ES2531403T3 - Compuestos de organosilicio cíclicos como donantes de electrones para catalizadores de poliolefina - Google Patents

Compuestos de organosilicio cíclicos como donantes de electrones para catalizadores de poliolefina Download PDF

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Publication number
ES2531403T3
ES2531403T3 ES09843481T ES09843481T ES2531403T3 ES 2531403 T3 ES2531403 T3 ES 2531403T3 ES 09843481 T ES09843481 T ES 09843481T ES 09843481 T ES09843481 T ES 09843481T ES 2531403 T3 ES2531403 T3 ES 2531403T3
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group
cyclic organosilicon
organosilicon compounds
electron donors
independently
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Yiqun Fang
Honglan Lu
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Formosa Plastics Corp USA
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Formosa Plastics Corp USA
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un sistema de catalizadores para la polimerización o co-polimerización de alfa-olefina que comprende un componente de catalizador tipo Ziegler-Natta sólido, un componente de co-catalizador y un componente de donante de electrones que comprende al menos un compuesto de organosilicio cíclico de fórmula:**Fórmula** en la que Q1 y Q2 son cada uno un heteroátomo independientemente seleccionado del grupo que consiste en N, O, S, Si, B, P, con la condición de que Q1 y Q2 no pueden ser ambos N o ser ambos O; en la que R1 y R2 son cada uno independientemente un sustituyente basado en hidrocarburo para Q1 y Q2, respectivamente; en la que m y n son independientemente 0 a 3; en la que R3 es un grupo alifático, alicíclico o aromático; en la que R4 es un grupo de hidrocarburo con 1 a 6 átomos de carbono; y en la que R5 es un grupo de puente con una longitud de cadena del esqueleto entre los dos heteroátomos Q1 y Q2 siendo 1 a 8 átomos, en la que el esqueleto de dicho grupo de puente está seleccionado del grupo que consiste en radicales alifáticos, alicíclicos y aromáticos.
ES09843481T 2009-04-13 2009-12-09 Compuestos de organosilicio cíclicos como donantes de electrones para catalizadores de poliolefina Active ES2531403T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/422,741 US7619049B1 (en) 2009-04-13 2009-04-13 Cyclic organosilicon compounds as electron donors for polyolefin catalysts
PCT/US2009/067371 WO2010120331A1 (en) 2009-04-13 2009-12-09 Cyclic organosilicon compounds as electron donors for polyolefin catalysts

Publications (1)

Publication Number Publication Date
ES2531403T3 true ES2531403T3 (es) 2015-03-13

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ES09843481T Active ES2531403T3 (es) 2009-04-13 2009-12-09 Compuestos de organosilicio cíclicos como donantes de electrones para catalizadores de poliolefina

Country Status (6)

