ES2225223T3 - Composicion termoplastica retardante de llama con propiedades mejoradas. - Google Patents
Composicion termoplastica retardante de llama con propiedades mejoradas.Info
- Publication number
- ES2225223T3 ES2225223T3 ES00964776T ES00964776T ES2225223T3 ES 2225223 T3 ES2225223 T3 ES 2225223T3 ES 00964776 T ES00964776 T ES 00964776T ES 00964776 T ES00964776 T ES 00964776T ES 2225223 T3 ES2225223 T3 ES 2225223T3
- Authority
- ES
- Spain
- Prior art keywords
- flame retardant
- polyamide
- composition
- weight
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 16
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000003063 flame retardant Substances 0.000 claims abstract description 39
- 229920000642 polymer Polymers 0.000 claims abstract description 31
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 21
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 21
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000004952 Polyamide Substances 0.000 claims abstract description 15
- 229920002647 polyamide Polymers 0.000 claims abstract description 15
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 9
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims abstract description 6
- 229920000098 polyolefin Polymers 0.000 claims abstract description 3
- 229920006345 thermoplastic polyamide Polymers 0.000 claims description 22
- 239000003365 glass fiber Substances 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 4
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 4
- 150000001463 antimony compounds Chemical class 0.000 claims description 3
- 239000011152 fibreglass Substances 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 abstract description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004417 polycarbonate Substances 0.000 abstract description 2
- 229920000515 polycarbonate Polymers 0.000 abstract description 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 238000006068 polycondensation reaction Methods 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- -1 for example Polymers 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 230000002195 synergetic effect Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 230000000979 retarding effect Effects 0.000 description 4
- 229920000388 Polyphosphate Polymers 0.000 description 3
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 3
- 239000004760 aramid Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical compound BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 description 2
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 2
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 2
- XVZXORKCIPSWKZ-UHFFFAOYSA-N 5-bromo-7-oxabicyclo[4.1.0]hepta-1(6),2,4-triene Chemical compound BrC1=CC=CC2=C1O2 XVZXORKCIPSWKZ-UHFFFAOYSA-N 0.000 description 2
- OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical class C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 description 1
- JVPKLOPETWVKQD-UHFFFAOYSA-N 1,2,2-tribromoethenylbenzene Chemical compound BrC(Br)=C(Br)C1=CC=CC=C1 JVPKLOPETWVKQD-UHFFFAOYSA-N 0.000 description 1
- SVHAMPNLOLKSFU-UHFFFAOYSA-N 1,2,2-trichloroethenylbenzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1 SVHAMPNLOLKSFU-UHFFFAOYSA-N 0.000 description 1
