EP2164630A2 - CATALYSEUR SOUS ENVELOPPE Pd/Au À TENEUR EN HfO2, PROCÉDÉ DE PRODUCTION ET D'UTILISATION DUDIT CATALYSEUR - Google Patents

CATALYSEUR SOUS ENVELOPPE Pd/Au À TENEUR EN HfO2, PROCÉDÉ DE PRODUCTION ET D'UTILISATION DUDIT CATALYSEUR

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Publication number
EP2164630A2
EP2164630A2 EP08773355A EP08773355A EP2164630A2 EP 2164630 A2 EP2164630 A2 EP 2164630A2 EP 08773355 A EP08773355 A EP 08773355A EP 08773355 A EP08773355 A EP 08773355A EP 2164630 A2 EP2164630 A2 EP 2164630A2
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EP
European Patent Office
Prior art keywords
catalyst
catalyst support
coated
solution
precursor compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP08773355A
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German (de)
English (en)
Inventor
Alfred Hagemeyer
Gerhard Mestl
Peter Scheck
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Sued Chemie IP GmbH and Co KG
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Sued Chemie AG
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Publication of EP2164630A2 publication Critical patent/EP2164630A2/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding

Definitions

  • the present invention relates to a coated catalyst for the production of vinyl acetate monomer (VAM) comprising an oxidic porous catalyst support of Hafniumoxidein- units containing an outer shell containing metallic Pd and Au, and its preparation.
  • VAM vinyl acetate monomer
  • VAM is an important monomer building block in the production of plastic polymers.
  • the main application areas of VAM are i.a. the preparation of polyvinyl acetate, polyvinyl alcohol and polyvinyl acetal and the co- and terpolymerization with other monomers such as ethylene, vinyl chloride, acrylate, maleate, fumarate and vinyl laurate.
  • VAM is predominantly produced in the gas phase from acetic acid and ethylene by reaction with oxygen, wherein the catalysts used for this synthesis preferably contain Pd and Au as the catalytically active metals and an alkali metal component as a promoter, preferably potassium in the form of its acetate.
  • the catalytically active metals Pd and Au are presumably not present in the form of metal particles of the respective pure metal, but rather in the form of Pd / Au alloy particles of possibly different composition, although non-alloyed particles can not be excluded.
  • VAM is predominantly produced by means of so-called shell catalysts in which the catalytically active Metals of the catalyst formed as a Formkorper Katrzationstrager not completely in the entire mold body are present, but rather only in a more or less wide outer region, the so-called shell of the catalyst transformer Formkorpers are contained (see, for this purpose EP 565 952 Al , EP 634 214 Al, EP 634 209 Al and EP 634 208 Al).
  • the further inner areas of the carrier are virtually free of the catalytically active metals.
  • coated catalysts a more selective reaction is possible in many cases than with catalysts in which the carriers impregnated into the carrier core with the catalytically active components (" istragniert") are.
  • the shell catalysts known from the prior art for the preparation of VAM have, for example, catalyst supports based on silica, alumina, aluminosilicates, titanium oxide or zirconium oxide (cf., for this, EP 839 793 A1, WO 98/018553 A1, WO 2000 / 058008 Al and WO 2005/061107 Al).
  • catalyst supports based on titanium oxide or zirconium oxide are currently scarcely used, since these catalyst carriers are not long-term stable or relatively expensive with respect to acetic acid.
  • the predominant fraction of catalysts currently used for the preparation of VAM are coated catalysts with a Pd / Au shell on an oxide porous catalyst support designed as a shaped body, for example a porous, amorphous aluminosilicate support in the form of a sphere based on natural, acid-treated, calcined bentonitrile.
  • the catalyst support is usually impregnated with potassium acetate as a so-called promoter.
  • VAM shell catalysts are usually prepared by a wet-chemical process, in which the catalyst carrier with corresponding solutions of metal precursor compounds, for example by immersing the carrier in the solutions or by means of the incipient wetness method (pore filling method), in which the carrier is loaded with a solution volume corresponding to its pore volume by impregnation.
  • a wet-chemical process in which the catalyst carrier with corresponding solutions of metal precursor compounds, for example by immersing the carrier in the solutions or by means of the incipient wetness method (pore filling method), in which the carrier is loaded with a solution volume corresponding to its pore volume by impregnation.
  • the Pd / Au shell of the catalyst can be produced, for example, by first treating the catalyst support in a first step with a solution of a Pd salt, e.g. B. a Na 2 PdCl 4 - solution, soaked and then in a second step, the Pd component is fixed by applying a NaOH solution to the catalyst support in the form of their Pd hydroxide compound.
  • a solution of a gold salt e.g. As a NaAuCl 4 solution, and then the Au component are also fixed by means of NaOH.
  • the loaded catalyst support is then washed substantially free of chloride and Na ions, subsequently dried and finally reduced at 150 ° C. with ethylene.
  • the generated Pd / Au shell usually has a thickness of about 100 to 500 microns.
  • the catalyst support loaded with the noble metals is usually used with
  • Potassium acetate is not only in the outer shell loaded with precious metals, but rather the catalyst support is completely thoroughly impregnated with the promoter.
  • the catalyst carrier used can be, for example, a spherical carrier with the name "KA-160" from Süd-Chemie AG on the basis of naturally occurring acid-treated calcined benzene. tonites are used, which has a BET surface area of about 160 m 2 / g.
  • the selectivities in the preparation of VAM using the known from the prior art Pd / Au shell catalysts are about 90 mol .-% based on the ethylene used, the remaining 10 mol .-% of the reaction products consisting essentially of CO 2 exist, which is formed by total oxidation of the organic starting materials / products.
  • US Pat. No. 6,849,243 B1 describes, in addition to the use of TiO 2 as constituent of the catalyst support, the use of barium and cadmium as additional promoter metal components.
  • barium and cadmium as additional promoter metal components.