Country Link
US (1) US7619049B1 (es)
EP (1) EP2419210B1 (es)
JP (1) JP5718314B2 (es)
CN (1) CN102481556B (es)
ES (1) ES2531403T3 (es)
WO (1) WO2010120331A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746426A (zh) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备和应用
US10654947B2 (en) * 2011-10-28 2020-05-19 Formosa Plastics Corporation, Usa Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability
US9815918B2 (en) 2012-03-19 2017-11-14 Formosa Plastics Corporation, U.S.A. Catalyst component for high activity and high stereoselectivity in olefin polymerization
US8993693B2 (en) 2012-03-23 2015-03-31 Formosa Plastics Corporation Ethylene copolymers with a novel composition distribution and processes for making the same
US8575283B1 (en) 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
US9790291B2 (en) 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US9815920B1 (en) 2016-10-14 2017-11-14 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
CN108727422B (zh) * 2017-04-24 2021-01-01 中国石油天然气股份有限公司 一种六元氮氧硅杂环化合物及其制备方法
US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4107414A (en) 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4226963A (en) 1971-06-25 1980-10-07 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olephins
US4186107A (en) 1978-04-14 1980-01-29 Hercules Incorporated Solid catalyst component for olefin polymerization
US4347160A (en) 1980-06-27 1982-08-31 Stauffer Chemical Company Titanium halide catalyst system
JPS57153005A (en) 1981-03-19 1982-09-21 Ube Ind Ltd Polymerization of alpha-olefin
US4530912A (en) 1981-06-04 1985-07-23 Chemplex Company Polymerization catalyst and method
ATE20239T1 (de) 1981-08-07 1986-06-15 Ici Plc Uebergangsmetallzusammensetzung auf einem traeger aufgebracht.
US4382019A (en) 1981-09-10 1983-05-03 Stauffer Chemical Company Purified catalyst support
IT1190682B (it) 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
IT1190683B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4532313A (en) 1982-10-13 1985-07-30 Himont Incorporated Method for preparing an improved catalyst support, Ziegler-Natta catalyst utilizing said support and polymerization of 1-olefins utilizing said catalyst
US4560671A (en) 1983-07-01 1985-12-24 Union Carbide Corporation Olefin polymerization catalysts adapted for gas phase processes
US4657882A (en) 1984-11-26 1987-04-14 Amoco Corporation Supported olefin polymerization catalyst produced from a magnesium alkyl/organophosphoryl complex
US4581342A (en) 1984-11-26 1986-04-08 Standard Oil Company (Indiana) Supported olefin polymerization catalyst
JPH0621133B2 (ja) 1987-04-01 1994-03-23 チッソ株式会社 高溶融粘弾性ポリプロピレンの連続製造法
JP2713595B2 (ja) 1989-03-06 1998-02-16 三井東圧化学株式会社 プロピレンの連続重合方法
US5208302A (en) 1989-07-11 1993-05-04 Showa Denko K.K. Catalyst, process for preparation of same and process for polymerization of olefins using same
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5726262A (en) 1990-04-13 1998-03-10 Mitsui Petrochemical Industries, Ltd. Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
JP2873061B2 (ja) 1990-07-23 1999-03-24 東燃株式会社 α―オレフィン重合用触媒
JP2873055B2 (ja) 1990-07-23 1999-03-24 東燃株式会社 α―オレフィン重合用触媒
JP2873056B2 (ja) 1990-07-24 1999-03-24 東燃株式会社 α―オレフィン重合用触媒成分
JP2873057B2 (ja) 1990-07-24 1999-03-24 東燃株式会社 α―オレフィン重合用触媒成分
JPH04175313A (ja) 1990-11-08 1992-06-23 Tonen Corp α―オレフイン重合用触媒
JPH04370103A (ja) 1991-06-18 1992-12-22 Tonen Corp ポリプロピレンの製造方法
JPH04372609A (ja) 1991-06-24 1992-12-25 Tonen Corp ポリプロピレンの製造方法
