EP2566871A2 - Procédé de production de dithiine-tétracarboxy-diimides - Google Patents

Procédé de production de dithiine-tétracarboxy-diimides

Info

Publication number
EP2566871A2
EP2566871A2 EP11716588A EP11716588A EP2566871A2 EP 2566871 A2 EP2566871 A2 EP 2566871A2 EP 11716588 A EP11716588 A EP 11716588A EP 11716588 A EP11716588 A EP 11716588A EP 2566871 A2 EP2566871 A2 EP 2566871A2
Authority
EP
European Patent Office
Prior art keywords
alkyl
formula
thiourea
dichloromaleimide
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11716588A
Other languages
German (de)
English (en)
Inventor
Norbert Lui
Jens-Dietmar Heinrich
Thomas Himmler
Frank Volz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP11716588A priority Critical patent/EP2566871A2/fr
Publication of EP2566871A2 publication Critical patent/EP2566871A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
    • C07D495/14—Ortho-condensed systems

Definitions

  • the present invention relates to a novel process for the preparation of dithiine-tetracarboxy-diimides.
  • Dithiine-tetracarboxy-diimides as such are already known. It is also known that these dithiine tetracarboxiimides can be used as anthelminthics against internal parasites of animals, in particular nematodes, and have insecticidal activity (cf US Pat. No. 3,364,229). In addition, it is known that certain dithiine-tetracarboxy-diimides have antibacterial activity and have some activity against human mycoses (see II Farmaco 2005, 60, 944-947). It is also known that dithiine-tetracarboxy-diimides can be used as fungicides against phytopathogenic fungi in crop protection (compare WO 2010/043319).
  • dithiine-tetracarboxy-diimides can be used as pigments in electrophotographic photoreceptors or as dyes in paints and polymers (compare JP-A 10-251265, PL-B 143804).
  • R 1 and R 2 are the same or different and are hydrogen, for optionally mono- or polysubstituted by halogen, -OR 3 , -COR 4 -substituted Ci-Cg-alkyl, optionally mono- or polysubstituted by halogen, Ci-C / i-alkyl or Ci-C / i-haloalkyl substituted C3-C 7 -cycloalkyl, in each case optionally mono- or polysubstituted (by halogen, Ci-C / i-alkyl, Ci-C / i-haloalkyl, -COR 4 or sulfonylamino substituted aryl or aryl Ci-C 4 alkyl),
  • R 3 is hydrogen, C 1 -C 1 -alkyl, C 1 -C 4 -alkylcarbonyl or aryl which is optionally monosubstituted or polysubstituted by halogen, C 1 -C 6 -alkyl or C 1 -C 6 -haloalkyl,
  • R 4 is hydroxy, C 1 -C 4 -alkyl or C 1 -C 4 -alkoxy
  • succinic anhydride is reacted in a first stage with an amine of formula (II) optionally in the presence of a diluent.
  • the succinic acid amides of the formula (III) thus obtained are then reacted with a large excess of thionyl chloride in the presence of dioxane as diluent at room temperature, the dithiine-tetracarboxiimides of the formula (I) finally being obtained in a series of reaction steps ,
  • the dithiine-tetracarboxydiimides are optionally isolated directly from the reaction mixture or after addition of water by filtration.
  • dithiine diisoimides of the formula (IV) it is possible under certain circumstances for the dithiine diisoimides of the formula (IV) to be isolated before they are converted into the dithiine-tetracarboximides of the formula (I):
  • a disadvantage of this process is the long reaction time and the result that either the yields obtained usually do not exceed about 30-40% of theory or the purities of the isolated products are insufficient.
  • in an aqueous workup of the reaction mixture is disadvantageous that thereby large amounts of thionyl chloride are destroyed; The resulting gases (SO 2 and HCl) must be disposed of.
  • Another disadvantage is the fact that experience has shown that the product is not obtained in one portion. Rather, it is often the case that after a first product isolation by filtration from the filtrate after prolonged standing (for example, overnight), further product precipitates, which must be isolated again by filtration. Sometimes this process needs to be done again. This way of working is very cumbersome and time consuming.
  • R is R 1 or R 2 ,
  • the dichloromaleimides used as starting materials in carrying out the process according to the invention are generally defined by the formula (VI).
  • R stands for the meanings of R or R.
  • R 1 and R 2 are preferably identical or different and preferably represent hydrogen, represent optionally mono- or polysubstituted by fluorine, chlorine, bromine, -OR 3, -COR 4 substituted C ö alkyl optionally mono- or polysubstituted by chlorine, Methyl or trifluoromethyl-substituted C 3 -C 7 -cycloalkyl, each optionally mono- or polysubstituted by fluorine, chlorine, bromine, methyl, trifluoromethyl, -COR 4 , sulfonylamino-substituted phenyl or phenyl- (C 1 -C 4 -alkyl).