- BMSUWQXMTMGEOM-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-ethenylbenzene Chemical compound BrC1=C(Br)C(Br)=C(C=C)C(Br)=C1Br BMSUWQXMTMGEOM-UHFFFAOYSA-N 0.000 description 1
- AUHKVLIZXLBQSR-UHFFFAOYSA-N 1,2-dichloro-3-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC(Cl)=C1Cl AUHKVLIZXLBQSR-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- IKESTNSVBKCNNO-UHFFFAOYSA-N 2,3-dibromo-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound C1=C(O2)C(Br)=C(Br)C2=C1 IKESTNSVBKCNNO-UHFFFAOYSA-N 0.000 description 1
- NKFNPXNLISIOJU-UHFFFAOYSA-N 2,3-dichloro-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound C1=C(O2)C(Cl)=C(Cl)C2=C1 NKFNPXNLISIOJU-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- PTSGHGGLRADEFP-UHFFFAOYSA-N 4-methylpiperidin-2-one Chemical compound CC1CCNC(=O)C1 PTSGHGGLRADEFP-UHFFFAOYSA-N 0.000 description 1
- 229920013339 Akulon® K122 Polymers 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 241001247482 Amsonia Species 0.000 description 1
- 241000531908 Aramides Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102100023794 ETS domain-containing protein Elk-3 Human genes 0.000 description 1
- 229920006060 Grivory® Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 101800001701 Saposin-C Proteins 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
- SZXAQBAUDGBVLT-UHFFFAOYSA-H antimony(3+);2,3-dihydroxybutanedioate Chemical compound [Sb+3].[Sb+3].[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O.[O-]C(=O)C(O)C(O)C([O-])=O SZXAQBAUDGBVLT-UHFFFAOYSA-H 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QFNNDGVVMCZKEY-UHFFFAOYSA-N azacyclododecan-2-one Chemical compound O=C1CCCCCCCCCCN1 QFNNDGVVMCZKEY-UHFFFAOYSA-N 0.000 description 1
- WULPUQZASCZTPO-UHFFFAOYSA-N azacycloundecan-2-one Chemical compound O=C1CCCCCCCCCN1 WULPUQZASCZTPO-UHFFFAOYSA-N 0.000 description 1
- KBLFLMTZLPQGIF-UHFFFAOYSA-N azecan-2-one Chemical compound O=C1CCCCCCCCN1 KBLFLMTZLPQGIF-UHFFFAOYSA-N 0.000 description 1
- JUWXSPFZUDXNDX-UHFFFAOYSA-N azepan-2-one Chemical compound O=C1CCCCCN1.O=C1CCCCCN1 JUWXSPFZUDXNDX-UHFFFAOYSA-N 0.000 description 1
- BPGBVGUMPQVVAU-UHFFFAOYSA-N azetidin-2-one Chemical compound O=C1CCN1.O=C1CCN1 BPGBVGUMPQVVAU-UHFFFAOYSA-N 0.000 description 1
- QVYYDFPVUFYWAC-UHFFFAOYSA-N aziridin-2-one Chemical group N1C(C1)=O.C1(CN1)=O QVYYDFPVUFYWAC-UHFFFAOYSA-N 0.000 description 1
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
- YDLSUFFXJYEVHW-UHFFFAOYSA-N azonan-2-one Chemical compound O=C1CCCCCCCN1 YDLSUFFXJYEVHW-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- YVIVRJLWYJGJTJ-UHFFFAOYSA-N gamma-Valerolactam Chemical compound CC1CCC(=O)N1 YVIVRJLWYJGJTJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- GVYLCNUFSHDAAW-UHFFFAOYSA-N mirex Chemical compound ClC12C(Cl)(Cl)C3(Cl)C4(Cl)C1(Cl)C1(Cl)C2(Cl)C3(Cl)C4(Cl)C1(Cl)Cl GVYLCNUFSHDAAW-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1013134A NL1013134C2 (nl) | 1999-09-24 | 1999-09-24 | Vlamvertragende thermoplastische samenstelling met verbeterde eigenschappen. |
| NL1013134 | 1999-09-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2225223T3 true ES2225223T3 (es) | 2005-03-16 |
Family
ID=19769933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00964776T Expired - Lifetime ES2225223T3 (es) | 1999-09-24 | 2000-09-12 | Composicion termoplastica retardante de llama con propiedades mejoradas. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6951896B2 (enExample) |
| EP (1) | EP1232217B1 (enExample) |
| JP (1) | JP4717307B2 (enExample) |
| KR (1) | KR100681646B1 (enExample) |
| CN (1) | CN1146643C (enExample) |
| AT (1) | ATE274031T1 (enExample) |
| AU (1) | AU7561100A (enExample) |
| DE (1) | DE60013166T2 (enExample) |
| ES (1) | ES2225223T3 (enExample) |
| NL (1) | NL1013134C2 (enExample) |
| TW (1) | TWI256407B (enExample) |
| WO (1) | WO2001021711A1 (enExample) |
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| EP1479728A1 (en) * | 2003-05-22 | 2004-11-24 | DSM IP Assets B.V. | Flame retardant polyamide composition |
| US7202296B2 (en) * | 2003-12-19 | 2007-04-10 | Albemarle Corporation | Flame retardant compositions and their use |
| EP1681313A1 (en) * | 2005-01-17 | 2006-07-19 | DSM IP Assets B.V. | Heat stabilized moulding composition |
| EP2046882B1 (en) * | 2006-07-28 | 2015-09-02 | DSM IP Assets B.V. | Flame retardant thermoplastic composition |
| CN100372886C (zh) * | 2006-11-24 | 2008-03-05 | 北京理工大学 | 一种阻燃聚苯乙烯组合物及其制备方法 |
| JP5577755B2 (ja) * | 2010-03-04 | 2014-08-27 | 東レ株式会社 | ポリエステル樹脂組成物 |
| WO2012062594A1 (de) * | 2010-11-11 | 2012-05-18 | Basf Se | Wärmealterungsbeständige polyamide |
| US20130029151A1 (en) * | 2011-03-18 | 2013-01-31 | E. I. Du Pont De Nemours And Company | Flame-resistant finish for inherently flame resistant polymer yarns and process for making same |
| BR112013030906B1 (pt) * | 2011-06-09 | 2021-04-06 | Solvay Specialty Polymers Usa, Llc | Composições de poliamidas apresentando estabilidade térmica melhorada |
| CN103387709B (zh) * | 2012-05-08 | 2017-08-29 | 合肥杰事杰新材料股份有限公司 | 一种热塑性复合材料、制备方法及其应用 |
| EP2893829B1 (en) * | 2012-09-06 | 2019-02-06 | YKK Corporation | Molded component for slide fasteners and slide fastener provided therewith |
| JP6482755B2 (ja) * | 2013-09-10 | 2019-03-13 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| US9732446B2 (en) * | 2013-11-04 | 2017-08-15 | E I Du Pont De Nemours And Company | Heat resistant outershell fabric |
| EP3145726B1 (en) * | 2014-05-20 | 2018-10-03 | DSM IP Assets B.V. | Laser-marked product from a laser-markable polyamide composition |
| US10199175B2 (en) * | 2015-04-08 | 2019-02-05 | Kemet Electronics Corporation | Method of producing solid electrolytic capacitor and capacitor made thereby |
| WO2017144209A1 (de) * | 2016-02-22 | 2017-08-31 | Basf Se | Polyamidmischungen mit pyrrolidon enthaltenden polyamiden |
| US10487201B2 (en) | 2017-03-01 | 2019-11-26 | Aei Compounds Ltd. | Cable sheathing composition |
| WO2018158224A1 (de) * | 2017-03-01 | 2018-09-07 | Basf Se | Flammgeschuetzte polyamide mit pvp |
| US10672535B2 (en) | 2017-03-01 | 2020-06-02 | Saco Aei Polymers, Inc. | Wire sheathing and insulation compositions |
| JP6483193B2 (ja) * | 2017-06-07 | 2019-03-13 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| JP6483230B2 (ja) * | 2017-12-13 | 2019-03-13 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| JP6386652B2 (ja) * | 2017-12-13 | 2018-09-05 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| JP6483229B2 (ja) * | 2017-12-13 | 2019-03-13 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| JP6483228B2 (ja) * | 2017-12-13 | 2019-03-13 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| JP6687771B2 (ja) * | 2019-02-12 | 2020-04-28 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物の製造方法 |
