EP2824225B1 - Composite spinneret and method of manufacturing composite fiber - Google Patents

Composite spinneret and method of manufacturing composite fiber Download PDF

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Publication number
EP2824225B1
EP2824225B1 EP13758377.9A EP13758377A EP2824225B1 EP 2824225 B1 EP2824225 B1 EP 2824225B1 EP 13758377 A EP13758377 A EP 13758377A EP 2824225 B1 EP2824225 B1 EP 2824225B1
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Prior art keywords
virtual
hole
island component
polymer
discharge holes
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German (de)
English (en)
French (fr)
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EP2824225A4 (en
EP2824225A1 (en
Inventor
Joji Funakoshi
Masato Masuda
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Toray Industries Inc
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Toray Industries Inc
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/36—Matrix structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00—Spinnerette packs; Cleaning thereof
    • D01D4/06—Distributing spinning solution or melt to spinning nozzles

Definitions

  • the present invention relates to a composite spinneret and a method of manufacturing a composite fiber.
  • Fibers using a thermoplastic polymer such as polyester or polyamide are excellent in mechanical characteristics and dimensional stability, and therefore, the fibers have a variety of uses and many fibers provided with various functionalities are developed.
  • the composite fiber includes a core-sheath type fiber, a side-by-side type fiber and an islands-in-the-sea fiber which are attained by using the composite spinneret, and an alloy type fiber which is attained by melt-kneading polymers with each other.
  • the core-sheath type enables to provide sensitive effects such as textures and bulkiness or mechanical properties such as strength, elastic modulus and abrasion resistance which cannot be achieved by fibers of a single component only since a core component is covered with a sheath component.
  • the side-by-side type enables to exhibit a crimping property which cannot be obtained by fibers of a single component only and provide a stretching property and the like.
  • ultrafine fibers having a yarn diameter of monofilament of nano-order can be obtained by eluting an easy-to-elute component (sea component) after melt spinning.
  • the ultrafine fibers exhibit the soft touch and delicacy unavailable from general fibers, and can be applied to artificial leathers and textiles exhibiting new feelings and senses, and since fiber clearances become compact, the ultrafine fibers can be developed for sports clothing requiring wind-breaking capability and water-repelling capability as high-density woven fabrics.
  • ultrafine fibers since the ultrafine fibers have large specific surface areas and high dust collectability, these can be applied to high performance filters or the like, and since ultrafine fibers enter into fine grooves and wipe out dirt, these can also be applied to wiping cloths and precision polishing cloths for precision apparatuses, etc.
  • the core-sheath type enables to provide sensitive effects such as textures and bulkiness or mechanical properties such as strength, elastic modulus and abrasion resistance which cannot be achieved by fibers of a single component only since a core component is covered with a sheath component.
  • the side-by-side type enables to exhibit a crimping property which cannot be obtained by fibers of a single component only and provide a stretching property and the like.
  • a technique of manufacturing a composite fiber by a composite spinneret is generally referred to as a composite spinning method
  • a technique of manufacturing a composite fiber by melt-kneading polymers with one another is generally referred to as a polymer alloy method.
  • the polymer alloy method can be employed; however, there is a limitation in controlling a fiber diameter, and it is difficult to obtain uniform and homogeneous ultrafine fibers.
  • the composite spinning method is supposed to be superior to the polymer alloy method in that a composite polymer stream is precisely controlled by the composite spinneret, and a highly precise form of a yarn cross section can be uniformly and homogeneously formed in the running direction of a yarn.
  • a composite spinneret technology in the composite spinning method is extremely important in stably determining the form of the yarn cross section, and various proposals are heretofore made.
  • Patent Document 1 discloses a composite spinneret as shown in Fig. 11.
  • Fig. 11 (b) is a plan view of the composite spinneret of Patent Document 1
  • Fig. 11 (a) is a partially enlarged plan view of Fig. 11 (b) .
  • a black circle 1 indicates an island component discharge hole for discharging an island component polymer
  • an open circle 4 indicates a sea component discharge hole for discharging a sea component polymer
  • reference numerals 5 and 8 indicate a lowermost layer distribution plate and a distribution groove, respectively.
  • a description of the drawing may not be given by use of the same reference symbol or numeral.
  • Patent Document 1 describes that a plurality of distribution plates are overlaid, and a lowermost layer distribution plate 5, which is provided with distribution grooves 8, island component discharge holes 1 and sea component discharge holes 4, is arranged at the lowest layer of the distribution plates, and an island component polymer of a hard-to-elute component and a sea component polymer of an easy-to-elute component are previously distributed as many streams to the lowermost layer distribution plate 5 by the distribution plate, and then the polymers of both components are discharged from the island component discharge holes 1 and the sea component discharge holes 4, respectively, of the lowermost layer distribution plate 5 to be combined into one immediately after discharging, and thereby, islands-in-the-sea composite fibers can be manufactured.
  • Patent Document 1 also describes that a composite fiber, in which an island form has a hexagonal cross section (honeycomb form) and 61 pieces are uniformly distributed, can be manufactured by using this composite spinneret.
  • the composite spinneret is generally referred to as a spinneret of a distribution plate system.
  • an island form has a hexagon in cross section by disposing the sea component discharge holes 4 so as to form a hexagon around the island component discharge hole 1 as a disposition pattern of a hole group; however, another disposition pattern of a hole group is not presented, and islands-in-the-sea composite fibers having a variety of island forms may not be obtained in some cases.
  • the island component discharge hole 1 and the sea component discharge hole 4 are arranged at the same plane as that of the lowermost layer distribution plate 5, a great number of the island component discharge holes 1 may not be arranged and the hole packing density may not be increased, and consequently, the ultrafine fibers having a diameter of nano-order may not be obtained in some cases.
  • a denier value of the resulting fiber is 0.06 denier (fiber diameter in a trial calculation: about 2.5 ⁇ m) of a micron size and does not reach a nano-order size.
  • the composite spinneret may become larger to cause problems that productivity and operability are low in spinning facility of a multi-spindle type in a textile area in some cases.
  • Fig. 9 and Fig. 10 are partially enlarged plan views of the composite spinnerets of Patent Document 3 and Patent Document 5.
  • the pattern in Patent Document 3 or Patent Document 5 is a pattern in which three or four sea component discharge holes 4 are equally arranged around the island component discharge hole 1 (zigzag alignment), and it appears that islands-in-the-sea composite fibers in which the island component form is polygonal can be obtained at a glance; however, according to findings by the present inventors, in actual, the island component polymer streams may join with one another.
  • the sea component polymer since the sea component polymer is eluted after melt spinning, a discharge ratio of the sea component polymer to be eluted is decreased and a discharge ratio of the island component polymer is increased; however, in this case, island component polymer streams may join with one another more remarkably in some cases. Further, according to findings by the present inventors, when the island component polymer streams join with one another once, the problem may not be solved in some cases even when changing spinning conditions such as discharge amounts and a ratio between discharge amounts of the respective component polymers, and in the worst case, the production may become impossible and the productivity may be deteriorated in some cases if not changing the composite spinneret.
  • Fig. 14(a) is a sectional view showing a cross section form of a composite fiber manufactured with the composite spinneret of Patent Document 2. It is described that in the composite spinneret of Patent Document 2, a plurality of the island component discharge holes 1 are gathered into an arbitrary shape and arranged, and thereby an island shape can be formed into an arbitrary shape. It is described in Patent Document 2 that a cross section form of the resulting composite fiber, as shown in Fig. 14(a) , has a plurality of star-type cross section shapes in a cross section of one composite fiber.
  • Patent Document 5 discloses a composite spinneret using a distribution plate system and manufacturing a composite fiber having a complicated island shape.
  • Fig. 12 is a partially enlarged plan view of a lowermost layer distribution plate of the composite spinneret of Patent Document 5
  • Fig. 14(b) is a sectional view showing a cross section form of a composite fiber manufactured with a composite spinneret of Patent Document 5. Further, Figs.
