ES2509893T3 - Composiciones y sistemas catalíticos de precursores de metal y diluyentes olefínicos - Google Patents

Composiciones y sistemas catalíticos de precursores de metal y diluyentes olefínicos Download PDF

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ES2509893T3
ES2509893T3 ES09744887.2T ES09744887T ES2509893T3 ES 2509893 T3 ES2509893 T3 ES 2509893T3 ES 09744887 T ES09744887 T ES 09744887T ES 2509893 T3 ES2509893 T3 ES 2509893T3
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compositions
chromium
metal precursors
catalytic systems
olefin
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Bruce E. Kreischer
Ronald D. Knudsen
Orson L. Sydora
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Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
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Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/903—Catalyst and recycle considerations with hydrocarbon recycle to control synthesis reaction, e.g. by cooling, quenching

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrrole Compounds (AREA)

Abstract

Una composición que comprende: a) un precursor de catalizador de cromo; precursor de catalizador de cromo que es un compuesto organometálico de cromo (II) o cromo (III) y b) un diluyente olefínico que tiene entre 6 y 18 átomos de carbono, en la que la relación en peso de diluyente al átomo de cromo en el precursor oscila de 13:1 a 44:1 y en la que la composición no comprende un compuesto alquílico de metal.

Description

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Claims (1)

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ES09744887.2T 2008-10-31 2009-10-30 Composiciones y sistemas catalíticos de precursores de metal y diluyentes olefínicos Active ES2509893T3 (es)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US110407P 1998-12-01
US11047608P 2008-10-31 2008-10-31
US11039608P 2008-10-31 2008-10-31
US11040708P 2008-10-31 2008-10-31
US110396P 2008-10-31
US110476P 2008-10-31
PCT/US2009/062681 WO2010051405A1 (en) 2008-10-31 2009-10-30 Compositions and catalyst systems of metal precursors and olefinic diluents

Publications (1)

Publication Number Publication Date
ES2509893T3 true ES2509893T3 (es) 2014-10-20

Family

ID=41471037

Family Applications (3)

Application Number Title Priority Date Filing Date
ES09744580T Active ES2530892T3 (es) 2008-10-31 2009-10-30 Sistema y método para desactivar e inactivar un catalizador de oligomerización
ES09744887.2T Active ES2509893T3 (es) 2008-10-31 2009-10-30 Composiciones y sistemas catalíticos de precursores de metal y diluyentes olefínicos
ES09744578T Active ES2530891T3 (es) 2008-10-31 2009-10-30 Sistema catalizador de oligomerización y procedimiento para oligomerizar olefinas

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ES09744580T Active ES2530892T3 (es) 2008-10-31 2009-10-30 Sistema y método para desactivar e inactivar un catalizador de oligomerización

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ES09744578T Active ES2530891T3 (es) 2008-10-31 2009-10-30 Sistema catalizador de oligomerización y procedimiento para oligomerizar olefinas