| CN112322033B (zh) * | 2020-10-13 | 2022-08-09 | 天津金发新材料有限公司 | 一种低结晶温度、高性能聚酰胺复合材料 |
| CN114292517B (zh) * | 2021-12-27 | 2025-04-08 | 金发科技股份有限公司 | 一种阻燃聚酰胺复合材料及其制备方法和应用 |
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| JPS4933334B1 (enExample) * | 1970-03-13 | 1974-09-06 | ||
| US3787356A (en) * | 1972-05-08 | 1974-01-22 | Velsicol Chemical Corp | Fire retardant compositions |
| US4010225A (en) * | 1973-06-13 | 1977-03-01 | Hoechst Aktiengesellschaft | Bromine containing telomeric phosphonic acid esters as flame retardant agents |
| DE2329924A1 (de) * | 1973-06-13 | 1975-02-13 | Hoechst Ag | Bromhaltige, telomere phosphonsaeureester |
| US4369264A (en) * | 1980-12-30 | 1983-01-18 | Ppg Industries, Inc. | Aqueous treating composition for glass fiber strands used to produce mats for thermoplastic polymers |
| CA1263778A (en) * | 1983-12-01 | 1989-12-05 | Michael D. Golder | Segmented thermoplastic copolyester elastomers stabilized with polyvinylpyrrolidone |
| US4847322A (en) * | 1987-10-22 | 1989-07-11 | Allied-Signal Inc. | Thermoplastic compositions containing acyllactam graft linkages |
| DE3903099A1 (de) * | 1989-02-02 | 1990-08-16 | Hoechst Ag | Homogen gemischte legierungen aus aromatischen polyamiden und poly-n-vinylpyrrolidon, verfahren zu ihrer herstellung und ihre verwendung |
| US5073440A (en) * | 1989-06-05 | 1991-12-17 | E. I. Du Pont De Nemours And Company | Poly(vinyl pyrrolidone)/p-phenylene terephthalamide composite fibers (pvp/ppd-t) |
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| US5156775A (en) * | 1991-10-17 | 1992-10-20 | Blount David H | Flame retardant compositions |
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-
1999
- 1999-09-24 NL NL1013134A patent/NL1013134C2/nl not_active IP Right Cessation
-
2000
- 2000-09-12 CN CNB008159645A patent/CN1146643C/zh not_active Expired - Fee Related
- 2000-09-12 EP EP00964776A patent/EP1232217B1/en not_active Expired - Lifetime
- 2000-09-12 JP JP2001525277A patent/JP4717307B2/ja not_active Expired - Fee Related
- 2000-09-12 KR KR1020027003821A patent/KR100681646B1/ko not_active Expired - Fee Related
- 2000-09-12 WO PCT/NL2000/000647 patent/WO2001021711A1/en not_active Ceased
- 2000-09-12 ES ES00964776T patent/ES2225223T3/es not_active Expired - Lifetime
- 2000-09-12 DE DE60013166T patent/DE60013166T2/de not_active Expired - Lifetime
- 2000-09-12 AU AU75611/00A patent/AU7561100A/en not_active Abandoned
- 2000-09-12 AT AT00964776T patent/ATE274031T1/de not_active IP Right Cessation
- 2000-09-15 TW TW089119000A patent/TWI256407B/zh not_active IP Right Cessation
-
2002
- 2002-03-25 US US10/104,051 patent/US6951896B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TWI256407B (en) | 2006-06-11 |
| CN1146643C (zh) | 2004-04-21 |
| JP2003510396A (ja) | 2003-03-18 |
| DE60013166T2 (de) | 2005-09-08 |
| US6951896B2 (en) | 2005-10-04 |
| JP4717307B2 (ja) | 2011-07-06 |
| CN1391598A (zh) | 2003-01-15 |
| EP1232217B1 (en) | 2004-08-18 |
| ATE274031T1 (de) | 2004-09-15 |
| EP1232217A1 (en) | 2002-08-21 |
| KR20020040816A (ko) | 2002-05-30 |
| AU7561100A (en) | 2001-04-24 |
| US20030055152A1 (en) | 2003-03-20 |
| WO2001021711A1 (en) | 2001-03-29 |
| DE60013166D1 (de) | 2004-09-23 |
| NL1013134C2 (nl) | 2001-03-27 |
| KR100681646B1 (ko) | 2007-02-09 |
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