  • 14(c), 14(d) are sectional views showing a cross section form of a composite fiber obtained by using the composite spinneret (employing a distribution plate system) of Patent Document 4 though the hole distributing pattern of the lowermost layer distribution plate 5 is not shown. It is described that in the composite spinneret of Patent Document 5, a cross-type cross section form can be formed by arranging 4 pieces of the sea component discharge holes 4 at an outer circumference of the island component discharge hole 1. It is described in Patent Document 5 that a cross section form of the resulting composite fiber, as shown in Fig. 14 (b) , has one cross-type cross section form in a cross section of one composite fiber.
  • one star-type or trilobal cross section can be formed in a cross section of one composite fiber by disposing a plurality the island component discharge holes 1 in a close-packed state so as to be a star-type or trilobal shape.
  • the composite spinneret is a core-sheath type in which one island-shaped cross section exists in a cross section of one composite fiber, and a plurality of island shapes cannot be formed as distinct from an islands-in-the-sea type, that is, a hole disposition pattern of the composite spinneret of a core-sheath type may not be applied directly to the composite spinneret of an islands-in-the-sea type.
  • the composite spinneret is not an islands-in-the-sea type, the resulting fiber diameter may not reach a micron-order size and hence a nano-order size in some cases.
  • a composite fiber having a cross-section shape with a complicated island shape and having a few hundred to a few thousand island components in one fiber may not be attained in some cases.
  • Fig. 13 is a schematic sectional view of the composite spinneret of Patent Document 6, and the spinneret is referred to as a pipe system spinneret.
  • Fig. 13 is a schematic sectional view of the composite spinneret of Patent Document 6, and the spinneret is referred to as a pipe system spinneret.
  • a reference numeral 30 indicates a pipe
  • a reference numeral 31 indicates a sea component polymer introduction flow path
  • a reference numeral 32 indicates an island component polymer introduction flow path
  • a reference numeral 33 indicates an upper spinneret plate
  • a reference numeral 34 indicates a middle spinneret plate
  • a reference numeral 35 indicates a lower spinneret plate
  • a reference numeral 40 indicates a distribution chamber for a sea component polymer
  • a reference numeral 41 indicates a pipe insertion hole
  • a reference numeral 42 indicates a spinneret discharge hole, respectively.
  • the spinneret of Patent Document 6 is composed of the upper spinneret plate 33 provided with the sea component polymer introduction flow paths 31, the island component polymer introduction flow paths 32 and the pipes 30; the middle spinneret plate 34 provided with the pipe insertion hole 41 with a diameter equal to or larger than an outer diameter of the pipe 30; and the lower spinneret plate 35 provided with the spinneret discharge holes 42.
  • the sea component polymer of an easy-to-elute component is guided from the sea component polymer introduction flow paths 31 to the distribution chamber 40 for a sea component polymer to fill the outer circumference of the pipe 30, but on the other hand, the island component polymer of a hard-to-elute component is guided from the island component polymer introduction flow path 32 to the pipes 30, and discharged from the pipe 30, and thereby, polymers of both components join with each other to form a sea-island composite cross section, and then a composite polymer is discharged from the spinneret discharge hole 42 through the pipe insertion holes 41, and thereby, islands-in-the-sea composite fibers can be manufactured.
  • the pipe system spinneret of Patent Document 6 has a large problem that since a pipe thickness is added for manufacturing an island, an area per a pipe is increased. Further, since the pipe 30 is press-fitted in the upper spinneret plate 33 and fixed to the upper spinneret plate 33 by welding for manufacturing a spinneret, a welding clearance is required, and since a hole for insertion of the pipe 30 is arranged, a space between pipes cannot be narrowed because of a problem of strength. Accordingly, the pipes 30 may not be arranged in a close-packed state per a unit area, and thus it may be difficult to manufacture ultrafine fibers with a fiber diameter of nano-order size in some cases.
  • the resulting shape of island is limited to a circular shape or an elliptical shape similar to the circular shape, the islands-in-the-sea composite fibers having a complicated shape such as a polygonal shape of island may not be obtained in some cases. Since this spinneret has a low degree of freedom for an arrangement of the pipes 30 and a controllable fiber cross section form is limited, it may be difficult to manufacture fibers in which complicated cross sections are layered in some cases.
  • the sea component polymer introduction flow path 31 is arranged at the outer circumference of a pipe group where the pipes 30 are arranged in a close-packed state, it is difficult to supply an adequate sea component polymer to the center of the pipe group, and particularly the island component polymer streams discharged from the pipes 30 at the center of the pipe group may join with one another in some cases.
  • the above-mentioned problem becomes more remarkable.
  • the spinneret has a problem that the spinneret has a very complicated structure and facility cost is expensive since for example, in order to arrange the sea component polymer introduction flow path 31 in the group of pipes, it is necessary to arrange the sea component polymer introduction flow path 31 by bending the pipe 30 on the way.
  • a composite spinneret for the manufacture of islands-in-the-sea composite fibers, to provide a composite spinneret which can prevent the island component polymer streams from joining with one another while increasing the hole packing density of the discharge holes for the island component polymer, and thereby, can form various fiber cross section forms, particularly heteromorphic cross sections having high degree of heteromorphy, with high accuracy while maintaining high dimensional stability of the cross section, and a method of manufacturing composite fibers in which melt spinning is performed by a composite spinning machine using the composite spinneret.
  • a composite spinneret for discharging a composite polymer stream composed of an island component polymer and a sea component polymer, comprising one or more distribution plates in which distribution holes and distribution grooves for distributing the polymer components are formed; and a lowermost layer distribution plate positioned to the downstream side of the distribution plate in the direction of the polymer spinning path and provided with a plurality of island component discharge holes and a plurality of sea component discharge holes, wherein the composite spinneret has a plurality of hole groups composed of n (n is a natural number of 3 or more, the same shall apply hereafter) island component discharge holes centered on a virtual center O and arranged on a virtual circular line C1 with a radius R1, n sea component discharge holes centered on the virtual center O and arranged on a virtual circular line C2 with a radius R2, n virtual group centers
  • the composite spinneret which has a similar hole arrangement also when the virtual group center P adjacent to the virtual center O is taken as the virtual center O.
  • the composite spinneret wherein a hole packing density of the island component discharge hole is 0.5 hole/mm 2 or more.
  • melt spinning is performed by a composite spinning machine using the above-mentioned composite spinneret in which flow-path pressure losses at the respective flow paths from the distribution plate to the island component discharge holes of the lowermost layer distribution plate are the same, and flow-path pressure losses at the respective flow paths from the distribution plate to the sea component discharge holes of the lowermost layer distribution plate are the same.
  • melt spinning is performed at a ratio of the island component polymer of 50% or more by a composite spinning machine using the composite spinneret.
  • the distribution hole refers to a hole which is formed by combining a plurality of distribution plates into one and plays a role of distributing a polymer in the direction of the polymer spinning path.
  • the distribution groove refers to a groove which is formed by combining a plurality of distribution plates into one and plays a role of distributing a polymer in the direction perpendicular to the direction of the polymer spinning path.
  • the distribution groove may be a long and thin hole (slit), or a long and thin groove may be cut.
  • the direction of the polymer spinning path refers to a main direction in which the respective polymer components flow from a metering plate to a spinneret discharge hole of a discharge plate.
  • the direction perpendicular to the direction of the polymer spinning path refers a direction perpendicular to the main direction in which the respective polymer components flow from a metering plate to a spinneret discharge hole of a discharge plate.
  • the virtual circular line C1 with a radius R1 refers to a circular line C1 of a virtual circle with a radius R1 centered on a virtual center O at the time when a virtual polygonal shape is formed with line segments connecting the centers of n island component discharge holes, the barycenter of the virtual polygonal shape is taken as a virtual center O, and a center distance between the virtual center O and the island component discharge hole forming the virtual polygonal shape is take as a radius R1.
  • the virtual circular line C2 with a radius R2 refers to a circular line C2 of a vertical circle with a radius R2 centered on a virtual center O at the time when a center distance between the virtual center O and the sea component discharge hole closest to the virtual center O is take as a radius R2.
  • the virtual circular line C3 with a radius R3 refers to a circular line C3 of a virtual circle with a radius R3 centered on a virtual center O at the time when the barycenter of a hole group of the island component discharge holes forming n virtual polygonal shapes, which are positioned on an outer circumference of the virtual circular line C3 and are closest to the virtual center O, is taken as a virtual group center P, and a center distance between the virtual center O and the virtual group center P is take as a radius R3.
  • the virtual circular line C5 with a radius R1 refers to a circular line C5 of a virtual circle with a radius R1 centered on a virtual group center P at the time when a center distance between the island component discharge hole closest to the virtual group center P and the virtual group center P is take as a radius R1.
  • the virtual circular line C6 with a radius R2 refers to a circular line C6 of a virtual circle with a radius R2 centered on a virtual group center P at the time when a center distance between the sea component discharge hole closest to the virtual group center P and the virtual group center P is take as a radius R2.
  • the phase angle ⁇ 1 between the discharge holes arranged on the C1 and the C2 refers to an angle at which a line segment connecting the virtual center O and the center of the sea component discharge hole arranged on the virtual circular line C2, and a line segment connecting the virtual center O and the center of the island component discharge hole arranged on the virtual circular line C1 intersect.
  • the phase angle ⁇ 1 between the discharge holes arranged on the C5 and the C6 refers to an angle at which a line segment connecting the virtual group center P and the center of the sea component discharge hole arranged on the virtual circular line C6, and a line segment connecting the virtual group center P and the center of the island component discharge hole arranged on the virtual circular line C5 intersect.
  • the phase angle ⁇ 2 refers to an angle at which a line segment connecting the virtual center O and the center of the sea component discharge hole arranged on the virtual circular line C2, and a line segment connecting the virtual center O and the virtual group center P arranged on the virtual circular line C3 intersect.
  • the center angle refers to an intersection angle of two line segments connecting the virtual center O and the centers of two island component discharge holes which are arranged on the virtual circular line C1 and are adjacent to each other in a circumferential direction or the centers of two sea component discharge holes which are arranged on the virtual circular line C2 and are adjacent to each other in a circumferential direction, or an intersection angle of two line segments connecting the virtual group center P and the centers of two island component discharge holes which are arranged on the virtual circular line C5 and are adjacent to each other in a circumferential direction or the centers of two sea component discharge holes which are arranged on the virtual circular line C6 and are adjacent to each other in a circumferential direction, or an intersection angle of two line segments connecting the virtual center O and two virtual group centers P which are virtually arranged on the virtual circular line C3 and are adjacent to each other in a circumferential direction.
  • the polymer flow through path refers to a path formed by communicating the distribution hole formed within the distribution plate with the distribution groove formed within the
  • the hole packing density refers to a value determined by referring to n island component discharge holes arranged on the virtual circular line C1 as one hole group for an island component, and dividing the number of hole groups for an island component by a cross section area of the discharge introduction hole.
  • the hole packing density is larger, a composite fiber is obtained which is composed of more island component polymers.
  • the island component polymer is uniformly distributed and the island component polymer streams are prevented from joining with one another while increasing the hole packing density of the discharge holes for the island component polymer, and thereby, various fiber cross sections, particularly heteromorphic cross section forms, are formed with high accuracy while maintaining high dimensional stability of the cross section.
  • FIG. 5 is a schematic sectional view of a composite spinneret used in an embodiment of the present invention
  • Fig. 7 is a view taken in the direction of arrows X-X in Fig. 5
  • Fig. 1 is a partially enlarged plan view of Fig. 7
  • Figs. 2 and 3 are respectively a partially enlarged plan view of a lowermost layer distribution plate used in another embodiment of the present invention
  • Fig. 6 is a schematic sectional view of a composite spinneret, and surroundings of a spin pack and a cooling apparatus, which are used in an embodiment of the present invention
  • Fig. 6 is a schematic sectional view of a composite spinneret, and surroundings of a spin pack and a cooling apparatus, which are used in an embodiment of the present invention
  • Fig. 5 is a schematic sectional view of a composite spinneret used in an embodiment of the present invention
  • Fig. 7 is a view taken in the direction of arrows X-X in Fig. 5
  • FIG. 8 is a schematic partial sectional view of a distribution plate and a lowermost layer distribution plate used in an embodiment of the present invention.
  • these are conceptual drawings for correctly expressing the essential points of the present invention and are simplified, and the composite spinneret of the present invention is not limited to these, and the number of holes and grooves, and a dimensional ratio of holes and grooves may be changed according to the embodiment.
  • a composite spinneret 18 used in an embodiment of the present invention is fitted in a spin pack 15 and fixed in a spin block 16, and a cooling apparatus 17 is configured immediately below the composite spinneret 18.
  • Two types or more of polymers introduced into the composite spinneret 18 respectively pass through a metering plate 9, a distribution plate 6 and a lowermost layer distribution plate 5, and are discharged from a spinneret discharge hole 42 of a discharge plate 10 and then cooled by an air stream blown out from the cooling apparatus 17 and provided with a spinning oil, and then the polymers are taken up as islands-in-the-sea composite fibers.
  • a metering plate 9 As shown in Fig. 6 , a composite spinneret 18 used in an embodiment of the present invention is fitted in a spin pack 15 and fixed in a spin block 16, and a cooling apparatus 17 is configured immediately below the composite spinneret 18.
  • Two types or more of polymers introduced into the composite spinneret 18 respectively pass through a metering plate 9, a
  • the annular cooling apparatus 17 which blows an air stream annually-inwardly is employed; however, a cooling apparatus which blows an air stream from one direction may be used.
  • a cooling apparatus which blows an air stream from one direction may be used.
  • a flow path or the like used in the existing spin pack 15 may be used, and the member does not need to be exclusive.
  • the composite spinneret 18 used in an embodiment of the present invention is configured by stacking the metering plate 9, at least one distribution plate 6, the lowermost layer distribution plate 5 and the discharge plate 10 in turn, and particularly the distribution plate 6 and the lowermost layer distribution plate 5 are preferably composed of a thin plate.
  • the metering plate 9 and the distribution plate 6, and the lowermost layer distribution plate 5 and the discharge plate 10 are positioned so as to be aligned with the center position (core) of the spin pack 18 by a locating pin, stacked, and then may be fixed by a screw or bolt, or may be metal-joined (diffusion-bonded) by thermocompression bonding.
  • the distribution plates 6, and the distribution plate 6 and the lowermost layer distribution plate 5 are preferably metal-joined (diffusion-bonded) with each other by thermocompression bonding since a thin plate is used for these plates.
  • the thickness of the thin plate is preferably in the range of 0.01 to 0.5 mm, and further suitably 0.05 to 0.3 mm.
  • the thickness of the thin plate is small, there are advantages that hole diameters, groove widths and hole pitches/groove pitches of processable holes/grooves can be reduced and hence the hole packing density can be increased.
  • the hole packing density can be more increased.
  • the hole packing density can be more increased; however, further in order to minimize uneven discharge of the island component polymer, the BT and the DMIN more preferably satisfy the expression (7) .
  • the thicknesses of the distribution plate 6 and the lowermost layer distribution plate 5 are reduced within the range of 0.01 to 0.5 mm, since the strength of the thin plate is deteriorated and bending tends to occur, a type of a polymer capable of being used may be limited in some cases (with a high viscous polymer, a pressure loss is increased and bending occurs). In this case, a whole thickness may be increased by stacking and metal-joining a plurality of thin plates to improve the strength. Further, since the strength per a plate is improved by increasing the thickness of the thin plate, there is an advantage of increasing a type of polymer capable of being used.
  • the thickness of the distribution plate having a great number of holes may be reduced, and the thickness of the distribution plate having a smaller number of holes may be increased.
  • polymers of the respective components supplied from the metering plate 9 pass through the distribution groove 8 and a distribution hole 7 of the distribution plate 6 formed by stacking at least one plate, and then are discharged from the island component discharge hole 1 for discharging an island component polymer and a sea component discharge hole 4 for discharging a sea component polymer of the lowermost layer distribution plate 5, and thereby, the polymers of the respective components join with each other to form a composite polymer stream. Thereafter, the composite polymer stream passes through a discharge introduction hole 11 and a contracting hole 12 of the discharge plate 10, and is discharged from the spinneret discharge hole 42.
  • all of diameters of the island component discharge holes 1 arranged in the lowermost layer distribution plate 5 are preferably the same, and all of diameters of the sea component discharge holes 4 arranged in the lowermost layer distribution plate 5 are preferably the same.
  • This can make the discharge velocities of the island component polymer discharged from the island component discharge hole 1 and the sea component polymer discharged from the sea component discharge hole 4 uniform, and therefore an island component cross section having excellent regularity can be attained.
  • the hole diameter of the island component discharge hole 1 may be different from that of the sea component discharge hole 4, and these hole diameters may be appropriately determined according to the ratio of the island component to the sea component.
  • the hole diameter of the island component discharge hole 1 from which a larger amount of a polymer is discharge is increased, or the hole diameter of the sea component discharge hole 4 from which a smaller amount of a polymer is discharge is decreased so that the discharge velocity (the discharge velocity refers to a value obtained by dividing a discharge flow rate by a cross section area of the island component discharge hole 1 or the sea component discharge hole 4) of the island component polymer discharged from one island component discharge hole 1 is roughly equal to the discharge velocity of the sea component polymer discharged from one sea component discharge hole 4.
  • the diameters of the island component discharge hole 1 and the sea component discharge hole 4 are preferably in the range of 0.01 to 0.5 mm, and further suitably in the range of 0.05 to 0.3 mm.
  • the island component polymer streams can be prevented from joining with one another, and various fiber cross section forms, particularly cross sections with high degree of heteromorphy (in the degree of heteromorphy referred to in the present invention, the degree of heteromorphy is high when a ratio (circumscribed circle/inscribed circle) of the diameter of a circumscribed circle to the diameter of an inscribed circle of a yarn with a heteromorphic cross section is high), can be formed with high accuracy, and this can be achieved at a high hole packing density.
  • the reason for this is that in the case where the cross section form of the island component is a circular shape or a cross-section shape with a low degree of heteromorphy (hexagonal cross section, etc.) similar to the circular shape, the island component polymer streams join with one another mainly on a line connecting between the centers of neighboring island component discharge holes 1, whereas, in the cross-section shape with a high degree of heteromorphy having an acute edge (corner) portion, the island component polymer streams join with one another not only on a line connecting between the barycenters of the island component discharge holes 1 but also between the edge portions of the neighboring island components.
  • the island component polymer streams join with one another more remarkably. That is, according to findings by the present inventors, the island component polymer streams more easily join with one another when the degree of heteromorphy of the cross-section shape of the island component becomes larger, and it becomes more difficult to achieve the high degree of heteromorphy with high production efficiency.
  • Examples of other method capable of forming a high degree of heteromorphy include, as an example of a core-sheath type composite spinneret, a method of arranging diagonally four sea component discharge holes 4 around the island component discharge hole 1, as shown in Fig. 12 .
  • the island polymer discharged from the island component discharge hole 1 joins with the sea polymer discharged from the sea component discharge hole 4 to ultimately obtain a throwing star-shaped cross section form.
  • the above hole arrangement is applied to an islands-in-the-sea type as-is, as shown in Fig.
  • the hole arrangement of the lowermost layer distribution plate 5 obtained in the composite spinneret of the core-sheath type (an island component is surrounded with one sea component) cannot be applied directly to the islands-in-the-sea type where the number of the island components is a few hundred to a few thousand.
  • the lowermost layer distribution plate 5 of an embodiment of the present invention has n island component discharge holes 1 forming virtual polygonal shapes centered on a virtual center O on a virtual circular line C1 with a radius R1, n sea component discharge holes 4 arranged on a virtual circular line C2 with a radius R2, and n virtual group centers P on a virtual circular line C3 with a radius R3, n island component discharge holes 1 centered on the virtual group center P and arranged on a virtual circular line C5 with a radius R1, and n sea component discharge holes 4 centered on the virtual group center P and arranged on a virtual circular line C6 with a radius R2 are collectively referred to as a hole group; and a plurality of the hole groups are arranged.
  • n 3 4 or 6
  • a density of arrangement of the hole group can be increased, and hence the hole packing density can be increased by arranging the discharge holes so as to have a similar hole arrangement also when the virtual group center P adjacent to the virtual center O is taken as the virtual center O.
  • the hole group cannot be periodically arranged; however, a composite fiber having a plurality of cross sections of an island component can be obtained by arranging the hole group at regular intervals, and arranging the sea component discharge holes 4 between the hole groups.
  • n is a number other than the above-mentioned numbers
  • a cross section has a shape in which the edge portions of an n-gonal cross section have projections. Further, when n is a small number, a cross-section shape with a high degree of heteromorphy can be attained.
  • a virtual polygonal shape is formed by line segments connecting the centers of three neighboring island component discharge holes 1a, 1b and 1c
  • the barycenter of the virtual polygonal shape is taken as the virtual center O
  • a center distance between the virtual center O and the island component discharge hole 1 is take as the radius R1
  • a center distance between the virtual center O and the nearest sea component discharge hole 4 is take as the radius R2
  • the barycenter of a hole group of the island component discharge holes 1 forming three virtual polygonal shapes, which are positioned on an outer circumference of the virtual circular line C3 and are closest to the virtual center O, is taken as the virtual group center P
  • a center distance between the virtual center O and the virtual group center P is take as the radius R3, R1, R2 and R3 satisfy the following expression (1) and (2)
  • each discharge hole is arranged according to the conditions (3), (4) and (5).
  • the island component has a uniform and highly heteromorphic cross section (Y-shaped cross section).
  • both the island component polymer and the sea component polymer are discharged all together toward the discharge introduction hole 11 located the downstream side of the lowermost layer distribution plate 5, flow in the direction of the polymer spinning path while expanding their width in the direction perpendicular to the direction of the polymer spinning path, and join with one another to form a composite polymer stream.
  • the radius R2 of the virtual circular line C2 forming the hole group of the sea component discharge holes 4 may be determined so as to satisfy the expressions (1) and (2) in the case where the sea component discharge holes 4 are arranged between the hole group (island component discharge holes 1a, 1b, 1c) of the island component discharge holes 1 arranged on the virtual circular line C1 and the hole group of the island component discharge holes 1 arranged on the virtual circular line C5.
  • island component polymer streams discharged from the three island component discharge holes 1a, 1b and 1c join with one another to form one heteromorphic cross section of the island component.
  • a triangular cross section whose apexes are roughly the island component discharge holes 1 is formed.
  • the sea component polymer streams are discharged from the sea component discharge holes 4 to spaces between the island component discharge holes 1a and 1b, and the island component discharge holes 1b and 1c, and the island component discharge holes 1c and 1a, and a part of the sea component polymer penetrates into a space between the island component polymer streams to join with each other, so that depressions can be formed at sides of a triangular cross section, and consequently a cross section form with a high degree of heteromorphy (Y-shaped cross section) can be formed.
  • the island component discharge holes 1a, 1b and 1c centered on the virtual center O and arranged on the virtual circular line C1 are arranged equally at a center angle of 120 degrees
  • the sea component discharge holes 4 on the virtual circular line C2 are arranged equally at a center angle of 120 degrees with a phase angle of 60 degrees
  • the three island component discharge holes 1 centered on the virtual group center P and arranged on the virtual circular line C5 with a radius R1 are arranged equally at a center angle of 120 degrees as with the pattern of hole arrangement centered on the virtual center O
  • the sea component discharge holes 4 are arranged on the virtual circular line C6 with a radius R2 equally at a center angle of 120 degrees with a phase angle of 60 degrees.
