JP5431632B2 - 干渉顔料 - Google Patents
干渉顔料 Download PDFInfo
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- JP5431632B2 JP5431632B2 JP2005502428A JP2005502428A JP5431632B2 JP 5431632 B2 JP5431632 B2 JP 5431632B2 JP 2005502428 A JP2005502428 A JP 2005502428A JP 2005502428 A JP2005502428 A JP 2005502428A JP 5431632 B2 JP5431632 B2 JP 5431632B2
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Description
(A)層厚が5〜350nmのSiO2の層、
(B)屈折率が1.8を超える高屈折率被覆、および/または
(C)高屈折率および低屈折率の交互層からなる干渉系、
および任意に
(D)外側保護層
を含むことを特徴とする薄片状基材に基づく干渉顔料に関する。
ガラス薄片+SiO2+TiO2
ガラス薄片+SiO2+Fe2O3
ガラス薄片+SiO2+Fe3O4
ガラス薄片+SiO2+Cr2O3
ガラス薄片+SiO2+TiO2+ベルリン・ブルー
ガラス薄片+SiO2+TiO2+カーミン・レッド
ガラス薄片+SiO2+TiO2+SiO2+TiO2
ガラス薄片+SiO2+TiO2+Cr
雲母薄片+SiO2+TiO2
雲母薄片+SiO2+Fe2O3
雲母薄片+SiO2+Fe3O4
雲母薄片+SiO2+Cr2O3
雲母薄片+SiO2+TiO2+ベルリン・ブルー
雲母薄片+SiO2+TiO2+カーミン・レッド
雲母薄片+SiO2+TiO2+SiO2+TiO2
雲母薄片+SiO2+TiO2+Cr
Al2O3薄片+SiO2+TiO2
Al2O3薄片+SiO2+Fe2O3
Al2O3薄片+SiO2+Fe3O4
Al2O3薄片+SiO2+Cr2O3
Al2O3薄片+SiO2+TiO2+ベルリン・ブルー
Al2O3薄片+SiO2+TiO2+カーミン・レッド
Al2O3薄片+SiO2+TiO2+SiO2+TiO2
Al2O3薄片+SiO2+TiO2+Cr
特に好ましい干渉顔料のなかでも、被覆されたガラス薄片が特に好ましく、また被覆されたAl2O3薄片が好ましい。
平均層厚700nmのガラス薄片(表1のガラスA)150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。次に、懸濁液のpHを、5%塩酸を用いて7.5に調整する。続いて、ナトリウム水ガラス溶液(脱イオン水112gに溶解したSiO226.8%を含むナトリウム水ガラス溶液112g)を滴下し、その間5%塩酸を同時に計量添加することによりpHを7.5で一定に維持する。添加が完了すると、混合物をさらに0.5時間攪拌する。懸濁液のpHを、次に1.8に調整し、懸濁液をさらに15分間攪拌し、四塩化錫の塩酸溶液(25%塩酸15mlおよび脱イオン水85mlに溶解したSnCl4・5H2O3g)を滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。
銀白色顔料を、実施例1に記載のプロセスにより調製する。表1の組成Aのガラス薄片の代わりに、同じ厚さおよび寸法分布(20〜200μm)を有する組成Bのガラス薄片を用いる。二酸化チタンの被覆を、実施例1と同じ終点まで行う。得られた顔料は、実施例1からの顔料と視覚的に区別することができない。
ガラス薄片に基づき以下の重量割合のSiO2を有する銀白色顔料を、実施例1に示す手順により調製する。
実施例4:水28gに溶解された水ガラス溶液28gを計量添加することによりSiO2が5%
実施例5:水56gに溶解された水ガラス溶液56gを計量添加することによりSiO2が10%
二酸化チタンの被覆を、実施例1および2と同じ色調まで行う。
(第1のSiO2層を有さない比較例)
平均層厚700nmの表1の組成Aのガラス薄片150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。懸濁液のpHを、塩酸を用いて1.8に調整する。続いて、四塩化錫の塩酸溶液(25%塩酸22.5mlおよび脱イオン水128mlに溶解したSnCl4・5H2O4.5g)を滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。これに続いて30%四塩化チタン溶液を計量添加し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。所望の銀色終点に到達すると、混合物をさらに15分間攪拌する。
(比較例)
平均層厚700nmの表1の組成Aのガラス薄片150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。pHを5.5に調整する。塩化アルミニウムの塩酸溶液(塩化アルミニウム六水和物18g)180mlを、攪拌下に75℃で滴下し、その間水酸化ナトリウム溶液を用いてpHを5に維持する。添加が完了すると、混合物を75℃でさらに2時間攪拌する。被覆されたガラス薄片を濾別し、洗浄し、150℃で乾燥し、400℃で30分間脱水する。冷却後、酸化アルミニウム(Al2O3約5%)で被覆されたガラス薄片を、実施例6に示す手順によりチタンを用いてさらに加工して、銀白色顔料を得る。
(機械的安定性の試験)
化粧製剤中における顔料の摩耗安定性を、実用試験において試験することができる。ここで、顔料の機械的安定性が、使用、例えばコンパクトパウダーまたはクリームに適しているかどうかが決められる。迅速試験として、掌上での指による顔料サンプルの摩擦は良好であると分かった。摩擦による顔料粒子の破壊または相剥離の場合、摩擦サンプルの光沢は低下または完全に損なわれる。光沢の低下を、視覚により1〜5の段階で評価し、段階1は変化無しまたは摩擦中における光沢の増加を示し、段階5は強度のつや消しを示す。段階3は、実用において制限された範囲で利用可能と見なされ、段階4および5は利用不可能と見なされる。
(比較実験)
