ES2761816T5 - Hfo/water-expanded hard foam systems - Google Patents
Hfo/water-expanded hard foam systems Download PDFInfo
- Publication number
- ES2761816T5 ES2761816T5 ES12740369T ES12740369T ES2761816T5 ES 2761816 T5 ES2761816 T5 ES 2761816T5 ES 12740369 T ES12740369 T ES 12740369T ES 12740369 T ES12740369 T ES 12740369T ES 2761816 T5 ES2761816 T5 ES 2761816T5
- Authority
- ES
- Spain
- Prior art keywords
- polyol component
- bromo
- tetrafluoropropene
- trifluoropropene
- trifluoro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000006260 foam Substances 0.000 title description 52
- 229920005862 polyol Polymers 0.000 claims description 86
- 150000003077 polyols Chemical class 0.000 claims description 86
- 150000001336 alkenes Chemical class 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000004604 Blowing Agent Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 27
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 25
- 229920000570 polyether Polymers 0.000 claims description 25
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 24
- 239000011496 polyurethane foam Substances 0.000 claims description 23
- 239000005056 polyisocyanate Substances 0.000 claims description 20
- 229920001228 polyisocyanate Polymers 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims description 13
- OQISUJXQFPPARX-UHFFFAOYSA-N 2-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(Cl)=C OQISUJXQFPPARX-UHFFFAOYSA-N 0.000 claims description 13
- NLOLSXYRJFEOTA-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)C=CC(F)(F)F NLOLSXYRJFEOTA-UHFFFAOYSA-N 0.000 claims description 12
- LNSBXPNZJPZBQZ-UPHRSURJSA-N (e)-1-bromo-1,2,3,3,3-pentafluoroprop-1-ene Chemical compound F\C(Br)=C(/F)C(F)(F)F LNSBXPNZJPZBQZ-UPHRSURJSA-N 0.000 claims description 11
- XRZHWZVROHBBAM-OWOJBTEDSA-N (e)-1-bromo-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Br XRZHWZVROHBBAM-OWOJBTEDSA-N 0.000 claims description 11
- RRUCZSCEAWFDBM-UPHRSURJSA-N (z)-1-bromo-2,3,3,3-tetrafluoroprop-1-ene Chemical compound Br\C=C(/F)C(F)(F)F RRUCZSCEAWFDBM-UPHRSURJSA-N 0.000 claims description 11
- DMUPYMORYHFFCT-UHFFFAOYSA-N 1,2,3,3,3-pentafluoroprop-1-ene Chemical compound FC=C(F)C(F)(F)F DMUPYMORYHFFCT-UHFFFAOYSA-N 0.000 claims description 11
- VSZURNDHYWQPTO-UHFFFAOYSA-N 2-bromo-1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=C(Br)C(F)(F)F VSZURNDHYWQPTO-UHFFFAOYSA-N 0.000 claims description 11
- QKBKGNDTLQFSEU-UHFFFAOYSA-N 2-bromo-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(Br)=C QKBKGNDTLQFSEU-UHFFFAOYSA-N 0.000 claims description 11
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical compound FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 claims description 11
- SPZXNEBFTNEDGH-UHFFFAOYSA-N 3-bromo-1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=C(F)C(F)(F)Br SPZXNEBFTNEDGH-UHFFFAOYSA-N 0.000 claims description 11
- FRVWTAHTVVUDFK-UHFFFAOYSA-N 3-bromo-1,1,3,3-tetrafluoroprop-1-ene Chemical compound FC(F)=CC(F)(F)Br FRVWTAHTVVUDFK-UHFFFAOYSA-N 0.000 claims description 11
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 claims description 11
- ICTYZHTZZOUENE-NSCUHMNNSA-N (e)-1,1,1-trifluorobut-2-ene Chemical compound C\C=C\C(F)(F)F ICTYZHTZZOUENE-NSCUHMNNSA-N 0.000 claims description 10
- GJAJMLHFWTWPES-UPHRSURJSA-N (z)-2-bromo-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C(/Br)C(F)(F)F GJAJMLHFWTWPES-UPHRSURJSA-N 0.000 claims description 10
- NUPBXTZOBYEVIR-UHFFFAOYSA-N 1,1,2,3,3,4,4-heptafluorobut-1-ene Chemical compound FC(F)C(F)(F)C(F)=C(F)F NUPBXTZOBYEVIR-UHFFFAOYSA-N 0.000 claims description 10
- -1 alkylene carbonates Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 7
- 239000002671 adjuvant Substances 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 150000004040 pyrrolidinones Chemical class 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 42
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 238000012360 testing method Methods 0.000 description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 9
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 9