  • a sea component discharge hole 4 is arranged at a point of intersection of a line segment connecting the center points of the virtual center O and the virtual group center P, the virtual circular line C2, and the virtual circular line C6.
  • the island component polymer streams discharged from the island component discharge holes 1 arranged on the virtual circular line C1 may join with the island component polymer streams discharged from the island component discharge holes 1 arranged on the virtual circular line C5 in some cases.
  • R1 in the expression (1) is reduced, the above-mentioned joining between the island component polymer streams can be suppressed; however, the degree of heteromorphy of the resulting cross-section shape of an island component is lowered, and therefore R1 may be determined according to a desired cross section form.
  • a radius of the island component discharge hole 1, denoted by r satisfies the relationship of R1 ⁇ ⁇ 3 • r, and when R1 is in this range, a yarn with a Y-shaped cross section having a high degree of heteromorphy can be formed.
  • a hole arrangement pattern of forming the yarn with a Y-shaped cross section is characterized in that a ratio of the island component polymer can be increased, and fibers can be obtained in which the island component polymer streams do not join with one another even when the ratio of the island component polymer is as high as 70% or more and the island component has a uniform Y-shaped cross section. Moreover, since many islands can be arranged to increase the island packing density, this arrangement pattern is suitable for obtaining a composite fiber having a fiber diameter of nano-order size such as a nanofiber.
  • an arrangement pattern in which the island component has a cross-type cross section includes a pattern in which n is 4.
  • This is a pattern in which four island component discharge holes 1 centered on the virtual center O and arranged on the virtual circular line C1 with a radius R1 are arranged equally at a center angle of 90 degrees, four sea component discharge holes 4 on the virtual circular line C2 with a radius R2 are arranged equally at a center angle of 90 degrees with a phase angle of 45 degrees, four island component discharge holes 1 centered on the virtual group center P and arranged on the virtual circular line C5 with a radius R1 are arranged equally at a center angle of 90 degrees, four sea component discharge holes 4 on the virtual circular line C6 with a radius R2 are arranged equally at a center angle of 90 degrees with a phase angle of 45 degrees, and sea component discharge holes 4 are arranged at points of intersection of line segments connecting the center points of the virtual center O and the virtual group center P, the virtual circular line C2, and the virtual circular lines C6.
  • a hole arrangement pattern of forming a yarn with the cross-type cross section is characterized by arranging the sea component discharge holes 4 on the virtual circular line C2 between the hole group of the island component discharge holes 1 on the virtual circular line C1 and the hole group of the island component discharge holes 1 on the virtual circular line C5 so as to satisfy the expression (6) which is a narrower condition than the expression (1).
  • (6) R 1 ⁇ R 2 / 2
  • a radius of the island component discharge holes 1, denoted by r satisfies the relationship of R1 ⁇ 1.5 • ⁇ 2 • r.
  • an arrangement pattern in which the island component has an asteroid-type cross section includes a pattern in which n is 6.
  • This is a pattern in which six island component discharge holes 1 centered on the virtual center O and arranged on the virtual circular line C1 with a radius R1 are arranged equally at a center angle of 60 degrees, six sea component discharge holes 4 on the virtual circular line C2 with a radius R2 are arranged equally at a center angle of 60 degrees with a phase angle of 30 degrees, six island component discharge holes 1 centered on the virtual group center P and arranged on the virtual circular line C5 with a radius R1 are arranged equally at a center angle of 60 degrees, six sea component discharge holes 4 on the virtual circular line C6 with a radius R2 are arranged equally at a center angle of 60 degrees with a phase angle of 30 degrees, and sea component discharge holes 4 are arranged at points of intersection of line segment connecting center points of the virtual center O and the virtual group center P, the virtual circular line C2, and the virtual circular lines C6.
  • a hole arrangement pattern of forming a yarn with the asteroid-type cross section is characterized by arranging the sea component discharge holes 4 on the virtual circular line C2 between the hole group of the island component discharge holes 1 on the virtual circular line C1 and the hole group of the island component discharge holes 1 on the virtual circular line C5 so as to satisfy the expression (7) which is a narrower condition than the expression (1).
  • a radius of the island component discharge hole 1, denoted by r satisfies the relationship of R1 ⁇ 3 • r.
  • the stacked plural distribution plates 6 are configured in such a way that the number of the distribution holes 7 formed in the distribution plate 6 increases toward the downstream side in the direction of the polymer spinning path, and the distribution groove 8 is formed so as to communicate the distribution hole 7 positioned to the upstream side in the direction of the polymer spinning path with the distribution hole 7 positioned to the downstream side in the direction of the polymer spinning path by alternately stacking a distribution plate 6 in which a distribution hole 7 guiding a polymer in the direction of the polymer spinning path is formed, and a distribution plate 6 in which the distribution groove 8 guiding a polymer in the direction perpendicular to the direction of the polymer spinning path is formed.
  • a flow through path of a polymer of a sequential branch system is formed, in which one distribution groove 8 in communication with a position at the downstream side in the direction of the polymer spinning path is formed per one distribution hole 7 and a plurality (two in Fig. 8 ) of the distribution holes 7 in communication with an end of the distribution groove 8 are formed.
  • the lengths of paths from the distribution hole 7 or the distribution groove 8 of the distribution plate 6 positioned at the highest end in the direction of the polymer spinning path to the island component discharge holes 1 of the lowermost layer distribution plate 5 are equal.
  • the flow through path of a polymer has a structure in which hole diameters of the distribution holes 7, and widths, depths and lengths of the distribution grooves 8 are equalized in each distribution plate 6 of the stacked plural distribution plates 6.
  • a hole diameter of the distribution hole 7 or a width or depth of the distribution groove 8 is increased sequentially to suppress an increase in the flow-path pressure loss.
  • the flow through path of a polymer of a sequential branch system of two-way branch is suitable, in which one distribution groove 8 is communicated with two distribution holes 7 at the downstream side in the direction of the polymer spinning path; however, the sequential branch system is not limited to this.
  • the distribution groove 8 is communicated with two or more distribution holes 7 (the case of a flow path of a sequential branch system of two-way or more branch), it is preferred to equalize flow-path pressure losses of the flow through paths of the respective polymers by respectively equalizing groove lengths, groove widths and groove depths of the distribution groove 8 from the distribution hole 7 on the upstream side to the distribution hole 7 on the downstream side in the direction of the polymer spinning path. Further, by disposing the distribution hole 7 at an end part of the distribution groove 8, this structure has an advantage of eliminating abnormal retention of a polymer, and uniformly distributing and precisely controlling a polymer.
  • examples of other structures in which flow-path pressure losses of the flow through paths of the respective polymers are equalized, include structures with respect to a plurality of polymer flow through paths composed of the distribution hole 7 and the distribution groove 8 within the distribution plate 6, a diameter of the distribution hole 6 in a path in which a length of the polymer flow through path from an upper end of the distribution plate 6 to the lowermost layer distribution plate 5 is comparatively long is larger than a diameter of the distribution hole 6 in a path in which a length of the polymer flow through path is comparatively short, and thereby, it becomes possible to equalize flow-path pressure losses.
  • examples of other structures in which flow-path pressure losses of the flow through paths of the respective polymers are equalized, include structures in which a diameter of the island component discharge hole 1 of the lowermost layer distribution plate 5 is adjusted so that flow-path pressure losses are equalized in the respective flow paths of the distribution plate 6 on the upstream side thereof. Specifically, it becomes possible to equalize flow-path pressure losses by increasing a diameter of the island component discharge hole 1 in communication with a flow path having a large flow-path pressure loss, and decreasing a diameter of the island component discharge hole 1 in communication with a flow path having a smaller flow-path pressure loss on the upstream side.
  • a shape of the composite spinneret 18 in the present invention is not limited to a circular shape, and may be a tetragonal shape or a polygonal shape. Further, an array of the spinneret discharge holes 42 in the composite spinneret 18 may be appropriately determined according to the number of the islands-in-the-sea composite fibers, the number of lines of yarn, and the cooling apparatus 17. With respect to the cooling apparatus 17, for an annular cooling apparatus, the spinneret discharge holes 42 may be arrayed in an annular form over one column or plural columns, and for a cooling apparatus of one way, the spinneret discharge holes 42 may be arrayed in zigzag alignment.