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US (3) US8049052B2 (es)
EP (3) EP2349563B1 (es)
KR (3) KR101647524B1 (es)
CN (4) CN102164672A (es)
AU (3) AU2009308801B2 (es)
BR (3) BRPI0921731B1 (es)
CA (3) CA2740217C (es)
ES (3) ES2530892T3 (es)
SG (2) SG194381A1 (es)
WO (3) WO2010051415A1 (es)
ZA (3) ZA201101619B (es)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8471085B2 (en) 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
US8672837B2 (en) 2010-06-24 2014-03-18 Hansen Medical, Inc. Methods and devices for controlling a shapeable medical device
RU2471762C1 (ru) * 2011-06-22 2013-01-10 Открытое акционерное общество "СИБУР Холдинг" (ОАО "СИБУР Холдинг") Способ выделения продуктов олигомеризации олефинов и разложения остатков катализатора олигомеризации
US8957235B2 (en) 2011-12-12 2015-02-17 Chevron Phillips Chemical Company Lp Preparation of transition metal carboxylates
US9956548B2 (en) 2011-12-12 2018-05-01 Chevron Phillips Chemical Company Lp Preparation of an olefin oligomerization catalyst
WO2013095720A1 (en) 2011-12-22 2013-06-27 Exxonmobil Chemical Patents Inc. Methods and apparatus for deactivating a catalyst composition
US10654948B2 (en) 2013-03-13 2020-05-19 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US10577440B2 (en) 2013-03-13 2020-03-03 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US9057600B2 (en) 2013-03-13 2015-06-16 Hansen Medical, Inc. Reducing incremental measurement sensor error
US9271663B2 (en) 2013-03-15 2016-03-01 Hansen Medical, Inc. Flexible instrument localization from both remote and elongation sensors
US9629595B2 (en) 2013-03-15 2017-04-25 Hansen Medical, Inc. Systems and methods for localizing, tracking and/or controlling medical instruments
US9014851B2 (en) 2013-03-15 2015-04-21 Hansen Medical, Inc. Systems and methods for tracking robotically controlled medical instruments
US11020016B2 (en) 2013-05-30 2021-06-01 Auris Health, Inc. System and method for displaying anatomy and devices on a movable display
US9627200B2 (en) 2013-07-29 2017-04-18 US Nano LLC Synthesis of CdSe/ZnS core/shell semiconductor nanowires
US9306110B2 (en) 2013-07-31 2016-04-05 US Nano LLC Apparatus and methods for continuous flow synthesis of semiconductor nanowires
US9382348B2 (en) 2013-11-13 2016-07-05 Chevron Phillips Chemical Company Lp System and method for polymerization
KR101568186B1 (ko) 2014-01-06 2015-11-11 대림산업 주식회사 에틸렌과 알파-올레핀의 중합 장치 및 제조방법
RU2549833C1 (ru) * 2014-02-18 2015-04-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Каталитический комплекс селективной тримеризации этилена в 1-гексен
US9175109B1 (en) * 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
WO2016129845A1 (ko) * 2015-02-12 2016-08-18 주식회사 엘지화학 비활성화제 및 이를 이용한 올레핀 올리고머화의 부산물 저감 방법
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
JP6824967B2 (ja) 2015-09-18 2021-02-03 オーリス ヘルス インコーポレイテッド 管状網のナビゲーション
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
WO2017078974A1 (en) 2015-11-05 2017-05-11 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US10143526B2 (en) 2015-11-30 2018-12-04 Auris Health, Inc. Robot-assisted driving systems and methods
CN107233919B (zh) * 2016-03-28 2020-10-20 中国石油化工股份有限公司 一种齐聚催化剂组合物及其应用
CN107235885B (zh) * 2016-03-28 2021-11-19 中国石油化工股份有限公司 一种配体化合物及其制备方法和应用
US10414698B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10414699B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Process improvements in selective ethylene oligomerizations
US10329212B2 (en) 2016-05-27 2019-06-25 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10244926B2 (en) 2016-12-28 2019-04-02 Auris Health, Inc. Detecting endolumenal buckling of flexible instruments
US10604457B2 (en) 2016-12-29 2020-03-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
US20180186708A1 (en) 2016-12-29 2018-07-05 Chevron Phillips Chemical Company Lp Ethylene Oligomerization Processes
US10407360B2 (en) 2017-12-22 2019-09-10 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
EP3600031A4 (en) 2017-03-31 2021-01-20 Auris Health, Inc. ROBOTIC NAVIGATION SYSTEMS IN LUMINAL NETWORKS COMPENSATION FOR PHYSIOLOGICAL NOISE
US10550252B2 (en) 2017-04-20 2020-02-04 Chevron Phillips Chemical Company Lp Bimodal PE resins with improved melt strength
US10232339B2 (en) 2017-06-06 2019-03-19 Chevron Phillips Chemical Company Lp Fouling protection for an oligomerization reactor inlet
US10022192B1 (en) 2017-06-23 2018-07-17 Auris Health, Inc. Automatically-initialized robotic systems for navigation of luminal networks
