EP1937860B2 - Verfahren zur herstellung eines aluminiumbandes für lithographische druckplattenträger - Google Patents
Verfahren zur herstellung eines aluminiumbandes für lithographische druckplattenträger Download PDFInfo
- Publication number
- EP1937860B2 EP1937860B2 EP06819101.4A EP06819101A EP1937860B2 EP 1937860 B2 EP1937860 B2 EP 1937860B2 EP 06819101 A EP06819101 A EP 06819101A EP 1937860 B2 EP1937860 B2 EP 1937860B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- aluminum
- printing plate
- aluminum strip
- strip
- roughening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 77
- 229910052782 aluminium Inorganic materials 0.000 title claims description 77
- 238000000034 method Methods 0.000 title claims description 48
- 238000007639 printing Methods 0.000 title claims description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000004411 aluminium Substances 0.000 title claims 3
- 230000008569 process Effects 0.000 claims description 44
- 229910000838 Al alloy Inorganic materials 0.000 claims description 36
- 238000000137 annealing Methods 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 238000005098 hot rolling Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 238000005275 alloying Methods 0.000 claims 4
- 238000007788 roughening Methods 0.000 description 45
- 239000011572 manganese Substances 0.000 description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 238000005096 rolling process Methods 0.000 description 18
- 238000005452 bending Methods 0.000 description 15
- 229910045601 alloy Inorganic materials 0.000 description 14
- 239000000956 alloy Substances 0.000 description 14
- 239000011777 magnesium Substances 0.000 description 14
- 239000002800 charge carrier Substances 0.000 description 10
- 229910052748 manganese Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 6
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 5
- 238000005097 cold rolling Methods 0.000 description 5
- 238000005238 degreasing Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 240000003517 Elaeocarpus dentatus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/22—Light metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/12—Preparation of material for subsequent imaging, e.g. corona treatment, simultaneous coating, pre-treatments
Definitions
- the aluminum strip produced according to the invention has, on the one hand, very good properties with regard to electrochemical roughening of the strip and, on the other hand, improved mechanical properties, in particular after a stoving process has been carried out.
- This is all the more surprising since the experts have previously believed that only an Fe content of max. 0.4% by weight may be present in an aluminum strip for lithographic printing plate supports in order not to lead to uneven roughening of the strip due to coarse precipitation phases in the cast, which are preferably attacked during electrochemical roughening.
- the elimination of coarse phases in the cast does not occur in the aluminum strip produced according to the invention, since a uniform roughening structure is achieved during the electrochemical roughening.
- the aluminum strip according to the invention has an elastic limit Rp0.2 of at least 180 MPa and a tensile strength Rm of at least 190 MPa in the rolling direction and / or an elastic limit Rp0 , 2 of at least 190 MPa and a tensile strength Rm of at least 200 MPa transverse to the rolling direction at room temperature.
- the aluminum strip produced according to the invention has a heat treatment of 240 ° C for 10 min. a yield strength Rp0.2 of at least 140 MPa and a tensile strength Rm of at least 150 MPa across or in the direction of rolling, the aluminum strip produced according to the invention is particularly suitable for lithographic printing plate supports for particularly long runs, since these lose as little strength as possible after the baking process should.
- the aluminum strip produced according to the invention is further improved in that the alternating bending strength of the aluminum strip in the rolling direction is more than 3000 bending cycles, preferably more than 3200 bending cycles in the rolling direction.
- the above-mentioned number of bending cycles in the rolling direction is achieved by the aluminum strip produced according to the invention, in particular in the hard-rolled state, and thus exceeds conventional ones Aluminum strips in hard-rolled condition clearly.
- the flexural fatigue strength was measured by taking samples with a length of 100 mm and a width of 20 mm from the aluminum strip, the longitudinal axis of the samples corresponding to the rolling direction. The samples were then subjected to an alternating bend over a radius of 30 mm and the number of bends to break was determined.
- the number of bends is a measure of the stability of a printing plate carrier made from the aluminum strip during the printing process. In the present case, the number of bending cycles was statistically determined from twelve samples.
- the aluminum strip produced according to the invention thus enables the production of printing plate carriers with a particularly long service life.
- Aluminum strips in condition H18 were also produced from the melts V486 and V488, with intermediate annealing taking place during cold rolling.