  • a cross section of the spinneret discharge hole 42 in the direction perpendicular to the direction of the polymer spinning path is not limited to a circular shape, and may be a cross section other than the circular shape or a hollow cross section. However, when a cross section other than the circular shape is employed, a length of the spinneret discharge hole 42 is preferably lengthened in order to ensure the polymer metering capability.
  • a cross section in the direction perpendicular to the direction of the polymer spinning path is not limited to a circular shape, and may be a cross section other than the circular shape or a hollow cross section.
  • all shapes of the island component discharge holes 1 arranged in the lowermost layer distribution plate 5 are preferably the same.
  • the island component discharge hole 1 is previously shaped to a similar shape, so that fibers with a heteromorphic cross section are easily obtained.
  • the island component discharge hole 1 has a cross section other than a circular shape
  • the discharge introduction hole 11 in the present invention can mitigate a difference in flow velocities immediately after the island component polymer stream joins with the sea component polymer stream by providing a certain entrance section from a bottom surface of the lowermost layer distribution plate 5 in the direction of the polymer spinning path to stabilize a composite polymer stream.
  • a diameter of the discharge introduction hole 11 is preferably configured to be larger than an outer diameter of a virtual circle 19 of a group of discharge holes of the island component discharge holes 1 and the sea component discharge holes 4 arranged in the lowermost layer distribution plate 5, and is preferably configured in such a way that a ratio of a cross section area of the virtual circle 19 to a cross section area of the discharge introduction hole 11 is as small as possible. Accordingly, each polymer stream discharged from the lowermost layer distribution plate 5 is prevented from expanding in width and a composite polymer stream can be stabilized.
  • the contracting hole 12 in the present invention it is possible to reduce a size of the composite spinneret 18 and inhibit unstable phenomena such as draw resonance of the composite polymer stream and supply the composite polymer stream stably by setting a taper angle ⁇ of a flow path from the discharge introduction hole 11 to the spinneret discharge hole 42 to the range of 50° to 90°.
  • the island component discharge hole 1, the sea component discharge hole 4 and the distribution hole 7 in the present invention preferably have a hole cross section area which is constant in the direction of the polymer spinning path; however, the hole cross section area may gradually decrease or may increase, or may gradually decrease and increase.
  • the reason for this is that in the distribution plate 6 and the lowermost layer distribution plate 5 in the present invention, since hole processing is mainly performed by using etching processing, the hole cross section area may not become constant in some cases in processing minute holes, and in this case, processing conditions and the like may be appropriately made to be proper.
  • the number of the lowermost layer distribution plates 5 in the present invention may be one; however, a plurality of the lowermost layer distribution plates 5 may be stacked. In this case, one lowermost layer distribution plate 5 cannot achieve the polymer metering capability of the island component discharge holes 1 and the sea component discharge holes 4, and in the case where a fiber form varies with time, the metering capability of a polymer can be ensured by stacking a plurality of the lowermost layer distribution plates 5.
  • the distribution hole 7 may be arranged on the upstream side of the distribution plate 6, and the distribution groove 8 (downstream side) may be arranged in communication with the distribution hole 7, or the distribution groove 8 may be arranged on the upstream side of the distribution plate 6, and the distribution hole 7 (downstream side) may be arranged in communication with the distribution groove 8.
  • the polymer can be distributed by communicating the distribution hole 7 with the distribution groove 8 and repeating the communication once or more.
  • the distribution plate 6 and the lowermost layer distribution plate 5 of the present invention have a stack structure of thin plates.
  • the distribution hole 7 arranged at the distribution plate 6 distributes a polymer mainly in the direction of the polymer spinning path, and the distribution groove 8 distributes a polymer mainly in a direction perpendicular to the direction of the polymer spinning path.
  • a polymer By alternately stacking the distribution plate 6 having the distribution hole 7 arranged and the distribution plate 6 having the distribution groove 8 arranged, a polymer can be freely and easily distributed in a direction of the fiber cross section. By the use of this, the island component discharge holes 1 and the sea component discharge holes 4 can be arranged in an extremely narrow region.
  • the composite spinneret 18 of the present invention may be used in a publicly known composite spinning machine.
  • a spinning temperature a temperature at which principally a polymer with a high melting point or high viscosity of two types or more of polymers exhibits flowability is selected.
  • a melting point of the polymer is a standard, and the spinning temperature may be set to melting point + 60°C or lower.
  • a spinning velocity varies depending on the properties of the polymer and an object of the composite fibers, and can be set to about 500 to 6000 m/min. Particularly, when high mechanical properties are required in industrial material applications, preferably, a high molecular weight polymer is used and spun at a spinning velocity of 500 to 2000 m/min, and thereafter the resultant is stretched at a high ratio.
  • a temperature at which a polymer can be softened such as the glass transition temperature of the polymer is used as a standard, and a pre-heating temperature is appropriately set.
  • a temperature is preferably set at which fluctuations of a yarn route due to self-extension of a fiber does not occur in a pre-heating process.
  • the pre-heating temperature is generally set to about 80 to 95°C.
  • a discharge velocity ratio between polymers of the respective components discharged from the island component discharge holes 1 and the sea component discharge holes 4 of the present invention is preferably controlled by a discharge amount, a hole diameter and the number of holes.
  • a discharge velocity of the island component polymer per a single hole is denoted by Va
  • a discharge velocity of the sea component polymer is denoted by Vb
  • a ratio thereof is preferably in the range of 0.05 to 20, and more preferably in the range of 0.1 to 10
  • a cross section form is significantly stabilized and can be maintained accurately.
  • a melt viscosity ratio of the polymer used in the present invention is less than 2.0, a composite polymer stream can be stably formed.
  • the melt viscosity ratio is 2.0 or more, a composite polymer stream becomes unstable when the island component polymer joins with the sea component polymer, and uneven thickness of the resulting fiber cross section may occur in a running direction in some cases.
  • etching such as fine processing by transferring a pattern to a thin plate and chemically treating the transferred pattern, which is generally used for processing electric/electronic parts, is suitable.
  • etching processing is a processing method in which a thin plate is etched (dissolved/chemically cut) with the use of a chemical reaction/corrosive action by chemicals such as an etching solution, and in this method, an objective processing shape is subjected to anti-corrosion treatment by masking (required partial surface is partially coated/protected), and an unnecessary portion is removed with a corrosive agent such as an etching solution, and thereby, an objective processing shape can be obtained with significantly high precision.
  • a common corrosive agent is sufficient for the corrosive agent such as an etching solution.
  • nitric acid, sulfuric acid and hydrochloric acid can be used.
  • the cross section form can be altered by replacing only the distribution plate 6 and the lowermost layer distribution plate 5, and therefore this is a preferable feature recently in the progress of high performance and various kinds of fiber products.
  • As other methods of preparing the distribution plate and the lowermost layer distribution plate it is possible to employ a method of using a turning machine, machining, press, laser machining and the like which are drilling or metal precision processing used in conventional spinneret preparation.
  • the processing has a limitation on a lower limit of the thickness of a plate to be processed from the viewpoint of suppressing distortion of the processed materials, it is necessary to consider the thickness of the distribution plate 6 for applying the processing to the composite spinneret of the present invention formed by stacking a plurality of distribution plates.
  • the fibers obtained by the composite spinneret of the present invention means fibers formed by combining two types or more of polymers into one, and refer to fibers in which two types or more of polymers exist in the form of islands-in-the-sea or the like at the transverse section of the fiber.
  • two types or more of polymers referred to in the present invention includes that two types or more of polymers having different molecular structures such as polyester, polyamide, polyphenylenesulfide, polyolefin, polyethylene, and polypropylene are used; however, this also includes that within a range not impairing the stability of yarn-making, the addition amounts of delustering agents such as titanium dioxide; various functional particles such as silicon oxide, kaolin, anticoloring agent, stabilizer, antioxidant agent, deodorant, flame retarder, anti-yarn friction agent, color pigment and surface modifier; and additives or particles of organic compounds are different, and that molecular weights thereof are different, and that copolymerization thereof is performed, and the like.