  • R 1 and R 2 are particularly preferably identical or different and are particularly preferably hydrogen, optionally substituted once or more by fluorine, chlorine, hydroxyl, methoxy, ethoxy, methylcarbonyloxy, carboxyl-substituted Ci-C i-alkyl, optionally mono- or polysubstituted by Chlorine, methyl or trifluoromethyl-substituted C 3 -C 7 -cycloalkyl, in each case optionally monosubstituted to trisubstituted by fluorine, chlorine, bromine, methyl, trifluoromethyl, -COR 4 , sulfonylamino, phenyl, benzyl, 1-phenethyl, 2-phenethyl or 2- methyl-2-phenethyl.
  • R 1 and R 2 are very particularly preferably identical or different and are very particularly preferably hydrogen, methyl, ethyl, n-propyl, isopropyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, in each case optionally by chlorine, methyl or trifluoromethyl substituted cyclopropyl or cyclohexyl.
  • R 1 and R 2 are insJbesondere ⁇ beyorzugt simultaneously methyl.
  • R 3 is preferably hydrogen, methyl, ethyl, methylcarbonyl, ethylcarbonyl or optionally mono- or polysubstituted by fluorine, chlorine, methyl, ethyl, n-propyl, isopropyl or trifluoromethyl-substituted phenyl.
  • R 3 particularly preferably represents hydrogen, methyl, methylcarbonyl or phenyl.
  • R is preferably hydroxy, methyl, ethyl, methoxy or ethoxy. is particularly preferably hydroxy or methoxy.
  • N-methyldichloromaleimide (VI-1), R Me, as starting material, to give, as the end product, the compound (1-1) 2,6-dimethyl-1H, 5H- [1,4-dithiino [ 2,3-c: 5,6-c '] dipyrrolyl, 3,5,7 (2H, 6H) -tetrone.
  • the process according to the invention requires no organic solvent which has to be disposed of or recovered after the end of the reaction, and achieves higher yields.
  • the thiourea is used in amounts between 0.8 and 2 moles per mole of dichloromaleimide of the formula (VI). Preferably, amounts between 0.9 and 1.7 moles of thiourea, more preferably between 1.0 and 1.3 moles of thiourea per mole of dichloromaleimide of the formula (VI).
  • the thiourea may be added to the reaction mixture in solid form or as a solution / suspension in water. Preference is given to the thiourea in water before.
  • the reaction temperature of the process according to the invention can be varied within wide limits and is between 40 ° C and 150 ° C. To achieve satisfactory space-time yields, it is preferred to work at temperatures between 50 ° C and 120 ° C; more preferably between 60 ° C and 100 ° C.
  • the Dichlormaleinklareimid of formula (VI) is preferably added at temperatures of 60 ° C to 90 ° C to the aqueous solution.
  • phase transfer catalyst In the reaction in water, if necessary, a phase transfer catalyst (PTC) may be added.
  • PTC phase transfer catalyst
  • Such compounds may, for example, be phase transfer catalysts from the series of quaternary ammonium salts or quaternary phosphonium salts.
  • This phase transfer catalyst preferably has the general formula (VII)
  • A is N or P
  • R 5 , R 6 , R 7 and R 8 are the same or different and are independently branched or unbranched ci
  • X for halogen, hydrogen sulfate, sulfate, dihydrogen phosphate, hydrogen phosphate, phosphate or
  • phase transfer catalysts of formula (VII) include: Benzyltributylammonium- bromide, benzyltributylammonium chloride, benzyltriethylammonium bromide, Benzyltriethylammoniumchlo- chloride, benzyltrimethylammonium chloride, cetyltrimethylammonium bromide, Didecyldimethylammoniumchlo- chloride, Dimethyldistearylammoniumbisulfat, Dimethyldistearylammonium methosulfate, Dodecyltrimethylam- ammonium bromide, dodecyltrimethylammonium chloride, Methyltributyl ammonium chloride, moniumhydrogensulfat Methyltributylam-, methyltricaprylyl
  • phase transfer catalysts such as 4-dialkylamino-pyridinium salts or hexaalkyl-guanidiniumsalze can be used.
  • the phase transfer catalyst can be used in the range from 0.1 to 20 mol% based on the dichloromaleic acid amide of the formula (VI).
  • the reaction time of the inventive method is between 15 minutes and 24 hours. Preference is given to working between 30 minutes and 12 hours, more preferably between 1 and 6 hours.
  • the work-up of the product is carried out by filtration.
  • the comparative example is carried out according to Chemische Berichte 1967. 100, 1559-1570 (page 1566, method B).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)

Abstract

La présente invention concerne un nouveau procédé de production de dithiine-tétracarboxy-diimides
EP11716588A 2010-05-06 2011-05-02 Procédé de production de dithiine-tétracarboxy-diimides Withdrawn EP2566871A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11716588A EP2566871A2 (fr) 2010-05-06 2011-05-02 Procédé de production de dithiine-tétracarboxy-diimides

