EP2342365B1 - Procédé de fabrication d'un alliage de beta-gamma ti-al - Google Patents
Procédé de fabrication d'un alliage de beta-gamma ti-al Download PDFInfo
- Publication number
- EP2342365B1 EP2342365B1 EP10765988A EP10765988A EP2342365B1 EP 2342365 B1 EP2342365 B1 EP 2342365B1 EP 10765988 A EP10765988 A EP 10765988A EP 10765988 A EP10765988 A EP 10765988A EP 2342365 B1 EP2342365 B1 EP 2342365B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- base alloy
- electrode
- titanium
- tial base
- tial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 104
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 102
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000002844 melting Methods 0.000 claims abstract description 50
- 230000008018 melting Effects 0.000 claims abstract description 48
- 239000010936 titanium Substances 0.000 claims abstract description 45
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 35
- 229910010038 TiAl Inorganic materials 0.000 claims abstract description 13
- 238000010313 vacuum arc remelting Methods 0.000 claims abstract description 7
- 238000009826 distribution Methods 0.000 claims abstract 3
- 229910006281 γ-TiAl Inorganic materials 0.000 claims description 41
- 239000002131 composite material Substances 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 238000004512 die casting Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000005495 investment casting Methods 0.000 claims 1
- 239000012768 molten material Substances 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 238000000365 skull melting Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 239000000155 melt Substances 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 230000002950 deficient Effects 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000010309 melting process Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910021362 Ti-Al intermetallic compound Inorganic materials 0.000 description 1
- 229910021325 alpha 2-Ti3Al Inorganic materials 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 238000009750 centrifugal casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 210000003625 skull Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910021324 titanium aluminide Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1295—Refining, melting, remelting, working up of titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/20—Arc remelting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
Definitions
- the invention relates to a process for the production of ⁇ -TiAl base alloys by means of vacuum arc melting (VAR), which solidify completely or at least partially primarily via the ⁇ -phase.
- VAR vacuum arc melting
- Such target alloys will hereinafter be referred to as ⁇ - ⁇ -TiAl base alloy.
- the technical field of the present invention is the melt metallurgical production of ⁇ - ⁇ -TiAl alloys by means of vacuum arc melting (VAR).
- VAR vacuum arc melting
- the DE 195 81 384 T1 describes intermetallic TiAl compounds and processes for their preparation, wherein the alloy by heat treatment of an alloy having a Ti concentration of 42 to 48 atom%, an Al concentration of 44 to 47 atom%, a Nb concentration of 6 to 10 at.% And a Cr concentration of 1 to 3 at.% At a temperature in the range of 1300 to 1400 ° C.
- the DE 196 31 583 A1 discloses a method for producing an alloy TiAl-Nb product in which an alloy electrode is first prepared from the alloy components. The formation of the alloy electrode is carried out by pressing and / or sintering the alloy components to the electrode. The latter is melted off by an induction coil.
- a heat-resistant TiAl based alloy is known in which specific amounts of V and Cr are incorporated into a Ti-Al intermetallic compound for the purpose of improving heat resistance and ductility.
- a new generation of ⁇ -TiAl high performance materials has a structural design different from conventional TiAl alloys.
- ⁇ -stabilizing elements such as Cr, Cu, Hf, Mn, Mo, Nb, V, Ta and Zr is set a primary solidification path over the ⁇ -Ti phase. This results in very fine microstructure, in addition to lamellar ⁇ 2 / ⁇ colonies also contain globular ⁇ grains and globular ⁇ grains, sometimes including globular ⁇ 2 grains.
- a temperature field of melting temperature (about 1570 ° C.) at the bottom of the electrode extends to near room temperature at the electrode suspension through the material. Not far from the melt front, the critical temperature interval between 1000 and 1200 ° C is reached.
- the relatively poor ductility of the intermetallic material then leads in this zone to the fact that the stresses formed there discharge in the form of cracks, which in turn lead to the described chipping of unmelted pieces from the electrode.
