ES2159319T3 - Hidrogenacion de un sustrato estando el sustrato y el hidrogeno en una disolucion super-critica o casicritica esencialmente homogenea. - Google Patents
Hidrogenacion de un sustrato estando el sustrato y el hidrogeno en una disolucion super-critica o casicritica esencialmente homogenea.Info
- Publication number
- ES2159319T3 ES2159319T3 ES95925223T ES95925223T ES2159319T3 ES 2159319 T3 ES2159319 T3 ES 2159319T3 ES 95925223 T ES95925223 T ES 95925223T ES 95925223 T ES95925223 T ES 95925223T ES 2159319 T3 ES2159319 T3 ES 2159319T3
- Authority
- ES
- Spain
- Prior art keywords
- hydrogenation
- reaction
- substrate
- gas
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/008—Processes carried out under supercritical conditions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/029—Preparation from hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/02—Reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Chemically Coating (AREA)
- Lubricants (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
UN REACTOR DE HIDROGENACION TIPICO, CONSISTE EN UN TANQUE LLENO DE UN LIQUIDO, UN GAS, Y UN CATALIZADOR DE PEQUEÑAS PARTICULAS. LA REACCION SE LLEVA A CABO A ELEVADAS PRESIONES Y TEMPERATURAS. LA FALTA DE GAS EN LA SUPERFICIE DEL CATALIZADOR, LIMITA LA VELOCIDAD DE LA REACCION, POR LO QUE SE HA TRABAJADO MUCHO PARA AUMENTAR LA CANTIDAD DE GAS SOBRE EL CATALIZADOR, SIN QUE HAYA SIDO POSIBLE AUN RESOLVER ESTE PROBLEMA DE FORMA EFECTIVA, CON LAS TECNICAS ACTUALES. DE ACUERDO CON LA INVENCION, SE AÑADE UN DISOLVENTE EXTRA A LA MEZCLA DE REACCION, Y SE SOMETE LA MEZCLA COMPLETA (DISOLVENTE, SUSTRATO, HIDROGENO, Y PRODUCTOS DE REACCION), A UN ESTADO SUPER-CRITICO, O PROXIMO AL SUPER-CRITICO, OBTENIENDOSE ASI UNA MEZCLA SUSTANCIALMENTE HOMOGENEA. MEDIANTE DICHO METODO, SE PUEDE CONTROLAR LA CONCENTRACION DE GAS SOBRE EL CATALIZADOR, HASTA EL NIVEL DESEADO, INCREMENTANDOSE POR TANTO LA VELOCIDAD DE LA REACCION CONSIDERABLEMENTE. LAS REACCIONES DE HIDROGENACION PRINCIPALMENTE IMPLICADAS, COMPRENDENLA HIDROGENACION DE DOBLES ENLACES CARBONO-CARBONO (C=C) EN LIPIDOS; HIDROGENACION DE COOR A HO-R, PARA PRODUCIR ALCOHOLES ACIDOS; Y LA HIDROGENACION DIRECTA DE OXIGENO A PEROXIDO DE HIDROGENO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9402362A SE504029C2 (sv) | 1994-07-01 | 1994-07-01 | Hydrering av lipider utan stereo- eller positions- isomerisering |
SE9501159A SE9501159D0 (sv) | 1995-03-28 | 1995-03-28 | Hydrering av lipider |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2159319T3 true ES2159319T3 (es) | 2001-10-01 |
Family
ID=26662091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95925223T Expired - Lifetime ES2159319T3 (es) | 1994-07-01 | 1995-07-03 | Hidrogenacion de un sustrato estando el sustrato y el hidrogeno en una disolucion super-critica o casicritica esencialmente homogenea. |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP0791041B1 (es) |
JP (1) | JP4015186B2 (es) |
CN (1) | CN1092708C (es) |
AT (1) | ATE200512T1 (es) |
AU (1) | AU694929B2 (es) |
BR (1) | BR9508217A (es) |
CA (1) | CA2194140C (es) |
CZ (1) | CZ293018B6 (es) |
DE (2) | DE29522355U1 (es) |
DK (1) | DK0791041T3 (es) |
ES (1) | ES2159319T3 (es) |
FI (1) | FI970001A (es) |
HU (1) | HU222744B1 (es) |
MX (1) | MX214427B (es) |