  • neodymium, titanium, magnesium, zirconium, yttrium, praseodymium, lanthanides and rubidium and their binary combinations are disclosed as additional promoters in the shell of the shell catalyst in US 2006/0135809 A1.
  • EP 1 102 635 Bl teaches the use of one or more hafnium compounds which are arranged on the support, in particular in the shell of the shell catalyst, so that the catalytically active component of the formula Pd / Au / HfO 2 obeys.
  • hafnium in addition to palladium and gold in the shell of the coated catalyst proved to be unsuccessful, in particular due to the insufficient solubility of hafnium compounds.
  • the object of the present invention was therefore to provide a novel coated catalyst, in particular for the production of VAM, which is characterized by a high activity and VAM selectivity and continues to retain the increased activity and selectivity over a long period of time.
  • a shell catalyst in particular for the production of vinyl acetate monomer (VAM) comprising an oxidic porous catalyst support having an outer shell, the outer shell containing metallic Pd and Au and wherein the framework structure of the porous catalyst support hafnium oxide units (HfO 2).
  • VAM vinyl acetate monomer
  • hafnium oxide units (HfO 2 ) is understood here to mean either discrete hafnium oxide in particle form, which firmly adheres, for example by sintering, to the framework structure of the catalyst support and thus forms an integral part of the framework structure of the support
  • silica, alumina or ZrO 2 units of the corresponding support materials by HfO 2 - units in the backbone for example in the form of HfO 4 tetrahedra in place of the SiO 4 - can contact 4 tetrahedra or ZrO, and thus have a chemical bond to the backbone structure -, AlO 4 and thus also an integral part of the framework structure.
  • HfO 2 in one form or another, is an integral part of the framework structure.
  • the replacement of the scaffolding constituents can be achieved by the person skilled in the art by methods known per se, for example even in the direct synthesis of such support materials or by solid-state ion exchange or liquid ion exchange, for example in aluminosilicates.
  • the catalyst according to the invention is distinguished by a higher activity and higher VAM selectivity than the hafnium oxide-containing VAM catalysts known from the prior art. This activity and selectivity he keeps over long periods of time.
  • the activity and selectivity were related to the conditions of the conventional VAM preparation: Typically, the reaction to produce VAM is performed in plants at 45% oxygen conversion and then the space-time yield of VAM (kg VAM per liter of catalyst per hour) is determined ,
  • a hafnium doping according to the invention leads to an increase of the RZA by> 5%, preferably even> 10%.
  • the activity advantage can be further transformed into a selectivity improvement of the catalyst of the invention of> 1%.
  • Typical values are 20-40 m 2 / g (BET) for pure HfO 2 , and about 60-120 m 2 / g (BET) for calcined acid-treated phyllosilicates with an HfO 2 content (scaffold doping) of 0.01 to 50 % By weight, preferably from 0.01 to 25% by weight.
  • the oxidic porous catalyst support either per se already formed as a homogeneous molded body, or is on a porous or non-porous shaped body of z.
  • steatite bentonite, alumina, etc. or other suitable material such as ZrO 2 or mixtures of these ma- materials applied.
  • the hafnium oxide units are preferably evenly distributed in the framework structure of the catalyst support, but also an uneven distribution in the framework structure is provided according to the invention.
  • hafnium oxide units in a corresponding form are either homogeneously distributed as individual or groups of hafnium oxide units in the framework of the porous catalyst support or that the hafnium oxide is present in the framework of the catalyst support is present in the form of hafnium oxide particles which are uniformly distributed in the framework structure of the catalyst support, in other words, the framework structure of the catalyst support. gers of a solid structure of fauxgesinterten together particles of porous oxidic catalyst support and hafnium oxide is formed. In the case of HfO 2 - scaffold-doped ZrO 2 often arise HfO 2 -ZrO 2 mixed oxides, which are preferred according to the invention.
  • the term "uniformly distributed" used according to the invention excludes those catalyst supports of which only the inner or the inner and outer surface of the porous catalyst support is coated or coated with the doping oxide or the HfO 2 is enriched only in an outer shell
  • Such catalyst supports are obtained, for example, by impregnating the surface of a porous oxidic catalyst carrier shaped body with a solution of a corresponding compound and then converting the compound into the corresponding oxide.
  • the hafnium oxide unit-containing catalyst carrier (in other words, the hafnium oxide-doped catalyst carrier) can be obtained, for example, by the following method comprising the steps of
  • step b) shaping a shaped body from the mixture obtained according to step a);
  • hafnium compounds include, but are not limited to (NH 4 J 2 [HfF 6], HfCl 4, HfO 2, HfI 3, HfCl 3, HfCl 2, HfOCl 2, HfO (NOA) 2, HfO (OAc) 2, HfB 5 , K 5 [Hf (CN) 5 ], [Hf (bipy) 3 ], Hf (SO 4 J 2 , Na 2 HfO 3 , Na 4 HfO 4 .
  • the porous oxidic catalyst support is a silicon oxide, aluminum oxide, aluminosilicate (eg zeolites), zirconium oxide, titanium oxide, a calcined acid-treated bentonite, more generally sheet silicates or a mixture of two or more comprising or being composed of the aforementioned oxides.
  • aluminosilicate eg zeolites
  • zirconium oxide titanium oxide
  • a calcined acid-treated bentonite more generally sheet silicates or a mixture of two or more comprising or being composed of the aforementioned oxides.
  • pure zirconium dioxide and calcined bentonite / sheet silicates which contain up to 20% by weight of ZrO 2 .
  • the hafnium oxide units in the framework structure of the catalyst support are contained in a proportion of 0.03 to 20 wt .-%, based on the weight of the pure catalyst support. If the hafnium oxide units are present in a proportion of less than 0.03% by weight in the framework structure of the catalyst support, the properties of the hafnium oxide which increase the activity of the shell catalyst according to the invention have only a slight effect, while above a fraction of 25% by weight. the increase in the activity of the catalyst is accompanied by a significant decrease in VAM selectivity.
