EP2997171B1 - Tôle en alliage d'aluminium pour bouteille métallique ou boîtier d'aérosol - Google Patents
Tôle en alliage d'aluminium pour bouteille métallique ou boîtier d'aérosol Download PDFInfo
- Publication number
- EP2997171B1 EP2997171B1 EP14731678.0A EP14731678A EP2997171B1 EP 2997171 B1 EP2997171 B1 EP 2997171B1 EP 14731678 A EP14731678 A EP 14731678A EP 2997171 B1 EP2997171 B1 EP 2997171B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sheet metal
- bottle
- rolling
- aerosol
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000443 aerosol Substances 0.000 title claims description 21
- 229910000838 Al alloy Inorganic materials 0.000 title claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 238000000137 annealing Methods 0.000 claims description 19
- 238000005097 cold rolling Methods 0.000 claims description 19
- 238000005096 rolling process Methods 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000001953 recrystallisation Methods 0.000 claims description 10
- 235000013361 beverage Nutrition 0.000 claims description 9
- 238000005266 casting Methods 0.000 claims description 9
- 239000004411 aluminium Substances 0.000 claims description 6
- 238000005098 hot rolling Methods 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000004479 aerosol dispenser Substances 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims 2
- 238000007669 thermal treatment Methods 0.000 claims 2
- 238000010409 ironing Methods 0.000 claims 1
- 238000001907 polarising light microscopy Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 18
- 239000011572 manganese Substances 0.000 description 16
- 239000011777 magnesium Substances 0.000 description 15
- 229910045601 alloy Inorganic materials 0.000 description 12
- 239000000956 alloy Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 239000002966 varnish Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 238000007493 shaping process Methods 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 241001249696 Senna alexandrina Species 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000009957 hemming Methods 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000007688 edging Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000000399 optical microscopy Methods 0.000 description 3
- 241000209149 Zea Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/28—Deep-drawing of cylindrical articles using consecutive dies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/24—Making hollow objects characterised by the use of the objects high-pressure containers, e.g. boilers, bottles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/26—Making hollow objects characterised by the use of the objects cans or tins; Closing same in a permanent manner
- B21D51/2615—Edge treatment of cans or tins
- B21D51/2638—Necking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/12—Cans, casks, barrels, or drums
- B65D1/14—Cans, casks, barrels, or drums characterised by shape
- B65D1/16—Cans, casks, barrels, or drums characterised by shape of curved cross-section, e.g. cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/38—Details of the container body
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B2001/221—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by cold-rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B2003/001—Aluminium or its alloys
Definitions
- the invention relates to the field of metallic aluminum alloy bottles as well as aerosol cans, still known to those skilled in the art under the names of “bottle-can” or “bottle beverage can” and aerosol can, respectively. , manufactured by stamping-stretching, that is to say according to a process including these two basic steps, associated in particular with the complementary steps of necking (or “necking"), possible threading (or “threading”) and hemming (or “curling”) ").
- the invention relates more particularly to aluminum alloy sheets of composition and heat treatment which are particularly suitable for this type of application and which in particular have good formability during the abovementioned stages, in particular for shrinking, as well as a low anisotropy necessary in particular during the drawing and drawing stages.
- Aluminum alloys are increasingly used in the manufacture of beverage cans, also known under the name of "cans” or “beverage cans”, but also of metallic bottles or “bottle-cans” and aerosol, because of their very good aesthetic appearance, especially in relation to plastics and steels, their ability to be recycled and their good resistance to corrosion. All aluminum alloys referred to below are designated, unless otherwise stated, according to the designations defined by the “Aluminum Association” in the “Registration Record Series” which it publishes regularly.
- Beverage boxes, or cans, also known to those skilled in the art under the name of "cans” or “beverage cans”, are produced by stamping-drawing from alloy sheets of the 3104 type in metallurgical state. H19.
- This metallurgical state corresponds to a continuous vertical plate casting, followed by scalping, homogenization, hot rolling followed by cold rolling in several passes with an overall cold reduction rate of 80 to 90%, without intermediate annealing.
- the sheet undergoes a first cutting and stamping operation; during this stage, the sheet metal coil feeds a press, also called a "cupper", which cuts discs called blanks and performs a first stamping operation to produce cups also known as "cups”.
- the cups are then routed to a second press or "bodymaker” where they undergo at least a second stamping, also called re-stamping or recovery stamping, and several successive draws; these consist in passing the stamped blank through drawing rings in order to lengthen the metal and to thin it.
- the bottom on the other hand, is shaped like an inverted dome so that it can withstand the internal pressure produced by the container. Boxes are thus gradually obtained, the walls of which are thinner than the bottom. These boxes are then treated in a machine which gives them a rotary movement while a shear cuts them to the desired height. These are then washed in several cleaning and rinsing baths and then typically dried between 180 and 250 ° C for 5 to 10 minutes. They are then printed by rollers and then varnished on the outside before baking typically between 200 and 230 ° C for 5 to 10 minutes. A coating is then sprayed inside the preform before a new cooking, typically between 190 and 220 ° C for 3 to 10 minutes. The box obtained at this stage is called "preform".
- the beverage cans are then routed to a shrinking and planking station (or edging) also known as a "necker flanger" where the upper part of the preform undergoes several successive narrowing in diameter and a edging intended for the subsequent laying of the lid.
- a shrinking and planking station also known as a "necker flanger”
- Metal bottles and aerosol cans or aerosol cans, made of aluminum alloy, are traditionally manufactured by impact spinning, from pins produced by casting on a wheel.
- the shape of the developed perimeter is not favorable. It is in fact a profile with six horns, two of which positioned respectively at 0 and 180 ° from the rolling direction and four at 45 ° on either side of said direction, in accordance with the figure 1 . It turns out that such a configuration, due to the horns at 0 and 180 °, presents a serious risk of giving rise to the phenomenon known as “pinched horns” well known to those skilled in the art, with the risk of breakage during subsequent stretching. What is more, the material does not soften very much, that is to say that its mechanical resistance decreases little during the firing of varnishes, which makes shaping for shrinking or "necking" more delicate.
- the document FR2432555 A1 describes an aluminum alloy with magnesium and manganese as main alloying constituents for the production of a strip suitable for the production of bodies and can lids by stamping and re-stretching, and its production method.
- the alloy described contains: 1.3 to 2.5% magnesium; 0.4 to 1.0% manganese; 0.1 to 0.9% iron; 0.1 to 1.0% silicon; 0.05 to 0.4% copper; 0 to 0.2% titanium; the rest essentially of aluminum.
- the total magnesium and manganese content is 2.0 to 3.3% and the magnesium / manganese ratio is 1.4: 1 to 4.4: 1.
- the invention aims to solve these difficulties by allowing deep drawing of the cups with drawing ratios up to 1.9 or more, stretching without breakage, and above all shaping by shrinking or "necking" with a reduction in diameter. of the “preform” of the order of 50%, without cracks or folds, as during “threading” in the case of bottles and hemming in this same case as well as in that of aerosol cans.
- the invention also relates to a sheet produced by a process as mentioned above and whose elastic limit after a heat treatment of 10 min. at 205 ° C, simulating the firing of varnishes, is from 170 to 210 MPa and the breaking load from 200 to 240 MPa.
- the reduction in the elastic limit of said sheet before and after heat treatment simulating the firing of varnishes is from 20 to 40 MPa.
- the anisotropy index of said sheet measured after its cold rolling to a thickness of 0.35 to 1.0 mm, by the method of buckets according to standard NF EN 1669 is from 0.5 to 4.0 %.
- said sheet has, at the end of the test according to the bucket method, horns at 45 ° on either side of the rolling direction and no horn at 0 and 180 ° from said direction.
- the formability of said sheet is such that it does not reveal any cracks or folds during deep drawing in two passes, the first with a drawing ratio, ratio between diameter of the blank and diameter of the punch, between 1.5 and 1.9, the second with a stamping ratio between 1.3 and 1.6.
- said sheet has, after cold rolling up to a thickness of 0.35 to 1.0 mm, an elongated grain microstructure with a slenderness factor, ratio of grain size in the direction of rolling related to the grain size in the thickness direction, measured after anodic oxidation and in optical microscopy in polarized light, between 2 and 10.
- the subject of the invention is also a metal bottle, also known to a person skilled in the art under the name of "bottle can” or “bottle type beverage can”, made from such a sheet having one or more of the characteristics mentioned above, including a so-called metallic bottle, that is to say one whose main walls are not strictly cylindrical.
- aerosol can also known to those skilled in the art under the name of "aerosol can” or even “aerosol dispenser”, made from said sheet having one or more of the characteristics aforementioned, including a so-called aerosol can, that is to say one whose main walls are not strictly cylindrical.
- the figure 1 represents the "horn profile", that is to say the shape of the perimeter developed from the top of the "cups" at the end of the first stamping, with, on the ordinate, the ratio of the height of the horn to the average height of the cup and, on the abscissa, the angle ⁇ with respect to the rolling direction.
- the figure 2 represents the Vickers Hv microhardness measured under a load of 100 g on preforms before shrinking (therefore having undergone the firing of varnishes) as a function of the elastic limit R0.2 in MPa measured on the sheets before transformation but after simulation treatment 10 min. at 205 ° C.
- the black diamonds correspond to the material according to the invention, and the white squares to materials not in accordance with the invention. It reveals a linear correlation between these two values.
- the figure 3 represents the scrap rate in%, according to three zones (A from 0 to 10%, B from 10 to 30% and C beyond) during the shrinking or "necking" operation depending on the Vickers Hv microhardness ci above, for materials in accordance with the invention (black diamonds) and non-conforming (white squares).
- the invention consists in a judicious choice of alloy and heat treatment, as well as of transformation range, of the sheet or strip used for the manufacture of metal bottles, or "bottle-cans", or aerosol cans.
- the chemical composition of the alloy expressed in weight percentages (% by weight) is as follows: Si: 0.20 - 0.35, Fe: 0.30 - 0.55, Cu: 0.05 - 0.20, Mn: 0.70-0.90, Mg: 0.80 - 1.25, Zn: ⁇ 0.25, Ti: ⁇ 0.10, other elements ⁇ 0.05 each, and ⁇ 0.15 at total, aluminum remains.
- a minimum of 0.10%, and preferably 0.20% makes it possible to obtain a sufficient rate of Al 12 (Fe, Mn) 3 Si phase at the end of the homogenization treatment after casting of the plates.
- This type of abrasive phase has the particularity of avoiding fouling of the drawing rings by agglomerates of alloy particles and oxide and therefore of ensuring a good surface quality of the blanks by avoiding that the he skilled in the art knows as "gripping".
- Fe is also, in general, an impurity, the content of which increases during recycling. This must be less than 0.55% and preferably 0.50% to avoid the formation of coarse primary phases during casting, phases detrimental to formability.
- a Si content of at least 0.10% and better of 0.20%, as well as of Fe of 0.30% and better 0.35%, is necessary for a good control of the anisotropy of the final product, that is to say say sheet or strip, and therefore subsequent shaping operations.
- the Si content is at least 0.20%.
- the elements Cu, Mn and Mg are essentially hardening elements, the contents of which allow the mechanical characteristics of the sheet to be controlled at the various stages of manufacture, from the blank to the final product.
- Hardening is mainly linked to the presence of these elements in solid solution in the primary aluminum matrix. Cu also allows hardening through fine precipitates.
- Cu has a content limited to 0.20% to promote restoration during the heat treatment of varnish firing and thereby improve the formability necessary in particular for shrinking or "necking" as well as for threading and / or hemming.
- Mn is limited to 1.0% and better 0.90% to avoid the formation of coarse primary phases during casting, detrimental to formability.
- the Mn content is limited to 0.90%
- Mg is limited to 1.3% and better 1.25% so as not to reduce formability too significantly, especially for stamping operations.
- the Mg content is limited to 1.25%.
- the minimum contents of Cu, Mn and Mg ensure the minimum mechanical characteristics required, in particular for the resistance to internal pressure of the bottom of the bottle or case.
- Zn is limited to 0.25% mainly due to the legislation on products for food applications translated into standard NF EN 602.
- Ti is a refining element of the casting structure but also forms primary phases unfavorable to formability. For the latter reason, its content is limited to less than 0.1%.
- the manufacture of the sheets according to the invention mainly comprises the casting, typically continuous vertical (CCV), of the plates and their scalping.
- CCV continuous vertical
- the scalped plates then undergo conventional homogenization and then hot rolling followed by a first cold rolling with a reduction rate of 35 to 80%.
- the reduction rate before intermediate annealing must be at least 35% to obtain complete recrystallization during said intermediate annealing. It must not exceed 80% so that the reduction carried out after said intermediate annealing is sufficient to obtain mechanical characteristics after annealing for 10 minutes at 205 ° C in the ranges announced below.
- the intermediate product undergoes recrystallization annealing at a temperature between 300 and 400 ° C, better between 340 and 360 ° C, or at a target temperature of 350 ° C, for at least one hour.
- the sheets or strips thus obtained have, after heat treatment for 10 min. at 205 ° C simulating the cumulative drying treatments after cleaning and curing of the varnishes and interior coating, an elastic limit Rp 0.2 of between 170 and 210 MPa and a breaking load between 200 and 240 MPa.
- Another advantage of the invention is an anisotropy index, which reflects the ability of the metal to be shaped in a homogeneous manner during the manufacture of the cups and their stretching, measured by the method of cups according to the NF standard. EN 1669, between 0.5 and 4.0%.
- stamping ratio 1.5 to 1.9 in a first pass and with a stamping ratio of 1.3 to 1.6 in a second pass , which corresponds to an overall drawing ratio up to 2.8.
- stamping can be carried out in more than two passes.
- the sheet according to the invention is also characterized by the fact that after cold rolling up to a thickness of 0.35 to 1.0 mm, it has a microstructure with elongated grains with a slenderness factor, ratio of grain size in the direction of rolling compared to grain size in the direction of thickness, measured by optical microscopy in polarized light after anodic oxidation, between 2 and 10.
- the other (“Invention”) underwent cold rolling up to the thickness of 0.65 mm and then recrystallization annealing for one hour at 350 ° C. followed by the final cold rolling up to the thickness of 0.505 mm. This gives the metallurgical state H14.
- the horn “profiles” are summarized in figure 1 corresponding to the average for 10 cups of each type (“3104 H14” according to the invention and “3104 H19” of the prior art).
- the cups according to the invention were of better quality than according to the prior art, that is to say having fewer folds and above all, as shown in the figure 1 , an absence of horns at 0 and 180 ° from the rolling direction, therefore without pinched horns, which is not the case with the cups of the prior art.
- the profile according to the invention reveals horns at 45 ° on either side of the rolling direction, ie 45 °, 135 °, 225 °, and 315 °, which do not present the risk known as “pinched horns” , unlike horns at 0 and 180 ° from the cups of the prior art.
- Plate 1 underwent the same transformation range as the reference plate of Example 1, i.e. without recrystallization annealing, and the other plates 2 to 9 underwent the same transformation range, identical to the previous one until rolling. cold namely: They were all scalped and then homogenized at a temperature of approximately 580 ° C for approximately 3 hours before undergoing hot rolling to a thickness of 2.8 mm.
- the granular structure was characterized on these same sheets by optical microscopy in polarized light, after anodic oxidation, with a magnification of 50.
- the ratio of the grain size in the direction of rolling L to that was measured. of the grain size in the thickness direction or “short cross Tc”, that is to say in a plane (L, Tc), and this substantially at mid-width of the initial sheet.
- the values reported in Table 4 below correspond to an average of about fifty measurements for each case.
- the sheets according to the invention all have a pitch ratio of between 1 and 10, and in this case from 3 to 5, while it reaches the value of 30 in the case of sheet metal according to the prior art in metallurgical state H19 (reference 1).
- Table 4 ⁇ /b> Anisotropy index S 45 (%) Anisotropy index S 0 (%) Grain slenderness report Reference 1 4.5 1.7 30 Reference 2 4.1 - 5 Invention 3 3.4 - 5 Invention 4 3.5 - 5 Invention 5 3.8 - 5 Invention 6 2.0 - 5 Invention 7 3.2 - 5 Invention 8 3.0 - 4 Invention 9 2.9 - 3
- a classification from A to C could be made according to the number of parts eliminated in%, that is to say the "scrap rate". This classification is established as follows: A for a reject rate of 0 to 10%, B from 10 to 30% and C beyond.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Ceramic Engineering (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Metal Rolling (AREA)
- Wrappers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1301143A FR3005664B1 (fr) | 2013-05-17 | 2013-05-17 | Tole en alliage d'alliage pour bouteille metallique ou boitier d'aerosol |
PCT/FR2014/000104 WO2014184450A1 (fr) | 2013-05-17 | 2014-05-13 | Tôle en alliage d'aluminium pour bouteille métallique ou boîtier d'aérosol |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2997171A1 EP2997171A1 (fr) | 2016-03-23 |
EP2997171B1 true EP2997171B1 (fr) | 2020-07-08 |
Family
ID=48979814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14731678.0A Active EP2997171B1 (fr) | 2013-05-17 | 2014-05-13 | Tôle en alliage d'aluminium pour bouteille métallique ou boîtier d'aérosol |
Country Status (7)
Country | Link |
---|---|
US (1) | US10577683B2 (pt) |
EP (1) | EP2997171B1 (pt) |
CN (1) | CN105229183B (pt) |
BR (1) | BR112015028352B1 (pt) |
FR (1) | FR3005664B1 (pt) |
RU (1) | RU2668357C2 (pt) |
WO (1) | WO2014184450A1 (pt) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11433441B2 (en) | 2016-08-30 | 2022-09-06 | Kaiser Aluminum Warrick, Llc | Aluminum sheet with enhanced formability and an aluminum container made from aluminum sheet |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6657116B2 (ja) * | 2014-04-30 | 2020-03-04 | アルコア ユーエスエイ コーポレイション | 向上した成形性を有するアルミニウムシートからアルミニウム容器を製造する方法 |
WO2016100800A1 (en) * | 2014-12-19 | 2016-06-23 | Novelis Inc. | Aluminum alloy suitable for the high speed production of aluminum bottle and the process of manufacturing thereof |
RU2687791C2 (ru) * | 2015-03-13 | 2019-05-16 | Новелис Инк. | Алюминиевые сплавы для упаковочной продукции сложной формы и способы их получения |
SI24969A (sl) * | 2015-04-03 | 2016-10-28 | TALUM d.d. KidriÄŤevo | Aluminijeva zlitina za izdelavo aluminijevih aerosol doz s protismernim izstiskovanjem in postopek za njeno izdelavo |
CN109196128A (zh) * | 2016-05-02 | 2019-01-11 | 诺维尔里斯公司 | 具有增强的可成形性的铝合金以及相关方法 |
CN106038489B (zh) * | 2016-05-25 | 2018-11-02 | 华润双鹤药业股份有限公司 | 异丙托溴铵气雾剂 |
TWI601836B (zh) * | 2016-06-02 | 2017-10-11 | 中國鋼鐵股份有限公司 | 鋁片之製造方法 |
CN106862268B (zh) * | 2017-03-07 | 2018-10-30 | 新疆众和股份有限公司 | 一种为镜面铝轧制提供1090镜面毛料的冷加工方法 |
BR112022004472A2 (pt) * | 2019-09-10 | 2022-05-31 | Anheuser Busch Llc | Redução de uso de material e etapas de deformação de plástico na fabricação de recipientes de alumínio |
RU2718370C1 (ru) * | 2019-11-18 | 2020-04-06 | Акционерное общество "Арнест" | Сплав на основе алюминия и аэрозольный баллон из этого сплава |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003082429A (ja) * | 2001-09-11 | 2003-03-19 | Kobe Steel Ltd | ボトル缶用アルミニウム合金板 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3032448A (en) * | 1958-05-17 | 1962-05-01 | Aluminium Walzwerke Singen | Method for producing lacquered thin sheets of aluminum |
JPS548327B2 (pt) * | 1974-03-29 | 1979-04-14 | ||
US4282044A (en) | 1978-08-04 | 1981-08-04 | Coors Container Company | Method of recycling aluminum scrap into sheet material for aluminum containers |
US4260419A (en) * | 1978-08-04 | 1981-04-07 | Coors Container Company | Aluminum alloy composition for the manufacture of container components from scrap aluminum |
