ES2541456T3 - Installation and method for the production of combustible substances by depolymerization of rubber products - Google Patents

Installation and method for the production of combustible substances by depolymerization of rubber products Download PDF

Info

Publication number
ES2541456T3
ES2541456T3 ES05750151.2T ES05750151T ES2541456T3 ES 2541456 T3 ES2541456 T3 ES 2541456T3 ES 05750151 T ES05750151 T ES 05750151T ES 2541456 T3 ES2541456 T3 ES 2541456T3
Authority
ES
Spain
Prior art keywords
tube
depolymerization
phase
chamber
opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES05750151.2T
Other languages
Spanish (es)
Inventor
Franco Fini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IDROEDIL Srl
PROGET ENERGY Srl
Original Assignee
IDROEDIL Srl
PROGET ENERGY Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IDROEDIL Srl, PROGET ENERGY Srl filed Critical IDROEDIL Srl
Application granted granted Critical
Publication of ES2541456T3 publication Critical patent/ES2541456T3/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/02—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in retorts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

Una instalación para la producción de sustancias combustibles por medio de despolimerización de productos de caucho, que comprende un dispositivo de despolimerización despresurizado (1), en la que la despolimerización de una cantidad predeterminada de productos se produce dentro de la misma, e incluye un divisor o separador de fases (2) colocado corriente abajo de dicho dispositivo de despolimerización (1), que está formado básicamente por un cuerpo cilíndrico con una base superior (20) y una base inferior (21), y se conecta con el dispositivo de despolimerización (1) por medio de un tubo (3): y dicho separador de fases (2) se diseña para conseguir la separación de al menos una parte de la fase líquida de los productos que salen del dispositivo de despolimerización (1) de la fase gaseosa y presenta una salida (23) para la fase líquida separada de este modo y una salida (24) para la parte restante de los productos en fase básicamente gaseosa, en la que el dispositivo de despolimerización (1) mencionado se despresuriza por medio de una unidad de aspiración (4) colocada corriente abajo de dicho separador de fases (2) y la misma se conecta con este por medio de un tubo correspondiente (6), caracterizado por que el separador de fases mencionado (2) comprende una cámara (25) en un lado en la que se coloca una pared (26), para delimitar una segunda cámara (27) cerrada en la parte superior y abierta en la parte inferior, y dicha segunda cámara (27) aloja un tubo (28) colocado verticalmente con un extremo en correspondencia con dicha abertura (24) de la base inferior (21) de dicho cuerpo (2), el otro extremo de dicho tubo (28) permanece a una distancia predeterminada desde la abertura inferior de la pared (26), y dicho tubo (28) se conecta con la unidad (4) mediante dicho tubo (6), bajo dicha abertura (23) para la fase líquida presentada por el separador (2), colocándose un recipiente (29), en el que el líquido se vacía a través de un tubo correspondiente (290), y dicho recipiente (29) tiene una abertura inferior (293) conectada con una bomba (291) que vuelve a introducir en la cámara (25) el líquido que sale de ella, por medio de uno o varios inyectores o nebulizadores (292), colocados a una distancia predeterminada desde la base superior (20) del cuerpo (2), y la conexión entre dicha abertura (293) del recipiente (29) y dicha bomba (291) se consigue por medio de un tubo (295) y la conexión entre la bomba (291) y los inyectores (292) se consigue por medio de un tubo (296) cuyo tramo final está dentro de la cámara (25) y pasa a través de la base superior (20) del cuerpo (2), dicho recipiente (29) tiene adicionalmente una abertura lateral superior (294) para drenar el líquido que no se recicla con la bomba (291).An installation for the production of combustible substances by means of depolymerization of rubber products, comprising a depressurized depolymerization device (1), in which the depolymerization of a predetermined quantity of products occurs within it, and includes a divider or phase separator (2) placed downstream of said depolymerization device (1), which is basically formed by a cylindrical body with an upper base (20) and a lower base (21), and is connected to the depolymerization device (1) by means of a tube (3): and said phase separator (2) is designed to achieve the separation of at least a part of the liquid phase of the products leaving the depolymerization device (1) of the phase gas and presents an outlet (23) for the liquid phase thus separated and an outlet (24) for the remaining part of the products in the basically gas phase, in which the device for depolymerization (1) mentioned is depressurized by means of a suction unit (4) placed downstream of said phase separator (2) and it is connected thereto by means of a corresponding tube (6), characterized in that the separator of phases mentioned (2) comprises a chamber (25) on one side in which a wall (26) is placed, to delimit a second chamber (27) closed at the top and open at the bottom, and said second chamber (27) houses a tube (28) positioned vertically with one end corresponding to said opening (24) of the lower base (21) of said body (2), the other end of said tube (28) remains at a predetermined distance from the lower opening of the wall (26), and said tube (28) is connected to the unit (4) by said tube (6), under said opening (23) for the liquid phase presented by the separator (2), placing a container (29), in which the liquid is emptied through a corresponding tube tooth (290), and said container (29) has a lower opening (293) connected to a pump (291) that re-introduces into the chamber (25) the liquid leaving it, by means of one or more injectors or nebulizers (292), placed at a predetermined distance from the upper base (20) of the body (2), and the connection between said opening (293) of the container (29) and said pump (291) is achieved by means of a tube (295) and the connection between the pump (291) and the injectors (292) is achieved by means of a tube (296) whose final section is inside the chamber (25) and passes through the upper base (20) of the body (2), said container (29) additionally has an upper side opening (294) to drain the liquid that is not recycled with the pump (291).

