KR940021510A - 과산화성 가오존분해 생성물의 가수소분해적 환원방법 - Google Patents

과산화성 가오존분해 생성물의 가수소분해적 환원방법 Download PDF

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KR940021510A
KR940021510A KR1019940004761A KR19940004761A KR940021510A KR 940021510 A KR940021510 A KR 940021510A KR 1019940004761 A KR1019940004761 A KR 1019940004761A KR 19940004761 A KR19940004761 A KR 19940004761A KR 940021510 A KR940021510 A KR 940021510A
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South Korea
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catalyst
hydrogen
vessel
reaction solution
pump
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KR1019940004761A
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English (en)
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폴함머 스테판
샬러 요제프
비네쯔함머 빌리발트
Original Assignee
알프레트 노이바우어, 디트프리트
케미 린쯔 게젤샤프트 엠.베.하.
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Priority claimed from AT0048493A external-priority patent/AT398759B/de
Application filed by 알프레트 노이바우어, 디트프리트, 케미 린쯔 게젤샤프트 엠.베.하. filed Critical 알프레트 노이바우어, 디트프리트
Publication of KR940021510A publication Critical patent/KR940021510A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/40—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with ozone; by ozonolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/46—Oxygen atoms
    • C07D213/48—Aldehydo radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/54—Radicals substituted by oxygen atoms

Abstract

단일암체 촉매 및 불활성 유기 희석제 존재하에 0.01 내지 2.0MPa의 수소압 및 -10 내지 150℃의 온도에서 과산화성 가오존분해 생성물을 상응하는 카보닐 화합물로 가수소분해적으로 환원시키는 방법 및 수소로 가수소분해시킴으로써 균일한 신규 생성물을 수득하게 하는 화학적 화합물의 촉매적 가수소분해용 장치.

Description

과산화성 가오존분해 생성물의 가수소분해적 환원방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 수소를 사용한 가수소분해용 장치를 나타낸다.

Claims (10)

  1. 촉매로서 단일암체 촉매를 사용함을 특징으로 하여, 0.01 내지 2.0MPa의 수소압 및 -10 내지 150℃의 온도에서 촉매 존재하에서 반응 조건하에 불활성인 유기 희석제중 과산화성 가오존분해 생성물을 상응하는 카보닐 화합물로 가수소분해적으로 환원시키는 방법.
  2. 제1항에 있어서, 귀금속으로 피복된 촉매 지지체로 이루어진 단일암체 촉매임을 특징으로 하는 방법.
  3. 제1항에 있어서, 금속으로 이루어진 촉매 지지체임을 특징으로 하는 방법.
  4. 제1항에 있어서, 불활성 유기 희석제로서 탄소원자 1 내지 6개를 갖는 알콜을 사용함을 특징으로 하는 방법.
  5. 제1항에 있어서, 0.1 내지 1.0MPa의 수소압을 유지함을 특징으로 하는 방법.
  6. 제1항에 있어서, 15 내지 70℃의 온도를 유지함을 특징으로 하는 방법.
  7. 가수소분해되는 화학적 화합물을 위한 저장 유기 용기 V, 화학적 화합물을 급송(feed in)하기 위한 펌프 P, 수소를 도입시키기 위한 배열 VE, 수소압 측정을 위한 압력 게이지 p, 단일암체 촉매가 있는 컨테이너 F, 온도 조절을 위한 배열 T 및 생성물 용액을 수거하기 위한 배열 E1 및 E2가 장착된 반응 용액 회수용 용기 G, 반응 용액 운송을 위한 순환 펌프 K 및 샘플을 취하기 위한 장치 A가 장착된, 수소를 사용하여 화학적 화합물을 가수소분해시키기 위한 장치에 있어서, 저장 용기 V, 펌프 P, 수소 밸브 VE, 수소 압력 게이지 p, 단일암체 촉매 F, 용기 G, 순환 펌프 K 및 샘플을 취하는 장치 A가 반응 용액에 대한 라인(line)을 통해 순서대로 연결되어 있음으로써, 가수소분해되는 화학적 화합물 및 수소가 동시에 단일암체 촉매 F를 통해 반응 용액 회수용 용기 G내로 급속되어지고, 또한 순환 펌프의 보조로 단일암체 촉매를 통한 회수 용기로부터의 반응 용액의 반복된 급송 가능성이 보장되어짐을 특징으로 하는 장치.
  8. 제7항에 있어서, 가수소분해되는 화학적 화합물이 과산화물을 함유하는 가온존분해 생성물임을 특징으로 하는 장치.
  9. 제7항에 있어서, 용기 G가 반응 용액에 대한 라인을 통해 증류 단위 D와 연결되어짐을 특징으로 하는 장치.
  10. 제1항에 있어서, 제7항의 장치를 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940004761A 1993-03-12 1994-03-11 과산화성 가오존분해 생성물의 가수소분해적 환원방법 KR940021510A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0048493A AT398759B (de) 1993-03-12 1993-03-12 Hydrogenolytische reduktion peroxidischer ozonolyseprodukte und vorrichtung zu ihrer durchführung
AT?A484/93? 1993-03-12