- the present invention seeks to provide a method for producing a ⁇ -phase solidified ⁇ -TiAl base alloy - hereinafter referred to as ⁇ - ⁇ -TiAl base alloy - specify that Avoiding the cracking problem leads to a reliable production of such a target alloy.
- the successive remelting steps during the vacuum arc melting are thus subdivided into the melting of a primary alloy in the first remelting steps, wherein a base melted electrode is produced from a conventional ⁇ -TiAl primary alloy, and the melting of the target alloy in the form of the desired ⁇ - ⁇ -TiAl-based alloy in the last remelting step.
- the primary alloy has a deficiency of titanium and / or a deficiency of ⁇ -stabilizing elements such as Nb, Mo, Cr, Mn, V, and Ta.
- the alloy is a defined amount of titanium and / or ⁇ in the preparation of the pressed base melt electrode deprived of stabilizing elements, so that an aluminum content of the primary alloy preferably between 45 at .-% (particularly preferably 45.5 at .-%) and 50 at .-% sets.
- the contents of aluminum and ⁇ -stabilizing elements are chosen so that the solidification path of the primary alloy is at least partially via the peritectic conversion. It is thus set a structure analogous to conventional TiAl alloys, which can be processed easily in the VAR oven.
- the target alloy is readjusted by the addition of the materials originally removed from the press electrode.
- these materials are welded as cladding to form a composite electrode firmly on the outer surface of the Abschmelzelektrode to safely exclude a solid state drop into the molten bath. It is also possible to accomplish this by a sheath insert of the deficient alloy content on the inside of the Umschmelzkokille the VAR furnace.
- the VAR furnace 1 has a copper crucible 4 with a bottom plate 5.
- a water jacket 6 with water inlet 7 and 8 water outlet is arranged.
- the copper crucible 4 is also closed at the top of a vacuum bell 9, passes through the top of a lifting bar 10 vertically displaceable. At this lifting bar 10 sits the holder 11, on which the actual electrode 2 is suspended.
- a DC voltage is applied between the copper crucible 4 and the lifting rod 10, due to which a high-current arc is ignited and maintained between the electrode 2 electrically connected to the lifting rod 10 and the copper crucible 4.
- the electrode 2 is successively remelted to ingot 3 under homogenization of the alloy components.
- the target composition of the ⁇ - ⁇ -TiAl alloy is Ti-43.5Al-4.0Nb-1.0Mo-0.1B (at.%) Or Ti-A128.6-Nb9.1-Mo2.3. B0.03 (m-%).
- the composition of the primary alloy for the base melt electrode is determined by a reduction of the titanium content to Ti - 45.93Al - 4.22Nb - 1.06Mo - 0.11B (at .-%).
- a ingot 3 of the primary alloy of 200 mm in diameter and 1.4 m in length is prepared from a press electrode 2 by 2-fold VAR melting as described above, without cracking problem.
- As starting materials for the production of the pressing electrode 2 titanium sponge pure aluminum and master alloys are used.
- the entire surface area of the ingot 3 becomes of the primary alloy Pure titanium sheet 15 with a thickness of 3 mm (mass 12 kg) wound and partially welded to the outer surface 16 of the ingot 3, as shown in Fig. 2 is shown.
- the upper edge 17 of the titanium sheet 15 is completely welded over the circumference of the ingot 3 with this.
- welding point 18 are set distributed over the lateral surface 16.
- the self-consumable electrode thus assembled is remelted as a composite electrode 19 in a final melting step in the VAR furnace 1 to a ingot 3 having a diameter of 280 mm and the composition of the target alloy.
- the target composition, the feeds used and the composition of the primary alloy correspond to Embodiment 1.
- an ingot 3 having a diameter of 140 mm and a length of 1.8 m is manufactured by simply VAR-melting press electrodes 2.
- the mass of the ingot is 115 kg.
- a sheet of pure titanium with the dimensions circumference 628 mm x height 880 mm x thickness 3 mm (mass 7.6 kg) in the inserted inner surface.