Description

imagen1image 1

imagen2image2

imagen3image3

imagen4image4

E05750151 E05750151

02-07-2015 07-02-2015

El método propuesto para la producción de sustancias combustibles de acuerdo con la presente invención comprende, a la vista de lo que se ha descrito anteriormente, una fase de despolimerización de productos de caucho como neumáticos usados y similares, con producción de una mezcla fluida de dos fases, implica la separación y recogida de al menos una parte de la fase líquida de dicha mezcla. Tanto la despolimerización como la separación de las fases se pueden realizar en condiciones despresurizadas. La fase básicamente gaseosa se puede usar para alimentar un quemador, a introducir, con el aire comburente, en un motor diésel o de cualquier otra manera. The proposed method for the production of combustible substances according to the present invention comprises, in view of what has been described above, a depolymerization phase of rubber products such as used tires and the like, with production of a fluid mixture of two phases, involves the separation and collection of at least a part of the liquid phase of said mixture. Both depolymerization and phase separation can be performed under depressurized conditions. The basically gas phase can be used to feed a burner, to be introduced, with the combustion air, into a diesel engine or in any other way.

TABLA 1 TABLE 1

Método de ensayo Testing method
Tipo de ensayo M.U. Resultados Test type M.U. Results

ASTM D 1298/90 ASTM D 1298/90
Densidad a 15 ºC Kg/m3 958,5 Density at 15 ° C Kg / m3 958.5

ASTM D 445/94 ASTM D 445/94
Viscosidad a 50 ºC mm2/s 9,654 Viscosity at 50 ° C mm2 / s 9,654

NOM 47/71 NOM 47/71
Viscosidad a 50 ºC conversión ºE 1,801 Viscosity at 50 ° C conversion ºE 1,801

ASTM D 445/94 ASTM D 445/94
Viscosidad a 100 ºC mm2/s 2,339 Viscosity at 100 ° C mm2 / s 2,339

NOM 47/71 NOM 47/71
Viscosidad a 100 ºC conversión ºE 1,154 Viscosity at 100 ° C conversion ºE 1,154

ASTM D 97/93 ASTM D 97/93
Punto de deslizamiento ºC −21 Slip point ºC −21

ASTM D 240/92 ASTM D 240/92
Energía calorífica superior MJ/kg 42,814 Superior heat energy MJ / kg 42,814

Kcal/kg Kcal / kg
10228 10228

ASTM D 240/92 ASTM D 240/92
Energía calorífica superior MJ/kg 40,562 Superior heat energy MJ / kg 40,562

Kcal/kg Kcal / kg
9688 9688

ASTM D 5291/92 ASTM D 5291/92
Análisis elemental de C/H/N % en peso 87,08/10,62/0,34 Elemental Analysis of C / H / N % in weigh 87.08 / 10.62 / 0.34

ASTM D 3180/89 ASTM D 3180/89
Oxígeno (calculado) % en peso 0,77 Oxygen (calculated) % in weigh 0.77

ASTM D 4530/93 ASTM D 4530/93
Residuo de carbono % en peso 1,91 Carbon residue % in weigh 1.91