酸化アルミニウム薄片(EP0763573B1の実施例2に記載のように調製)100gを、5リッター実験室反応器内で脱イオン水2L中で懸濁する。水性SnCl4溶液(溶液1L当たりSnCl436g)200mlを攪拌下に75℃で3ml/分の割合で滴下する。懸濁液のpHを、水酸化ナトリウム溶液の計量添加により1.8に維持する。混合物を、さらに10分間攪拌し、次に四塩化チタン水溶液(溶液1L当たりTiCl4125g)を3ml/分の割合で計量添加し、その間水酸化ナトリウム溶液の添加によりpHを1.7〜1.9で維持する。このようにして、酸化アルミニウム薄片を、二酸化チタン層で被覆し、二酸化チタン層の層厚が増加すると、最初に銀白色、次に、1〜3倍の着色干渉色が形成される。被覆プロセス中、反応器に接続されていると共にそこを通して反応混合物が被覆中に連続的にポンプ送りされるギャップ型測定セルを用いて、干渉顔料の色特性を測定する。測定チャンバーのギャップを流通中、顔料薄片が流通方向に実質的に平行に配され、黒色背景に対して測定する。市販のMinolta CR 300色測定セルを用いて、フラッシュ照明後の所定の角度で反射した光を測定する。測定データを、DIN5033 Part3に従ってCIELAB値に変換し、表示する。このようにして、顔料の色特性を、被覆の任意の段階において決めることができる。図1は、被覆の色特性の推移をa*/b*グラフとして示す。この系において、+a値は赤を表わし、−a値は緑を表わし、+b値は黄を表わし、−b値は青を表わす。測定曲線は、座標原点で始まり、二酸化チタン被覆に対応した干渉色を示す。顔料の彩度が大きいと、色位置が座標原点からより離れる。
酸化アルミニウム薄片(EP 0 763 573 B1に記載のように調製、実施例2)100gを、実施例10の実験室反応器内で脱イオン水1.6L中で懸濁する。懸濁液のpHを8に設定し、続いてナトリウム水ガラス溶液(脱イオン水190gに溶解したSiO226.8%を含むナトリウム水ガラス溶液190g)を滴下し、その間5%塩酸を同時に計量添加することによりpHを8で一定に維持する。添加が完了すると、混合物をさらに0.5時間攪拌する。懸濁液のpHを、次に、5%塩酸を用いて1.8に調整し、混合物をさらに15分間攪拌し、四塩化錫の塩酸溶液(25%塩酸22.5mlおよび脱イオン水128mlに溶解したSnCl4・5H2O4.5g)を滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。添加が完了すると、混合物をさらに15分間攪拌し、四塩化チタン水溶液(溶液1L当たりTiCl4125g)を3ml/分の割合で計量添加し、その間、水酸化ナトリウム溶液の添加によりpHを1.7〜1.9で維持する。顔料の色特性をTiO2被覆中に実施例10のように測定する。比較により、本発明の顔料が、従来技術による顔料より著しく優れた彩度(「着色力」)を有することが示される(図2)。さらに、本発明の顔料は、著しく高い光沢を示す。
平均層厚900nmのガラス薄片(表4のガラスC)150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。次に、懸濁液のpHを、5%塩酸を用いて7.5に調整する。続いて、ナトリウム水ガラス溶液(脱イオン水112gに溶解したSiO226.8%を含むナトリウム水ガラス溶液112g)を滴下し、その間、5%塩酸を同時に計量添加することによりpHを7.5で一定に維持する。添加が完了すると、混合物をさらに0.5時間攪拌する。懸濁液のpHを、次に1.8に調整し、混合物をさらに15分間攪拌し、四塩化錫の塩酸溶液(25%塩酸15mlおよび脱イオン水85mlに溶解したSnCl4・5H2O3g)を滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。
銀白色顔料を、実施例12に記載のプロセスにより調製する。表4の組成Cのガラス薄片の代わりに、同じ厚さおよび寸法分布(20〜200μm)を有する組成Dのガラス薄片を用いる。二酸化チタンの被覆を、実施例12と同じ終点まで行う。得られた顔料は、実施例12からの顔料と視覚的に区別することができない。
ガラス薄片に基づき以下の重量割合のSiO2を有する銀白色顔料を、実施例12に示す手順により調製する。
実施例15:水28gに溶解された水ガラス溶液28gを計量添加することによりSiO2が5%
実施例16:水56gに溶解された水ガラス溶液56gを計量添加することによりSiO2が10%
二酸化チタンの被覆を、実施例12および13と同じ色調まで行う。
(第1のSiO2層を有さない比較例)
平均層厚900nmの表4の組成Cのガラス薄片150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。懸濁液のpHを、塩酸を用いて1.8に調整する。続いて四塩化錫の塩酸溶液(25%塩酸22.5mlおよび脱イオン水128mlに溶解したSnCl4・5H2O4.5g)を滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。これに続いて30%四塩化チタン溶液を計量添加し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。所望の銀終点に到達すると、混合物をさらに15分間攪拌する。
(比較例)
平均層厚900nmの表4の組成Cのガラス薄片150gを、脱イオン水1.9L中で攪拌下に75℃に加熱する。pHを5.5に調整する。塩化アルミニウムの塩酸溶液(塩化アルミニウム六水和物18g)180mlを、攪拌下に75℃で滴下し、その間水酸化ナトリウム溶液を用いてpHを5に維持する。添加が完了すると、混合物を75℃でさらに2時間攪拌する。被覆されたガラス薄片を濾別し、洗浄し、150℃で乾燥し、400℃で30分間脱水する。冷却後、酸化アルミニウム(Al2O3約5%)で被覆されたガラス薄片を、実施例17に示す手順により二酸化チタンを用いてさらに加工して、銀白色顔料を得る。
(機械的安定性の試験)
機械的安定性の試験を実施例9と同様に行う。
平均層厚500nmのガラス薄片(表4のガラスD)125gを、脱イオン水1.75L中で攪拌下に75℃に加熱する。次に、懸濁液のpHを、5%塩酸を用いて8に調整する。続いて、ナトリウム水ガラス溶液(脱イオン水67gに溶解したSiO226.8%を含むナトリウム水ガラス溶液67g)を滴下し、その間5%塩酸を同時に計量添加することによりpHを7.5で一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。懸濁液のpHを、次に2.8に調整し、混合物をさらに15分間攪拌し、塩化鉄の15%塩酸溶液320mlを滴下し、その間32%水酸化ナトリウム溶液を同時に滴下することによりpHを一定に維持する。被覆中に顔料の色特性を実施例10に記載のように測定する。添加が完了すると、混合物をさらに15分間攪拌する。顔料は、ガラス薄片に基づいて沈積SiO210%を含む。