- the composition of the primary alloy ingot forming the base melt electrode 2 and the titanium sheet thus provide the target composition.
- the remelting takes place in the lined with the titanium sheet copper crucible 4 to an intermediate electrode such that the outer skin of the titanium sheet is not completely melted with and remains as a stable shell.
- an intermediate electrode such that the outer skin of the titanium sheet is not completely melted with and remains as a stable shell.
- cracking may occur, but due to the mechanical stabilization by the ductile outer shell, this does not lead to cracking Drop down of electrode material in the melt reservoir 14 lead.
- the target composition, the feeds used and the composition of the primary alloy correspond to the embodiment 1, also the production of the composite electrode 19.
- the last remelting takes place in a so-called VAR skull melter, ie a vacuum arc melting device with a water-cooled, tiltable copper crucible.
- the target material's molten alloy material is poured into permanent molds made of stainless steel, which are attached to a rotating casting wheel.
- the casting bodies produced by centrifugal casting are used as starting material for the production of components from the target alloy.
- a ⁇ - ⁇ -TiAl alloy according to U.S. Patent 6,669,791 has a composition (target alloy) of Ti - 43.0Al - 6.0V (at .-%) and Ti - A129.7 - V7.8 (m%).
- the composition of the primary alloy is determined by the complete reduction of the strongly ⁇ -stabilizing element vanadium to Ti - 45.75A1 (at .-%) or Ti - A132.2 (m -%).
- the starting materials used are titanium sponge, aluminum and vanadium.
- a base melt electrode 2 is conventionally produced as an ingot of the binary TiAl primary alloy with a diameter of 200 mm and a length of 1 m by double VAR melting (mass 126 kg).
- FIG. 3 shows, along the entire surface 16 of the base melt electrode 2 along axialaxialparallel eight vanadium rods 20 with a diameter of 16.7 mm and a length of 1 m (total mass 10.7 kg) each offset by 45 ° to each other and thus uniformly over the circumference of Electrode 2 distributed welded.
- the resulting composite electrode 19 'of the binary primary alloy and the welded vanadium rods 20 is remelted in the final third melting process to an ingot of target alloy with a diameter of 300 mm in the VAR furnace 1.
- the target composition of the ⁇ -TiAl alloy corresponds to that of Embodiment 1 (Ti - 43.5A1 - 4.0Nb - 1.0Mo - 0.1 B at .-%).
- the composition of the primary alloy is determined by a complete reduction of the molybdenum content and a partial reduction of the titanium content to Ti - 49.63A1 - 4.57Nb - 0.11 B (at .-%).
- a base melt electrode 2 having a diameter of 200 mm and a length of 1 m is produced by double VAR melting.
- the ingot mass is 126 kg.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Claims (10)
- Procédé de fabrication d'un alliage de base γ-TiAl se solidifiant par la phase ß (alliage de base ß-γ-TiAl) par une fusion par arc sous vide,
caractérisé par les étapes de procédé suivantes :- fusion d'une électrode fusible de base (2) constituée d'un alliage primaire γ-TiAl traditionnel comprenant une teneur déficitaire en titane et/ou au moins en un élément de stabilisation β par rapport à l'alliage de base ß-γ-TiAl à fabriquer dans au moins une première étape de fusion par arc sous vide,- mise à l'équilibre avec une quantité de titane et/ou d'élément de stabilisation ß correspondant à la teneur déficitaire en titane et/ou en élément stabilisant ß dans une distribution homogène dans la longueur et le pourtour, et- alliage complémentaire de la quantité de titane et/ou d'élément de stabilisation ß correspondant à la teneur déficitaire en titane et/ou en élément de stabilisation ß dans l'électrode fusible de base pour la formation de l'alliage de base ß-γ-TiAl de base dans une dernière étape de fusion par arc sous vide. - Procédé de fabrication d'un alliage de base ß-γ-TiAl selon la revendication 1 caractérisé en ce que l'électrode fusible de base (2) constituée de l'alliage primaire γ-TiAl traditionnel présente une teneur en aluminium de 45 % en atomes à 50 % en atomes.