  • the thickness of the Pd / Au shell can be chosen to be larger, depending smaller the surface of the catalyst support is, without significant losses of VAM selectivity.
  • the specific surface area of the catalyst support has a value of less than or equal to 160 m 2 / g, preferably one of less than 140 m 2 / g, preferably less than 135 TVi 2 Zq preferably less than 120 m 2 / g, more preferably less than 100 m 2 / g, even more preferably less than 80 m 2 / g and most preferably less than 65 m 2 / g.
  • the term "specific surface area" of the catalyst support is understood to mean the BET surface area of the support which is determined by adsorption of nitrogen in accordance with DIN 66132.
  • the catalyst support has a specific surface area in the range of 160 to 40 m 2 / g, preferably one of between 140 and 50 m 2 / g, preferably one of between 135 and 50 m 2 / g, more preferably one of between 120 and 50 m 2 / g, most preferably one of between 100 and 50 m 2 / g.
  • catalyst support refers either to a molding of the aforementioned materials or their mixtures, or a layer, the z. B. in the form of a washcoat, ie an aqueous slurry of the aforementioned materials or mixtures thereof, was applied to a porous or non-porous shaped body and thus also forms a "shell".
  • “catalyst support” thus means the part of the shell catalyst according to the invention which absorbs the metallic damage. Ie carrying the Pd / Au catalyst. From the context, it results in the present casually, if moldings are meant consisting of the porous catalyst support material. Otherwise, the term “catalyst support” refers both to a shell containing or consisting of the catalyst carrier material and to a shaped body of the materials.
  • the porous catalyst support molding of the catalyst according to the invention can be prepared, for example, based on an iron oxide-doped, calcined acid-treated bentonite by a powdered (uncalcined) acid-treated bentonite with a powdered iron compound and / or an iron solution and ground water and then intimately to is mixed to homogeneity.
  • a powdered (uncalcined) acid-treated bentonite with a powdered iron compound and / or an iron solution and ground water and then intimately to is mixed to homogeneity.
  • there are naturally occurring bentonites which already contain iron as an impurity from which more or less iron can be washed out with acid to produce an iron-doped carrier without having to add additional iron.
  • the resulting mixture is compacted into a shaped article by means known to those skilled in the art per se devices such as extruders or tablet presses and then the uncured molded body is calcined to form a stable shaped body.
  • the calcination is preferably carried out at temperatures at which a solid structure results and optionally the iron compound is converted into iron (III) oxide.
  • the size of the specific surface of the doped catalyst support depends in particular on the quality of the (bent) bentonite used, the acid treatment process of the bentonite used, ie, for example, the nature and relative to bentonite and the concentration of the inorganic acid used, the acid treatment time and the temperature, from the compression pressure as well as the calcination time and temperature as well as the calcination atmosphere.
  • Acid-treated bentonites can be obtained by treatment of bentonites with strong (Br ⁇ nsted) acids, such as, for example, sulfuric acid, phosphoric acid or hydrochloric acid.
  • strong (Br ⁇ nsted) acids such as, for example, sulfuric acid, phosphoric acid or hydrochloric acid.
  • Bentonite used in the context of the present invention is given in: Römpp, Lexikon Chemie, 10th Edition, Georg Thieme Verlag Bentonites which are particularly preferred for the purposes of the present invention are natural aluminum-containing sheet silicates which contain montmorillonite (US Pat. In the form of smectite, the bentonite is usually washed with water, dried and ground to a powder.
  • the shell catalyst according to the invention is usually prepared by subjecting a large number of shaped bodies to a batch process in whose individual process steps the shaped bodies are mediated, for example, by stirring and mixing tools, subject to relatively high mechanical loads.
  • the catalyst according to the invention can be mechanically stressed during the filling of a reactor, which can lead to an undesirable development of dust and damage to the catalyst support, in particular its located in an outer region, catalytically active shell.
  • the catalyst support therefore preferably has a hardness greater than or equal to 20 N, preferably greater than or equal to 25 N, most preferably greater than or equal to 35 N and most preferably one of greater than or equal to 40 N.
  • the determination of the hardness in the present case by means of a tablet hardness tester 8M Fa. Schleuniger Pharmatron AG determined as an average of 99 pieces coated catalysts after drying the catalyst at 130 0 C for 2 h, where the machine settings are as follows:
  • the hardness of the catalyst support can also be influenced, for example, by the variation of the process parameters during its production, for example by selecting the support material and the type of hafnium starting material and its amount, the calcination time and / or the calcination temperature of an uncured molded part formed from a corresponding support mixture. or by certain optional additives, such as methyl cellulose or magnesium stearate.
  • the catalyst according to the invention therefore comprises a shaped body as the actual catalyst support, preferably based on a correspondingly doped, calcined acid-treated bentonite or a mixed oxide based on zirconium dioxide or mixtures thereof.
  • the catalyst according to the invention in this case comprises a doped calcined acid-treated bentonite It is preferred that the proportion of calcined acid-treated bentonite is greater than or equal to 50% by weight, preferably greater than or equal to 60% by weight, preferably greater than or equal to 70% by weight, more preferably greater than or equal to 80% by weight, based on the weight of the catalyst support containing hafnium dioxide units.
  • the VAM selectivity of the catalyst according to the invention was increased as the integral pore volume of the catalyst support increases.
  • the catalyst support has an integral BJH pore volume of greater than 0.25 ml / g, preferably greater than 0.30 ml / g, and most preferably greater than 0.35 ml / g.
  • the pore volume is in the range of 0.2-0.4 ml / g.
  • the integral pore volume of the catalyst support is determined by the method of BJH by means of nitrogen adsorption.
  • the surface of the catalyst support and its integral pore volume are determined by the BET or by the BJH method.