DE2929724C2 (de) * | 1978-08-04 | 1985-12-05 | Coors Container Co., Golden, Col. | Verfahren zum Herstellen eines Bandes aus einer Aluminiumlegierung für Dosen und Deckel |
JP2620923B2 (ja) | 1993-06-14 | 1997-06-18 | 株式会社東陽理化学研究所 | 魔法瓶における金属製真空二重瓶の外瓶の製造方法 |
US5681405A (en) * | 1995-03-09 | 1997-10-28 | Golden Aluminum Company | Method for making an improved aluminum alloy sheet product |
EP0740971A1 (en) | 1995-05-04 | 1996-11-06 | Hoogovens Staal B.V. | Method of manufacturing a bottle-shaped metal container |
JPH10330897A (ja) * | 1997-05-30 | 1998-12-15 | Mitsubishi Alum Co Ltd | 深絞り成形用アルミニウム基合金板の製造方法 |
US6579387B1 (en) * | 1997-06-04 | 2003-06-17 | Nichols Aluminum - Golden, Inc. | Continuous casting process for producing aluminum alloys having low earing |
EP1134046B1 (en) | 1999-08-30 | 2005-08-03 | Daiwa Can Company | Production method for bottle type can and form-working tool |
US20030015261A1 (en) * | 2001-05-03 | 2003-01-23 | Bull Michael Jackson | Process for preparing an aluminum alloy sheet with improved bendability and aluminum alloy sheet produced therefrom |
US20040035871A1 (en) * | 2002-08-20 | 2004-02-26 | Thomas Chupak | Aluminum aerosol can and aluminum bottle and method of manufacture |
EP1870481A4 (en) | 2005-03-25 | 2008-05-28 | Kobe Steel Ltd | ALUMINUM ALLOY PLATE WITH EXCELLENT HIGH-TEMPERATURE BEHAVIOR FOR BOTTLE BOX |
US20150101382A1 (en) * | 2012-11-02 | 2015-04-16 | Golden Aluminum, Inc. | Method and composition for recycling aluminum containers |
-
2013
- 2013-05-17 FR FR1301143A patent/FR3005664B1/fr active Active
-
2014
- 2014-05-13 EP EP14731678.0A patent/EP2997171B1/fr active Active
- 2014-05-13 US US14/891,017 patent/US10577683B2/en active Active
- 2014-05-13 WO PCT/FR2014/000104 patent/WO2014184450A1/fr active Application Filing
- 2014-05-13 CN CN201480028773.9A patent/CN105229183B/zh active Active
- 2014-05-13 BR BR112015028352-7A patent/BR112015028352B1/pt active IP Right Grant
- 2014-05-13 RU RU2015153850A patent/RU2668357C2/ru active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003082429A (ja) * | 2001-09-11 | 2003-03-19 | Kobe Steel Ltd | ボトル缶用アルミニウム合金板 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11433441B2 (en) | 2016-08-30 | 2022-09-06 | Kaiser Aluminum Warrick, Llc | Aluminum sheet with enhanced formability and an aluminum container made from aluminum sheet |
Also Published As
Publication number | Publication date |
---|---|
CN105229183A (zh) | 2016-01-06 |
BR112015028352B1 (pt) | 2020-05-12 |
RU2668357C2 (ru) | 2018-09-28 |
US20160083825A1 (en) | 2016-03-24 |
CN105229183B (zh) | 2017-05-24 |
US10577683B2 (en) | 2020-03-03 |
RU2015153850A3 (pt) | 2018-03-30 |
RU2015153850A (ru) | 2017-06-22 |
EP2997171A1 (fr) | 2016-03-23 |
WO2014184450A1 (fr) | 2014-11-20 |
FR3005664A1 (fr) | 2014-11-21 |
BR112015028352A2 (pt) | 2017-07-25 |
FR3005664B1 (fr) | 2016-05-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2997171B1 (fr) | Tôle en alliage d'aluminium pour bouteille métallique ou boîtier d'aérosol | |
CN100489133C (zh) | 高温特性优良的瓶罐用铝合金板 | |
US9546411B2 (en) | Aluminum-alloy sheet and method for producing the same | |
EP0983129B1 (fr) | Procede de fabrication de bandes en alliages d'aluminium par coulee continue mince entre cylindres | |
JP2009221567A (ja) | 陽圧塗装缶蓋用アルミニウム合金板およびその製造方法 | |
JP2006265701A (ja) | 高温特性に優れたボトル缶用アルミニウム合金冷延板 | |
JP5568031B2 (ja) | ボトル缶用アルミニウム合金冷延板 | |
CN107002185A (zh) | 适合于铝瓶的高速生产的铝合金及其制造工艺 | |
JP2009235477A (ja) | 飲料缶胴用アルミニウム合金板およびその製造方法 | |
EP0660882A1 (fr) | Procede de fabrication d'une feuille mince apte a la confection d'elements constitutifs de boites | |
JP2007197815A (ja) | 耐流通ピンホール性に優れる缶ボディ用アルミニウム合金板 | |
JP2006283113A (ja) | 飲料缶胴用アルミニウム合金板およびその製造方法 | |
