-17 |
AU1936683A (en) | 1984-03-29 |
JPS5978265A (ja) | 1984-05-07 |
AU562638B2 (en) | 1987-06-18 |
CA1203953A (en) | 1986-05-06 |
ES525800A0 (es) | 1984-11-16 |
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MM | Patent lapsed |
Owner name: MERCK PATENT GESELLSCHAFT MIT BESCHRAENKTER HAFTUN |