  • the BET surface area is determined by the BET method according to DIN 66131; a publication of the BET method can also be found in J. Am. Chem. Soc. 60, 309 (1938).
  • the sample can be measured, for example, with a fully automatic nitrogen porosimeter from the company Mikromeritics, type ASAP 2010, by means of which an adsorption and a desorption isotherm are recorded.
  • the pore volume is determined from the measurement data using the BJH method (EP Barret, LG Joiner, PP Haienda, J. Am. Chem. Soc. 73 (1951, 373)). This procedure also takes into account effects of capillary condensation. Pore volumes of certain pore size ranges are determined by summing up incremental pore volumes, which are obtained from the evaluation of the adsorption isotherm according to BJH.
  • the integral pore volume according to the BJH method refers to pores with a diameter of 1.7 to 300 nm.
  • the water absorbency of the catalyst support is 40 to 75%, preferably 50 to 70% calculated as weight increase by water absorption.
  • the absorbency is determined by soaking 10 g of the carrier sample with deionized water for 30 minutes until gas bubbles no longer escape from the carrier sample. Then, the excess water is decanted and the soaked sample is blotted with a cotton cloth to free the sample from adhering moisture. Then the water-loaded carrier is weighed and the absorbency calculated according to:
  • the catalyst support has an integral pore volume according to BJH in the range of 0.25 and 0.7 ml / g, preferably in a range of 0.3 and 0.55 ml / g and very particularly preferably in the range from 0.35 to 0.5 ml / g.
  • the integral pore volume of the catalyst carrier according to BJH are formed by mesopores and macropores, preferably at least 85% and preferably at least 90%.
  • mesopores and macropores are understood to mean pores having a diameter of less than 1 nm, a diameter of 1 to 50 nm and a diameter of greater than 50 nm.
  • the catalyst carrier has an average pore diameter of 8 to 50 nm, preferably one of 9 to 20 nm and preferably one of 10 to 15 nm ,
  • the catalyst according to the invention should preferably have a bulk density of more than 0.4 g / ml, preferably one of more than 0.45 g / ml and more preferably a bulk density of between 0.45 and 0.75 g / ml.
  • the acid-treated bentonite therefore contains less than 10% by mass of Al 2 O 3 , preferably 0.1 to 3% by mass and preferably 0.3 to 1.0% by mass, based on the mass of the calcined acid-treated bentonite.
  • the acidity of the catalyst support advantageously influences the activity of the catalyst according to the invention in the gas-phase synthesis of VAM from acetic acid and ethene.
  • the catalyst support has a Bayer acidity of between 1 and 150 ⁇ val / g, preferably between 5 and 130 ⁇ val / g and more preferably between 10 and 100 ⁇ val / g.
  • the catalyst support of the catalyst according to the invention is preferably present as a so-called "shaped body.”
  • the catalyst support can basically take the form of any geometric body on which a shell, which contains catalytically active metals described below, can be applied.
  • the catalyst support as a ball, cylinder (even with rounded end faces), perforated cylinder (also with rounded faces), trilobus, "capped tablet”, tetralobus, ring, donut, star, cartwheel, "inverse” cartwheel , or is formed as a strand, preferably as a rib strand or star strand, is very particularly preferred since it can also be provided with a "shell” simply.
  • the diameter or the length and thickness of the catalyst support of the catalyst according to the invention is preferably 2 to 9 mm, depending on the geometry of the reactor tube in which the catalyst is to be used. If the catalyst support is designed as a sphere, the catalyst support preferably has a diameter of greater than 2 mm, preferably a diameter. greater than 3 mm and preferably 4 mm to 9 mm in diameter.
  • the shell of the catalyst has a thickness of less than 300 microns, preferably one of less than 200 microns, preferably one of less than 150 microns, more preferably one of less than 100 microns and even more preferably one of less than 80 microns.
  • the thickness of the shell can be optically measured by means of a microscope. Namely, the area where the noble metals Pd / Au are deposited appears black, while the non-precious areas appear white. The borderline between precious metal-containing and -free areas is usually very sharp and visually clearly visible. If the abovementioned boundary line is not sharp and can not be visually clearly identified, the thickness of the shell corresponds to the thickness of a shell, measured from the outer surface of the catalyst support, in which 95% of the noble metal deposited on the support is contained.
  • the Pd / Au shell can be formed with a relatively high thickness causing a high activity of the catalyst without a significant reduction in the VAM selectivity of the catalyst according to the invention to effect.
  • the shell of the catalyst therefore has a thickness in the range of 200 and 2000 ⁇ m to, preferably in the range of 250 and 1800 microns, most preferably in the range of 300 and 1500 microns and more preferably in the range of between 400 and 1200 microns.
  • the proportion of the catalyst in Pd is 0.5 to 2.5% by weight, preferably 0.6 to 2.3% by weight and preferably 0.7 to 2 Wt .-% based on the weight of the loaded with noble metal catalyst support.
  • the catalyst according to the invention may have a Pd content of from 1 to 20 g / l, preferably from 2 to 15 g / l and preferably from 3 to 10 g / l.
  • the Au / Pd atomic ratio of the catalyst is preferably between 0 and 1.2, preferably between 0.1 and 1, preferably between 0.3 and 0.9, and more preferably between 0.4 and 0.8.
  • the Au content of the catalyst of the present invention is from 1 to 20 g / L, preferably from 1.5 to 15 g / L, and preferably from 2 to 10 g / L.
  • the noble metal concentration should vary only relatively little over the shell thickness. That is, the profile of the noble metal concentration of the catalyst over a range of 90% of the shell thickness, with the outer and inner shell boundary regions each being spaced 5% of the shell thickness, decreases by a maximum of +/- 20% from the mean noble metal concentration of that region , in front- preferably by a maximum of +/- 15% and preferably by a maximum of +/- 10
  • hafnium oxide units are additionally present in the shell of the catalyst according to the invention, preferably in an amount of from 0.1 to 20% by weight, based on the weight of the total catalyst.