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon les revendications 1 ou 2 caractérisé en ce que l'électrode fusible de base (2) présente un déficit en titane et/ou au moins en un élément jouant un rôle de stabilisation ß dans l'alliage TiAl faisant partie du groupe constitué par le B, le Cr, le Cu, le Hf, le Mn, le Mo, le Nb, le Si, le Ta, le V et le Zr.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon l'une des revendications précitées caractérisé en ce que l'électrode fusible de base (2) est fabriquée par une ou plusieurs opérations de fusion d'un des constituants de l'alliage de l'électrode fusible de base (2) en une électrode de pression présentant une distribution homogène.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon l'une des revendications précitées caractérisé en ce que, pour équilibrer la teneur déficitaire en titane et/ou en élément de stabilisation ß pour l'électrode fusible de base, une électrode composite (19, 19') est fabriquée qui est constituée de l'électrode fusible de base (2) et, sur son pourtour et sur sa longueur, d'une couche (15) d'épaisseur régulière appropriée de titane et/ou d'élément de stabilisation ß.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon la revendication 5 caractérisé en ce que la couche est constituée d'un manchon dans une plaque de titane (15) s'étendant sur la longueur de l'électrode fusible de base (2).
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon la revendication 6 caractérisé en ce que le manchon constitué de la plaque de titane (15) est fixé à l'électrode de soudure de base au moyen de points de soudure (18) uniformément distribués sur la surface du manchon (16) et/ou au moyen d'un cordon de soudure sur le rebord (17) supérieur de l'électrode de soudure (2) sur son pourtour entier.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon la revendication 6 caractérisé en ce que le manchon constitué de la plaque de titane (15) est formé par un revêtement du manchon sur la face interne de la coquille de fusion (4) du four de fusion par arc sous vide (1), où, dans une étape intermédiaire de fusion, le manchon constitué de la plaque de titane (15) est collé par fusion sur l'électrode fusible de base (2) en formant une électrode intermédiaire et ensuite l'électrode intermédiaire est fondue une nouvelle fois dans une dernière étape de fusion par arc sous vide pour la formation de l'alliage de base homogène ß-γ-TiAl.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon l'une des revendications de 1 à 4 caractérisé en ce que, pour équilibrer la teneur déficitaire en titane et/ou en élément de stabilisation ß, une quantité appropriée de titane et/ou d'élément de stabilisation ß, une électrode composite (19') est fabriquée en plus de l'électrode fusible de base, qui est constituée de l'électrode fusible de base (2) et de plusieurs tiges (20) d'épaisseur appropriée en titane et/ou en élément de stabilisation ß, disposées parallèlement à son axe longitudinal de manière uniforme sur le pourtour de l'électrode fusible de base.
- Procédé de fabrication d'un alliage de base ß-γ-TiAl selon l'une des revendications précitées, caractérisé en ce que la dernière étape de fusion par arc sous vide pour la formation de l'alliage de base ß-γ-TiAl homogène est effectuée dans un dispositif de fusion par arc sous vide sur skull, après quoi le produit liquide fondu constitué par l'alliage de base ß-γ-TiAl est coulé en pièces par fonderie de précision ou par fonderie en coquille de l'alliage de base ß-γ-TiAl.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009050603A DE102009050603B3 (de) | 2009-10-24 | 2009-10-24 | Verfahren zur Herstellung einer β-γ-TiAl-Basislegierung |