- 239000012948 isocyanate Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 150000002513 isocyanates Chemical class 0.000 description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 4
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 4
- 239000004970 Chain extender Substances 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 3
- NLOLSXYRJFEOTA-OWOJBTEDSA-N (e)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C\C(F)(F)F NLOLSXYRJFEOTA-OWOJBTEDSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000004872 foam stabilizing agent Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
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- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
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- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
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- 150000008163 sugars Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
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- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 description 1
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
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- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OHKOAJUTRVTYSW-UHFFFAOYSA-N 2-[(2-aminophenyl)methyl]aniline Chemical compound NC1=CC=CC=C1CC1=CC=CC=C1N OHKOAJUTRVTYSW-UHFFFAOYSA-N 0.000 description 1
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- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- COPLXRFZXQINJM-UHFFFAOYSA-N isocyanic acid;hydrate Chemical compound O.N=C=O COPLXRFZXQINJM-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/127—Mixtures of organic and inorganic blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11176102 | 2011-08-01 | ||
| PCT/EP2012/064847 WO2013017554A1 (de) | 2011-08-01 | 2012-07-30 | Hfo/wassergetriebene hartschaum-systeme |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2761816T3 ES2761816T3 (es) | 2020-05-21 |
| ES2761816T5 true ES2761816T5 (en) | 2025-02-11 |
Family
ID=46582710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12740369T Active ES2761816T5 (en) | 2011-08-01 | 2012-07-30 | Hfo/water-expanded hard foam systems |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP2739676B2 (enExample) |
| JP (1) | JP6085299B2 (enExample) |
| KR (1) | KR102008541B1 (enExample) |
| CN (1) | CN103717656B (enExample) |
| AU (1) | AU2012292108B2 (enExample) |
| BR (1) | BR112014002392B1 (enExample) |
| DK (1) | DK2739676T4 (enExample) |
| ES (1) | ES2761816T5 (enExample) |
| HU (1) | HUE046764T2 (enExample) |
| MX (1) | MX354274B (enExample) |
| PL (1) | PL2739676T5 (enExample) |
| RU (1) | RU2611493C2 (enExample) |
| WO (1) | WO2013017554A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9816760B2 (en) | 2012-08-24 | 2017-11-14 | Nortek Air Solutions Canada, Inc. | Liquid panel assembly |
| WO2014137969A1 (en) * | 2013-03-06 | 2014-09-12 | Honeywell International Inc. | Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene |
| BR112017005482A2 (pt) * | 2014-09-19 | 2017-12-19 | Honeywell Int Inc | método para moldar uma espuma flexível com células abertas, método para moldar espuma flexível com células abertas no formato de uma almofada de assento de automóvel, composição espumante, e composição de agente de expansão |
| EP3426707B1 (en) * | 2016-03-07 | 2020-12-30 | Basf Se | Rigid polyurethane foam |
| JP2018123308A (ja) * | 2017-02-02 | 2018-08-09 | 三洋化成工業株式会社 | ポリオール組成物およびポリウレタンフォームの製造方法 |
| CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
| US20200131298A1 (en) * | 2017-06-05 | 2020-04-30 | Bridgestone Corporation | Composition for polyurethane foam production, polyurethane foam, and sound-absorbing member |
| CN109679130B (zh) * | 2017-10-19 | 2021-09-07 | 山东理工大学 | 包含六氟丁烯和有机醇胺盐化合物的复合发泡剂 |
| EP3549967A1 (en) | 2018-04-06 | 2019-10-09 | Soudal | Polyurethane foam forming compositions |
| WO2020031863A1 (ja) | 2018-08-10 | 2020-02-13 | 旭有機材株式会社 | フェノールフォーム製造用樹脂組成物 |
| CN115698114B (zh) * | 2020-06-22 | 2026-06-12 | 巴斯夫欧洲公司 | 粘弹性弹性体聚氨酯泡沫、其制备方法及其用途 |
| KR20230029846A (ko) | 2020-06-25 | 2023-03-03 | 바스프 에스이 | 높은 압축 강도, 낮은 열 전도도, 및 높은 표면 품질을 갖는 폴리이소시아누레이트 수지 발포체 |