JP2016141886A (ja) | 缶蓋用アルミニウム合金板 | |
JP5391234B2 (ja) | Ppキャップ用アルミニウム合金板 | |
JP6912886B2 (ja) | 飲料缶胴用アルミニウム合金板及びその製造方法 | |
JP3550259B2 (ja) | 高速しごき成形性の優れたdi缶胴用アルミニウム合金板およびその製造方法 | |
JP2003293105A (ja) | ボトル型飲料缶用アルミニウム合金板の製造方法 | |
JP5480688B2 (ja) | Ppキャップ用アルミニウム合金板およびその製造方法 | |
JP4467443B2 (ja) | アルミニウム合金板の製造方法 | |
JP2005048288A (ja) | ボトム部の形状の安定性及び強度に優れるボトル缶用アルミニウム合金板 | |
WO2016063876A1 (ja) | 缶蓋用アルミニウム合金板 | |
JP2017082277A (ja) | 異方性とネック成形性に優れた飲料缶ボディ用または飲料ボトル缶ボディ用アルミニウム合金板の製造方法 | |
JP4995494B2 (ja) | 広口ボトル缶キャップ用高強度アルミニウム合金板及びその製造方法 | |
JP5335189B2 (ja) | キャップ用アルミニウム合金板及びその製造方法 | |
WO2015064290A1 (ja) | 缶エンド用アルミニウム合金板及びその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20151203 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CONSTELLIUM NEUF-BRISACH |
|
DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20190611 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C22F 1/04 20060101ALI20191108BHEP Ipc: C22C 21/06 20060101ALI20191108BHEP Ipc: B65D 1/16 20060101ALI20191108BHEP Ipc: C22C 21/08 20060101ALI20191108BHEP Ipc: C22F 1/047 20060101ALI20191108BHEP Ipc: B65D 83/38 20060101ALI20191108BHEP Ipc: C22C 21/02 20060101ALI20191108BHEP Ipc: C22C 21/00 20060101AFI20191108BHEP |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
INTG | Intention to grant announced |
Effective date: 20191127 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: VICHERY, HERVE Inventor name: LAE, EMILIE Inventor name: STRIEBIG, MICHEL |
|
INTC | Intention to grant announced (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20200204 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1288514 Country of ref document: AT Kind code of ref document: T Effective date: 20200715 Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602014067471 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1288514 Country of ref document: AT Kind code of ref document: T Effective date: 20200708 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20200708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201009 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201008 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201008 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201109 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201108 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R026 Ref document number: 602014067471 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
26 | Opposition filed |
Opponent name: NOVELIS INC. Effective date: 20210329 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210531 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210513 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210531 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20210531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210513 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20140513 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230411 |
|
PLCK | Communication despatched that opposition was rejected |
Free format text: ORIGINAL CODE: EPIDOSNREJ1 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230525 Year of fee payment: 10 Ref country code: DE Payment date: 20230530 Year of fee payment: 10 Ref country code: CZ Payment date: 20230426 Year of fee payment: 10 |
|
PLAB | Opposition data, opponent's data or that of the opponent's representative modified |
Free format text: ORIGINAL CODE: 0009299OPPO |
|
APBM | Appeal reference recorded |
Free format text: ORIGINAL CODE: EPIDOSNREFNO |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
R26 | Opposition filed (corrected) |
Opponent name: NOVELIS INC. Effective date: 20210329 |
|
APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230529 Year of fee payment: 10 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200708 |