PCT/EP2010/064306 WO2011047937A1 (fr) | 2009-10-24 | 2010-09-28 | PROCÉDÉ DE FABRICATION D'UN ALLIAGE À BASE DE ß-γ-TIAL |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2342365A1 EP2342365A1 (fr) | 2011-07-13 |
EP2342365B1 true EP2342365B1 (fr) | 2013-03-06 |
Family
ID=43216184
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10765988A Active EP2342365B1 (fr) | 2009-10-24 | 2010-09-28 | Procédé de fabrication d'un alliage de beta-gamma ti-al |
Country Status (8)
Country | Link |
---|---|
US (1) | US8668760B2 (fr) |
EP (1) | EP2342365B1 (fr) |
JP (1) | JP5492982B2 (fr) |
CN (1) | CN102449176B (fr) |
DE (1) | DE102009050603B3 (fr) |
ES (1) | ES2406904T3 (fr) |
RU (1) | RU2490350C2 (fr) |
WO (1) | WO2011047937A1 (fr) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102312111B (zh) * | 2011-09-07 | 2013-02-06 | 上海交通大学 | 采用真空自耗电弧炉熔炼TiAl合金的方法 |
EP2850224A4 (fr) * | 2012-05-16 | 2016-01-20 | Gkn Aerospace Sweden Ab | Procédé d'application d'un alliage de titane sur un substrat |
JP5857917B2 (ja) * | 2012-08-28 | 2016-02-10 | 新日鐵住金株式会社 | Ni基超合金の鋳塊の製造方法 |
CN103014386B (zh) * | 2012-12-10 | 2014-07-09 | 西安诺博尔稀贵金属材料有限公司 | 一种铌钨钼锆合金铸锭的制备方法 |
CN103276229A (zh) * | 2013-06-06 | 2013-09-04 | 广西大学 | 一种减少高温结构材料Ti-40Al-10Fe合金熔炼过程中铝烧损的熔炼方法 |
EP2851445B1 (fr) * | 2013-09-20 | 2019-09-04 | MTU Aero Engines GmbH | Alliage TiAl résistant au fluage |
US9968996B2 (en) * | 2013-10-23 | 2018-05-15 | Byd Company Limited | Metal forming apparatus |
CN104532061A (zh) * | 2014-12-26 | 2015-04-22 | 北京科技大学 | 一种抗高温氧化钛铝合金及制备方法 |
DE102015103422B3 (de) * | 2015-03-09 | 2016-07-14 | LEISTRITZ Turbinentechnik GmbH | Verfahren zur Herstellung eines hochbelastbaren Bauteils aus einer Alpha+Gamma-Titanaluminid-Legierung für Kolbenmaschinen und Gasturbinen, insbesondere Flugtriebwerke |
CN104976888B (zh) * | 2015-06-08 | 2017-03-08 | 重庆钢铁(集团)有限责任公司 | 一种真空自耗冶炼炉 |
DE102015115683A1 (de) * | 2015-09-17 | 2017-03-23 | LEISTRITZ Turbinentechnik GmbH | Verfahren zur Herstellung einer Vorform aus einer Alpha+Gamma-Titanaluminid-Legierung zur Herstellung eines hochbelastbaren Bauteils für Kolbenmaschinen und Gasturbinen, insbesondere Flugtriebwerke |
RU2621500C1 (ru) * | 2015-12-21 | 2017-06-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Интерметаллический сплав на основе TiAl |
CN107385370B (zh) * | 2017-06-23 | 2019-04-05 | 太原理工大学 | Ti-44Al-4Nb-4V-0﹒3Mo合金细晶化热处理方法 |
KR102095463B1 (ko) | 2018-05-24 | 2020-03-31 | 안동대학교 산학협력단 | 우수한 고온 성형성을 가지는 TiAl계 합금 및 이를 이용한 TiAl계 합금 부재의 제조방법 |
CN110814481B (zh) * | 2019-10-30 | 2021-07-13 | 西部超导材料科技股份有限公司 | 一种钛合金用辅助电极的对焊方法 |
CN113234960A (zh) * | 2021-05-08 | 2021-08-10 | 陕西工业职业技术学院 | 一种合金的制备方法 |
CN113351838B (zh) * | 2021-05-17 | 2022-11-04 | 西部超导材料科技股份有限公司 | 一种用于钛合金铸锭制备的气体冷却装置、控制系统及控制方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1179006B (de) * | 1952-12-18 | 1964-10-01 | Crucible Steel Internat | Titanlegierungen |
JPH02277736A (ja) * | 1989-04-19 | 1990-11-14 | Mitsubishi Heavy Ind Ltd | TiAl基耐熱合金 |
US5332545A (en) * | 1993-03-30 | 1994-07-26 | Rmi Titanium Company | Method of making low cost Ti-6A1-4V ballistic alloy |
WO1996012827A1 (fr) * | 1994-10-25 | 1996-05-02 | Mitsubishi Jukogyo Kabushiki Kaisha | ALLIAGE A BASE DE COMPOSE INTERMETALLIQUE DE TiAl ET PROCEDE DE FABRICATION DUDIT ALLIAGE |
DE19631583C2 (de) * | 1996-08-05 | 2002-10-02 | Geesthacht Gkss Forschung | Verfahren zur Herstellung eines Erzeugnisses aus einer Legierung |
JP4287991B2 (ja) | 2000-02-23 | 2009-07-01 | 三菱重工業株式会社 | TiAl基合金及びその製造方法並びにそれを用いた動翼 |
DE10156336A1 (de) * | 2001-11-16 | 2003-06-05 | Ald Vacuum Techn Gmbh | Verfahren zur Herstellung von Legierungs-Ingots |
