AU2012292108B2 - HFO-/water-blown rigid-foam systems - Google Patents
HFO-/water-blown rigid-foam systems Download PDFInfo
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- AU2012292108B2 AU2012292108B2 AU2012292108A AU2012292108A AU2012292108B2 AU 2012292108 B2 AU2012292108 B2 AU 2012292108B2 AU 2012292108 A AU2012292108 A AU 2012292108A AU 2012292108 A AU2012292108 A AU 2012292108A AU 2012292108 B2 AU2012292108 B2 AU 2012292108B2
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- Australia
- Prior art keywords
- polyol component
- water
- amount
- mol
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims abstract description 57
- 229920005862 polyol Polymers 0.000 claims abstract description 81
- 150000003077 polyols Chemical class 0.000 claims abstract description 81
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- 239000004604 Blowing Agent Substances 0.000 claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 150000001336 alkenes Chemical class 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 23
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 23
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 25
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 25
- 229920000570 polyether Polymers 0.000 claims description 25
- 239000011496 polyurethane foam Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 16
- -1 alkylene carbonates Chemical class 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 4
- 125000005521 carbonamide group Chemical group 0.000 claims description 4
- 150000004040 pyrrolidinones Chemical class 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
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- 238000005259 measurement Methods 0.000 description 9
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
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- 125000002947 alkylene group Chemical group 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
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- 229910052782 aluminium Inorganic materials 0.000 description 5
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
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- 239000006071 cream Substances 0.000 description 3
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- 238000005187 foaming Methods 0.000 description 3
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- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
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- 235000000346 sugar Nutrition 0.000 description 3
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 3
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- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 2
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- COPLXRFZXQINJM-UHFFFAOYSA-N isocyanic acid;hydrate Chemical compound O.N=C=O COPLXRFZXQINJM-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000004805 propylene group Chemical class [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/127—Mixtures of organic and inorganic blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11176102 | 2011-08-01 | ||
| EP11176102.9 | 2011-08-01 | ||
| PCT/EP2012/064847 WO2013017554A1 (de) | 2011-08-01 | 2012-07-30 | Hfo/wassergetriebene hartschaum-systeme |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2012292108A1 AU2012292108A1 (en) | 2014-02-20 |
| AU2012292108B2 true AU2012292108B2 (en) | 2015-11-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2012292108A Ceased AU2012292108B2 (en) | 2011-08-01 | 2012-07-30 | HFO-/water-blown rigid-foam systems |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP2739676B2 (enExample) |
| JP (1) | JP6085299B2 (enExample) |
| KR (1) | KR102008541B1 (enExample) |
| CN (1) | CN103717656B (enExample) |
| AU (1) | AU2012292108B2 (enExample) |
| BR (1) | BR112014002392B1 (enExample) |
| DK (1) | DK2739676T4 (enExample) |
| ES (1) | ES2761816T5 (enExample) |
| HU (1) | HUE046764T2 (enExample) |
| MX (1) | MX354274B (enExample) |
| PL (1) | PL2739676T5 (enExample) |
| RU (1) | RU2611493C2 (enExample) |
| WO (1) | WO2013017554A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9816760B2 (en) | 2012-08-24 | 2017-11-14 | Nortek Air Solutions Canada, Inc. | Liquid panel assembly |
| WO2014137969A1 (en) * | 2013-03-06 | 2014-09-12 | Honeywell International Inc. | Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene |
| EP3194464A4 (en) * | 2014-09-19 | 2018-03-28 | Honeywell International Inc. | Flexible, open-cell thermoset foams and blowing agents and methods for making same |
| EP3426707B1 (en) | 2016-03-07 | 2020-12-30 | Basf Se | Rigid polyurethane foam |
| JP2018123308A (ja) * | 2017-02-02 | 2018-08-09 | 三洋化成工業株式会社 | ポリオール組成物およびポリウレタンフォームの製造方法 |
| CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
| US20200131298A1 (en) * | 2017-06-05 | 2020-04-30 | Bridgestone Corporation | Composition for polyurethane foam production, polyurethane foam, and sound-absorbing member |