Publications (1)

Publication Number Publication Date
KR940021510A true KR940021510A (ko) 1994-10-19

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Country Status (18)

Country Link
US (1) US5543560A (ko)
JP (1) JPH0859516A (ko)
KR (1) KR940021510A (ko)
AT (1) ATE153329T1 (ko)
AU (1) AU675688B2 (ko)
BG (1) BG61397B1 (ko)
DE (1) DE59402792D1 (ko)
EE (1) EE9400053A (ko)
ES (1) ES2101371T3 (ko)
HR (1) HRP940157B1 (ko)
LT (1) LT3239B (ko)
LV (1) LV10856B (ko)
RO (1) RO110477B1 (ko)
SI (1) SI9400126A (ko)
SK (1) SK29994A3 (ko)
TR (1) TR27554A (ko)
TW (1) TW299317B (ko)
ZA (1) ZA941725B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101482330B1 (ko) * 2012-12-21 2015-01-14 주식회사 포스코 수소 이용률을 극대화한 금속 산화물의 수소환원장치 및 금속 산화물의 수소환원공정 내 수소 가스의 농도 제어방법

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5869676A (en) * 1997-05-15 1999-02-09 Vion Pharmaceuticals, Inc. Process for the synthesis of ribonucleotide reductase inhibitors 3-AP and 3-AMP
WO2001062696A1 (en) 2000-02-25 2001-08-30 Akzo Nobel N.V. Process for the preparation of glyceraldehyde and derivatives thereof
CN1261415C (zh) * 2001-05-30 2006-06-28 大赛璐化学工业株式会社 喹啉甲醛的制造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU362000A1 (ko) * 1970-04-16 1972-12-13
US4425815A (en) 1980-08-29 1984-01-17 Mastergear Company Limited Wormwheels
US4513149A (en) * 1982-04-05 1985-04-23 Olin Corporation Raney nickel alloy expanded mesh hydrogenation catalysts
DE3224795A1 (de) * 1982-07-02 1984-01-05 Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München Verfahren zur herstellung von glyoxylsaeure und glyoxylsaeurederivaten
DE3346266A1 (de) * 1983-12-21 1985-07-11 Lentia Gmbh Verfahren zur herstelung von glyoxal, alkylglyoxalen und von deren acetalen
AT380008B (de) * 1983-12-23 1986-03-25 Chemie Linz Ag Verfahren zur herstellung von mono- oder biscarbonylverbindungen
DE3926561A1 (de) * 1989-08-11 1991-02-14 Basf Ag Palladiumkatalysatoren
AU676881B2 (en) * 1992-12-23 1997-03-27 Hydrodec Development Corporation Pty Ltd Destruction of halide containing organics and solvent purification

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101482330B1 (ko) * 2012-12-21 2015-01-14 주식회사 포스코 수소 이용률을 극대화한 금속 산화물의 수소환원장치 및 금속 산화물의 수소환원공정 내 수소 가스의 농도 제어방법

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BG98638A (bg) 1995-06-30
SK29994A3 (en) 1994-10-05
HRP940157B1 (en) 1998-08-31
US5543560A (en) 1996-08-06
ES2101371T3 (es) 1997-07-01
ZA941725B (en) 1994-10-13
HRP940157A2 (en) 1996-10-31
AU5774994A (en) 1994-09-15
EE9400053A (et) 1995-12-15
ATE153329T1 (de) 1997-06-15
LT3239B (en) 1995-04-25
TW299317B (ko) 1997-03-01
DE59402792D1 (de) 1997-06-26
RO110477B1 (ro) 1996-01-30
AU675688B2 (en) 1997-02-13
BG61397B1 (bg) 1997-07-31
SI9400126A (en) 1994-09-30
JPH0859516A (ja) 1996-03-05
LV10856B (en) 1996-06-20
LTIP1894A (en) 1994-10-25
TR27554A (tr) 1995-06-08
LV10856A (lv) 1995-10-20

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