  • the shell may also contain zirconia, the content of zirconia being in the range of 10 to 20% by weight, based on the weight of the total catalyst.
  • its content of chloride is less than 250 ppm, preferably less than 150 ppm.
  • the catalyst according to the invention preferably contains at least one alkali metal compound as further promoter, preferably a potassium, a sodium, a cesium or a rubidium compound, preferably a potassium compound.
  • alkali metal compound as further promoter, preferably a potassium, a sodium, a cesium or a rubidium compound, preferably a potassium compound.
  • Suitable and particularly preferred potassium compounds include potassium acetate KOAc, potassium carbonate K 2 CO 3 , potassium hydrogen carbonate KHCO 3 and potassium hydroxide KOH, as well as all potassium compounds which convert to potassium acetate (KOAc) under the particular reaction conditions of VAM synthesis.
  • the potassium compound can be applied both before and after the reduction of the metal components to the metals Pd and Au on the catalyst support.
  • the catalyst comprises an alkali metal acetate, preferably potassium acetate.
  • the content of the catalyst of alkali metal acetate is 0.1 to 0.7 mol / 1, preferably 0.3 to 0.5 mol / 1.
  • the alkali metal / Pd atomic ratio is between 1 and 12, preferably between 2 and 10 and more preferably between 4 and 9. In this case, the smaller the surface area of the alkali metal / Pd atomic ratio Catalyst carrier is.
  • the present invention further relates to a process for the preparation of a coated catalyst according to the invention, comprising the steps of
  • any Pd or Au compound can be used as Pd and Au precursor compounds, by means of which a high The degree of dispersion of the metals can be achieved.
  • the term "degree of dispersion” is understood to mean the ratio of the number of all surface metal atoms of all metal / alloy particles of a supported metal catalyst to the total number of all metal atoms of the metal / alloy particles
  • the degree of dispersion corresponds to a relatively high numerical value since in this case as many metal atoms as possible are freely accessible for a catalytic reaction.
  • the degree of dispersion of the metal particles is 1 to 20%.
  • the values of the degree of dispersion are determined by CO adsorption.
  • the Pd and Au precursor compounds are selected from the halides, in particular chlorides, oxides, nitrates, nitrites, formates, propionates, oxalates, acetates, hydroxides, bicarbonates, amine complexes or organic complexes, for example triphenylphosphine complexes or acetylacetonate complexes , these metals.
  • Pd precursor compounds are water-soluble Pd salts.
  • the Pd precursor compounds are selected from the group consisting of Pd (NH 3 J 4 (OH) 2 , Pd (NO 3 ) 2 , K 2 Pd (OAc) 2 (OH) 2 , Pd ( NH 3 MNO 2 ), Pd (NH 3 ) 4 (NO 3 ) 2 , K 2 Pd (NO 2 ) 4 , Na 2 Pd (NO 2 J 4 , Pd (OAc) 2 , PdCl 2 and Na 2 PdCl 4 and H 2 PdCl 4 and K 2 PdCl 4 and (NH 4 ) 2 PdCl 4 and Pd (NH 3 ) 4 Cl 2 and Pd (NH 3 ) 4 (HPO 4 ) and ammonium Pd oxalate and Pd oxalate and K 2 Pd (C 2 O 4 ) 2 and Pd (II) trifluoroacetate.
  • Pd nitrite precursor compounds may also be preferred.
  • Preferred Pd nitrite precursor compounds are, for example, those obtained by dissolving Pd (OAc) 2 in a NaNO 2 solution.
  • the Au precursor compound is selected from the group consisting of
  • Au (OAc) 3 or the KAuO 2 by precipitation of the oxide / hydroxide from a solution of gold acid, washing and isolation of the precipitate and recording the same in acetic acid or KOH fresh each time.
  • Suitable solvents for the precursor compounds are all solvents in which the selected precursor compounds are soluble and which, after application to the catalyst support, can easily be removed therefrom by drying.
  • Preferred solvent examples of the metal acetates as precursor compounds are, in particular, unsubstituted carboxylic acids, in particular acetic acid, and, for the metal chlorides, especially water or dilute hydrochloric acid. If the precursor compounds are not sufficiently soluble in acetic acid, water or dilute hydrochloric acid or mixtures thereof, alternatively or in addition to the solvents mentioned, other solvents may also be used.
  • Other solvents which may be considered here are preferably those solvents which are inert and which are miscible with acetic acid or water.
  • Preferred solvents which are suitable as an additive to acetic acid are ketones, for example acetone or acetylacetone, furthermore ethers, for example tetrahydrofuran or dioxane, acetonitrile, dimethylformamide and solvents based on hydrocarbons such as benzene, but also in others Embodiments can be used as the sole solvent.
  • Preferred solvents which are suitable as additives to water are ketones, for example acetone, or alcohols, for example ethanol or isopropanol or methoxyethanol, lyes, such as aqueous KOH or NaOH, or organic acids, such as acetic acid, formic acid, citric acid, tartaric acid, apples - Acid, glyoxylic acid, glycolic acid, oxalic acid, pyruvic acid or lactic acid, called, but which can also be used in other embodiments as the sole solvent.
  • ketones for example acetone
  • alcohols for example ethanol or isopropanol or methoxyethanol
  • lyes such as aqueous KOH or NaOH
  • organic acids such as acetic acid, formic acid, citric acid, tartaric acid, apples - Acid, glyoxylic acid, glycolic acid, oxalic acid, pyruvic acid or lactic acid, called, but which can also be used in other embodiments as the sole solvent.
  • chloride compounds are used as precursor compounds, it must be ensured that the chloride ions are reduced to a tolerable residual amount before use of the catalyst prepared by the process according to the invention, since chloride is a catalyst poison.