実施例22
平均層厚500nmのガラス薄片(表4のガラスD、粒径10〜60μm)125gを、脱イオン水1.75L中で攪拌下に75℃に加熱する。次に懸濁液のpHを、5%塩酸を用いて7.5に調整する。続いてナトリウム水ガラス溶液(脱イオン水67gに溶解したSiO226.8%を含むナトリウム水ガラス溶液67g)を滴下し、その間、5%塩酸を同時に計量添加することによりpHを7.5で一定に維持する。添加が完了すると、混合物をさらに15分間攪拌する。
Claims (5)
- 被覆された薄片状基材に基づく干渉顔料であって、該薄片状基材上に
(A)層厚が5〜350nmのSiO2の層と、
(B)二酸化チタンからなる屈折率nが1.8を超える高屈折率被覆または (C)TiO 2 層およびSiO 2 層の高屈折率および低屈折率の交互層からなる干渉系(但し、層の数は3〜7で、最内層はTiO 2 層である)と、
任意に
(D)外側保護層と
を順次に被覆してなり、前記薄片状基材が、ガラス薄片、雲母薄片または酸化アルミニウム薄片であることを特徴とする干渉顔料。 - 層(A)の厚さが30〜100nmである請求項1に記載の干渉顔料。
- 光、温度および天候安定性を増すための外側保護層(D)を有する請求項1または2に記載の干渉顔料。
- 請求項1に記載の干渉顔料を調製する方法であって、基材の被覆を、水性媒体中での金属塩の加水分解による湿式化学的法または流動床反応器中での気相被覆により行うことを特徴とする方法。
- 塗料、被覆、自動車塗料、粉末被覆、印刷インク、証券印刷インク、プラスチック、セラミック材料、ガラス、紙における、電子写真式印刷プロセス用のトナーにおける、種子における、温室シートおよびテント天幕における、紙およびプラスチックのレーザーマーキングにおける吸収剤としての、化粧用配合品における、水、有機および/または水性溶媒を用いる顔料ペーストの調製のための、および、顔料製剤および乾燥製剤の調製のための、請求項1に記載の干渉顔料の使用。
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DE2003102589 DE10302589A1 (de) | 2003-01-22 | 2003-01-22 | Interferenzpigmente |
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Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7303619B2 (en) * | 2003-08-21 | 2007-12-04 | Seiko Epson Corporation | Composite pigment original, composite pigment, process for producing ink composition, and ink composition |
DE102004039554A1 (de) | 2004-08-13 | 2006-02-23 | Merck Patent Gmbh | Perlglanzpigmente |
JP4982953B2 (ja) * | 2005-02-14 | 2012-07-25 | 日産自動車株式会社 | 樹脂組成物、樹脂組成物の製造方法、自動車用部材、建築用部材及び光学部品 |
EP1719633B2 (de) | 2005-05-03 | 2014-03-12 | Merck Patent GmbH | Verwendung von lasergravierten Druckformen |
CN101203574B (zh) * | 2005-06-22 | 2012-09-05 | 西巴特殊化学品控股有限公司 | 基于玻璃鳞片的干涉颜料 |
DE102006014095A1 (de) * | 2006-03-24 | 2007-09-27 | Merck Patent Gmbh | Glasplättchen und deren Verwendung als transparenter Füllstoff |
JP2007297621A (ja) * | 2006-04-21 | 2007-11-15 | Merck Patent Gmbh | 顔料 |
DE102006024289A1 (de) * | 2006-05-24 | 2007-11-29 | Merck Patent Gmbh | Partikel |
KR100824438B1 (ko) * | 2006-08-14 | 2008-04-23 | 씨큐브 주식회사 | 박편상 저광택 화장료용 안료 |
DE102007010986A1 (de) * | 2007-03-05 | 2008-09-11 | Merck Patent Gmbh | Übergangsmetallhaltige Effektpigmente |
EP1977729B1 (en) * | 2007-04-05 | 2010-03-03 | Eckart GmbH | Cosmetic compositions containing pearlescent pigments |
ATE432964T1 (de) * | 2007-04-05 | 2009-06-15 | Eckart Gmbh | Effektpigmente mit einem substrat aus glasplättchen |
US20100218703A1 (en) * | 2007-07-31 | 2010-09-02 | Patrice Bujard | Optical variable effect pigments |
JP5122227B2 (ja) * | 2007-09-25 | 2013-01-16 | パイロットインキ株式会社 | 変色性塗布液 |
DE102007058601A1 (de) * | 2007-12-04 | 2009-06-10 | Merck Patent Gmbh | Sicherheitspigment |