KR102578978B1 (ko) 2017-06-28 2023-09-19 아우리스 헬스, 인코포레이티드 전자파 왜곡 검출
CN110809452B (zh) 2017-06-28 2023-05-23 奥瑞斯健康公司 电磁场发生器对准
US10183960B1 (en) 2017-09-22 2019-01-22 Chevron Phillips Chemical Company Lp Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10294171B2 (en) 2017-09-22 2019-05-21 Chevron Phillips Chemical Company Lp Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene
US10493442B2 (en) 2017-09-22 2019-12-03 Chevron Phillips Chemical Company Lp Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10464862B2 (en) 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
KR102334363B1 (ko) * 2017-09-29 2021-12-02 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
US10555778B2 (en) 2017-10-13 2020-02-11 Auris Health, Inc. Image-based branch detection and mapping for navigation
US11058493B2 (en) 2017-10-13 2021-07-13 Auris Health, Inc. Robotic system configured for navigation path tracing
KR102334373B1 (ko) 2017-11-30 2021-12-02 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
KR20200100613A (ko) 2017-12-14 2020-08-26 아우리스 헬스, 인코포레이티드 기구 위치 추정을 위한 시스템 및 방법
WO2019125964A1 (en) 2017-12-18 2019-06-27 Auris Health, Inc. Methods and systems for instrument tracking and navigation within luminal networks
CN110891469B (zh) 2018-03-28 2023-01-13 奥瑞斯健康公司 用于定位传感器的配准的系统和方法
US10827913B2 (en) 2018-03-28 2020-11-10 Auris Health, Inc. Systems and methods for displaying estimated location of instrument
WO2019231895A1 (en) 2018-05-30 2019-12-05 Auris Health, Inc. Systems and methods for location sensor-based branch prediction
MX2020012898A (es) 2018-05-31 2021-02-26 Auris Health Inc Navegacion de redes tubulares basada en trayecto.
MX2020012897A (es) 2018-05-31 2021-05-27 Auris Health Inc Sistemas roboticos y metodos para navegacion de la red luminal que detectan ruido fisiologico.
US10898275B2 (en) 2018-05-31 2021-01-26 Auris Health, Inc. Image-based airway analysis and mapping
KR102604431B1 (ko) * 2018-07-26 2023-11-22 에스케이이노베이션 주식회사 선형 알파 올레핀 제조방법
KR20210121162A (ko) * 2019-02-22 2021-10-07 퍼블릭 조인트 스톡 컴퍼니 “시부르 홀딩” 올레핀 올리고머화 생성물(변이체)의 분리 방법
CN114340542B (zh) 2019-08-30 2023-07-21 奥瑞斯健康公司 用于位置传感器的基于权重的配准的系统和方法
CN114340540B (zh) 2019-08-30 2023-07-04 奥瑞斯健康公司 器械图像可靠性系统和方法
KR20220056220A (ko) 2019-09-03 2022-05-04 아우리스 헬스, 인코포레이티드 전자기 왜곡 검출 및 보상
TW202124465A (zh) * 2019-10-31 2021-07-01 日商Ｊｓｒ股份有限公司 改質共軛二烯系聚合物的製造方法、聚合物組成物、交聯體及輪胎
US11267909B2 (en) 2020-07-15 2022-03-08 Chevron Phillips Chemical Company Lp Oligomerization catalyst system activation and related ethylene oligomerization processes and reaction systems
FR3112969B1 (fr) * 2020-07-30 2022-08-05 Ifp Energies Now Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1
US11674023B2 (en) 2020-10-15 2023-06-13 Chevron Phillips Chemical Company Lp Polymer composition and methods of making and using same
US11612883B2 (en) 2020-11-30 2023-03-28 Saudi Arabian Oil Company Catalyst systems
US11440857B2 (en) 2020-11-30 2022-09-13 Saudi Arabian Oil Company Catalyst systems
WO2022115750A1 (en) 2020-11-30 2022-06-02 Saudi Arabian Oil Company Catalyst systems
WO2022115754A1 (en) 2020-11-30 2022-06-02 Saudi Arabian Oil Company Catalyst systems
WO2022115751A1 (en) 2020-11-30 2022-06-02 Saudi Arabian Oil Company Catalyst systems
AR124331A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS
EP4294564A1 (en) 2021-03-12 2023-12-27 Saudi Arabian Oil Company Catalyst systems
US11859041B2 (en) 2021-08-16 2024-01-02 Chevron Phillips Chemical Company Lp Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts
US11484871B1 (en) 2021-08-26 2022-11-01 Saudi Arabian Oil Company Catalyst systems
US11492305B1 (en) 2021-11-08 2022-11-08 Chevron Phillips Chemical Company, Lp Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene
US11505513B1 (en) 2021-11-08 2022-11-22 Chevron Phillips Chemical Company, Lp Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene
US11583843B1 (en) 2021-11-08 2023-02-21 Chevron Phillips Chemical Company, Lp Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene
US11623901B1 (en) 2022-08-31 2023-04-11 Saudi Arabian Oil Company Catalyst systems that include silyl ether moieties
US11639321B1 (en) 2022-08-31 2023-05-02 Saudi Arabian Oil Company Catalyst systems that include meta-alkoxy substituted n-aryl bis-diphosphinoamine ligands
US11878952B1 (en) * 2022-11-14 2024-01-23 Chevron Phillips Chemical Company Lp Oligomerization catalyst system deactivation and related ethylene oligomerization processes