  • the catalyst carrier is usually washed extensively with water after fixing the Pd and Au components of the Pd or Au precursor compound on the catalyst support. This is generally done either immediately after fixation by Hydroxide precipitation of the Pd and Au components by means of lye or after the reduction of the noble metal components to the respective metal / alloy.
  • chloride-free Pd and Au precursor compounds are used and chloride-free solvents in order to keep the content of the catalyst of chloride as low as possible and to avoid a complex chloride-free washing.
  • the corresponding acetate compounds are preferably used as precursor compounds, since they contaminate the catalyst support only to a very limited extent with chloride.
  • the deposition of the Pd and Au precursor compounds onto the catalyst support in the region of an outer shell of the catalyst support can be achieved by processes known per se. So the order of the precursor solutions can be made by impregnation by immersing the carrier in the precursor solutions or impregnated according to the Incipient-wetness method. Subsequently, a base, for example sodium hydroxide solution or potassium hydroxide solution, is applied to the catalyst support, whereby the noble metal components in the form of hydroxides are precipitated onto the support. For example, it is also possible first to impregnate the carrier with caustic and then to apply the precursor compounds to the carrier pretreated in this way. The same applies if in addition hafnium oxide is present in the shell, wherein likewise preferably water-soluble hafnium compounds are used.
  • a base for example sodium hydroxide solution or potassium hydroxide solution
  • the Pd and the Au precursor compound is applied to the catalyst support by the catalyst support with the solution of Pd- Precursor compound and with the solution of the Au precursor compound or with a solution containing both the Pd and the Au precursor compound is soaked.
  • the active metals Pd and Au and, if appropriate, Hf are applied starting from chloride compounds in the region of a shell of the support on the same by means of impregnation.
  • this technique has reached its limits in terms of minimum shell thicknesses and maximum Au loading and maximum Hf loading.
  • the shell thickness of the corresponding known VAM catalysts is about 100 ⁇ m and it is not foreseeable that still thinner shells can be obtained by means of impregnation.
  • higher Au loadings within the desired shell by impregnation are difficult to realize because the Au precursor compounds tend to diffuse from the shell to inner zones of the catalyst support body, resulting in wide Au shells that are scarcely in regions mixed with Pd.
  • the active metals, or rather their precursor compounds can for example also be applied to the carrier by means of so-called physical methods.
  • the support can preferably be sprayed, for example, with a solution of the precursor compounds, the catalyst support being moved in a coating drum in which warm air is blown in so that the solvent evaporates rapidly.
  • the solution of the Pd precursor compound and the solution of the Au precursor compound is applied to the catalyst support by spraying the solutions onto a fluidized bed or a fluidized bed of the catalyst support, preferably way by means of an aerosol of the solutions.
  • the shell thickness can be adjusted continuously and optimized, for example up to a thickness of 2 mm. But even very thin shells with a thickness of less than 100 microns are possible.
  • the abovementioned embodiment of the method according to the invention can be carried out by means of a fluidized bed system or fluidized bed system. It is particularly preferred if there is a so-called controlled air sliding layer in the system.
  • the catalyst carrier shaped bodies are thoroughly mixed by the controlled air sliding layer, while they rotate about their own axis, whereby they are dried uniformly by the process air.
  • the catalyst carrier shaped bodies pass the spraying process (application of the precursor compounds) in almost constant frequency.
  • a substantially uniform shell thickness of a treated batch of moldings is achieved. Furthermore, it is achieved that the noble metal concentration varies only relatively small over a relatively large range of shell thickness, ie that the noble metal concentration over a large range of shell thickness describes approximately a rectangular function, whereby a substantially uniform activity of the resulting catalyst on the thickness of the Pd / Au shell is ensured.
  • Suitable drageeing drums, fluidized bed systems or fluidized bed systems for carrying out the method according to the invention in accordance with preferred embodiments are known in the art and are described, for example, in US Pat.
  • the catalyst support is heated during the application of the solutions, for example by means of heated process air.
  • the degree of heating of the catalyst supports can be used to determine the drying rate of the applied solutions of the noble metal precursor compounds.
  • the rate of desiccation is relatively slow, so that, given appropriate quantitative coverage, the formation of larger shell thicknesses may occur due to the high diffusion of precursor compounds due to the presence of solvent.
  • the rate of desiccation is relatively high, so that solution of the precursor compounds coming into contact with the shaped body dries almost instantaneously, so solution applied to the catalyst support can not penetrate deeply into it.
  • relatively small shell thickness can be obtained with high precious metal loading.
  • the precursor compounds For the application of the precursor compounds to the catalyst support, preference is usually given to using aqueous Na 2 PdCl 4 and NaAuCl 3 solutions. These metal salt solutions are normally applied to the support at room temperature and then the metal components are fixed with NaOH as insoluble Pd or Au hydroxides. Thereafter, the loaded carrier is usually washed free of chloride with water.
  • the Au fixation is associated with disadvantages such as long exposure times of the base to induce the precipitation of the stable Au-Tetrachlorokomplexes, incomplete precipitation and associated poor Au retention.
  • the method comprises the steps of
  • a second solution of a Pd and / or an Au precursor compound is provided, wherein the first solution precipitates the noble metal component (s) of the precursor compound.
  • ferharm / en the second solution causes and vice versa;
  • This embodiment of the method according to the invention uses two mutually different precursor solutions, one of which, for example, contains one Pd and the other an Au precursor compound.
  • one of the solutions has a basic and the other an acidic pH, as a rule.
  • the application of the solutions to the catalyst support is usually carried out by first impregnating the support with the first and then in a subsequent step with the second solution as described above by impregnation. When applying the second solution, the two solutions are then combined on the support, whereby the pH of the solutions changes and the Pd or Au component of the respective precursor compound is precipitated onto the support, without having a as in the state oftechnik usual auxiliary base such as NaOH or KOH must be applied to the carrier.