EP2093260A1 (de) | 2008-02-20 | 2009-08-26 | Eckart GmbH | Effektpigmente basierend auf künstlich hergestellten Substraten mit enger Grössenverteilung |
EP2123721B1 (de) | 2008-04-15 | 2013-11-27 | Eckart GmbH | Perlglanzpigmente auf Basis von feinen und dünnen Substraten |
DE102008056870A1 (de) * | 2008-11-12 | 2010-05-20 | Mitsubishi Polyester Film Gmbh | Mehrschichtige, weiße, biaxial orientierte Polyesterfolie mit metallisch glänzender Deckschicht |
DE102009037935A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit silberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
DE102009037934A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit farbiger Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
DE102009037933A1 (de) * | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit nichtsilberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
DE102010049375A1 (de) * | 2010-10-26 | 2012-04-26 | Merck Patent Gmbh | Pigmente |
KR101239074B1 (ko) * | 2011-05-24 | 2013-03-11 | 씨큐브 주식회사 | 내후성이 우수한 외장재 안료 및 그 제조 방법 |
CN103987796B (zh) | 2011-12-09 | 2016-06-22 | 日本板硝子株式会社 | 光辉性颜料、和含有该光辉性颜料的光辉性涂料组合物及汽车外板涂敷物 |
EP2607432A1 (de) | 2011-12-21 | 2013-06-26 | Merck Patent GmbH | Effektpigmente basierend auf Substraten die einen Kreisformfaktor von 1,2-2 aufweisen |
EP2679566A1 (en) | 2012-06-28 | 2014-01-01 | Colorobbia España, S.A. | Method for obtaining optical interference effects by means of digital ink-jet technique |
KR101399954B1 (ko) * | 2012-09-10 | 2014-05-29 | 씨큐브 주식회사 | 높은 색강도를 갖는 간섭안료 및 그 제조 방법 |
US9951194B2 (en) | 2012-10-05 | 2018-04-24 | Basf Corporation | Iron oxide containing effect pigments, their manufacture and their use |
DE102012020392A1 (de) | 2012-10-18 | 2014-04-24 | Merck Patent Gmbh | Pigmente |
US9359015B2 (en) | 2012-12-10 | 2016-06-07 | Globe Composite Solutions, Ltd. | Hinged load panel for package delivery vehicles |
DE102013202329A1 (de) * | 2013-02-13 | 2014-08-14 | Henkel Ag & Co. Kgaa | Wasser-in-Öl-Emulsionen mit mehrschichtigen Pigmentkapseln |
DE102013202330A1 (de) * | 2013-02-13 | 2014-08-14 | Henkel Ag & Co. Kgaa | lamellare Öl-in-Wasser-Emulsionen mit mehrschichtigen Pigmentkapseln |
US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US11351652B2 (en) | 2013-05-02 | 2022-06-07 | Melior Innovations, Inc. | Polysilocarb binders and coatings |
US9481781B2 (en) | 2013-05-02 | 2016-11-01 | Melior Innovations, Inc. | Black ceramic additives, pigments, and formulations |
US10738206B2 (en) * | 2013-05-02 | 2020-08-11 | Melior Innovations, Inc. | Black ceramic additives, pigments, and formulations |
US9867764B2 (en) | 2013-09-10 | 2018-01-16 | Conopco, Inc. | Oral care composition |
US10010491B2 (en) | 2013-09-10 | 2018-07-03 | Conopco Inc. | Oral care composition |
US9376048B2 (en) * | 2014-02-11 | 2016-06-28 | Globe Composite Solutions, Ltd. | Stowable floor assembly for package delivery vehicles |