NO (1) | NO305915B1 (es) |
PL (1) | PL180955B1 (es) |
PT (1) | PT791041E (es) |
WO (1) | WO1996001304A1 (es) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI107382B (fi) * | 1996-02-23 | 2001-07-31 | Valtion Teknillinen | Menetelmä aromaattisten nitroyhdisteiden pelkistämiseksi |
KR100474061B1 (ko) * | 1996-04-17 | 2005-07-21 | 토마스 스완 앤드 컴퍼니 리미티드 | 초임계수소화법 |
GB9607917D0 (en) * | 1996-04-17 | 1996-06-19 | Swan Thomas & Co Ltd | Supercritical hydrogenation |
ID18866A (id) * | 1996-11-11 | 1998-05-14 | Hoffmann La Roche | Hidrogenasi katalitik |
DE19719431A1 (de) * | 1997-05-12 | 1998-11-19 | Degussa | Verfahren zur kontinuierlichen katalytischen Umsetzung von organischen Verbindungen |
CA2336513C (en) * | 2000-02-17 | 2010-08-24 | Tatsuo Tateno | Process for producing fatty acid esters and fuels comprising fatty acid ester |
DE10125613A1 (de) | 2001-05-25 | 2002-11-28 | Basf Ag | Kolloidkatalysierte Wasserstoffübertragung in überkritischer Phase |
EP1270710A1 (en) * | 2001-06-19 | 2003-01-02 | Feyecon Development & Implementation B.V. | A method of processing lipid materials |
DE10142306A1 (de) * | 2001-08-30 | 2003-03-27 | Cognis Deutschland Gmbh | Verfahren zur Härtung von ungesättigten Fettstoffen |
JP4236581B2 (ja) | 2001-10-16 | 2009-03-11 | 積水化学工業株式会社 | ポリビニルアセタール樹脂の製造方法 |
DE10215862A1 (de) * | 2002-04-11 | 2003-10-30 | Cognis Deutschland Gmbh | Verfahren zur Trennung von über- bzw. nahekritischen Gemischen |
US7034084B2 (en) * | 2002-07-08 | 2006-04-25 | Bridgestone Corporation | Process and apparatus for the hydrogenation of polymers under supercritical conditions |
BRPI0413177A (pt) | 2003-07-31 | 2006-10-03 | Cargill Inc | composições gordurosas com teor baixo de ácido trans-graxo; hidrogenação em temperatura baixa, por exemplo, de óleos comestìveis |
GB0321240D0 (en) * | 2003-09-11 | 2003-10-08 | Avecia Ltd | Process |
GB0406125D0 (en) | 2004-03-18 | 2004-04-21 | Univ Cambridge Tech | Methods of amination |
EP1737806A1 (en) * | 2004-03-31 | 2007-01-03 | Härröd Research Ab | Selective hydrogenation of functional groups in substrates and partially hydrogenated fatty acids and fatty acid derivatives |
ES2245901B1 (es) * | 2004-07-15 | 2007-04-01 | Universitat Politecnica De Catalunya | Proceso de hidrogenacion parcial de trigliceridos insaturados en fase vapor a alta presion y reactor para la realizacion de dicho proceso. |
JP5179107B2 (ja) * | 2007-07-24 | 2013-04-10 | 花王株式会社 | 水素添加用触媒 |
DE102008030101A1 (de) | 2007-12-11 | 2009-06-25 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Lötanschlusselement |
CN101422199B (zh) * | 2008-09-04 | 2011-05-04 | 东北农业大学 | 一种用超临界co2为溶解剂氢化小麦胚芽油的方法 |
ES2350669B1 (es) * | 2009-06-03 | 2011-11-15 | Universitat Politècnica De Catalunya | Proceso continuo de hidrogeneracion de aceites vegetales en fase liquida a presion y a temperatura con obtencion de una grasa con bajo contenido en isomero trans |
KR101404228B1 (ko) * | 2012-01-05 | 2014-06-11 | 한국과학기술연구원 | 초임계유체를 이용한 재생연료의 제조방법 |
CN103431074A (zh) * | 2013-07-23 | 2013-12-11 | 东北农业大学 | 一种超临界co2氢化葵花籽油的方法 |
CN105732312B (zh) * | 2016-03-25 | 2018-02-23 | 北京石油化工学院 | 一种醋酸仲丁酯超临界加氢制备仲丁醇联产乙醇的方法 |
US10189763B2 (en) | 2016-07-01 | 2019-01-29 | Res Usa, Llc | Reduction of greenhouse gas emission |