IP 143/96 IP 143/96
Asfaltenos % en peso 1 Asphaltenes % in weigh one

ASTM D 482/95 ASTM D 482/95
Cenizas % en peso 0,04 Ashes % in weigh 0.04

ASTM D 95/90 ASTM D 95/90
Agua para destilación % en volumen 0,1 Water for distillation % by volume 0.1

ASTM D 93/94 ASTM D 93/94
Punto de inflamabilidad ºC 72 Flash point ºC 72

ASTM D 2622/98 ASTM D 2622/98
Azufre % en peso 1,17 Sulfur % in weigh 1.17

IP 288/95 IP 288/95
Vanadio/Níquel mg/kg < 1/3 Vanadium / Nickel mg / kg <1/3

IP 288/95 IP 288/95
Sodio mg/kg 2 Sodium mg / kg 2

IP 377/95 IP 377/95
Aluminio mg/kg < 1 Aluminum mg / kg <1

IP 377/95 IP 377/95
Sedimentos totales (H.F.T.) % en peso 0,02 Total sediments (H.F.T.) % in weigh 0.02

ASTM D 664/89 ASTM D 664/89
Acidez mg de KOH/g 0,126 Acidity mg of KOH / g 0.126

ASTM D 86/95 ASTM D 86/95
Destilación Distillation

Destilado a 250 ºC Distilled at 250 ° C
% en volumen 19 % by volume 19

Destilado a 350 ºC Distilled at 350 ° C
% en volumen 74 % by volume 74

ASTM D 1500/91 ASTM D 1500/91
Color Negro Color Black

Olfativo Olfactory
Olor Intenso Odor Intense

10 TABLA 2 10 TABLE 2

Parámetro Parameter
Unidad Valor medio Desviación estándar Valor límite Unity Middle value Standard deviation Limit value

Sección del conducto de muestreo Sample conduit section
m2 0,119 m2 0.119

Velocidad del efluentes Effluent speed
m/s 5,6 0,3 m / s 5.6 0.3

Temperatura del afluente Tributary temperature
ºC 308,2 2,4 ºC 308.2 2.4

Presión atmosférica Atmospheric pressure
% en 992 % in 992

6 6

E05750151 E05750151

02-07-2015 07-02-2015

Parámetro Parameter
Unidad Valor medio Desviación estándar Valor límite Unity Middle value Standard deviation Limit value

mbar mbar

Vapor en el afluente Steam in the tributary
% en v/v 2,31 % in v / v 2.31

Densidad del afluente Density of the tributary
Kg/mc 0,6 Kg / mc 0.6

Caudal medido del afluente Measured tributary flow
mc/h 2408 123 mc / h 2408 123

Efluente normal seco Caudal Normal dry effluent Flow
NmcS/h 1082 60 NmcS / h 1082 60

Contenido de oxígeno medido Measured oxygen content
% en v/v 12,3 % in v / v 12.3

Contenido de oxígeno de referencia Reference oxygen content
% en v/v 11 % in v / v eleven

Concentración correcta de óxido de carbono Correct concentration of carbon oxide
mg/mc 3,4 1,1 100 mg / mc 3.4 1.1 100

Concentración correcta total de polvos Total correct concentration of powders
mg/NmcS 11,3 0,3 30 mg / NmcS 11.3 0.3 30

Flujo total de polvos Total powder flow
g/h 10,5 0,25 g / h 10.5 0.25

Concentración correcta de S.O.V. (como C.O.T.) Correct concentration of S.O.V. (as C.O.T.)
mg/NmcS 0,3 0,05 20 mg / NmcS 0.3 0.05 twenty

Flujo de masa de S.O.V. (como C.O.T.) S.O.V. mass flow (as C.O.T.)
g/h 0,27 0,05 g / h 0.27 0.05

Concentración correcta de óxido de azufre (como SO2) Correct concentration of sulfur oxide (as SO2)
mg/NmcS 61 6,7 200 mg / NmcS 61 6.7 200

Flujo de óxido de azufre total (como SO2) Total sulfur oxide flow (as SO2)
g/h 57 6,3 g / h 57 6.3

Concentración correcta de óxido de nitrógeno Correct concentration of nitrogen oxide
mg/NmcS 224 6,3 400 mg / NmcS 224 6.3 400

Flujo de óxido de nitrógeno total (como NO2) Total nitrogen oxide flow (as NO2)
g/h 212 6 g / h 212 6