CN103788712A (zh) * | 2014-02-12 | 2014-05-14 | 铜陵瑞莱科技有限公司 | 一种含熟贝壳粉的氧化铁黑颜料 |
US10787574B2 (en) | 2014-02-28 | 2020-09-29 | Melior Innovations, Inc. | Polymer derived ceramic effects particles, uses and methods of making |
EP2939655A1 (en) * | 2014-04-30 | 2015-11-04 | L'Oréal | Composition comprising microcapsules containing reflective particles |
JP2017528555A (ja) * | 2014-07-25 | 2017-09-28 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングMerck Patent Gesellschaft mit beschraenkter Haftung | 着色エフェクト顔料 |
US10280626B2 (en) | 2014-08-25 | 2019-05-07 | Andreas Hieke | Composite materials with tailored electromagnetic spectral properties, structural elements for enhanced thermal management, and methods for manufacturing thereof |
US11034841B2 (en) * | 2014-11-24 | 2021-06-15 | Basf Corporation | Carbon black in effect pigments |
ES2727632T3 (es) | 2014-12-19 | 2019-10-17 | Eckart Gmbh | Pigmentos de efecto metálico con croma elevado y brillo elevado, procedimiento para su producción y empleo de los mismos |
ES2733082T3 (es) | 2014-12-19 | 2019-11-27 | Eckart Gmbh | Pigmentos de efecto de color rojo con croma alto y brillo alto, procedimiento para su preparación y uso de los mismos |
EP3034564B1 (de) | 2014-12-19 | 2018-02-07 | Eckart GmbH | Effektpigmente mit hoher Transparenz, hohem Chroma und hoher Brillanz, Verfahren zu ihrer Herstellung und Verwendung derselben |
ES2726181T3 (es) | 2014-12-19 | 2019-10-02 | Eckart Gmbh | Pigmento de efecto de color con alto croma y alta brillantez, procedimiento para su preparación y uso del mismo |
SI3034562T2 (sl) | 2014-12-19 | 2022-04-29 | Eckart Gmbh | Absorbirni efektni pigmenti z visoko kromatičnostjo in visokim sijajem, postopek za njihovo pripravo in njihova uporaba |
EP3081601A1 (de) | 2015-04-15 | 2016-10-19 | Schlenk Metallic Pigments GmbH | Perlglanzpigmente auf der basis von monolithisch aufgebauten substraten |
CN107614628B (zh) * | 2015-06-01 | 2021-02-26 | 日本板硝子株式会社 | 干涉颜料、以及包含其的化妆料、涂料、油墨及树脂组合物 |
EP3341444B1 (en) | 2015-12-11 | 2020-10-07 | Hp Indigo B.V. | Electrostatic ink composition |
WO2018049223A2 (en) * | 2016-09-09 | 2018-03-15 | Melior Innovations | Polymer derived ceramic effects particles, uses and methods of making |
JP6703750B2 (ja) * | 2016-09-30 | 2020-06-03 | ブラザー工業株式会社 | 粘着テープカートリッジ |
JP6663567B2 (ja) * | 2016-09-30 | 2020-03-13 | ブラザー工業株式会社 | 粘着テープカートリッジ及び粘着テープロール並びに粘着テープロールの製造方法 |
JP6663569B2 (ja) * | 2016-09-30 | 2020-03-13 | ブラザー工業株式会社 | 粘着テープカートリッジ及び粘着テープロール並びに粘着テープロールの製造方法 |
CN106395894B (zh) * | 2016-11-23 | 2018-04-17 | 苏州黎元新能源科技有限公司 | 一种通过盖膜水解法制备薄膜材料的工艺 |
JP6243093B1 (ja) * | 2016-12-26 | 2017-12-06 | 日本板硝子株式会社 | 光輝性顔料、顔料含有組成物、及び顔料含有塗装体 |
US11028272B2 (en) | 2016-12-26 | 2021-06-08 | Nippon Sheet Glass Company, Limited | Glitter pigment, pigment-containing composition, and pigment-containing painted product |