JPH06128329A (ja) 1991-07-17 1994-05-10 Tonen Corp プロピレン共重合体の製造方法
JP2879391B2 (ja) 1992-04-14 1999-04-05 昭和電工株式会社 オレフィン重合用触媒およびオレフィン重合体の製造法
US5684173A (en) 1994-04-28 1997-11-04 Toho Titanium Co., Ltd. Organosilicon compound and ziegler-natta catalyst containing the same
US6015867A (en) 1994-09-28 2000-01-18 Showa Denko K.K. 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin
FR2738826B1 (fr) 1995-09-20 1997-10-17 Atochem Elf Sa Alcoxysilacycloalcanes, leur procede de preparation et leur utilisation pour la polymerisation des olefines
FR2793799B1 (fr) * 1999-05-18 2003-07-25 Atofina Polymerisation des olefines en presence de dialcoxysilacyclohexanes
JP3143057B2 (ja) 1996-02-16 2001-03-07 日本ポリオレフィン株式会社 オレフィン重合用固体触媒成分、その製造法およびポリオレフィンの製造法
US6376628B1 (en) 1998-05-21 2002-04-23 Grand Polymer Co., Ltd. Process for polymerization of alpha-olefin and alpha-olefin polymer
JP2000109514A (ja) 1998-10-05 2000-04-18 Tokuyama Corp オレフィン重合用触媒及びこれを用いるオレフィンの重合方法
JP2000109513A (ja) 1998-10-06 2000-04-18 Idemitsu Petrochem Co Ltd オレフィン重合用触媒およびオレフィン重合体の製造方法
SG80673A1 (en) 1999-02-25 2001-05-22 Sumitomo Chemical Co Catalyst component, catalyst for olefin polymerization, process for producing olefin polymer and use of organosilicon compound
JP2000273113A (ja) * 1999-03-23 2000-10-03 Tokuyama Corp 予備重合触媒及びそれを使用したポリオレフィンの重合方法
JP2000336112A (ja) 1999-06-01 2000-12-05 Idemitsu Petrochem Co Ltd 有機ケイ素化合物、オレフィン重合体製造用触媒およびオレフィン重合体の製造方法
ATE280188T1 (de) 1999-12-22 2004-11-15 Basell Poliolefine Spa Alpha-olefin enthaltendes polymerisationskatalysatorsystem, das ein aromatisches silan enthält
EP1209172B1 (en) 2000-04-24 2008-07-02 Toho Titanium Co., Ltd. Solid catalyst component and catalyst for olefin polymerization
EP1188774A4 (en) 2000-04-24 2005-07-06 Idemitsu Kosan Co CATALYST FOR MASS POLYMERIZATION, CATALYST FOR STEAM PHASE POLYMERIZATION, METHOD FOR POLYMERIZATION IN ITS USE, AND OLEFINE POLYMER OBTAINED THEREWITH
WO2003014167A1 (en) 2001-08-10 2003-02-20 Dsm N.V. Polymerization process using a specific organosilane as external donor
EP1336625A1 (en) * 2002-02-14 2003-08-20 Novolen Technology Holdings C.V. Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes
JP2005519118A (ja) * 2002-03-01 2005-06-30 ザ トラスティーズ オブ コロンビア ユニヴァーシティ イン ザ シティ オブ ニューヨーク 不斉アリル化、アルドール、およびタンデムアルドールおよびアリル化反応のための試薬
US6800703B1 (en) 2003-10-15 2004-10-05 Equistar Chemicals, Lp Method for preparing propylene polymers having broad molecular weight distribution
US7022797B2 (en) * 2004-02-20 2006-04-04 Fina Technology, Inc. Polymerization process
JP2006028312A (ja) 2004-07-14 2006-02-02 Ube Ind Ltd 環状アミノシラン、α−オレフィンの重合又は共重合用触媒、及びα−オレフィンの重合方法
KR100523474B1 (ko) 2005-03-29 2005-10-24 삼성토탈 주식회사 매우 높은 용융흐름성을 갖는 프로필렌 중합체의 제조방법
US20060252894A1 (en) 2005-05-06 2006-11-09 Fina Technology, Inc. Novel combinations of silane electron donors for use in catalyst compositions
JP5394747B2 (ja) 2006-11-29 2014-01-22 東邦チタニウム株式会社 オレフィン類重合用触媒成分および触媒並びにこれを用いたオレフィン類重合体の製造方法
KR101040388B1 (ko) 2007-01-30 2011-06-09 주식회사 엘지화학 트리옥사실로칸을 포함하는 올레핀 중합용 촉매 및 이를이용한 올레핀 중합 방법

Also Published As

Publication number Publication date
US7619049B1 (en) 2009-11-17
JP5718314B2 (ja) 2015-05-13
EP2419210B1 (en) 2014-11-26
WO2010120331A1 (en) 2010-10-21
JP2012523490A (ja) 2012-10-04
EP2419210A4 (en) 2013-10-16
CN102481556B (zh) 2014-10-01
CN102481556A (zh) 2012-05-30
EP2419210A1 (en) 2012-02-22

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