FI111765B - Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi - Google Patents

Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi Download PDF

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Publication number
FI111765B
FI111765B FI962648A FI962648A FI111765B FI 111765 B FI111765 B FI 111765B FI 962648 A FI962648 A FI 962648A FI 962648 A FI962648 A FI 962648A FI 111765 B FI111765 B FI 111765B
Authority
FI
Finland
Prior art keywords
hexacyanoferrate
cesium
transition element
transition
aqueous solution
Prior art date
Application number
FI962648A
Other languages
English (en)
Finnish (fi)
Swedish (sv)
Other versions
FI962648A0 (fi
FI962648A (fi
Inventor
Jukka Lehto
Risto Harjula
Original Assignee
Fortum Nuclear Services Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fortum Nuclear Services Oy filed Critical Fortum Nuclear Services Oy
Publication of FI962648A0 publication Critical patent/FI962648A0/fi
Priority to FI962648A priority Critical patent/FI111765B/fi
Priority to AT97929321T priority patent/ATE224577T1/de
Priority to PCT/FI1997/000413 priority patent/WO1997050092A1/en
Priority to AU33460/97A priority patent/AU3346097A/en
Priority to EP97929321A priority patent/EP0909447B1/de
Priority to JP50240998A priority patent/JP4168172B2/ja
Priority to DE69715623T priority patent/DE69715623T2/de
Priority to US09/202,453 priority patent/US6214234B1/en
Publication of FI962648A publication Critical patent/FI962648A/fi
Application granted granted Critical
Publication of FI111765B publication Critical patent/FI111765B/fi

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Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/08—Simple or complex cyanides of metals
    • C01C3/11—Complex cyanides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D17/00—Rubidium, caesium or francium compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Removal Of Specific Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
FI962648A 1996-06-26 1996-06-26 Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi FI111765B (fi)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FI962648A FI111765B (fi) 1996-06-26 1996-06-26 Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi
EP97929321A EP0909447B1 (de) 1996-06-26 1997-06-26 Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten
PCT/FI1997/000413 WO1997050092A1 (en) 1996-06-26 1997-06-26 Method for cesium removal from radioactive waste liquids and method for producing hexacyanoferrates
AU33460/97A AU3346097A (en) 1996-06-26 1997-06-26 Method for cesium removal from radioactive waste liquids and method for producing hexacyanoferrates
AT97929321T ATE224577T1 (de) 1996-06-26 1997-06-26 Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten
JP50240998A JP4168172B2 (ja) 1996-06-26 1997-06-26 ヘキサシアノ鉄酸塩の製造方法
DE69715623T DE69715623T2 (de) 1996-06-26 1997-06-26 Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten
US09/202,453 US6214234B1 (en) 1996-06-26 1997-06-26 Method for the removal of cesium from radioactive waste liquids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI962648 1996-06-26
FI962648A FI111765B (fi) 1996-06-26 1996-06-26 Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi

Publications (3)

Publication Number Publication Date
FI962648A0 FI962648A0 (fi) 1996-06-26
FI962648A FI962648A (fi) 1997-12-27
FI111765B true FI111765B (fi) 2003-09-15

Family

ID=8546291

Family Applications (1)

Application Number Title Priority Date Filing Date
FI962648A FI111765B (fi) 1996-06-26 1996-06-26 Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi

Country Status (8)