ES2967343T3 (es) | 2017-01-10 | 2024-04-29 | Schlenk Metallic Pigments Gmbh | Pigmentos nacarados obtenidos por oxidación húmeda |
CN107382076A (zh) * | 2017-06-09 | 2017-11-24 | 河北卓达建材研究院有限公司 | 一种白色泡沫玻璃 |
US11011657B2 (en) * | 2017-10-11 | 2021-05-18 | Toyota Motor Engineering & Manufacturing North America, Inc. | Colored solar panels and structures comprising the same |
US11014850B2 (en) | 2017-10-25 | 2021-05-25 | Melior Innovations, Inc. | SiOC ceramic and plastic additives for cements, concretes and structural decorative materials |
US10800924B2 (en) * | 2017-11-27 | 2020-10-13 | Cathy Cowan | Toy bubble forming composition containing glitter |
CN109054456B (zh) * | 2018-07-12 | 2020-10-20 | 福建坤彩材料科技股份有限公司 | 一种基于合成云母的银色珠光颜料及其制备方法和应用 |
WO2020023708A1 (en) * | 2018-07-27 | 2020-01-30 | Materion Corporation | Reflective color correction for phosphor illumination systems |
DE102018121767A1 (de) | 2018-09-06 | 2020-03-12 | Kommanditgesellschaft Synoptrix Lichttechnik Gmbh & Co. | Herstellungsverfahren eines Dekorelements und Verwendung des Dekorelements |
DE102020006456A1 (de) * | 2020-10-20 | 2022-04-21 | Giesecke+Devrient Currency Technology Gmbh | Herstellung von Pigmenten mit definierter Größe und Form |
EP4363233A1 (en) | 2021-07-02 | 2024-05-08 | HELIOSONIC GmbH | Radiation induced printing method using an effect pigment mixture |
JP7214276B1 (ja) | 2022-04-18 | 2023-01-30 | サンヨー化成株式会社 | プラスチック成形品用柄材及びこれを配合した柄入りプラスチック成形品並びにプラスチック成形品用柄材の製造方法 |
WO2024017885A1 (en) | 2022-07-19 | 2024-01-25 | Sun Chemical Corporation | Effect pigments with sparkle |
FR3142669A1 (fr) * | 2022-12-05 | 2024-06-07 | Lvmh Recherche | Pigments interférentiels à base de sulfure de zinc et leur procédé de synthèse |
FR3142668A1 (fr) * | 2022-12-05 | 2024-06-07 | Lvmh Recherche | Pigments interférentiels à base de sulfure de zinc et leur procédé de synthèse |
WO2024121506A1 (fr) * | 2022-12-05 | 2024-06-13 | Lvmh Recherche | Pigments interferentiels a base de sulfure de zinc, procede de synthese et composition cosmetique |
FR3142670A1 (fr) * | 2022-12-05 | 2024-06-07 | Lvmh Recherche | Pigments interférentiels dépourvus de dioxyde de titane |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL135722C (ja) | 1961-06-28 | |||
US3331699A (en) | 1963-10-24 | 1967-07-18 | Du Pont | Nacreous glass flake pigment compositions |
DE1522572A1 (de) | 1967-03-23 | 1969-09-18 | Marcus Cantarano | Verfahren und Vorrichtung zum photoelektrischen Herstellen von Reproduktionen |
DE2009566C2 (de) | 1970-02-28 | 1972-06-15 | Merck Patent Gmbh | Verfahren zur Herstellung von Titandioxid- bzw. Titandioxidaquatüberzügen |
CA964403A (en) | 1971-03-26 | 1975-03-18 | Howard R. Linton | Nacreous pigments of improved luster and process for their manufacture |