| US11753516B2 (en) | 2021-10-08 | 2023-09-12 | Covestro Llc | HFO-containing compositions and methods of producing foams |
| CN119731229A (zh) * | 2022-08-16 | 2025-03-28 | 巴斯夫欧洲公司 | 具有改善的储存稳定性的新型聚氨酯泡沫催化剂 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4121161A1 (de) | 1991-06-27 | 1993-01-07 | Basf Ag | Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen und treibmittel enthaltende emulsionen hierfuer |
| FR2678279B1 (fr) | 1991-06-27 | 1993-09-03 | Atochem | Application de (perfluoroalkyl)-ethylenes comme agents d'expansion et/ou gaz d'isolation pour mousses de polymeres. |
| DE4339702A1 (de) * | 1993-11-22 | 1995-05-24 | Bayer Ag | Verfahren zur Herstellung von harten Polyurethanschaumstoffen |
| US5494942A (en) * | 1993-12-27 | 1996-02-27 | The Dow Chemical Company | Process for preparing a rigid polyurethane foam and laminate articles therewith |
| DE19723193A1 (de) * | 1997-06-03 | 1998-12-10 | Bayer Ag | Verfahren zur Herstellung von geschlossenzelligen Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit |
| US9796848B2 (en) | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
| US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| EP1817358A1 (en) * | 2004-11-29 | 2007-08-15 | Fritz Nauer AG | Polyurethane foam |
| TW201533108A (zh) | 2005-06-24 | 2015-09-01 | Honeywell Int Inc | 含有經氟取代之烯烴之發泡劑及組合物，及發泡方法 |
| CA2840435A1 (en) | 2005-11-01 | 2007-05-10 | E.I. Du Pont De Nemours And Company | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| US9695267B2 (en) * | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
| JP5763338B2 (ja) | 2007-03-29 | 2015-08-12 | アーケマ・インコーポレイテッド | ヒドロフルオロオレフィンとヒドロクロロフルオロオレフィンの発泡剤組成物 |
| US9279039B2 (en) | 2007-03-29 | 2016-03-08 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin |
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| CN101878253B (zh) * | 2007-11-29 | 2013-05-29 | 纳幕尔杜邦公司 | 包含顺式-1,1,1,4,4,4-六氟-2-丁烯泡沫形成组合物的组合物以及所述组合物制备基于多异氰酸酯的泡沫的用途 |
| WO2009089400A1 (en) | 2008-01-11 | 2009-07-16 | E. I. Du Pont De Nemours And Company | Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams |
| US20100216904A1 (en) * | 2009-02-24 | 2010-08-26 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams |
| RU2553254C2 (ru) * | 2009-09-29 | 2015-06-10 | Басф Се | Способ получения жестких пенополиуретанов |
-
2012
- 2012-07-30 CN CN201280037132.0A patent/CN103717656B/zh active Active
- 2012-07-30 AU AU2012292108A patent/AU2012292108B2/en not_active Ceased
- 2012-07-30 WO PCT/EP2012/064847 patent/WO2013017554A1/de not_active Ceased
- 2012-07-30 MX MX2014001114A patent/MX354274B/es active IP Right Grant
- 2012-07-30 HU HUE12740369A patent/HUE046764T2/hu unknown
- 2012-07-30 ES ES12740369T patent/ES2761816T5/es active Active
- 2012-07-30 BR BR112014002392-1A patent/BR112014002392B1/pt active IP Right Grant
- 2012-07-30 KR KR1020147005535A patent/KR102008541B1/ko active Active
- 2012-07-30 EP EP12740369.9A patent/EP2739676B2/de active Active
- 2012-07-30 JP JP2014523295A patent/JP6085299B2/ja active Active
- 2012-07-30 DK DK12740369.9T patent/DK2739676T4/da active
- 2012-07-30 RU RU2014107761A patent/RU2611493C2/ru active
- 2012-07-30 PL PL12740369.9T patent/PL2739676T5/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2014001114A (es) | 2014-02-27 |
| EP2739676B2 (de) | 2024-08-14 |
| DK2739676T3 (da) | 2019-12-09 |
| CN103717656A (zh) | 2014-04-09 |
| AU2012292108A1 (en) | 2014-02-20 |
| BR112014002392B1 (pt) | 2020-11-10 |
| PL2739676T5 (pl) | 2024-11-04 |
| MX354274B (es) | 2018-02-21 |
| KR102008541B1 (ko) | 2019-08-08 |
| BR112014002392A2 (pt) | 2017-02-21 |
| DK2739676T4 (da) | 2024-11-11 |
| EP2739676B1 (de) | 2019-09-25 |
| RU2611493C2 (ru) | 2017-02-27 |
| RU2014107761A (ru) | 2015-09-10 |
| HUE046764T2 (hu) | 2020-03-30 |
| CN103717656B (zh) | 2016-03-23 |
| EP2739676A1 (de) | 2014-06-11 |
| JP6085299B2 (ja) | 2017-02-22 |
| AU2012292108B2 (en) | 2015-11-26 |
| WO2013017554A1 (de) | 2013-02-07 |
| ES2761816T3 (es) | 2020-05-21 |
| KR20140066713A (ko) | 2014-06-02 |
| JP2014521798A (ja) | 2014-08-28 |
| PL2739676T3 (pl) | 2020-04-30 |
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