ES2722413T3 - Componente de catalizador para polimerización de olefinas, procedimiento de preparación del mismo y catalizador que comprende el mismo - Google Patents

Componente de catalizador para polimerización de olefinas, procedimiento de preparación del mismo y catalizador que comprende el mismo Download PDF

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ES2722413T3
ES2722413T3 ES14854754T ES14854754T ES2722413T3 ES 2722413 T3 ES2722413 T3 ES 2722413T3 ES 14854754 T ES14854754 T ES 14854754T ES 14854754 T ES14854754 T ES 14854754T ES 2722413 T3 ES2722413 T3 ES 2722413T3
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formula
poly
alkyl
polymer dispersion
polyvinyl
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Xianzhi Xia
Jin Zhao
Weili Li
Yuexiang Liu
Yongtai Ling
Ping Gao
Yang Tan
Futang Gao
Renqi Peng
Jigui Zhang
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6423—Component of C08F4/64 containing at least two different metals
    • C08F4/6425—Component of C08F4/64 containing at least two different metals containing magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un componente de catalizador para polimerización de olefinas, que comprende productos de reacción de los siguientes componentes: (1) un componente sólido; (2) al menos un compuesto de titanio; y (3) al menos dos donadores de electrones internos; en el que el componente sólido comprende un compuesto de magnesio representado por la fórmula (1) y un epóxido representado por la fórmula (2) y en el que el componente sólido se obtiene haciendo reaccionar una disolución de aducto haluro de magnesio-alcohol con el epóxido representado por la fórmula (2) en presencia de al menos un estabilizador de dispersión polimérico, en el que el estabilizador de dispersión polimérico es al menos uno elegido de poliacrilatos, copolímeros de estireno-anhídrido maleico, sulfonatos de poliestireno, productos de condensación de ácido naftalensulfónico-formaldehído, sulfatos de alquil fenil éteres condensados, fosfatos de polioxietilen éteres de alquilfenoles condensados, polietileniminas modificadas con copolímeros de acrilato de oxialquilo, poli(bromuro de 1-dodecil-4-vinilpiridinio), poli(sal de trimetilvinilbencilamonio), poli(alcohol vinílico), poliacrilamidas, copolímeros de bloques de óxido de etilenoóxido de propileno, polivinilpirrolidonas (PVP), poli(vinilpirrolidona-co-acetato de vinilo), polietilenglicoles (PEG), alquilfenil polioxietilen éteres y poli(metilacrilato de alquilo), preferiblemente al menos uno de polivinilpirrolidona, poli(vinilpirrolidona-co-acetato de vinilo) y polietilenglicoles, y el peso molecular promedio en peso del estabilizador de dispersión polimérico es mayor de 1000, preferiblemente mayor de 3000, y más preferiblemente de 6.000 hasta 2.000.000 **(Ver fórmula)** en el que, RI es un alquilo C1-C12 lineal o ramificado; RII y RIII son idénticos o diferentes, y son independientemente hidrógeno o alquilo C1-C5 lineal o ramificado no sustituido o sustituido con halógeno; X es halógeno; m está en un intervalo de 0,1 hasta 1,9, n está en un intervalo de 0,1 hasta 1,9, y m + n = 2; y en el que el contenido del epóxido representado por la fórmula (2) está en un intervalo de 0,01 hasta 0,8 moles por mol del compuesto de magnesio representado por la fórmula (1).
ES14854754T 2013-10-18 2014-10-17 Componente de catalizador para polimerización de olefinas, procedimiento de preparación del mismo y catalizador que comprende el mismo Active ES2722413T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201310491626.2A CN104558282B (zh) 2013-10-18 2013-10-18 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用
PCT/CN2014/088808 WO2015055137A1 (zh) 2013-10-18 2014-10-17 用于烯烃聚合的催化剂组分、其制备方法和包含它的催化剂

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ES2722413T3 true ES2722413T3 (es) 2019-08-09

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US (1) US9809663B2 (es)
EP (1) EP3059264B1 (es)
JP (1) JP6523271B2 (es)
KR (1) KR101973078B1 (es)
CN (1) CN104558282B (es)
AU (1) AU2014336758B2 (es)
BR (1) BR112016008602B1 (es)
ES (1) ES2722413T3 (es)
MY (1) MY178722A (es)
RU (1) RU2674026C2 (es)
SA (1) SA516370960B1 (es)
SG (1) SG11201602999WA (es)
TW (1) TWI650336B (es)
WO (1) WO2015055137A1 (es)

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SG11201602999WA (en) 2016-05-30
TWI650336B (zh) 2019-02-11
AU2014336758B2 (en) 2018-07-05
JP6523271B2 (ja) 2019-05-29
SA516370960B1 (ar) 2021-02-24
CN104558282B (zh) 2017-02-15
CN104558282A (zh) 2015-04-29
EP3059264B1 (en) 2018-12-26
JP2016537455A (ja) 2016-12-01
RU2016118998A (ru) 2017-11-23
TW201527340A (zh) 2015-07-16
RU2674026C2 (ru) 2018-12-04
MY178722A (en) 2020-10-20
WO2015055137A1 (zh) 2015-04-23
US20160264694A1 (en) 2016-09-15
EP3059264A4 (en) 2017-05-24
KR101973078B1 (ko) 2019-04-26
US9809663B2 (en) 2017-11-07
KR20160073978A (ko) 2016-06-27
EP3059264A1 (en) 2016-08-24
BR112016008602B1 (pt) 2021-01-19

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