  • delustering agents such as titanium dioxide
  • various functional particles such as silicon oxide, kaolin, anticoloring agent, stabilizer, antioxidant agent, deodorant, flame retarder, anti-yarn friction agent, color pigment and surface modifier
  • additives or particles of organic compounds are different, and that molecular weights thereof
  • a cross section of a single yarn of fibers obtained by the composite spinneret 18 of the present invention may have a shape such as a triangle shape or a flat shape other than a circular shape in addition to a circular shape.
  • the present invention is an extremely versatile invention, and it is not particularly limited by a single yarn fineness of the composite fibers, nor particularly limited by the number of single yarns of the composite fibers, nor particularly limited by the number of lines of yarns of the composite fibers, and may be one line of yarn or multi lines of two or more lines of yarns.
  • the islands-in-the-sea composite fiber obtained by the composite spinneret of the present invention refers to, as shown in Figs. 4 (a), 4(b) and 4(c) , a fiber in which different two types or more of polymers form an islands-in-the-sea structure
  • the islands-in-the-sea structure referred to herein is a structure in which an island portion composed of an island component polymer 13 is separated into plural portions by a sea portion composed of a sea component polymer 20) in the cross section perpendicular to the direction of a fiber axis. It is possible to obtain an islands-in-the-sea composite fiber which has a Y-shaped cross section shown in Fig.
  • the number of islands achieved by using the composite spinneret of the present invention can be theoretically from 2 to infinite as far as a space allows; however, a substantially applicable and preferable range is 2 to 10000.
  • a range where the superiority of the composite spinneret of the present invention is attained is more preferably 100 to 10000.
  • the hole packing density is preferably 0.5 hole/mm 2 or more.
  • the hole packing density is 0.5 hole/mm 2 or more, the difference from conventional composite spinneret technology is more apparent.
  • a hole packing density of 0.5 to 20 hole/mm 2 can be performed. From the viewpoint of the hole packing density, it is preferably in a range of 1 to 20 hole/mm 2 as the range where the superiority of the composite spinneret of the present invention can be achieved.
  • the islands-in-the-sea composite fibers in the present invention by eluting a sea component polymer 20, can prepare highly uniform filament type nanofibers having a circumscribing fiber diameter of 10 to 1000 nm and a fiber diameter CV% of 0 to 30% which represents fiber diameter variation, as highly reduced extremely ultrafine heteromorphic fibers unavailable from spinning of a single component.
  • This filament type nanofibers can be suitably used for finish processing an aluminum alloy substrate or a glass substrate used for magnetic recording disks with ultra high precision by forming the fibers into a sheet.
  • sheet-like products can be prepared, in which a part of islands are made to join together intentionally to control a fiber diameter distribution freely.
  • composite forms which can be manufactured by the composite spinneret 18 of the present invention have been described by way of examples of conventionally known cross section forms; however, since in the composite spinneret 18 of the present invention, the cross section form can be arbitrarily controlled, a free form can be prepared without limiting to the above-mentioned forms.
  • the strength of the composite fiber of the present invention is preferably 2 cN/dtex or more, and preferably 5 cN/dtex or more in consideration of mechanical properties required in industrial material applications.
  • a practical upper limit of the strength is 20 cN/dtex.
  • An elongation is preferably set to 2 to 60% for stretched yarns, and 2 to 25% for an industrial material field in which particularly high strength is required, and 25 to 60% for clothing.
  • the composite fiber of the present invention can be formed into multipurpose fiber products such as fiber take-up package, tow, cut fiber, cotton, fiber ball, cord, pile, textile, nonwoven fabric, paper and liquid dispersion.
  • the islands-in-the-sea composite fibers were immersed in a solution in which a sea component of an easy-to-elute component can be eluted to remove the sea component to obtain multifilaments of the island component of a hard-to elute component.
  • the easy-to-elute component is copolymerized PET formed by copolymerization of 5-sodium sulfoisophthalic acid and the like, polylactic acid (PLA) or the like
  • an alkali aqueous solution such as sodium hydroxide aqueous solution was used. Since the alkali aqueous solution can accelerate the progress of hydrolysis when it is heated to 50°C or higher, if a fluid dyeing machine or the like is used for treatment, a large amount can be treated at a time.
  • the obtained multifilaments composed of ultrafine fibers were embedded with an epoxy resin, and the embedded sample was frozen by Cryosectioning System FC•4E manufactured by Reichert, and the frozen sample was cut by Reichert-Nissei Ultracut N (ultramicrotome) equipped with a diamond knife, and the cut surfaces were photographed at a magnification of 5000 times by using VE-7800 scanning electron microscope (SEM) manufactured by KEYENCE CORPORATION. From the obtained photographs, 150 ultrafine fibers selected at random were sampled, and all circumscribed-circle diameters (fiber diameters) were measured from the photographs using image processing software (WINROOF), and an average fiber diameter and a fiber diameter standard deviation were determined.
  • SEM scanning electron microscope
  • the circumscribed-circle refers to a broken line 14 in Fig. 4 (a) .
  • the fiber diameter CV% coefficient of variation
  • the inscribed-circle refers to a broken line 19 in Fig. 4 (a) .
  • the islands-in-the-sea composite fibers were circularly knitted, and 99% or more of the easy-to-solve component in the knitted fabric was removed by immersing the composite fiber in a 3 wt% sodium hydroxide aqueous solution (80°C, bath ratio 1:100), and then multifilaments composed of ultrafine fibers were drawn out by releasing knitted fibers, and 1 m of the multifilament was weighed and was multiplied by 10000 to determine fineness. This determination was repeated 10 times, and the second place of decimals of the simple average value was rounded to determine the fineness.
  • a polymer in a chip shape was dried to a water content of 200 ppm or less by a vacuum drying machine, and the melt viscosity was measured using "Capillograph 1B" manufactured by Toyo Seiki Seisaku-sho, Ltd., while stepwisely changing the strain rate.
  • the measurement temperature was the same as the spinning temperature, and each Example or Comparative Example describes a melt viscosity at 1216/s. Incidentally, the measurement was started at 5 minutes after charging a sample into a heating furnace, and it was performed in a nitrogen atmosphere.
  • PET Polyethylene terephthalate
  • IV intrinsic viscosity
  • copolymerized PET melt viscosity: 140 Pa•s
  • IV IV of 0.58 dl/g as a sea component polymer
  • island component discharge holes per one discharge introduction hole were holed at equal intervals in a lowermost layer distribution plate for island component polymers.
  • a ratio between the sea component and the island component was set to 30/70, and the discharged composite polymer streams were cooled/solidified, and then provided with a spinning oil, and wound at a spinning speed of 1500 m/min, to obtain non-stretched fibers of 110 dtex-15 filaments (discharged amount of a single hole 2.25 g/min).
  • the wound non-stretched fibers were drawn by 3.0 times between rollers heated to 90°C and 130°C to form islands-in-the-sea composite fibers of 50 dtex-15 filaments, and 99% or more of the sea component was dissolved by the above-mentioned method to obtain 11000 multifilaments.
  • a distribution plate having holed distribution holes and a distribution plate having cut distribution grooves are alternately stacked, and at the downstream side of the distribution plate, a lowermost layer distribution plate shown in Fig. 1 is stacked thereon.
  • the distribution plate has a thickness of 0.1 mm, and holes and grooves are holed and cut under the conditions of a hole diameter of 0.2 mm, a groove width of 0.3 mm, a groove depth of 0.1 mm and a minimum hole pitch of 0.4 mm.
  • the lowermost layer distribution plate has a thickness of 0.1 mm, and island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are arranged on virtual circular lines C1 and C5 with a radius R1 of 0.22 mm and virtual circular lines C2 and C6 with a radius R2 of 0.44 mm so that n is 3 according to the expressions (1), (2) and the condition (3).