CA957108A (en) | 1971-03-30 | 1974-11-05 | E. I. Du Pont De Nemours And Company | Pigments treated with methacrylatochromic chloride for improved humidity resistance |
DE2244298C3 (de) | 1972-09-09 | 1975-06-19 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente und Verfahren zu ihrer Herstellung |
DE2313331C2 (de) | 1973-03-17 | 1986-11-13 | Merck Patent Gmbh, 6100 Darmstadt | Eisenoxidhaltige Glimmerschuppenpigmente |
DE3137809A1 (de) | 1981-09-23 | 1983-03-31 | Merck Patent Gmbh, 6100 Darmstadt | "perlglanzpigmente, ihre herstellung und ihre verwendung" |
DE3137808A1 (de) | 1981-09-23 | 1983-03-31 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente mit verbesserter lichtechtheit, verfahren zur herstellung und verwendung |
DE3151355A1 (de) | 1981-12-24 | 1983-07-07 | Merck Patent Gmbh, 6100 Darmstadt | "perlglanzpigmente mit verbesserter lichtbestaendigkeit, ihre herstellung und verwendung" |
DE3151343A1 (de) | 1981-12-24 | 1983-07-07 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente mit verbesserter lichtbestaendigkeit, ihre herstellung und ihre verwendung |
DE3151354A1 (de) | 1981-12-24 | 1983-07-07 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente, verfahren zu ihrer herstellung und ihre verwendung |
DE3211602A1 (de) | 1982-03-30 | 1983-10-13 | Merck Patent Gmbh, 6100 Darmstadt | Verfahren zur herstellung von perlglanzpigmenten mit verbesserten glanzeigenschaften |
DE3235017A1 (de) | 1982-09-22 | 1984-03-22 | Merck Patent Gmbh, 6100 Darmstadt | Perlglanzpigmente |
IN169017B (ja) | 1986-12-13 | 1991-08-17 | Marck Patent Gmbh | |
DE3825702A1 (de) | 1988-07-28 | 1990-02-01 | Michael Huber Muenchen Gmbh Fa | Goniochromatische pigmente, verfahren zu deren herstellung und deren verwendung zur herstellung von sicherheits- und effektfarben |
CZ283898B6 (cs) | 1991-10-18 | 1998-07-15 | MERCK Patent Gesellschaft mit beschränkter Haftung | Destičkovitý pigment, způsob jeho výroby a jeho použití |
JPH07759B2 (ja) * | 1992-09-09 | 1995-01-11 | 大阪真空工業株式会社 | 有彩色の光輝性パウダー |
DE4437753A1 (de) * | 1994-10-21 | 1996-04-25 | Basf Ag | Mehrfach beschichtete metallische Glanzpigmente |
DE19525503A1 (de) | 1995-07-13 | 1997-01-16 | Basf Ag | Goniochromatische Glanzpigmente auf Basis transparenter, nichtmetallischer, plättchenförmiger Substrate |
DE19618569A1 (de) * | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
US6045914A (en) | 1996-06-03 | 2000-04-04 | Engelhard Corporation | Pearlescent glass pigment |
US6132873A (en) * | 1996-09-21 | 2000-10-17 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Multilayered interference pigments |
DE19746067A1 (de) * | 1997-10-17 | 1999-04-22 | Merck Patent Gmbh | Interferenzpigmente |
DE19808657A1 (de) * | 1998-03-02 | 1999-09-09 | Basf Ag | Goniochromatische Glanzpigmente auf Basis mehrfach beschichteter Eisenoxidplättchen |
DE19905427A1 (de) * | 1999-02-10 | 2000-08-17 | Merck Patent Gmbh | Farbiges Interferenzpigment |