Family Cites Families (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2935495A (en) * 1956-11-27 1960-05-03 Sun Oil Co Manufacture of polyolefins
US3100764A (en) * 1960-08-04 1963-08-13 Sun Oil Co Control of pentane-soluble polymers in the polymerization of propylene
US3662021A (en) * 1960-09-14 1972-05-09 Exxon Research Engineering Co Process for preparing linear olefins
US4486615A (en) * 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
US4409414A (en) * 1960-09-14 1983-10-11 Exxon Research And Engineering Co. Preparation of linear olefin products
US3347840A (en) * 1964-06-16 1967-10-17 Union Carbide Corp Polymerization process
US3300458A (en) * 1963-08-19 1967-01-24 Union Carbide Corp Continuous processes for the production of ethylene polymers and catalysts suitable therefor
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3231550A (en) * 1964-06-04 1966-01-25 Union Carbide Corp Olefin polymerization
US3534006A (en) * 1966-03-25 1970-10-13 Toray Industries Methods of polymerizing alpha-olefins with a transition metal and a bis(dialkylaluminumoxy)alkane compound
US3558676A (en) * 1967-04-19 1971-01-26 Edward E Doherty Fatty acid chromium complex salts and compositions thereof
US3968135A (en) * 1970-01-19 1976-07-06 Aerojet-General Corporation Chromium salt catalysts
US3635869A (en) * 1970-03-16 1972-01-18 Aerojet General Co Catalysis of epoxy resin/carboxylic acid systems with trivalent chromium iii tricarboxylate salts
US3838101A (en) * 1970-04-13 1974-09-24 Aerojet General Co Reactions between an organic diimide and an epoxy resin with a chromium iii tricarboxylate catalyst
US3873602A (en) * 1970-09-18 1975-03-25 Aerojet General Co Beta hydroxy esters
BE794059A (fr) * 1972-01-14 1973-05-02 Aerojet General Co Nouvelles compositons a base d'oxiranne-imide leur preparation et leur utilisation
US3978026A (en) * 1972-02-18 1976-08-31 Aerojet-General Corporation Catalysts of the oxirane-anhydride reaction
US3977996A (en) * 1972-02-18 1976-08-31 Aerojet-General Corporation Catalysts for the oxirane-anhydride reaction
US3962182A (en) * 1972-11-21 1976-06-08 Aerojet-General Corporation Imide oxirane reactions
US4017429A (en) * 1973-08-17 1977-04-12 Aerojet-General Corporation Preparation of 2-hydroxyalkyl esters
US3932285A (en) * 1973-10-03 1976-01-13 Tenneco Chemicals, Inc. Chromium salt compositions and a process for their production
FR2253029A2 (en) 1973-12-03 1975-06-27 Ethylene Plastique Sa Highly stereospecific polyolefins prodn. - using Ziegler catalyst and pyrrole carboxaldehyde additive
US4426229A (en) 1976-11-26 1984-01-17 Petrolite Corporation Oxidized alpha-olefins
US4224181A (en) * 1979-03-07 1980-09-23 Exxon Research & Engineering Co. Ziegler type catalyst system
JPS5817104A (ja) * 1981-07-23 1983-02-01 Chisso Corp α−オレフイン重合体の製造方法
JPS6067508A (ja) * 1983-09-22 1985-04-17 Toa Nenryo Kogyo Kk オレフインの重合方法
US4806513A (en) * 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
FR2565591B1 (fr) * 1984-06-08 1986-08-29 Inst Francais Du Petrole Procede de fabrication d'un copolymere ethylene-butene-1 a partir d'ethylene
US4668808A (en) * 1984-08-13 1987-05-26 Phillips Petroleum Company Polychromium compounds and processes to make same
US4636572A (en) 1985-03-11 1987-01-13 Phillips Petroleum Company Permeability contrast correction employing propionate-sequestered chromium(III) prepared by nitrite/dichromate redox
US4644073A (en) 1985-03-11 1987-02-17 Phillips Petroleum Company Permeability contrast correction employing a sulfate-free propionate-sequestered chromium (III) solution