  • the abovementioned embodiment of the method according to the invention is therefore based on an impregnation of the catalyst support with the first solution of a Pd and / or Au precursor compound and the second solution of a Pd and / or Au precursor compound, the two solutions being incompatible with one another, ie that the first solution causes a precipitation of the noble metal component (s) of the precursor compound (s) of the second solution, and vice versa, so that in the contact zone of both solutions both the preimpregnated Pd / Au component (s) and the postimpregnated Pd - / Au Component / n precipitate almost simultaneously and thus lead to an intimate Pd / Au mixing. Between the two impregnation steps can be optionally dried.
  • Suitable aqueous solutions of Pd precursor compounds for impregnation with incompatible solutions are listed by way of example in Table 1.
  • the corresponding diamine complexes with ethylenediamine as ligand or the complexes with ethanolamine as ligand can also be used.
  • Suitable combinations of incompatible solutions for base-free precipitation of the noble metal components are, for example, a PdCl 2 and a KAuO 2 solution; a Pd (NOs) 2 and a KAuO 2 solution; a Pd (NH 3 ) 4 (OH) 2 and an AuCl 3 or HAuCl 4 solution.
  • Pd can also be precipitated with incompatible Pd solutions and analogously to Au with incompatible Au solutions, for example by contacting a PdCl 2 solution with a Pd (NH 3 ) 4 (OH) 2 - Solution or a HAuCl 4 - with a KAuO 2 solution.
  • PdCl 2 solution with a Pd (NH 3 ) 4 (OH) 2 - Solution or a HAuCl 4 - with a KAuO 2 solution.
  • a mixed solution is a solution containing PdCl 2 and AuCl 3 , whose noble metal components have a KAuO 2 solution can be precipitated, or a solution containing Pd (NH 3 ) 4 (OH) 2 and KAuO 2 whose noble metal components can be precipitated with a solution containing PdCl 2 and HAuCl 4 .
  • Another example of a mixed solution is the pair HAuCl 4 and KAuO 2 .
  • the impregnation with the incompatible solutions is preferably carried out by impregnation or by spray impregnations, the incompatible solutions being sprayed simultaneously, for example, by one or more double nozzles or simultaneously by two nozzles or nozzle groups or sequentially by one or more nozzles.
  • Impregnation with the incompatible solutions may result in thinner shells due to the rapid immobilization (fixation) of the metallic components of the precursor compounds in the shell, and the concomitant shortened Pd and Au diffusion, than the conventional use of mutually compatible solutions.
  • fixation the metallic components of the precursor compounds in the shell
  • the concomitant shortened Pd and Au diffusion than the conventional use of mutually compatible solutions.
  • high precious metal contents in thin shells, improved metal retention, faster and more complete precipitation of the noble metals, the reduction of the interfering Na residual content of the carrier, the simultaneous fixation of Pd and Au in only one fixing step and the omission of the NaOH costs and the NaOH handling and avoidance of a mechanical weakening of the carrier by contact with excess NaOH can be achieved.
  • the catalyst support is subjected to a fixing step for fixing the noble metal component (s) Precursor compound (s) on the catalyst support.
  • the fixation step may, as already stated above, include the treatment of the support with caustic or a calcination of the support for transferring the noble metal component (s) into a hydroxide compound (s) or into an oxide.
  • the fixing step may also be omitted and reduced directly, e.g. in the gas phase.
  • the doped catalyst support as a powder and to impregnate it with the precursor compounds of the active metals.
  • the pretreated powder can then be applied in the form of a washcoat to a suitable shaped body, for example a sphere made of steatite or a KA-160 support, and then further processed by calcination and reduction to give the catalyst.
  • the invention relates to a second process for preparing a coated catalyst according to the invention, comprising the steps of a) providing a powdery oxidic porous catalyst support containing hafnium oxide (HfO 2 ) units in its framework structure and wherein the catalyst support is loaded with a Pd and an Au precursor compound or with Pd and Au particles;
  • the said method can also be carried out by first applying the powder-shaped catalyst support not loaded with noble metal to a shaped body and only then applying the noble metals.
  • the support can be calcined to convert the noble metal components into the corresponding oxides.
  • the calcination is preferably carried out at temperatures of less than 700 0 C. Particularly preferably between 300-450 0 C with access of air.
  • the calcination time depends on the calcination temperature and is preferably chosen in the range of 0.5-6 hours. At a calcination temperature of about 400 ° C., the calcination time is preferably 1-2 hours. At a calcination temperature of 300 ° C., the calcination time is preferably up to 6 hours.
  • the noble metal components are typically reduced before the use of the catalyst, wherein the reduction in situ, ie in the process reactor, or ex situ, ie in a special reduction reactor, can be performed.
  • the reduction in situ is preferably carried out with ethylene (5% by volume) in nitrogen at a temperature of about 150 ° C. over a period of, for example, 5 hours.
  • the reduction can situ ex, for example, 5 vol .-% hydrogen in nitrogen, for example by forming gas, are carried out at temperatures in the range of preferably 150-500 0 C over a period of 5 hours.
  • Gaseous or vaporizable reducing agents such as CO, NH 3 , formaldehyde, methanol and hydrocarbons may also be used, which gaseous reducing agents may also be diluted with inert gas such as carbon dioxide, nitrogen or argon.
  • inert gas such as carbon dioxide, nitrogen or argon.
  • an inert gas diluted reducing agent is used.
  • the reduction of the noble metals can also be carried out in the liquid phase, preferably by means of the reducing agents hydrazine, K-formate, H 2 O 2 or Na-hypophosphite, K-hypophosphite, hypophosphorous acid.
  • the amount of reducing agent is preferably chosen so that during the treatment time at least the necessary for the complete reduction of the noble metal components equivalent is passed over the catalyst. Preferably, however, an excess of reducing agent is passed over the catalyst to ensure rapid and complete reduction. Preferably, it is depressurized, ie at an absolute pressure of about 1 bar, reduced.