  • the island component had a Y-shaped cross section, the island component polymer streams did not join with one another, fiber diameter variation was 5.3%, the degree of heteromorphy was 2.3, and variation of the degree of heteromorphy was 4.5%, and a fiber diameter of the multifilament was 870 nm.
  • Example 2 the same composite spinneret as in Example 1 was used except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate so that n is 4 according to the expressions (1), (2) and the condition (3).
  • Six hundred island component discharge holes per one discharge introduction hole were holed at equal intervals in a lowermost layer distribution plate for island component polymers .
  • Spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1 except for changing the ratio between the sea component and the island component to 50/50 to obtain 9000 multifilaments.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.25 mm and a virtual circular line C2 with a radius R2 of 0.5 mm.
  • the island component had a cross-type cross section
  • the island component polymer streams did not join with one another
  • fiber diameter variation was 5.9%
  • the degree of heteromorphy was 2.4
  • variation of the degree of heteromorphy was 4.4%
  • a fiber diameter of the multifilament was 710 nm.
  • Example 3 the same composite spinneret as in Example 1 was used except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate so that n is 6 according to the expressions (1), (2) and the condition (3).
  • Five hundred island component discharge holes per one discharge introduction hole were holed at equal intervals in a lowermost layer distribution plate for island component polymers .
  • Spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1 except for changing the ratio between the sea component and the island component to 50/50 to obtain 7500 multifilaments.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.33 mm and a virtual circular line C2 with a radius R2 of 0.51 mm.
  • the island component had an asteroid-type cross section, the island component polymer streams did not join with one another, fiber diameter variation was 5.9%, the degree of heteromorphy was 2.3, and variation of the degree of heteromorphy was 4.8%, and a fiber diameter of the multifilament was 994 nm.
  • Example 2 The same composite spinneret as in Example 1 was used except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate as shown in Fig. 12 .
  • one island component discharge hole for an island component polymer per one discharge introduction hole and four sea component discharge holes around the island component discharge hole were holed in the lowermost layer distribution plate .
  • a ratio between the sea component and the island component was set to 50/50, and the discharged composite polymer streams were cooled/solidified, and then provided with a spinning oil, and wound at a spinning speed of 1500 m/min to obtain non-stretched fibers of 110 dtex-150 filaments (discharged amount of a single hole 2.25 g/min) .
  • the wound non-stretched fibers were drawn by 3.0 times between rollers heated to 90°C and 130°C to form islands-in-the-sea composite fibers of 36 dtex-150 filaments, and 99% or more of the sea component was dissolved by the above-mentioned method to obtain 150 multifilaments.
  • Comparative Example 2 and Comparative Example 3 will be described as a comparative example in which the same composite spinneret as in Example 1 except for changing a ratio of the radius R2 of the virtual circular line C2 to the radius R1 of the virtual circular line C1 was used, spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1, and the ratio between the sea component and the island component was varied.
  • the respective discharge holes were arranged so that the radius R1 of the virtual circular line C1 on which the island component discharge holes were arranged was 0.33 mm and the radius R2 of the virtual circular line C2 on which the sea component discharge holes were arranged was 0.44 mm, and the ratio between the sea component and the island component was set to 30/70 in Comparative Example 2 and the ratio between the sea component and the island component was set to 50/50 in Comparative Example 3 to manufacture islands-in-the-sea composite fibers.
  • the ratios of the island component polymers were as high as 50% or 70%, island component polymer streams joined with one another, and multifilaments having a Y-shaped cross section could not be obtained.
  • Comparative Example 4 will be described as a comparative example in which the same composite spinneret as in Example 2 except for changing a ratio of the radius R2 of the virtual circular line C2 to the radius R1 of the virtual circular line C1 was used, spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 2, and the ratio between the sea component and the island component was varied.
  • the respective discharge holes were arranged so that the radius R1 of the virtual circular line C1 on which the island component discharge holes were arranged was 0.35 mm and the radius R2 of a virtual circular line C2 on which the sea component discharge holes were arranged was 0.44 mm, and the ratio between the sea component and the island component was set to 50/50 to manufacture islands-in-the-sea composite fibers.
  • the island component polymer streams joined with one another, and multifilaments having a cross-type cross section could not be obtained.
  • Comparative Example 5 will be described as a comparative example in which the same composite spinneret as in Example 3 except for changing a ratio of the radius R2 of the virtual circular line C2 to the radius R1 of the virtual circular line C1 was used, spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 3, and the ratio between the sea component and the island component was varied.
  • the respective discharge holes were arranged so that the radius R1 of the virtual circular line C1 on which the island component discharge holes were arranged was 0.44 mm and the radius R2 on the virtual circular line C2 on which the sea component discharge holes were arranged was 0.51 mm, and the ratio between the sea component and the island component was set to 50/50 to manufacture islands-in-the-sea composite fibers.
  • the island component polymer streams joined with one another, and multifilaments having an asteroid-type cross section could not be obtained.
  • the present invention can be applied not only to composite spinnerets used in a common solution spinning method, but also to composite spinnerets used in a melt blowing method and a spunbonding method and further to spinnerets used in a wet spinning method and a dry-wet spinning method; however, its application range is not limited to these.
EP13758377.9A 2012-03-09 2013-02-25 Composite spinneret and method of manufacturing composite fiber Active EP2824225B1 (en)

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JP2012053048A JP5821714B2 (ja) 2012-03-09 2012-03-09 複合口金および複合繊維の製造方法
PCT/JP2013/054669 WO2013133056A1 (ja) 2012-03-09 2013-02-25 複合口金および複合繊維の製造方法

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JP6127942B2 (ja) * 2013-12-02 2017-05-17 トヨタ紡織株式会社 メルトブロー用口金及び不織布製造装置
US20160338645A1 (en) 2014-01-28 2016-11-24 Nippon Telegraph And Telephone Corporation Electrode material and device
JP6301969B2 (ja) 2014-01-28 2018-03-28 日本電信電話株式会社 生体信号検出衣料
JP6881651B2 (ja) * 2014-08-05 2021-06-02 Jnc株式会社 静電紡糸用スピナレット
JP6699093B2 (ja) * 2014-08-05 2020-05-27 Jnc株式会社 静電紡糸用スピナレット
CN104195656A (zh) * 2014-08-26 2014-12-10 江苏巨鸿超细纤维制造有限公司 一种涤纶锦纶复合丝的复合纺组件的分配板
TWI719183B (zh) 2016-04-18 2021-02-21 日商東麗股份有限公司 導電性纖維構造物、電極構件及導電性纖維構造物之製造方法
WO2018047814A1 (ja) 2016-09-07 2018-03-15 東レ株式会社 生体信号検出衣料
JP7052724B2 (ja) * 2017-06-28 2022-04-12 東レ株式会社 紡糸用パックおよび繊維の製造方法
CN109112655B (zh) * 2018-06-15 2021-03-02 高君超 原配色丝及其制备工艺
JP6494008B1 (ja) * 2018-12-11 2019-04-03 株式会社化繊ノズル製作所 複合紡糸装置
JPWO2021177171A1 (ko) 2020-03-02 2021-09-10
CN113147270B (zh) * 2021-06-02 2022-09-27 青岛森麒麟轮胎股份有限公司 一种可镶钉轮胎
WO2023171363A1 (ja) * 2022-03-11 2023-09-14 東レ株式会社 複合繊維の製造方法および複合口金
CN115262008B (zh) * 2022-08-02 2023-08-11 江苏立新化纤科技有限公司 一种制备超细双中空弹性纤维复合喷丝组件
CN116334780A (zh) * 2023-03-14 2023-06-27 桐昆集团浙江恒盛化纤有限公司 一种海星型纤维的生产制备工艺

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EP2824225A4 (en) 2015-11-11
CN104160072A (zh) 2014-11-19
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KR20140131909A (ko) 2014-11-14
EP2824225A1 (en) 2015-01-14

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