RU2269584C1 (ru) * | 2004-07-30 | 2006-02-10 | Открытое Акционерное Общество "Корпорация Всмпо-Ависма" | Сплав на основе титана |
DE102007060587B4 (de) * | 2007-12-13 | 2013-01-31 | Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH | Titanaluminidlegierungen |
CN101476061B (zh) * | 2009-02-06 | 2010-08-25 | 洛阳双瑞精铸钛业有限公司 | 一种耐高温钛铝基合金及其制备方法 |
-
2009
- 2009-10-24 DE DE102009050603A patent/DE102009050603B3/de not_active Expired - Fee Related
-
2010
- 2010-09-28 JP JP2012511306A patent/JP5492982B2/ja active Active
- 2010-09-28 US US13/130,643 patent/US8668760B2/en active Active
- 2010-09-28 ES ES10765988T patent/ES2406904T3/es active Active
- 2010-09-28 EP EP10765988A patent/EP2342365B1/fr active Active
- 2010-09-28 WO PCT/EP2010/064306 patent/WO2011047937A1/fr active Application Filing
- 2010-09-28 CN CN201080023762.3A patent/CN102449176B/zh not_active Expired - Fee Related
- 2010-09-28 RU RU2011143579/02A patent/RU2490350C2/ru active
Also Published As
Publication number | Publication date |
---|---|
RU2490350C2 (ru) | 2013-08-20 |
EP2342365A1 (fr) | 2011-07-13 |
ES2406904T3 (es) | 2013-06-10 |
RU2011143579A (ru) | 2013-05-10 |
US20110219912A1 (en) | 2011-09-15 |
JP2012527533A (ja) | 2012-11-08 |
CN102449176A (zh) | 2012-05-09 |
US8668760B2 (en) | 2014-03-11 |
JP5492982B2 (ja) | 2014-05-14 |
CN102449176B (zh) | 2014-04-16 |
DE102009050603B3 (de) | 2011-04-14 |
WO2011047937A1 (fr) | 2011-04-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2342365B1 (fr) | Procédé de fabrication d'un alliage de beta-gamma ti-al | |
DE60224514T2 (de) | Verfahren zur herstellung von blöcken aus nickelbasislegierung mit grossem durchmesser | |
DE2230317C2 (de) | Verfahren zum Gießen von metallenen Werkstücken, insbesondere Turbinenschaufeln | |
EP1287173B1 (fr) | Composant a base d'alliages gamma-tial comportant des zones de structure graduee | |
DE60002474T2 (de) | Verfahren zum giessen von halbfesten metall-legierungen | |
DE69520779T2 (de) | Verfahren zur Herstellung von einer aktiven metallenthaltenden Kupferlegierung | |
DE102015016729B4 (de) | Verfahren zur Herstellung einer Nickel-Basislegierung | |
DE3828612A1 (de) | Verfahren zur herstellung von titanlegierungen | |
EP1444065B1 (fr) | Procede de production d'alliages intermetalliques (ingots) | |
DE4016340C1 (de) | Verfahren zur Behandlung von chrom- und niobmodifizierten Titan-Aluminium-Legierungen | |
DE60001249T2 (de) | Ti-Al-(Mo,V,Si,Fe) Legierungen und Verfahren zu ihrer Herstellung | |
EP1851350B1 (fr) | Procede de moulage d'un alliage de titane | |
DE60036646T2 (de) | Giesssysteme und verfahren mit hilfskühlung der flüssigen oberfläche der giesskörper | |
AT406384B (de) | Verfahren zum elektroschlacke-strangschmelzen von metallen | |
DE102009025197B4 (de) | Verfahren zur Herstellung von Verbundmetall-Halbzeugen | |
DE3421488A1 (de) | Verfahren zum herstellen von legierungspulver und vorrichtung zur durchfuehrung des verfahrens | |
WO2003008655A2 (fr) | Piece moulee realisee en matiere gamma-ti-al intermetallique | |
DE4142941A1 (de) | Verwendung einer aushaertbaren kupferlegierung | |
DE4327227A1 (de) | Kornfeinungsmittel, seine Herstellung und Verwendung | |
DE3740732C2 (fr) | ||
JPH05214458A (ja) | チタン合金インゴットのvar 法による溶解方法 | |
DE3805503A1 (de) | Verfahren zur verbesserung von hochtemperaturlegierungen | |
DE19505689C2 (de) | Gießform zum Herstellen von Gußteilen aus reaktiven Metallen | |
DE19504359C1 (de) | Verfahren zum Herstellen von Legierungen in einem induktiv beheizten Kaltwandtiegel | |
DE69113676T2 (de) | Vorrichtung und Verfahren zum Präzisionsgiessen. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20110211 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: GUETHER, VOLKER Inventor name: FUERWITT, WILLY Inventor name: NICOLAI, HANS-PETER Inventor name: ACHTERMANN, MATTHIAS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