  • a rotary kiln or fluidized bed reactor is preferably used to ensure a uniform reduction of the catalyst.
  • the invention furthermore relates to the use of the catalyst according to the invention as oxidation catalyst, as hydrogenation / dehydrogenation catalyst, as catalyst in hydrodesulfurization, as hydrodenitrification catalyst, as hydrodeoxigenation catalyst or as catalyst in the synthesis of alkenylalkanoates, in particular in the synthesis of vinyl acetate monomer, in particular in the gas phase oxidation of ethylene and acetic acid to vinyl acetate monomer.
  • the catalyst according to the invention is preferably used for the production of VAM. This is generally carried out by passing acetic acid, ethylene and oxygen or oxygen-containing gases at temperatures of 100-200 0 C, preferably 120-200 ° C, and at pressures of 1-25 bar, preferably 1-20 bar, over the catalyst of the invention, wherein unreacted starting materials can be recycled.
  • the oxygen concentration is expediently kept below 10% by volume.
  • a dilution with inert gases such as nitrogen or carbon dioxide is advantageous.
  • carbon dioxide is suitable for dilution since it is formed in small amounts in the course of VAM synthesis.
  • the resulting vinyl acetate is isolated by suitable methods described, for example, in US 5,066,365 A.
  • Example 1 The following exemplary embodiments serve to explain the invention without it being to be understood as limiting:
  • Example 1 The following exemplary embodiments serve to explain the invention without it being to be understood as limiting:
  • the resulting mixture was taken up in water and made into a dough by means of a mixer from which spherical shaped bodies were prepared under pressure by means of a tablet press.
  • the balls were calcined at a temperature of 640 0 C over a period of 4 h.
  • the shaped bodies thus obtained have the characteristics listed in Table 3:
  • the carrier beads were fluidized under the above conditions over a period of 30 minutes with a 0.05 molar NaOH solution.
  • the NaOH was allowed to act on the moldings for 16 hours.
  • the supports were washed extensively with water in the fluidized bed apparatus to free the support as much as possible from alkali metal and chloride introduced into the support via the noble metal compounds and NaOH.
  • the molded bodies were dried in the fluidized bed apparatus at a temperature of 200 to 250 ° C.
  • the resulting coated catalyst contained about 1.2% by weight of Pd and had an Au / Pd atomic ratio of about 0.5, a shell thickness of about 170 ⁇ m and a hardness of 37 N.
  • the noble metal concentration of the Pd / Au coated catalyst thus produced deviated over a range of 90% of the shell thickness, with the outer and inner shell boundary areas each spaced 5% of the shell thickness, from the average noble metal concentration of this region by a maximum of +/- 10 % off.
  • the HfO 2 / ZrO 2 powder thus obtained has the characteristics listed in Table 4:
  • the HfO 2 / ZrO 2 powder was mixed with 30 g of a 20% zirconate ZrO (OAc) 2 solution as a binder, stirred for Ih and then sprayed onto 75 g KA-O (Süd-Chemie). The held balls were calcined at 600 0 C for 5h. The result was a Hf ⁇ 2 / Zr ⁇ 2 shell of 261 ⁇ m.
  • OAc a 20% zirconate ZrO
  • the carrier beads were fluidized under the above conditions over a period of 30 minutes with a 0.05 molar NaOH solution.
  • the NaOH was allowed to act on the moldings for 16 hours.
  • the supports were washed extensively with water in the fluidized bed apparatus to free the support as much as possible from alkali metal and chloride introduced into the support via the noble metal compounds and NaOH.
  • the molded bodies were dried in the fluidized bed apparatus at a temperature of 200 to 250 ° C.
  • the moldings After drying the moldings, they were reduced to a Pd / Au coated catalyst with a gas mixture of ethylene (5% by volume) in nitrogen at a temperature of about 150 ° C. in the fluidized bed apparatus.
  • the resulting coated catalyst contained about 1.2 mass% Pd and had an Au / Pd atomic ratio of about 0.5, a shell thickness of about 210 microns and a hardness of 43 N.
  • the noble metal concentration of the Pd / Au coated catalyst thus produced deviated over a range of 90% of the shell thickness, with the outer and inner shell boundary areas each spaced 5% of the shell thickness, from the average noble metal concentration of this region by a maximum of +/- 10 % off.

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Abstract

La présente invention concerne un catalyseur sous enveloppe destiné à la production de monomère d'acétate de vinyle (VAM), lequel catalyseur comprend un support de catalyseur poreux oxydé pourvu d'une enveloppe extérieure, renfermant du palladium et de l'or sous forme métallique, le squelette du support de catalyseur poreux contenant des motifs oxyde de hafnium. Ce catalyseur sous enveloppe convient à la production de VAM et se caractérise par une activité et une sélectivité vis-à-vis du monomère d'acétate de vinyle relativement fortes, lesdites activité et sélectivité étant maintenues sur des durées d'utilisation relativement longues. L'invention concerne également un procédé de production dudit catalyseur sous enveloppe.
EP08773355A 2007-05-31 2008-05-30 CATALYSEUR SOUS ENVELOPPE Pd/Au À TENEUR EN HfO2, PROCÉDÉ DE PRODUCTION ET D'UTILISATION DUDIT CATALYSEUR Withdrawn EP2164630A2 (fr)

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PCT/EP2008/004333 WO2008145392A2 (fr) 2007-05-31 2008-05-30 CATALYSEUR SOUS ENVELOPPE Pd/Au À TENEUR EN HfO2, PROCÉDÉ DE PRODUCTION ET D'UTILISATION DUDIT CATALYSEUR

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DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
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CN101687175A (zh) 2010-03-31
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JP2010527779A (ja) 2010-08-19
CN101687175B (zh) 2012-11-28
US20110166010A1 (en) 2011-07-07
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US8466082B2 (en) 2013-06-18

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