Concentración correcta de ácido clorhídrico total (como HCl) Correct concentration of total hydrochloric acid (as HCl)
mg/NmcS 11,2 2 40 mg / NmcS 11.2 2 40

Flujo de masa ácido clorhídrico total (como HCl) Total hydrochloric acid mass flow (as HCl)
g/h 10,6 1,8 g / h 10.6 1.8

Concentración correcta de flúor total (F−) Correct concentration of total fluorine (F−)
mg/NmcS 3,24 0,4 4 mg / NmcS 3.24 0.4 4

Flujo de masa de flúor total (como HCl) Total fluoride mass flow (as HCl)
g/h 3,1 0,4 g / h 3.1 0.4

TABLA 3 TABLE 3

Componente Component
% Kcal/Nm3 a 0 ºC Kcal/Nm3 a 15,5 ºC % Kcal / Nm3 at 0 ° C Kcal / Nm3 at 15.5 ° C

CO CO
13,2 400,5 378,8 13.2 400.5 378.8

CO2 CO2
14,2 0 0 14.2 0 0

CH4 CH4
2,16 185,1 175,3 2.16 185.1 175.3

O2 O2
0,63 0 0 0.63 0 0

H2 H2
5,77 148,9 140,9 5.77 148.9 140.9

N2 N2
64,0 0 0 64.0 0 0

Otros Others
0,04 0 0 0.04 0 0

Total Total
100 734,5 695,0 100 734.5 695.0

TABLA 4 TABLE 4

Nº de ensayo Test number
I II III IV I II III IV

Paceite (Watt Eléctricos) Paceite (Electric Watts)
2768 3089 5716 8979 2768 3089 5716 8979

Paceite + gas (Watt Eléctricos) Paceite + gas (Electric Watts)
4850 5631 9512 12715 4850 5631 9512 12715

∆P (Watt Eléctricos) ∆P (Watt Electric)
2082 2542 3796 3736 2082 2542 3796 3736

Caudal de Gas (Nm3/h) Gas flow (Nm3 / h)
12,7 15,2 23,4 23,3 12.7 15.2 23.4 23.3

Energía del Gas (Watt térmicos) Gas Energy (Thermal Watt)
10300 12300 18900 18800 10300 12300 18900 18800

CR (%) CR (%)
20,2 20,7 20,1 19,9 20.2 20.7 20.1 19.9

7 7

Claims (1)

imagen1image 1 imagen2image2
ES05750151.2T 2004-06-09 2005-05-31 Installation and method for the production of combustible substances by depolymerization of rubber products Active ES2541456T3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITFI20040127 2004-06-09
IT000127A ITFI20040127A1 (en) 2004-06-09 2004-06-09 PLANT AND PROCEDURE FOR THE PRODUCTION OF COMBUSTIBLE SUBSTANCES BY DEPOLYMERIZATION OF RUBBER PRODUCTS
PCT/IT2005/000309 WO2005121278A1 (en) 2004-06-09 2005-05-31 Plant and method for producing combustible substances by depolymerization of gum products

Publications (1)

Publication Number Publication Date
ES2541456T3 true ES2541456T3 (en) 2015-07-20

Family

ID=34971239

Family Applications (1)

Application Number Title Priority Date Filing Date
ES05750151.2T Active ES2541456T3 (en) 2004-06-09 2005-05-31 Installation and method for the production of combustible substances by depolymerization of rubber products

Country Status (15)