| CN109679130B (zh) * | 2017-10-19 | 2021-09-07 | 山东理工大学 | 包含六氟丁烯和有机醇胺盐化合物的复合发泡剂 |
| EP3549967A1 (en) | 2018-04-06 | 2019-10-09 | Soudal | Polyurethane foam forming compositions |
| EP3835344A4 (en) | 2018-08-10 | 2022-04-20 | Asahi Yukizai Corporation | RESIN COMPOSITION FOR THE PRODUCTION OF PHENOLIC FOAM |
| EP4168464B1 (en) * | 2020-06-22 | 2025-08-06 | Basf Se | Viscoelastic elastomeric polyurethane foams, process for preparing them and use thereof |
| KR20230029846A (ko) | 2020-06-25 | 2023-03-03 | 바스프 에스이 | 높은 압축 강도, 낮은 열 전도도, 및 높은 표면 품질을 갖는 폴리이소시아누레이트 수지 발포체 |
| US11753516B2 (en) | 2021-10-08 | 2023-09-12 | Covestro Llc | HFO-containing compositions and methods of producing foams |
| CN119731229A (zh) * | 2022-08-16 | 2025-03-28 | 巴斯夫欧洲公司 | 具有改善的储存稳定性的新型聚氨酯泡沫催化剂 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| WO2009073487A1 (en) * | 2007-11-29 | 2009-06-11 | E. I. Du Pont De Nemours And Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4121161A1 (de) | 1991-06-27 | 1993-01-07 | Basf Ag | Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen und treibmittel enthaltende emulsionen hierfuer |
| FR2678279B1 (fr) | 1991-06-27 | 1993-09-03 | Atochem | Application de (perfluoroalkyl)-ethylenes comme agents d'expansion et/ou gaz d'isolation pour mousses de polymeres. |
| DE4339702A1 (de) * | 1993-11-22 | 1995-05-24 | Bayer Ag | Verfahren zur Herstellung von harten Polyurethanschaumstoffen |
| US5494942A (en) * | 1993-12-27 | 1996-02-27 | The Dow Chemical Company | Process for preparing a rigid polyurethane foam and laminate articles therewith |
| DE19723193A1 (de) * | 1997-06-03 | 1998-12-10 | Bayer Ag | Verfahren zur Herstellung von geschlossenzelligen Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit |
| US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| US9796848B2 (en) | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
| US20080015272A1 (en) * | 2004-11-29 | 2008-01-17 | Henri Mispreuve | Polyurethane Foam |
| TW201815923A (zh) | 2005-06-24 | 2018-05-01 | 美商哈尼威爾國際公司 | 含有經氟取代之烯烴之發泡劑及組合物，及發泡方法 |
| KR20140105870A (ko) | 2005-11-01 | 2014-09-02 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 불포화 플루오로카본을 포함하는 발포체 형성을 위한 발포제 |
| US9695267B2 (en) * | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
| US20100112328A1 (en) | 2007-03-29 | 2010-05-06 | Van Horn Brett L | Hydrofluoropropene blowing agents for thermoplastics |
| WO2008121787A1 (en) | 2007-03-29 | 2008-10-09 | Arkema Inc. | Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin |
| WO2009089400A1 (en) | 2008-01-11 | 2009-07-16 | E. I. Du Pont De Nemours And Company | Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams |
| US20100216904A1 (en) * | 2009-02-24 | 2010-08-26 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams |
| BR112012006879A2 (pt) * | 2009-09-29 | 2016-06-07 | Basf Se | processo para produzir espumas de poliuretano rígidas, e, espuma de poliuretano rígida |
-
2012
- 2012-07-30 EP EP12740369.9A patent/EP2739676B2/de active Active
- 2012-07-30 HU HUE12740369A patent/HUE046764T2/hu unknown
- 2012-07-30 MX MX2014001114A patent/MX354274B/es active IP Right Grant
- 2012-07-30 JP JP2014523295A patent/JP6085299B2/ja active Active
- 2012-07-30 RU RU2014107761A patent/RU2611493C2/ru active
- 2012-07-30 CN CN201280037132.0A patent/CN103717656B/zh active Active
- 2012-07-30 WO PCT/EP2012/064847 patent/WO2013017554A1/de not_active Ceased
- 2012-07-30 BR BR112014002392-1A patent/BR112014002392B1/pt active IP Right Grant
- 2012-07-30 AU AU2012292108A patent/AU2012292108B2/en not_active Ceased
- 2012-07-30 ES ES12740369T patent/ES2761816T5/es active Active
- 2012-07-30 KR KR1020147005535A patent/KR102008541B1/ko active Active
- 2012-07-30 PL PL12740369.9T patent/PL2739676T5/pl unknown
- 2012-07-30 DK DK12740369.9T patent/DK2739676T4/da active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| WO2009073487A1 (en) * | 2007-11-29 | 2009-06-11 | E. I. Du Pont De Nemours And Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2739676B2 (de) | 2024-08-14 |
| ES2761816T3 (es) | 2020-05-21 |
| MX354274B (es) | 2018-02-21 |
| CN103717656A (zh) | 2014-04-09 |
| PL2739676T5 (pl) | 2024-11-04 |
| EP2739676A1 (de) | 2014-06-11 |
| RU2611493C2 (ru) | 2017-02-27 |
| ES2761816T5 (en) | 2025-02-11 |
| JP6085299B2 (ja) | 2017-02-22 |
| DK2739676T3 (da) | 2019-12-09 |
| KR102008541B1 (ko) | 2019-08-08 |
| EP2739676B1 (de) | 2019-09-25 |
| JP2014521798A (ja) | 2014-08-28 |
| HUE046764T2 (hu) | 2020-03-30 |
| CN103717656B (zh) | 2016-03-23 |
| WO2013017554A1 (de) | 2013-02-07 |
| BR112014002392B1 (pt) | 2020-11-10 |
| DK2739676T4 (da) | 2024-11-11 |
| BR112014002392A2 (pt) | 2017-02-21 |
| RU2014107761A (ru) | 2015-09-10 |
| KR20140066713A (ko) | 2014-06-02 |
| MX2014001114A (es) | 2014-02-27 |
| AU2012292108A1 (en) | 2014-02-20 |
| PL2739676T3 (pl) | 2020-04-30 |
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| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |