ES2541456T3 - Instalación y método para la producción de sustancias combustibles por despolimerización de productos de caucho - Google Patents

Instalación y método para la producción de sustancias combustibles por despolimerización de productos de caucho Download PDF

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Publication number
ES2541456T3
ES2541456T3 ES05750151.2T ES05750151T ES2541456T3 ES 2541456 T3 ES2541456 T3 ES 2541456T3 ES 05750151 T ES05750151 T ES 05750151T ES 2541456 T3 ES2541456 T3 ES 2541456T3
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tube
depolymerization
phase
chamber
opening
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Franco Fini
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IDROEDIL Srl
PROGET ENERGY Srl
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IDROEDIL Srl
PROGET ENERGY Srl
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/02—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in retorts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

Una instalación para la producción de sustancias combustibles por medio de despolimerización de productos de caucho, que comprende un dispositivo de despolimerización despresurizado (1), en la que la despolimerización de una cantidad predeterminada de productos se produce dentro de la misma, e incluye un divisor o separador de fases (2) colocado corriente abajo de dicho dispositivo de despolimerización (1), que está formado básicamente por un cuerpo cilíndrico con una base superior (20) y una base inferior (21), y se conecta con el dispositivo de despolimerización (1) por medio de un tubo (3): y dicho separador de fases (2) se diseña para conseguir la separación de al menos una parte de la fase líquida de los productos que salen del dispositivo de despolimerización (1) de la fase gaseosa y presenta una salida (23) para la fase líquida separada de este modo y una salida (24) para la parte restante de los productos en fase básicamente gaseosa, en la que el dispositivo de despolimerización (1) mencionado se despresuriza por medio de una unidad de aspiración (4) colocada corriente abajo de dicho separador de fases (2) y la misma se conecta con este por medio de un tubo correspondiente (6), caracterizado por que el separador de fases mencionado (2) comprende una cámara (25) en un lado en la que se coloca una pared (26), para delimitar una segunda cámara (27) cerrada en la parte superior y abierta en la parte inferior, y dicha segunda cámara (27) aloja un tubo (28) colocado verticalmente con un extremo en correspondencia con dicha abertura (24) de la base inferior (21) de dicho cuerpo (2), el otro extremo de dicho tubo (28) permanece a una distancia predeterminada desde la abertura inferior de la pared (26), y dicho tubo (28) se conecta con la unidad (4) mediante dicho tubo (6), bajo dicha abertura (23) para la fase líquida presentada por el separador (2), colocándose un recipiente (29), en el que el líquido se vacía a través de un tubo correspondiente (290), y dicho recipiente (29) tiene una abertura inferior (293) conectada con una bomba (291) que vuelve a introducir en la cámara (25) el líquido que sale de ella, por medio de uno o varios inyectores o nebulizadores (292), colocados a una distancia predeterminada desde la base superior (20) del cuerpo (2), y la conexión entre dicha abertura (293) del recipiente (29) y dicha bomba (291) se consigue por medio de un tubo (295) y la conexión entre la bomba (291) y los inyectores (292) se consigue por medio de un tubo (296) cuyo tramo final está dentro de la cámara (25) y pasa a través de la base superior (20) del cuerpo (2), dicho recipiente (29) tiene adicionalmente una abertura lateral superior (294) para drenar el líquido que no se recicla con la bomba (291).

Description

imagen1
imagen2
imagen3
imagen4
E05750151
02-07-2015
El método propuesto para la producción de sustancias combustibles de acuerdo con la presente invención comprende, a la vista de lo que se ha descrito anteriormente, una fase de despolimerización de productos de caucho como neumáticos usados y similares, con producción de una mezcla fluida de dos fases, implica la separación y recogida de al menos una parte de la fase líquida de dicha mezcla. Tanto la despolimerización como la separación de las fases se pueden realizar en condiciones despresurizadas. La fase básicamente gaseosa se puede usar para alimentar un quemador, a introducir, con el aire comburente, en un motor diésel o de cualquier otra manera.
TABLA 1
Método de ensayo
Tipo de ensayo M.U. Resultados
ASTM D 1298/90
Densidad a 15 ºC Kg/m3 958,5
ASTM D 445/94
Viscosidad a 50 ºC mm2/s 9,654
NOM 47/71
Viscosidad a 50 ºC conversión ºE 1,801
ASTM D 445/94
Viscosidad a 100 ºC mm2/s 2,339
NOM 47/71
Viscosidad a 100 ºC conversión ºE 1,154
ASTM D 97/93
Punto de deslizamiento ºC −21
ASTM D 240/92
Energía calorífica superior MJ/kg 42,814
Kcal/kg
10228
ASTM D 240/92
Energía calorífica superior MJ/kg 40,562
Kcal/kg
9688
ASTM D 5291/92
Análisis elemental de C/H/N % en peso 87,08/10,62/0,34
ASTM D 3180/89
Oxígeno (calculado) % en peso 0,77
ASTM D 4530/93
Residuo de carbono % en peso 1,91
IP 143/96
Asfaltenos % en peso 1
ASTM D 482/95
Cenizas % en peso 0,04
ASTM D 95/90
Agua para destilación % en volumen 0,1
ASTM D 93/94
Punto de inflamabilidad ºC 72
ASTM D 2622/98
Azufre % en peso 1,17
IP 288/95
Vanadio/Níquel mg/kg < 1/3
IP 288/95
Sodio mg/kg 2
IP 377/95
Aluminio mg/kg < 1
IP 377/95
Sedimentos totales (H.F.T.) % en peso 0,02
ASTM D 664/89
Acidez mg de KOH/g 0,126
ASTM D 86/95
Destilación
Destilado a 250 ºC
% en volumen 19
Destilado a 350 ºC
% en volumen 74
ASTM D 1500/91
Color Negro
Olfativo
Olor Intenso
10 TABLA 2
Parámetro
Unidad Valor medio Desviación estándar Valor límite
Sección del conducto de muestreo
m2 0,119
Velocidad del efluentes
m/s 5,6 0,3
Temperatura del afluente
ºC 308,2 2,4
Presión atmosférica
% en 992
6
E05750151
02-07-2015
Parámetro
Unidad Valor medio Desviación estándar Valor límite
mbar
Vapor en el afluente
% en v/v 2,31
Densidad del afluente
Kg/mc 0,6
Caudal medido del afluente
mc/h 2408 123
Efluente normal seco Caudal
NmcS/h 1082 60
Contenido de oxígeno medido
% en v/v 12,3
Contenido de oxígeno de referencia
% en v/v 11
Concentración correcta de óxido de carbono
mg/mc 3,4 1,1 100
Concentración correcta total de polvos
mg/NmcS 11,3 0,3 30
Flujo total de polvos
g/h 10,5 0,25
Concentración correcta de S.O.V. (como C.O.T.)
mg/NmcS 0,3 0,05 20
Flujo de masa de S.O.V. (como C.O.T.)
g/h 0,27 0,05
Concentración correcta de óxido de azufre (como SO2)
mg/NmcS 61 6,7 200
Flujo de óxido de azufre total (como SO2)
g/h 57 6,3
Concentración correcta de óxido de nitrógeno
mg/NmcS 224 6,3 400
Flujo de óxido de nitrógeno total (como NO2)
g/h 212 6
Concentración correcta de ácido clorhídrico total (como HCl)
mg/NmcS 11,2 2 40
Flujo de masa ácido clorhídrico total (como HCl)
g/h 10,6 1,8
Concentración correcta de flúor total (F−)
mg/NmcS 3,24 0,4 4
Flujo de masa de flúor total (como HCl)
g/h 3,1 0,4
TABLA 3
Componente
% Kcal/Nm3 a 0 ºC Kcal/Nm3 a 15,5 ºC
CO
13,2 400,5 378,8
CO2
14,2 0 0
CH4
2,16 185,1 175,3
O2
0,63 0 0
H2
5,77 148,9 140,9
N2
64,0 0 0
Otros
0,04 0 0
Total
100 734,5 695,0
TABLA 4
Nº de ensayo
I II III IV
Paceite (Watt Eléctricos)
2768 3089 5716 8979
Paceite + gas (Watt Eléctricos)
4850 5631 9512 12715
∆P (Watt Eléctricos)
2082 2542 3796 3736
Caudal de Gas (Nm3/h)
12,7 15,2 23,4 23,3
Energía del Gas (Watt térmicos)
10300 12300 18900 18800
CR (%)
20,2 20,7 20,1 19,9
7

Claims (1)

  1. imagen1
    imagen2
ES05750151.2T 2004-06-09 2005-05-31 Instalación y método para la producción de sustancias combustibles por despolimerización de productos de caucho Active ES2541456T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITFI20040127 2004-06-09
IT000127A ITFI20040127A1 (it) 2004-06-09 2004-06-09 Impianto e procedimento per la produzione di sostanze combustibili mediante depolimerizzazione di prodotti in gomma
PCT/IT2005/000309 WO2005121278A1 (fr) 2004-06-09 2005-05-31 Installation et procédé pour la production de substances combustibles par dépolymérisation de produits en gomme

Publications (1)

Publication Number Publication Date
ES2541456T3 true ES2541456T3 (es) 2015-07-20

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US (1) US7628892B2 (es)
EP (1) EP1769052B1 (es)
JP (1) JP4819813B2 (es)
CN (1) CN1965057B (es)
BR (1) BRPI0511799B1 (es)
CA (1) CA2568977C (es)
DK (1) DK1769052T3 (es)
EA (1) EA013267B1 (es)
ES (1) ES2541456T3 (es)
IL (1) IL179552A (es)
IT (1) ITFI20040127A1 (es)
PL (1) PL1769052T3 (es)
PT (1) PT1769052E (es)
SI (1) SI1769052T1 (es)
WO (1) WO2005121278A1 (es)

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IL179552A0 (en) 2007-05-15
WO2005121278A1 (fr) 2005-12-22
US20080035079A1 (en) 2008-02-14
SI1769052T1 (sl) 2015-08-31
US7628892B2 (en) 2009-12-08
PT1769052E (pt) 2015-08-27
CA2568977A1 (fr) 2005-12-22
CA2568977C (fr) 2013-10-01
PL1769052T3 (pl) 2015-10-30
ITFI20040127A1 (it) 2004-09-09
BRPI0511799B1 (pt) 2015-11-03
EA200602250A1 (ru) 2007-06-29
EP1769052B1 (fr) 2015-05-20
DK1769052T3 (en) 2015-06-29
BRPI0511799A (pt) 2008-01-15
EP1769052A1 (fr) 2007-04-04
IL179552A (en) 2011-02-28
CN1965057A (zh) 2007-05-16
CN1965057B (zh) 2011-06-22
JP2008501845A (ja) 2008-01-24
EA013267B1 (ru) 2010-04-30
JP4819813B2 (ja) 2011-11-24

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