US4701504A (en) * 1986-01-23 1987-10-20 Du Pont Canada Inc. Reduction of isomerization in solution process for polymerization of alpha-olefins
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
DE3635710A1 (de) * 1986-10-21 1988-04-28 Basf Ag Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse
CA2020509C (en) 1989-08-10 1998-04-28 William K. Reagen Chromium compounds and uses thereof
US5376612A (en) 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
US5331104A (en) * 1989-08-10 1994-07-19 Phillips Petroleum Company Chromium compounds and uses thereof
US5451645A (en) * 1989-08-10 1995-09-19 Phillips Petroleum Company Process for olefin polymerization
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
US5438027A (en) * 1991-12-13 1995-08-01 Phillips Petroleum Company Chromium compounds and uses thereof
EP0548805B1 (en) * 1991-12-18 1997-03-05 Phillips Petroleum Company Process for the preparation of polymerisation catalysts
US6043401A (en) * 1992-05-26 2000-03-28 Bp Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US5243114A (en) * 1992-09-08 1993-09-07 Mobil Oil Corporation Oligomerization of alpha-olefins over layered silicate compositions containing pillars of silica and group VIB metal oxide
US5331070A (en) * 1992-11-13 1994-07-19 Phillips Petroleum Company Process for olefin polymerization
CA2087578C (en) 1993-01-19 1998-10-27 William Kevin Reagen Preparing catalyst for olefin polymerization
US5543375A (en) 1994-02-18 1996-08-06 Phillips Petroleum Company Olefin production
CA2134503C (en) * 1994-02-18 2001-04-10 Mark E. Lashier Olefin production
US5910619A (en) * 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers
JP3613642B2 (ja) * 1994-09-05 2005-01-26 住友化学株式会社 １−ヘキセンの製造方法
KR100414008B1 (ko) 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
US5591878A (en) 1995-09-19 1997-01-07 Kemin Industries, Inc. Catalyzed process for producing metal carboxylates for use as animal feed supplements
US5859303A (en) 1995-12-18 1999-01-12 Phillips Petroleum Company Olefin production
US5856612A (en) * 1996-02-02 1999-01-05 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
US6133495A (en) * 1996-03-14 2000-10-17 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
DE19617230A1 (de) 1996-04-30 1997-11-06 Basf Ag Oxidierte Metallocen-Polyolefin-Wachse
US5731381A (en) 1996-11-01 1998-03-24 Union Carbide Chemicals & Plastics Technology Corporation Termination of gas phase polymerizations of conjugated dienes, vinyl-substituted aromatic compounds and mixtures thereof
DE19700892A1 (de) 1997-01-14 1998-07-16 Basf Ag Verfahren zur Herstellung oxidierter Polyolefinwachse
US5856257A (en) * 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
US5986153A (en) * 1997-09-30 1999-11-16 Phillips Petroleum Company Olefin color stabilization
US20020182124A1 (en) 1997-10-14 2002-12-05 William M. Woodard Olefin production process
US6100223A (en) * 1997-12-30 2000-08-08 Chevron Chemical Company Llc Method of converting olefins into mixtures of secondary esters, products and uses thereof
GB9826755D0 (en) * 1998-12-04 1999-01-27 Bp Chem Int Ltd Oligomerisation process
CN1108193C (zh) * 1998-12-15 2003-05-14 北京燕山石油化工公司研究院 一种用于乙烯三聚的新型催化剂,其制备方法和应用
US20010053742A1 (en) 1998-12-18 2001-12-20 Ronald D. Knudsen Catalyst and processes for olefin trimerization
US6133496A (en) * 1999-03-09 2000-10-17 Phillips Petroleum Company Two-stage isomerization of saturated C.sub. 6 hydrocarbons
US6380451B1 (en) * 1999-12-29 2002-04-30 Phillips Petroleum Company Methods for restoring the heat transfer coefficient of an oligomerization reactor
