DE69715623T2 - Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten - Google Patents

Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten

Info

Publication number
DE69715623T2
DE69715623T2 DE69715623T DE69715623T DE69715623T2 DE 69715623 T2 DE69715623 T2 DE 69715623T2 DE 69715623 T DE69715623 T DE 69715623T DE 69715623 T DE69715623 T DE 69715623T DE 69715623 T2 DE69715623 T2 DE 69715623T2
Authority
DE
Germany
Prior art keywords
hexacyanoferrate
cesium
aqueous solution
transition element
volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69715623T
Other languages
English (en)
Other versions
DE69715623D1 (de
Inventor
Risto Harjula
Jukka Lehto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fortum Nuclear Services Oy
Original Assignee
Fortum Nuclear Services Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fortum Nuclear Services Oy filed Critical Fortum Nuclear Services Oy
Publication of DE69715623D1 publication Critical patent/DE69715623D1/de
Application granted granted Critical
Publication of DE69715623T2 publication Critical patent/DE69715623T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/08—Simple or complex cyanides of metals
    • C01C3/11—Complex cyanides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D17/00—Rubidium, caesium or francium compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Removal Of Specific Substances (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69715623T 1996-06-26 1997-06-26 Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten Expired - Lifetime DE69715623T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI962648A FI111765B (fi) 1996-06-26 1996-06-26 Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi
PCT/FI1997/000413 WO1997050092A1 (en) 1996-06-26 1997-06-26 Method for cesium removal from radioactive waste liquids and method for producing hexacyanoferrates

Publications (2)

Publication Number Publication Date
DE69715623D1 DE69715623D1 (de) 2002-10-24
DE69715623T2 true DE69715623T2 (de) 2003-04-24

Family

ID=8546291

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69715623T Expired - Lifetime DE69715623T2 (de) 1996-06-26 1997-06-26 Verfahren zur herstellung von nickel oder kobalt hexacyanoferraten

Country Status (8)

Country Link
US (1) US6214234B1 (de)
EP (1) EP0909447B1 (de)
JP (1) JP4168172B2 (de)
AT (1) ATE224577T1 (de)
AU (1) AU3346097A (de)
DE (1) DE69715623T2 (de)
FI (1) FI111765B (de)
WO (1) WO1997050092A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060141029A1 (en) * 2003-05-20 2006-06-29 Erimos Pharmaceuticals Llc Methods and compositions for delivery of catecholic butanes for treatment of diseases
US7291316B2 (en) * 2004-03-23 2007-11-06 Battelle Energy Alliance, Llc Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants
CN101279249B (zh) * 2008-05-23 2010-04-07 清华大学 以小球硅胶为载体的亚铁氰化锆钾的制备方法
US8158088B2 (en) * 2008-11-10 2012-04-17 Battelle Energy Alliance, Llc Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
US8270554B2 (en) * 2009-05-19 2012-09-18 The United States Of America, As Represented By The United States Department Of Energy Methods of producing cesium-131
JP5999675B2 (ja) * 2010-08-30 2016-09-28 国立研究開発法人産業技術総合研究所 無欠陥型プルシアンブルー類似体によるリチウムイオン２次電池用電極材料
JP5723715B2 (ja) * 2011-05-06 2015-05-27 大日精化工業株式会社 セシウム除去材
WO2013023932A1 (de) 2011-08-17 2013-02-21 BLüCHER GMBH Auf einem träger präzipitiertes adsorbens, verfahren zu seiner herstellung und seine verwendung
CN102557085B (zh) * 2011-11-03 2014-09-03 上海离岛电子新材料有限公司 一种生产铯、铷盐过程中提取钠盐的方法
RU2523823C2 (ru) * 2012-07-02 2014-07-27 Общество с ограниченной ответственностью Научно-производственное предприятие "Эксорб" Способ извлечения радионуклидов цезия из водных растворов
JP5715992B2 (ja) * 2012-07-12 2015-05-13 株式会社神鋼環境ソリューション 放射性セシウム含有水の処理方法、飛灰の処理方法、放射性セシウム含有水の処理装置及び飛灰の処理装置
RU2501603C1 (ru) * 2012-07-17 2013-12-20 Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" - Госкорпорация "Росатом" Способ получения сорбента на основе микросфер зол-уноса для очистки жидких радиоактивных отходов (варианты)
JP6000710B2 (ja) * 2012-07-23 2016-10-05 株式会社 微量元素開発 セシウムの除去方法
CN102773067B (zh) * 2012-08-22 2014-09-24 中国原子能科学研究院 一种磁性铯选择性吸附剂的制备方法
JP6262449B2 (ja) * 2013-05-17 2018-01-17 学校法人慈恵大学 放射性セシウム除染粒子の凝集体とその製造方法、並びに、放射性セシウムの除染方法
JP5713375B1 (ja) * 2013-12-02 2015-05-07 国立大学法人東京工業大学 セシウム吸着剤及びその製造方法並びにセシウム吸着剤を使用したセシウムの除去方法
EP3319726B1 (de) 2015-07-06 2019-09-11 LANXESS Deutschland GmbH Caesium selektive harze
RU2616064C1 (ru) * 2016-03-31 2017-04-12 Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") Способ получения сорбента на основе полимерного гидрогеля
WO2019011876A1 (de) * 2017-07-11 2019-01-17 Albemarle Germany Gmbh Verfahren zur cäsium-gewinnung aus wässrigen ausgangslösungen
KR102000679B1 (ko) * 2019-02-13 2019-07-17 한국원자력연구원 세슘 이온의 무기광물학적 제거 방법 및 장치

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3296123A (en) * 1964-04-01 1967-01-03 William E Prout Removal of cesium from aqueous solutions by ion exchange
FR2067743A5 (en) 1969-11-14 1971-08-20 Commissariat Energie Atomique Decontamination of effluent liquids contng cesium 137
US4448711A (en) * 1979-12-06 1984-05-15 Hitachi, Ltd. Process for producing zeolite adsorbent and process for treating radioactive liquid waste with the zeolite adsorbent
DE3704046A1 (de) 1987-02-10 1988-08-18 Allgaeuer Alpenmilch Verfahren zum entfernen von radioaktiven metallen aus fluessigkeiten, lebens- und futtermitteln
CA2101261C (en) * 1991-12-24 2000-03-07 Vicktor P. Remes Method of composite sorbents manufacturing
US5482632A (en) * 1994-04-28 1996-01-09 Ionex Corporation Extracting a target ion from an aqueous solution by ion exchange and electropotential ion transport
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts

Also Published As

Publication number Publication date
EP0909447B1 (de) 2002-09-18
DE69715623D1 (de) 2002-10-24
AU3346097A (en) 1998-01-14
ATE224577T1 (de) 2002-10-15
WO1997050092A1 (en) 1997-12-31
FI111765B (fi) 2003-09-15
US6214234B1 (en) 2001-04-10
JP2000512759A (ja) 2000-09-26
FI962648A (fi) 1997-12-27
FI962648A0 (fi) 1996-06-26
JP4168172B2 (ja) 2008-10-22
EP0909447A1 (de) 1999-04-21

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Legal Events

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8364 No opposition during term of opposition