US9981896B2 (en) | 2016-07-01 | 2018-05-29 | Res Usa, Llc | Conversion of methane to dimethyl ether |
WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT328597B (de) * | 1973-08-30 | 1976-03-25 | Studiengesellschaft Kohle Mbh | Verfahren zur gleichzeitigen hydrierung und desodorisierung von fetten und/oder olen |
DE3776997D1 (de) * | 1986-07-23 | 1992-04-09 | Henkel Kgaa | Verfahren zur direkthydrierung von glyceridoelen. |
WO1994006738A1 (en) * | 1992-09-14 | 1994-03-31 | Unichema Chemie B.V. | Process for the production of alcohols |
DE4405029C2 (de) * | 1994-02-17 | 1996-04-04 | Degussa | Verfahren zum Härten von ungesättigten Fetten, Fettsäuren oder Fettsäureestern |
-
1995
- 1995-07-03 DK DK95925223T patent/DK0791041T3/da active
- 1995-07-03 HU HU9603612A patent/HU222744B1/hu not_active IP Right Cessation
- 1995-07-03 CZ CZ19963714A patent/CZ293018B6/cs not_active IP Right Cessation
- 1995-07-03 AU AU29420/95A patent/AU694929B2/en not_active Ceased
- 1995-07-03 CA CA002194140A patent/CA2194140C/en not_active Expired - Fee Related
- 1995-07-03 PL PL95317994A patent/PL180955B1/pl not_active IP Right Cessation
- 1995-07-03 DE DE29522355U patent/DE29522355U1/de not_active Expired - Lifetime
- 1995-07-03 DE DE69520686T patent/DE69520686T2/de not_active Expired - Fee Related
- 1995-07-03 EP EP95925223A patent/EP0791041B1/en not_active Revoked
- 1995-07-03 AT AT95925223T patent/ATE200512T1/de not_active IP Right Cessation
- 1995-07-03 CN CN95194384A patent/CN1092708C/zh not_active Expired - Fee Related
- 1995-07-03 BR BR9508217A patent/BR9508217A/pt not_active IP Right Cessation
- 1995-07-03 JP JP50383996A patent/JP4015186B2/ja not_active Expired - Fee Related
- 1995-07-03 PT PT95925223T patent/PT791041E/pt unknown
- 1995-07-03 ES ES95925223T patent/ES2159319T3/es not_active Expired - Lifetime
- 1995-07-03 WO PCT/SE1995/000824 patent/WO1996001304A1/en active IP Right Grant
-
1996
- 1996-12-20 NO NO965533A patent/NO305915B1/no not_active IP Right Cessation
-
1997
- 1997-01-02 FI FI970001A patent/FI970001A/fi unknown
- 1997-10-27 MX MX9700330A patent/MX214427B/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
MX9700330A (en) | 1999-04-30 |
DE69520686D1 (de) | 2001-05-17 |
NO965533L (no) | 1997-02-28 |
JP4015186B2 (ja) | 2007-11-28 |
CZ293018B6 (cs) | 2004-01-14 |
CZ371496A3 (en) | 1997-05-14 |
JPH10505367A (ja) | 1998-05-26 |
PT791041E (pt) | 2001-10-30 |
CA2194140A1 (en) | 1996-01-18 |
DE29522355U1 (de) | 2002-05-23 |
AU2942095A (en) | 1996-01-25 |
ATE200512T1 (de) | 2001-04-15 |
FI970001A0 (fi) | 1997-01-02 |
NO305915B1 (no) | 1999-08-16 |
HU222744B1 (hu) | 2003-09-29 |
EP0791041B1 (en) | 2001-04-11 |
AU694929B2 (en) | 1998-08-06 |
CA2194140C (en) | 2005-10-18 |
HU9603612D0 (en) | 1997-02-28 |
DE69520686T2 (de) | 2001-11-22 |
BR9508217A (pt) | 1999-04-27 |
PL180955B1 (pl) | 2001-05-31 |
DK0791041T3 (da) | 2001-08-06 |
FI970001A (fi) | 1997-01-02 |
WO1996001304A1 (en) | 1996-01-18 |
HUT76040A (en) | 1997-06-30 |
NO965533D0 (no) | 1996-12-20 |
CN1157007A (zh) | 1997-08-13 |
EP0791041A1 (en) | 1997-08-27 |
MX214427B (en) | 2003-05-26 |
PL317994A1 (en) | 1997-05-12 |
CN1092708C (zh) | 2002-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Grant refused |
Effective date: 19980928 |
|
FG2A | Definitive protection |
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