Country Link
US (1) US7628892B2 (en)
EP (1) EP1769052B1 (en)
JP (1) JP4819813B2 (en)
CN (1) CN1965057B (en)
BR (1) BRPI0511799B1 (en)
CA (1) CA2568977C (en)
DK (1) DK1769052T3 (en)
EA (1) EA013267B1 (en)
ES (1) ES2541456T3 (en)
IL (1) IL179552A (en)
IT (1) ITFI20040127A1 (en)
PL (1) PL1769052T3 (en)
PT (1) PT1769052E (en)
SI (1) SI1769052T1 (en)
WO (1) WO2005121278A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0804349A2 (en) 2008-10-16 2010-07-13 Rm Materiais Refratarios Ltda apparatus and process for thermal decomposition of any type of organic material
AT511772B1 (en) 2011-05-05 2018-03-15 Omv Refining & Marketing Gmbh METHOD AND DEVICE FOR THE ENERGY EFFICIENT PREPARATION OF SECONDARY STORES
US10695953B2 (en) 2012-05-31 2020-06-30 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous carpet filament
US9636860B2 (en) 2012-05-31 2017-05-02 Mohawk Industries, Inc. Method of manufacturing bulked continuous filament
US10532495B2 (en) 2012-05-31 2020-01-14 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from recycled PET
US10538016B2 (en) 2012-05-31 2020-01-21 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous carpet filament
US9630353B2 (en) 2012-05-31 2017-04-25 Mohawk Industries, Inc. Method of manufacturing bulked continuous filament
US8597553B1 (en) 2012-05-31 2013-12-03 Mohawk Industries, Inc. Systems and methods for manufacturing bulked continuous filament
US11045979B2 (en) 2012-05-31 2021-06-29 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from recycled PET
US10487422B2 (en) 2012-05-31 2019-11-26 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from colored recycled pet
WO2015084192A1 (en) * 2013-12-04 2015-06-11 Get Energy Prime Italy Srl Fuel & power assembly
ES2955828T3 (en) 2016-07-26 2023-12-07 Prti Global Man Llc Apparatus and method for thermally dismantling tires and other waste products
US10751915B2 (en) 2016-11-10 2020-08-25 Aladdin Manufacturing Corporation Polyethylene terephthalate coloring systems and methods
AU2018212971B2 (en) 2017-01-30 2023-04-06 Aladdin Manufacturing Corporation Methods for manufacturing bulked continuous filament from colored recycled PET
AU2018227587A1 (en) 2017-03-03 2019-08-22 Aladdin Manufacturing Corporation Method of manufacturing bulked continuous carpet filament
CA3073425A1 (en) 2017-09-15 2019-03-21 Aladdin Manufacturing Corporation Polyethylene terephthalate coloring method and system for manufacturing a bulked continuous carpet filament
PL423297A1 (en) * 2017-10-30 2019-05-06 Dariusz Kalinowski Method for conducting a deepened process of organic wastes pyrolysis, preferably used up automobile tyres and method for conducting a deepened process of organic wastes pyrolysis, preferably used up automobile tyres
US11242622B2 (en) 2018-07-20 2022-02-08 Aladdin Manufacturing Corporation Bulked continuous carpet filament manufacturing from polytrimethylene terephthalate
CA3188369A1 (en) 2020-09-14 2022-03-17 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock

Family Cites Families (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4839151A (en) * 1984-10-12 1989-06-13 Fred Apffel Recovery process
US4752068A (en) * 1985-11-07 1988-06-21 Namco Ltd. Video game machine for business use
US4740270A (en) * 1986-06-19 1988-04-26 Universite Laval Vacuum pyrolysis of scrap tires
IT1210422B (en) * 1987-04-17 1989-09-14 Marangoni Meccanica SYSTEM FOR THE GENERATION OF WATER STEAM FOR COGENERATIVE SYSTEMS, THROUGH PYROLYSIS OF WHOLE TIRES, SELF-CLEANING AND AUTOMATIC REVIVAL OF COMBUSTION THROUGH A PARTICULAR GEOMETRIC AND CINEMATIC CONFERENCE OF THE COMBUSION TANK.
US5157176A (en) 1990-07-26 1992-10-20 Munger Joseph H Recycling process, apparatus and product produced by such process for producing a rubber extender/plasticizing agent from used automobile rubber tires
US5095040A (en) * 1991-02-11 1992-03-10 Ledford Charles D Process for conveying old rubber tires into oil and a useful residue
KR930010858B1 (en) * 1991-08-30 1993-11-15 이대성 Burner
US5369215A (en) * 1992-04-06 1994-11-29 S-P Reclamation, Inc. Depolymerization method for resource recovery from polymeric wastes
US5851246A (en) * 1992-05-07 1998-12-22 Hylsa, S.A. De C.V. Apparatus for gasifying organic materials
JPH07321751A (en) * 1994-05-23 1995-12-08 Nippon Denki Idou Tsushin Kk Receiver for television game data
IT1269889B (en) * 1994-07-28 1997-04-15 Alessia Fini METHOD AND PLANT FOR THE PRODUCTION OF COMBUSTIBLE SUBSTANCES
FI944244A0 (en) * 1994-09-13 1994-09-13 Waertsilae Nsd Oy Ab Foerfarande Foer framstaellning av dieselmotorbraensle av bildaeck ocjikne avfallsgummimaterial
US5575474A (en) * 1994-09-21 1996-11-19 Rossides; Michael Communications system using bets
US5830068A (en) * 1995-09-08 1998-11-03 Ods Technologies, L.P. Interactive wagering systems and processes
US6015344A (en) * 1996-04-05 2000-01-18 Rlt Acquisition, Inc. Prize redemption system for games
JPH09279171A (en) * 1996-04-10 1997-10-28 Nippon Steel Corp Purification of oil-containing thermal decomposition gas
US6009458A (en) * 1996-05-09 1999-12-28 3Do Company Networked computer game system with persistent playing objects
US6244958B1 (en) * 1996-06-25 2001-06-12 Acres Gaming Incorporated Method for providing incentive to play gaming devices connected by a network to a host computer
US6589417B2 (en) * 1996-09-27 2003-07-08 Alberta Oil Sands Tech And Research Authority Thermal apparatus and process for removing contaminants from oil
US5833537A (en) * 1996-09-30 1998-11-10 Forever Endeavor Software, Inc. Gaming apparatus and method with persistence effect
US6364765B1 (en) * 1998-07-01 2002-04-02 Walker Digital, Llc Electronic amusement device offering secondary game of chance and method for operating same
US6077163A (en) * 1997-06-23 2000-06-20 Walker Digital, Llc Gaming device for a flat rate play session and a method of operating same
US6012983A (en) * 1996-12-30 2000-01-11 Walker Asset Management Limited Partnership Automated play gaming device
US6234896B1 (en) * 1997-04-11 2001-05-22 Walker Digital, Llc Slot driven video story
US6165071A (en) * 1997-05-20 2000-12-26 Casino Data Systems Method and apparatus for gaming in a series of sessions
US5957775A (en) * 1997-07-01 1999-09-28 Horse Sense Corporation Wagering game based on ranking order of game participants
US6012045A (en) * 1997-07-01 2000-01-04 Barzilai; Nizan Computer-based electronic bid, auction and sale system, and a system to teach new/non-registered customers how bidding, auction purchasing works
US6511377B1 (en) * 1997-08-07 2003-01-28 Casino Data Systems Cashless gaming system: apparatus and method
US6249135B1 (en) * 1997-09-19 2001-06-19 Fujitsu Limited Method and apparatus for passive optical characterization of semiconductor substrates subjected to high energy (MEV) ion implantation using high-injection surface photovoltage
US6302790B1 (en) * 1998-02-19 2001-10-16 International Game Technology Audio visual output for a gaming device
ZA992256B (en) * 1998-03-24 2000-01-13 Wms Gaming Inc Bonus Game for a gaming machine.
US7559838B2 (en) * 1998-03-31 2009-07-14 Walker Digital, Llc Gaming device and method of operation thereof
US6005149A (en) * 1998-08-18 1999-12-21 Engineering, Separation & Recycling, Ltd. Co. Method and apparatus for processing organic materials to produce chemical gases and carbon char
SE513063C2 (en) * 1998-08-21 2000-06-26 Bengt Sture Ershag Process for the recovery of carbon and hydrocarbon compounds from polymeric material, preferably in the form of discarded tires, by pyrolysis in a pyrolysis reactor
US6113098A (en) * 1998-09-22 2000-09-05 Anchor Gaming Gaming device with supplemental ticket dispenser
AU2001287068A1 (en) * 1998-09-22 2002-03-22 Igt Methods and apparatus for providing tickets from gaming devices and/or lottery terminals which are not dependent on a players success of the underlying game
US6273820B1 (en) * 1999-02-04 2001-08-14 Haste, Iii Thomas E. Virtual player gaming method