Country Link
US (1) US6214234B1 (de)
EP (1) EP0909447B1 (de)
JP (1) JP4168172B2 (de)
AT (1) ATE224577T1 (de)
AU (1) AU3346097A (de)
DE (1) DE69715623T2 (de)
FI (1) FI111765B (de)
WO (1) WO1997050092A1 (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060141029A1 (en) * 2003-05-20 2006-06-29 Erimos Pharmaceuticals Llc Methods and compositions for delivery of catecholic butanes for treatment of diseases
US7291316B2 (en) * 2004-03-23 2007-11-06 Battelle Energy Alliance, Llc Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants
CN101279249B (zh) * 2008-05-23 2010-04-07 清华大学 以小球硅胶为载体的亚铁氰化锆钾的制备方法
US8158088B2 (en) * 2008-11-10 2012-04-17 Battelle Energy Alliance, Llc Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
US8270554B2 (en) * 2009-05-19 2012-09-18 The United States Of America, As Represented By The United States Department Of Energy Methods of producing cesium-131
JP5999675B2 (ja) * 2010-08-30 2016-09-28 国立研究開発法人産業技術総合研究所 無欠陥型プルシアンブルー類似体によるリチウムイオン２次電池用電極材料
JP5723715B2 (ja) * 2011-05-06 2015-05-27 大日精化工業株式会社 セシウム除去材
WO2013023932A1 (de) 2011-08-17 2013-02-21 BLüCHER GMBH Auf einem träger präzipitiertes adsorbens, verfahren zu seiner herstellung und seine verwendung
CN102557085B (zh) * 2011-11-03 2014-09-03 上海离岛电子新材料有限公司 一种生产铯、铷盐过程中提取钠盐的方法
RU2523823C2 (ru) * 2012-07-02 2014-07-27 Общество с ограниченной ответственностью Научно-производственное предприятие "Эксорб" Способ извлечения радионуклидов цезия из водных растворов
JP5715992B2 (ja) * 2012-07-12 2015-05-13 株式会社神鋼環境ソリューション 放射性セシウム含有水の処理方法、飛灰の処理方法、放射性セシウム含有水の処理装置及び飛灰の処理装置
RU2501603C1 (ru) * 2012-07-17 2013-12-20 Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" - Госкорпорация "Росатом" Способ получения сорбента на основе микросфер зол-уноса для очистки жидких радиоактивных отходов (варианты)
JP6000710B2 (ja) * 2012-07-23 2016-10-05 株式会社 微量元素開発 セシウムの除去方法
CN102773067B (zh) * 2012-08-22 2014-09-24 中国原子能科学研究院 一种磁性铯选择性吸附剂的制备方法
JP6262449B2 (ja) * 2013-05-17 2018-01-17 学校法人慈恵大学 放射性セシウム除染粒子の凝集体とその製造方法、並びに、放射性セシウムの除染方法
JP5713375B1 (ja) * 2013-12-02 2015-05-07 国立大学法人東京工業大学 セシウム吸着剤及びその製造方法並びにセシウム吸着剤を使用したセシウムの除去方法
EP3319726B1 (de) 2015-07-06 2019-09-11 LANXESS Deutschland GmbH Caesium selektive harze
RU2616064C1 (ru) * 2016-03-31 2017-04-12 Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") Способ получения сорбента на основе полимерного гидрогеля
WO2019011876A1 (de) * 2017-07-11 2019-01-17 Albemarle Germany Gmbh Verfahren zur cäsium-gewinnung aus wässrigen ausgangslösungen
KR102000679B1 (ko) * 2019-02-13 2019-07-17 한국원자력연구원 세슘 이온의 무기광물학적 제거 방법 및 장치

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US3296123A (en) * 1964-04-01 1967-01-03 William E Prout Removal of cesium from aqueous solutions by ion exchange
FR2067743A5 (en) * 1969-11-14 1971-08-20 Commissariat Energie Atomique Decontamination of effluent liquids contng cesium 137
US4448711A (en) * 1979-12-06 1984-05-15 Hitachi, Ltd. Process for producing zeolite adsorbent and process for treating radioactive liquid waste with the zeolite adsorbent
DE3704046A1 (de) * 1987-02-10 1988-08-18 Allgaeuer Alpenmilch Verfahren zum entfernen von radioaktiven metallen aus fluessigkeiten, lebens- und futtermitteln
CA2101261C (en) * 1991-12-24 2000-03-07 Vicktor P. Remes Method of composite sorbents manufacturing
US5482632A (en) * 1994-04-28 1996-01-09 Ionex Corporation Extracting a target ion from an aqueous solution by ion exchange and electropotential ion transport
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts

Also Published As

Publication number Publication date
US6214234B1 (en) 2001-04-10
DE69715623T2 (de) 2003-04-24
DE69715623D1 (de) 2002-10-24
AU3346097A (en) 1998-01-14
WO1997050092A1 (en) 1997-12-31
EP0909447B1 (de) 2002-09-18
FI962648A0 (fi) 1996-06-26
FI962648A (fi) 1997-12-27
JP4168172B2 (ja) 2008-10-22
ATE224577T1 (de) 2002-10-15
EP0909447A1 (de) 1999-04-21
JP2000512759A (ja) 2000-09-26

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