DAX | Request for extension of the european patent (deleted) | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: AT Ref legal event code: REF Ref document number: 599670 Country of ref document: AT Kind code of ref document: T Effective date: 20130315 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502010002484 Country of ref document: DE Effective date: 20130502 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2406904 Country of ref document: ES Kind code of ref document: T3 Effective date: 20130610 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130606 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130606 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: VDEP Effective date: 20130306 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: FG4A Ref document number: E008090 Country of ref document: EE Effective date: 20130515 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130607 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130708 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130706 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
26N | No opposition filed |
Effective date: 20131209 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502010002484 Country of ref document: DE Effective date: 20131209 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20130928 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20100928 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20130928 Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 8 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130306 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: EE Payment date: 20200921 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20200814 Year of fee payment: 11 Ref country code: BE Payment date: 20200921 Year of fee payment: 11 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: MM4A Ref document number: E008090 Country of ref document: EE Effective date: 20210930 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20210930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20220818 Year of fee payment: 13 Ref country code: RO Payment date: 20220922 Year of fee payment: 13 Ref country code: IT Payment date: 20220825 Year of fee payment: 13 Ref country code: GB Payment date: 20220819 Year of fee payment: 13 Ref country code: DE Payment date: 20220818 Year of fee payment: 13 Ref country code: AT Payment date: 20220819 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20220819 Year of fee payment: 13 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 502010002484 Country of ref document: DE Representative=s name: FORRESTERS IP LLP, DE Ref country code: DE Ref legal event code: R082 Ref document number: 502010002484 Country of ref document: DE Representative=s name: KUEHR, VERA, DIPL.-BIOL., DE |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20221003 Year of fee payment: 13 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 502010002484 Country of ref document: DE Representative=s name: FORRESTERS IP LLP, DE |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 502010002484 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230928 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 599670 Country of ref document: AT Kind code of ref document: T Effective date: 20230928 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20230928 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230928 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230928 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230928 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230930 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20240403 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230928 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230929 |