JP2000290661A (en) * 1999-04-05 2000-10-17 Nippon System Kanryu Kk Dry distillation facility for oil component-containing material such as rubber and the like
US6592457B1 (en) * 1999-05-26 2003-07-15 Wms Gaming Inc. Gaming machine with player selected events
US6268457B1 (en) * 1999-06-10 2001-07-31 Allied Signal, Inc. Spin-on glass anti-reflective coatings for photolithography
US6254481B1 (en) * 1999-09-10 2001-07-03 Wms Gaming Inc. Gaming machine with unified image on multiple video displays
US20030100362A1 (en) * 2000-01-31 2003-05-29 Deltronic Labs, Inc. System and method for providing incentive to user of a gaming device
US6656050B2 (en) * 2000-08-04 2003-12-02 Steven Busch Odds accelerator for promotional type sweepstakes, games, and contests
AUPQ968000A0 (en) * 2000-08-25 2000-09-21 Win Amusement Group Pty Ltd System and method of displaying a game on a gaming machine
US6311976B1 (en) * 2000-09-01 2001-11-06 Shuffle Master Inc Video game with bonusing or wild feature
US6974385B2 (en) * 2000-10-04 2005-12-13 Wms Gaming Inc. Gaming machine with visual and audio indicia changed over time
US6939226B1 (en) * 2000-10-04 2005-09-06 Wms Gaming Inc. Gaming machine with visual and audio indicia changed over time
US6514141B1 (en) * 2000-10-06 2003-02-04 Igt Gaming device having value selection bonus
KR100391121B1 (en) * 2000-12-11 2003-07-16 김현영 Method of gasifying high molecular weight organic material and apparatus therefor
US6758757B2 (en) * 2000-12-20 2004-07-06 Sierra Design Group Method and apparatus for maintaining game state
US6923721B2 (en) * 2000-12-20 2005-08-02 Sierra Design Group Apparatus and method for maintaining game state
US6811486B1 (en) * 2000-12-20 2004-11-02 Sierra Design Group Method and apparatus for enhancing game play through savable game play state
US20020093136A1 (en) * 2001-01-05 2002-07-18 Moody Ernest W. Method of operating a gaming machine with a ticket printer
US7156738B2 (en) * 2001-01-16 2007-01-02 Igt Casino gambling machine with bonus round award redemption
JP2002309270A (en) * 2001-04-17 2002-10-23 Toshiba Corp Circulation system for oil produced from waste plastic
US6722985B2 (en) * 2001-04-19 2004-04-20 Igt Universal player tracking system
AU2002310496A1 (en) * 2001-06-21 2003-01-08 Walker Digital, Llc Methods and systems for documenting a player's experience in a casino environment
US7008321B2 (en) * 2001-07-10 2006-03-07 Igt Method and system for issuing and using gaming machine receipts
US7008320B2 (en) * 2001-07-10 2006-03-07 Igt Gaming machine with receipt generation capabilities
US7377849B2 (en) * 2001-08-20 2008-05-27 Igt Gaming device having player selectable award digits and award modification options
US20030036427A1 (en) * 2001-08-20 2003-02-20 Steve Brandstetter Coin counter and ticket dispenser for a game machine
US6506118B1 (en) * 2001-08-24 2003-01-14 Igt Gaming device having improved award offer bonus scheme
US6663489B2 (en) * 2001-08-24 2003-12-16 Igt Gaming device having an award distributor and an award accumulator bonus game
US7785194B2 (en) * 2001-09-18 2010-08-31 Igt Player specific rewards
WO2003025828A2 (en) * 2001-09-18 2003-03-27 Acres Gaming Incorporated Gaming system whereby game contents is changed based on recorded data about different players
US6609974B2 (en) * 2001-09-28 2003-08-26 Igt Gaming device having a multiple round game that includes player choices and processor choices
US6780111B2 (en) * 2001-11-30 2004-08-24 Igt Method, apparatus and system for perpetual bonus game
US6902478B2 (en) * 2001-12-19 2005-06-07 Igt Method and apparatus for an interactive bonus game
US8702492B2 (en) * 2002-04-16 2014-04-22 Igt Methods and apparatus for employing audio/video programming to initiate game play at a gaming device
US20040053680A1 (en) * 2002-09-16 2004-03-18 Bradley Schultz Gaming device and method with bonus and displayed winning probabilities
US6776713B2 (en) * 2002-11-26 2004-08-17 Atronic International Gmbh Game for a gaming device where a player competes with a computer
US7662040B2 (en) * 2003-07-02 2010-02-16 Wms Gaming Inc. Gaming machine having a community game with side wagering
US7384337B2 (en) * 2004-01-15 2008-06-10 Wms Gaming Inc. Wagering game providing rewards independent from gaming session
US20060079317A1 (en) * 2004-09-24 2006-04-13 Wms Gaming Inc. Wagering game with bonus-game assets that can be preserved for subsequent gaming sessions
US20060079316A1 (en) * 2004-09-24 2006-04-13 Wms Gaming Inc. Wagering game with an array of player-selectable elements that are preserved for subsequent gaming sessions
US8764537B2 (en) * 2004-09-29 2014-07-01 Wms Gaming Inc. Wagering game with symbols collection
US20060084495A1 (en) * 2004-10-19 2006-04-20 Wms Gaming Inc. Wagering game with feature for recording records and statistics
US8033906B2 (en) * 2004-10-21 2011-10-11 Wms Gaming Inc. Wagering game with invitation for playing a wagering game at a subsequent gaming session

