ES2632712T3 - Procedimiento para la generación de un producto gaseoso rico en hidrógeno - Google Patents

Procedimiento para la generación de un producto gaseoso rico en hidrógeno Download PDF

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Publication number
ES2632712T3
ES2632712T3 ES07846494.8T ES07846494T ES2632712T3 ES 2632712 T3 ES2632712 T3 ES 2632712T3 ES 07846494 T ES07846494 T ES 07846494T ES 2632712 T3 ES2632712 T3 ES 2632712T3
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Spain
Prior art keywords
pyrolysis
zone
heat
heat carrier
starting material
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Application number
ES07846494.8T
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English (en)
Inventor
Heinz-Jürgen Mühlen
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Concord Blue Patent GmbH
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Concord Blue Patent GmbH
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/32—Other processes in ovens with mechanical conveying means
    • C10B47/44—Other processes in ovens with mechanical conveying means with conveyor-screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/12—Continuous processes using solid heat-carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/14—Continuous processes using gaseous heat-carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Procedimiento para la generación de un producto gaseoso rico en hidrógeno con alto poder calorífico a partir de un material de partida en forma de sustancias o mezclas de sustancias orgánicas, en el que el material de partida se descompone en una zona de pirólisis (2) mediante pirólisis en un residuo sólido conteniendo carbono y gas de pirólisis como fase volátil y los gases de pirólisis se mezclan con vapor de agua como reactivo y se calientan posteriormente en una zona de reacción (3) de tal manera que se produce un producto gaseoso con alto poder calorífico, con lo que el calor necesario para la pirólisis y el calentamiento posterior proviene al menos en su mayor parte de la combustión de los residuos sólidos conteniendo carbono de la pirólisis y se alimenta al sistema mediante un producto a granel como portador de calor, transportado en el circuito, que se calienta en una zona de calentamiento (13) con los gases calientes de la combustión de los residuos sólidos conteniendo carbono, a continuación se pone en contacto en la zona de reacción (3) con la mezcla de gas de pirólisis y vapor de agua, entonces aporta al menos una parte de su calor medible en la zona de pirólisis (2) y a continuación se devuelve por medio de un transportador de cargas a granel (6) al principio del circuito portador de calor, caracterizado porque en el circuito portador de calor antes de la zona de calentamiento (13), en la que el circuito portador de calor se calienta a una temperatura de 1050 °C a 1100 °C, se prevé una zona de precalentamiento (4), en la que el producto a granel se precalienta con el producto gaseoso caliente procedente de la zona de reacción (3) y además recibe la mayor parte de su calor, y porque la transferencia de calor del circuito portador de calor al material de partida en la etapa de pirólisis (2) se lleva a cabo indirectamente y sin contacto directo con el producto a granel a través de un medio calefactor gaseoso intermedio (17), que se calienta en una zona de enfriamiento (19) del circuito del portador de calor y a continuación emite una parte del calor absorbido en la zona de pirólisis (2) a través de la camisa calefactora de un aparato de pirólisis al material de partida a pirolizar, con lo que el circuito del portador de calor en la zona de enfriamiento (19) antes de la entrada en el transportador de cargas a granel (6) se enfría a una temperatura entre la temperatura ambiente y 200° C.

Description

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Claims (1)

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ES07846494.8T 2006-10-18 2007-10-16 Procedimiento para la generación de un producto gaseoso rico en hidrógeno Active ES2632712T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102006049701 2006-10-18
DE102006049701 2006-10-18
DE102007005799.9A DE102007005799B4 (de) 2006-10-18 2007-02-06 Verfahren zur Erzeugung eines wasserstoffreichen Produktgases
DE102007005799 2007-02-06
PCT/EP2007/008943 WO2008046578A2 (de) 2006-10-18 2007-10-16 Verfahren zur erzeugung eines wasserstoffreichen produktgases

Publications (1)

Publication Number Publication Date
ES2632712T3 true ES2632712T3 (es) 2017-09-15

Family

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Application Number Title Priority Date Filing Date
ES07846494.8T Active ES2632712T3 (es) 2006-10-18 2007-10-16 Procedimiento para la generación de un producto gaseoso rico en hidrógeno

Country Status (15)

Country Link
US (1) US8333951B2 (es)
EP (1) EP2082013B1 (es)
JP (1) JP5447835B2 (es)
CN (1) CN101541927B (es)
BR (1) BRPI0717650B1 (es)
CA (1) CA2666943C (es)
DE (1) DE102007005799B4 (es)
EA (1) EA014523B1 (es)
ES (1) ES2632712T3 (es)
HU (1) HUE035284T2 (es)
MX (1) MX2009004166A (es)
PL (1) PL2082013T3 (es)
PT (1) PT2082013T (es)
SI (1) SI2082013T1 (es)
WO (1) WO2008046578A2 (es)

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JP5301563B2 (ja) 2008-05-01 2013-09-25 ヴァイティー ファーマシューティカルズ，インコーポレイテッド １１β−ヒドロキシステロイドデヒドロゲナーゼ１の環状インヒビター
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Also Published As

Publication number Publication date
JP5447835B2 (ja) 2014-03-19
BRPI0717650A2 (pt) 2013-12-24
US20100119440A1 (en) 2010-05-13
DE102007005799A1 (de) 2008-04-24
DE102007005799B4 (de) 2018-01-25
WO2008046578A2 (de) 2008-04-24
HUE035284T2 (hu) 2018-05-02
EA014523B1 (ru) 2010-12-30
US8333951B2 (en) 2012-12-18
SI2082013T1 (sl) 2017-10-30
CN101541927B (zh) 2013-09-25
EA200970382A1 (ru) 2009-10-30
BRPI0717650B1 (pt) 2017-04-18
JP2010506813A (ja) 2010-03-04
PT2082013T (pt) 2017-07-14
CA2666943A1 (en) 2008-04-24
WO2008046578A3 (de) 2008-07-10
CN101541927A (zh) 2009-09-23
CA2666943C (en) 2015-12-29
EP2082013B1 (de) 2017-04-12
MX2009004166A (es) 2009-09-09
PL2082013T3 (pl) 2018-01-31
EP2082013A2 (de) 2009-07-29

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