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP10162126 2010-05-06
US34526810P 2010-05-17 2010-05-17
PCT/EP2011/056967 WO2011138281A2 (fr) 2010-05-06 2011-05-02 Procédé de production de dithiine-tétracarboxy-diimides
EP11716588A EP2566871A2 (fr) 2010-05-06 2011-05-02 Procédé de production de dithiine-tétracarboxy-diimides

Publications (1)

Publication Number Publication Date
EP2566871A2 true EP2566871A2 (fr) 2013-03-13

Family

ID=42229218

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11716588A Withdrawn EP2566871A2 (fr) 2010-05-06 2011-05-02 Procédé de production de dithiine-tétracarboxy-diimides

Country Status (9)

Country Link
US (1) US8609868B2 (fr)
EP (1) EP2566871A2 (fr)
JP (1) JP2013534904A (fr)
KR (1) KR20130065663A (fr)
CN (1) CN103270041A (fr)
BR (1) BR112012028395A2 (fr)
MX (1) MX2012012872A (fr)
RU (1) RU2012152237A (fr)
WO (1) WO2011138281A2 (fr)

Families Citing this family (209)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK2558473T3 (da) 2010-04-14 2016-12-19 Bayer Ip Gmbh Fremgangsmåde til fremstilling af dithiin-tetracarboximider
EP2611814B1 (fr) * 2010-09-03 2014-09-24 Bayer Intellectual Property GmbH Procédé de production de dithiine-tétracarboximides
EP2641908A1 (fr) * 2012-03-23 2013-09-25 Bayer CropScience AG Procédé de fabrication de dithiine-tétracarboximides
WO2017178549A1 (fr) 2016-04-12 2017-10-19 Syngenta Participations Ag Dérivés d'oxadiazole microbiocides
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AR108745A1 (es) 2016-06-21 2018-09-19 Syngenta Participations Ag Derivados de oxadiazol microbiocidas
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EP3487843A1 (fr) 2016-07-22 2019-05-29 Syngenta Participations AG Dérivés d'oxadiazole microbiocides
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US11974572B2 (en) 2017-03-31 2024-05-07 Sygenta Participations Ag Fungicidal compositions
WO2018185013A1 (fr) 2017-04-03 2018-10-11 Syngenta Participations Ag Dérivés d'oxadiazole microbiocides
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WO2024089023A1 (fr) 2022-10-25 2024-05-02 Syngenta Crop Protection Ag Dérivés hétérocycliques à activité pesticide avec des substituants contenant du soufre
WO2024089216A1 (fr) 2022-10-27 2024-05-02 Syngenta Crop Protection Ag Nouveaux composés hétéroaryl-carboxamides contenant du soufre
WO2024089191A1 (fr) 2022-10-27 2024-05-02 Syngenta Crop Protection Ag Dérivés de dihydrooxadiazine hétérobicycliques microbiocides
WO2024094575A1 (fr) 2022-10-31 2024-05-10 Syngenta Crop Protection Ag Dérivés hétérocycliques à activité pesticide avec des substituants contenant du soufre
WO2024100069A1 (fr) 2022-11-08 2024-05-16 Syngenta Crop Protection Ag Dérivés de pyridine microbiocides
WO2024100115A1 (fr) 2022-11-09 2024-05-16 Syngenta Crop Protection Ag Dérivés de pyrazole microbiocides
WO2024105104A1 (fr) 2022-11-16 2024-05-23 Syngenta Crop Protection Ag Dérivés de tétrahydroisoquinoline microbicides

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3364229A (en) * 1964-01-30 1968-01-16 Shell Oil Co 1, 4 dithiin-2, 3, 5, 6-tetracarboximides and process for their preparation
PL143804B2 (en) * 1985-10-15 1988-03-31 Univ Lodzki Process for preparing novel derivatives of 2,6-diphenyl-2,3,6,7-tetrahydro-1h,5h-1,4-dithiin-/2,3-c:5,6-c/-diprolo-1,3,5,7-tetraon substituted in phenyl ring
JP3530702B2 (ja) 1997-03-06 2004-05-24 京セラミタ株式会社 ジチオマレイン酸イミド誘導体を用いた電子写真感光体
CN1746175B (zh) * 2004-09-11 2010-06-23 张家港市国泰华荣化工新材料有限公司 巯基烷基烷氧基硅烷的制备方法
CN100448854C (zh) * 2006-06-26 2009-01-07 山东金城医药化工股份有限公司 一种制备氨噻肟酸的方法
US8865759B2 (en) 2008-10-15 2014-10-21 Bayer Intellectual Property Gmbh Use of dithiine-tetracarboximides for controlling phytopathogenic fungi

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2011138281A2 *

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BR112012028395A2 (pt) 2015-09-15
WO2011138281A3 (fr) 2015-09-03
CN103270041A (zh) 2013-08-28
KR20130065663A (ko) 2013-06-19
MX2012012872A (es) 2012-11-29
JP2013534904A (ja) 2013-09-09
RU2012152237A (ru) 2014-06-20
WO2011138281A2 (fr) 2011-11-10
US8609868B2 (en) 2013-12-17

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