Also Published As

Publication number Publication date
JP2008501845A (en) 2008-01-24
EA013267B1 (en) 2010-04-30
WO2005121278A1 (en) 2005-12-22
PL1769052T3 (en) 2015-10-30
US7628892B2 (en) 2009-12-08
JP4819813B2 (en) 2011-11-24
EP1769052A1 (en) 2007-04-04
DK1769052T3 (en) 2015-06-29
BRPI0511799A (en) 2008-01-15
ITFI20040127A1 (en) 2004-09-09
CA2568977A1 (en) 2005-12-22
IL179552A0 (en) 2007-05-15
SI1769052T1 (en) 2015-08-31
CA2568977C (en) 2013-10-01
BRPI0511799B1 (en) 2015-11-03
EA200602250A1 (en) 2007-06-29
EP1769052B1 (en) 2015-05-20
IL179552A (en) 2011-02-28
US20080035079A1 (en) 2008-02-14
CN1965057B (en) 2011-06-22
CN1965057A (en) 2007-05-16
PT1769052E (en) 2015-08-27

Similar Documents

Publication Publication Date Title
ES2541456T3 (en) Installation and method for the production of combustible substances by depolymerization of rubber products
AR054337A1 (en) PROCEDURE AND DEVICE FOR COQUIFICATION OF CARBON WITH ELEVATE CONTENT OF VOLATILE SUBSTANCES
ES2844186T3 (en) Procedure for the treatment of carbonaceous materials by steam-thermolysis
ES2558318T3 (en) Apparatus and method of thermochemical carbonization and wet biomass gasification
BR112015003952A2 (en) systems and methods for the devolatilization of thermally produced liquids
ES2971344T3 (en) Installation for the production and production method of oil, gas and carbonaceous residue for a carbon black from elastomers, especially rubber waste, in the continuous pyrolysis process
US10792587B2 (en) Method for aeration of a flammable liquid to extract flammable vapor
CN205710587U (en) A kind of coal sample pyrolysis-char gasification integrated system
ES2339050T3 (en) PROCEDURE FOR BREAKING THE CARBON CHAINS OF ORGANIC MOLECULES OF SOLID MATERIALS AND CORRESPONDING APPLIANCE.
CN104614308A (en) Experimental device for simulating sulfuric acid dew point corrosion
CN204556467U (en) A kind of experimental provision of simulating corrosion of sulfuric acid dew
CN108717051B (en) Device and method for measuring natural gas calorific value by combining TDLAS (tunable diode laser absorption spectroscopy) and photoacoustic spectroscopy
CN203216915U (en) Explosive gas analyzer
RU2011114240A (en) METHOD FOR DETERMINING THE NECESSARY QUANTITY OF FLAMMABLE LIQUID IN EXPLOSION PROTECTION MEMBRANES TESTS
CN101975405A (en) Supercharged boiler deflagration-preventing device and method
CN208383705U (en) A kind of TDLAS surveys the device of heating value of natural gas in conjunction with optoacoustic spectroscopy
CN101885988B (en) Steam and air mixed medium biomass gasifier
Zadmajid The development of a new experimental facility for pyrolysis liquid biofuel (bio-oil) combustion
BR102016027627A2 (en) PYROLYTIC CONTINUOUS FLOW REACTOR, CONTINUOUS FLOW PYROLYSIS PROCESS AND RECYCLING PLANT
ES2581602T3 (en) Heating of a process exhaust gas
CN206540189U (en) A kind of separate type alcohol-based fuel burner of convenient disassembly
JP2010133918A (en) Vaporizer for measuring content of hydrocarbon component contained in soil
CN201737904U (en) Biomass gasification furnace utilizing mixture of steam and air medium
CN104914212B (en) It is a kind of to be used to detect the detection device and method that gas is discharged during precoated sand coremaking
WO2012108751A1 (en) Device for recycling tyres by pyrolysis