BR112012005902A2 - formulação de catalisador de quelato de ti, uso da formulação de catalisador de quelato de ti ou de um composto, composição, processo para a polimeração de compostos, catalisador de quelato de ti, uso da composição polimerizável, e, substrato revestido - Google Patents

formulação de catalisador de quelato de ti, uso da formulação de catalisador de quelato de ti ou de um composto, composição, processo para a polimeração de compostos, catalisador de quelato de ti, uso da composição polimerizável, e, substrato revestido

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Publication number
BR112012005902A2
BR112012005902A2 BR112012005902A BR112012005902A BR112012005902A2 BR 112012005902 A2 BR112012005902 A2 BR 112012005902A2 BR 112012005902 A BR112012005902 A BR 112012005902A BR 112012005902 A BR112012005902 A BR 112012005902A BR 112012005902 A2 BR112012005902 A2 BR 112012005902A2
Authority
BR
Brazil
Prior art keywords
chelate catalyst
catalyst formulation
optionally substituted
compound
composition
Prior art date
Application number
BR112012005902A
Other languages
English (en)
Other versions
BR112012005902B1 (pt
Inventor
Antoine Carroy
Caroline Lordelot
Didier Bauer
Rachel Kohli Steck
Tobias Hintermann
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BR112012005902A2 publication Critical patent/BR112012005902A2/pt
Publication of BR112012005902B1 publication Critical patent/BR112012005902B1/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Catalysts (AREA)
  • Sealing Material Composition (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

formulação de catalisador de quelato de ti, uso da formulação de catalisador de quelato de ti ou de um composto, composição processo para a polimerização de compostos, catalisador de quelato de ti, uso da composição polimerizável, e, substrato revestido. apresente invenção provê uma formulação de catalisador de quelato de titânio fotolatente, que compreende (i) pelo menos um composto da fórmula i (i), em que r~1~ é alquila c~1~-c~20~ou alquila c~2~-c~20~,=, que é interrompido por um ou mais átomos de o não- consecutivos; y é ou fenila opcionalmente substituído; y~1~ é ou fenila opcionalmente substituído; y~2~ é ou fenila opcionalmente substituído; y~3~ ou fenila opcionalmente substituído; r~2~, r~3~, r~4~, r~5~, r~6~, r~7~, r~8~, r~9~, r~10~, r~11~, r~12~ e r~13~, independentemente um do outro , são cada qual hidrogênio, halogênio, alquila c~1~-c~20~ opcionalmente substituído, ou r~2~, r~3~, r~4~, r~5~, r~6~, r~7~, r~8~, r~9~, r~10~, r~11~, r~12~ e r~13~ independentemente um do outro, são cada qual arila c~6~ -c~14~ opcionalmente substituído, contanto que apenas um de r ~2~, r~3~, r~4~ seja hidrogênio e apenas um de r~5~, r~6~, r~7~ seja hidrogênio e apenas um de r~8~, r~9~, r~10~ seja hidrogênio, e apenas um de r~11~, r~12~,r~13~ seja hidrogênio; e (ii) pelo menos um composto ligante de quelato da fórmula iia, iib ou iic em que, y<39> é r<39> ~2~, r<39>~3~, r<39>~4~, r<39>~5~, r<39>~6~ e r<39>~7~ independentemente um do outro, possuem os significados, tais que dadaos para r~2~, r~3~, r~4~, r~5~, r~6~, r~7~, r~8~, r~9~, r~10~, r~11~, r~12~ e r~13~; e r<39>~14~, r~15~ e r~16~ independentemente um do outros, possuem os significados como fornecidos para r~14~, r~15~ e r~16~.
BR112012005902-5A 2009-09-15 2010-09-09 Formulação de catalisador de quelato de ti, uso da formulação de catalisador de quelato de ti, composição polimerizável, processo para a polimerização de compostos, uso da composição polimerizável, substrato revestido, e, composição polimerizada ou reticulada BR112012005902B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09170301.7 2009-09-15
EP09170301 2009-09-15
PCT/EP2010/063198 WO2011032875A1 (en) 2009-09-15 2010-09-09 Photo-latent titanium catalysts

Publications (2)

Publication Number Publication Date
BR112012005902A2 true BR112012005902A2 (pt) 2016-03-15
BR112012005902B1 BR112012005902B1 (pt) 2019-09-17

Family

ID=41665034

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012005902-5A BR112012005902B1 (pt) 2009-09-15 2010-09-09 Formulação de catalisador de quelato de ti, uso da formulação de catalisador de quelato de ti, composição polimerizável, processo para a polimerização de compostos, uso da composição polimerizável, substrato revestido, e, composição polimerizada ou reticulada

Country Status (8)

Country Link
US (1) US10207261B2 (pt)
EP (1) EP2477739B1 (pt)
JP (1) JP5645939B2 (pt)
KR (1) KR101752516B1 (pt)
CN (1) CN102497931B (pt)
BR (1) BR112012005902B1 (pt)
RU (1) RU2556979C2 (pt)
WO (1) WO2011032875A1 (pt)

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EP2694211A1 (en) 2011-04-05 2014-02-12 Basf Se Photo-latent titanium-oxo-chelate catalysts
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EP2828001A1 (de) 2012-03-22 2015-01-28 Basf Se Verfahren und vorrichtung zur herstellung von gehärteten lackschichten
US10053596B2 (en) * 2016-08-30 2018-08-21 Prc-Desoto International, Inc. Curable film-forming compositions demonstrating increased wet-edge time
CN117362353A (zh) * 2018-09-20 2024-01-09 北京夏禾科技有限公司 含有新型辅助配体的有机发光材料
CN110105533A (zh) * 2019-05-05 2019-08-09 湖北三江航天江河化工科技有限公司 多官能度双固化线型聚氨酯丙烯酸酯树脂及其制备方法
KR102296629B1 (ko) * 2019-11-13 2021-09-01 주식회사 케이씨씨 우레탄 도료 조성물
CN113493476B (zh) * 2021-09-07 2021-11-30 苏州源展材料科技有限公司 一种ald前驱体钛配合物的制备方法

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Also Published As

Publication number Publication date
EP2477739A1 (en) 2012-07-25
RU2556979C2 (ru) 2015-07-20
WO2011032875A1 (en) 2011-03-24
KR101752516B1 (ko) 2017-06-29
CN102497931B (zh) 2016-03-09
JP5645939B2 (ja) 2014-12-24
CN102497931A (zh) 2012-06-13
BR112012005902B1 (pt) 2019-09-17
KR20120103764A (ko) 2012-09-19
US10207261B2 (en) 2019-02-19
US20120220685A1 (en) 2012-08-30
JP2013504673A (ja) 2013-02-07
RU2012114680A (ru) 2013-10-27
EP2477739B1 (en) 2019-04-10

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2640 DE 10-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.