CA2392233C (en) 1999-12-29 2006-10-24 Phillips Petroleum Company Processes for preventing generation of hydrogen halides in an oligomerization product recovery system
US6455648B1 (en) 1999-12-29 2002-09-24 Chevron Phillips Chemical Company Lp Olefin production
US7259284B2 (en) * 2000-05-31 2007-08-21 Chevron Phillips Chemical Company, Lp Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
US6525148B1 (en) * 2000-08-18 2003-02-25 Phillips Petroleum Company Polymerization catalyst systems and processes therefor and therewith
US7396970B1 (en) * 2000-11-03 2008-07-08 Chevron Phillips Chemical Company Lp Monitoring and control of processes for making 1-hexene
US6911506B2 (en) * 2001-12-10 2005-06-28 Chevron Phillips Chemical Company Lp Catalyst composition and olefin polymerization using same
EP2272814A2 (en) * 2002-04-22 2011-01-12 Chevron Phillips Chemical Company LP Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
US7297832B2 (en) * 2002-12-20 2007-11-20 Sasol Technology (Pty) Limited Tetramerization of olefins
US7045632B2 (en) * 2003-03-04 2006-05-16 Chevron Phillips Chemical Company, Lp Composition and method for a hexadentate ligand and bimetallic complex for polymerization of olefins
TW200502038A (en) * 2003-03-14 2005-01-16 Chevron Phillips Chemical Co Process to decrease or eliminate corrosion from the decomposition of halide containing olefin catalysts
ATE372967T1 (de) * 2003-10-31 2007-09-15 Chevron Phillips Chemical Co Verfahren und system zum in-kontakt-bringen eines ionischen flüssigen katalysators mit sauerstoff zur verbesserung einer chemischen umsetzung
US7026415B2 (en) * 2004-02-17 2006-04-11 Equistar Chemicals, Lp Clathrochelates as olefin polymerization catalyst components
US20050187098A1 (en) * 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) * 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7476775B2 (en) 2004-03-03 2009-01-13 Chevron Phillips Chemical Company Lp Method and system for separating an oligomerization reactor effluent
US7307133B2 (en) * 2004-04-22 2007-12-11 Chevron Phillips Chemical Company Lp Polymers having broad molecular weight distributions and methods of making the same
US7615510B2 (en) * 2004-05-12 2009-11-10 Chevron Phillips Chemical Company Lp Methods of activating chromium catalysts
US7527686B2 (en) 2004-11-23 2009-05-05 Chevron Phillips Chemical Company, Lp Olefin waxes having improved hardness or viscosity
US7456284B2 (en) * 2004-12-10 2008-11-25 Chevron Phillips Chemical Company Lp Methods for producing a hexadentate bimetallic complex
CA2556520C (en) 2005-01-27 2008-10-28 Ocean Nutrition Canada Ltd. Chromium-fatty acid compounds and methods of making and using thereof
US7425661B2 (en) * 2005-03-09 2008-09-16 Exxonmobil Chemicals Patents Inc. Methods for oligomerizing olefins
US7268096B2 (en) * 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7271121B2 (en) * 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7129304B1 (en) * 2005-07-21 2006-10-31 Chevron Phillips Chemical Company Lp Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
EP1754694A1 (en) * 2005-08-10 2007-02-21 Linde AG Method for deactivation and removal of catalytic components in the oligomerisation of ethylene
US7982085B2 (en) * 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US7687672B2 (en) * 2006-02-03 2010-03-30 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US7378537B2 (en) * 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
US8471085B2 (en) 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins

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