DE19915153A1 (de) * | 1999-02-15 | 2000-08-17 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
US6284032B2 (en) * | 1999-03-09 | 2001-09-04 | Merck Patent Gmbh | Multilayer interference pigments |
DE19917388A1 (de) * | 1999-04-16 | 2000-10-19 | Merck Patent Gmbh | Pigmentmischung |
JP2001098186A (ja) * | 1999-07-29 | 2001-04-10 | Merck Japan Ltd | 薄片状顔料及びその製造方法 |
DE19941607A1 (de) | 1999-09-01 | 2001-03-08 | Merck Patent Gmbh | Pigmentmischung enthaltend BIOCI-Pigmente |
DE19951869A1 (de) * | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
JP3655513B2 (ja) * | 1999-11-29 | 2005-06-02 | 株式会社ハイミラー | 干渉色を有する粉体およびその製造方法 |
US6767633B2 (en) * | 2000-04-11 | 2004-07-27 | Merck Patent Gmbh | Transparent medium having angle-selective transmission or reflection properties and/or absorption properties |
US6569529B1 (en) * | 2000-10-10 | 2003-05-27 | Flex Product, Inc. | Titanium-containing interference pigments and foils with color shifting properties |
JP2002179947A (ja) * | 2000-12-11 | 2002-06-26 | Nittetsu Mining Co Ltd | 粉体、その製造方法および色材組成物 |
DE10106198A1 (de) * | 2001-02-10 | 2002-08-14 | Merck Patent Gmbh | Glanzpigmente und Füllkörper enthaltendes Kunststoffteil |
DE10124657A1 (de) * | 2001-05-18 | 2002-11-21 | Merck Patent Gmbh | Elektrophotographischer Trockentoner mit winkelabhängigen Glanzpigmenten |
CN1622981A (zh) * | 2001-07-12 | 2005-06-01 | 默克专利股份有限公司 | 玻璃鳞片基多层颜料 |
DE10137831A1 (de) * | 2001-08-02 | 2003-02-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
US7045007B2 (en) * | 2002-12-31 | 2006-05-16 | Engelhard Corporation | Effect pigment |
-
2003
- 2003-12-09 JP JP2005502428A patent/JP5431632B2/ja not_active Expired - Fee Related
- 2003-12-09 AU AU2003292216A patent/AU2003292216A1/en not_active Abandoned
- 2003-12-09 US US10/539,592 patent/US20060225609A1/en not_active Abandoned
- 2003-12-09 EP EP03767774.7A patent/EP1572812B1/de not_active Expired - Lifetime
- 2003-12-09 WO PCT/EP2003/013943 patent/WO2004055119A1/de active Application Filing
- 2003-12-15 TW TW092135451A patent/TWI395794B/zh not_active IP Right Cessation
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2010
- 2010-03-22 US US12/728,790 patent/US8500901B2/en not_active Expired - Lifetime
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- 2012-07-06 JP JP2012152339A patent/JP2012224858A/ja active Pending
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WO2004055119A1 (de) | 2004-07-01 |
US20060225609A1 (en) | 2006-10-12 |
EP1572812A1 (de) | 2005-09-14 |
TW200422355A (en) | 2004-11-01 |
EP1572812B1 (de) | 2019-05-15 |
US20100175587A1 (en) | 2010-07-15 |
AU2003292216A1 (en) | 2004-07-09 |
TWI395794B (zh) | 2013-05-11 |
US8500901B2 (en) | 2013-08-06 |
JP2012224858A (ja) | 2012-11-15 |
JP2006510797A (ja) | 2006-03-30 |
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