- the degree of rolling down to the final thickness was limited to 65% to 85% after the intermediate annealing.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Printing Plates And Materials Therefor (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06819101.4A EP1937860B2 (de) | 2005-10-19 | 2006-10-19 | Verfahren zur herstellung eines aluminiumbandes für lithographische druckplattenträger |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05022772 | 2005-10-19 | ||
EP06819101.4A EP1937860B2 (de) | 2005-10-19 | 2006-10-19 | Verfahren zur herstellung eines aluminiumbandes für lithographische druckplattenträger |
PCT/EP2006/067573 WO2007045676A1 (de) | 2005-10-19 | 2006-10-19 | Aluminiumband für lithographische druckplattenträger |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1937860A1 EP1937860A1 (de) | 2008-07-02 |
EP1937860B1 EP1937860B1 (de) | 2013-08-14 |
EP1937860B2 true EP1937860B2 (de) | 2020-06-03 |
Family
ID=35708600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06819101.4A Active EP1937860B2 (de) | 2005-10-19 | 2006-10-19 | Verfahren zur herstellung eines aluminiumbandes für lithographische druckplattenträger |
Country Status (7)
Country | Link |
---|---|
US (1) | US9914318B2 (pt) |
EP (1) | EP1937860B2 (pt) |
JP (1) | JP4913816B2 (pt) |
CN (1) | CN101321882B (pt) |
BR (1) | BRPI0617702B8 (pt) |
ES (1) | ES2435404T5 (pt) |
WO (1) | WO2007045676A1 (pt) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006134542A2 (en) * | 2005-06-15 | 2006-12-21 | Hulett Aluminium (Proprietary) Limited | Aluminium alloy for lithographic sheet and process for producing the same |
EP1820866B2 (de) † | 2006-02-13 | 2018-08-08 | Hydro Aluminium Rolled Products GmbH | Aluminiumcarbidfreie Aluminiumlegierung |
ES2556166T3 (es) * | 2006-07-21 | 2016-01-13 | Hydro Aluminium Rolled Products Gmbh | Banda de aluminio para soporte de placa de impresión litográfica |
ES2407655T5 (es) * | 2007-11-30 | 2023-02-23 | Speira Gmbh | Banda de aluminio para soportes para planchas de impresión litográfica y su producción |
US20110039121A1 (en) * | 2007-11-30 | 2011-02-17 | Hydro Aluminium Deutschland Gmbh | Aluminum strip for lithographic printing plate carriers and the production thereof |
GB2461240A (en) * | 2008-06-24 | 2009-12-30 | Bridgnorth Aluminium Ltd | Aluminium alloy for lithographic sheet |
EP2192202B2 (de) | 2008-11-21 | 2022-01-12 | Speira GmbH | Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit |
EP2243848B1 (de) | 2009-04-24 | 2016-03-30 | Hydro Aluminium Rolled Products GmbH | Mangan- und magnesiumreiches Aluminiumband |
EP2243849B1 (de) | 2009-04-24 | 2013-07-10 | Hydro Aluminium Deutschland GmbH | Mangan- und hoch magnesiumreiches Aluminiumband |
CN102459674B (zh) | 2009-05-08 | 2015-09-16 | 诺夫利斯公司 | 铝平版印刷片 |
WO2012059362A1 (en) | 2010-11-04 | 2012-05-10 | Novelis Inc. | Aluminium lithographic sheet |
ES2544707T3 (es) | 2011-03-02 | 2015-09-03 | Hydro Aluminium Rolled Products Gmbh | Banda de aluminio para soporte de planchas de impresión litográficas con recubrimientos basados en agua |
JP6051213B2 (ja) * | 2011-06-21 | 2016-12-27 | ハイドロ アルミニウム ロールド プロダクツ ゲゼルシャフト ミット ベシュレンクテル ハフツングHydro Aluminium Rolled Products GmbH | 化学処理したアルミニウム製またはアルミニウム合金製集電体箔 |
CN102337430A (zh) * | 2011-09-03 | 2012-02-01 | 乳源东阳光精箔有限公司 | 一种铝合金印刷版基及其制造方法 |
EP2623639A1 (de) | 2012-02-02 | 2013-08-07 | Hydro Aluminium Deutschland GmbH | Aluminiumlegierungsband mit verbesserter Oberflächenoptik und Verfahren zu dessen Herstellung |
ES2748106T3 (es) | 2016-04-20 | 2020-03-13 | Hydro Aluminium Rolled Prod | Fabricación de banda litográfica con alta disminución por pasada de laminación en frío |
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EP0239995A2 (en) † | 1986-04-01 | 1987-10-07 | Furukawa Aluminum Co., Ltd. | Aluminum alloy supporter for lithographic printing plate |
JPH09111427A (ja) † | 1995-10-19 | 1997-04-28 | Kobe Steel Ltd | 印刷版用アルミニウム合金板及びその製造方法 |
EP1172228A2 (en) † | 2000-07-11 | 2002-01-16 | Fuji Photo Film Co., Ltd. | Support for lithographic printing plate and pre-sensitized plate |
EP1293579A2 (en) † | 2001-09-12 | 2003-03-19 | Fuji Photo Film Co., Ltd. | Support for lithographic printing plate and presensitized plate |
WO2003023079A1 (en) † | 2001-09-12 | 2003-03-20 | Alcan International Limited | Ai alloy for lithographic sheet |
US6555247B2 (en) † | 2000-07-11 | 2003-04-29 | Mitsubishi Aluminum Kabushiki Kaisha | Aluminum alloy plate for planographic printing plate |
EP1516744A2 (en) † | 2003-09-19 | 2005-03-23 | Fuji Photo Film Co., Ltd. | Aluminium alloy blank for lithographic printing plate and support for lithographic printing plate |
EP1820866A1 (de) † | 2006-02-13 | 2007-08-22 | Hydro Aluminium Deutschland GmbH | Aluminiumcarbidfreie Aluminiumlegierung |
EP1880861A1 (de) † | 2006-07-21 | 2008-01-23 | Hydro Aluminium Deutschland GmbH | Aluminiumband für lithografische Druckplattenträger |
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JPS6347349A (ja) * | 1986-08-18 | 1988-02-29 | Sky Alum Co Ltd | 平版印刷版用アルミニウム合金支持体 |
JPH01247547A (ja) | 1988-03-29 | 1989-10-03 | Showa Alum Corp | フッ素樹脂塗装用アルミニウム合金 |
JPH03222796A (ja) * | 1990-01-30 | 1991-10-01 | Nippon Light Metal Co Ltd | 平版印刷版用アルミニウム支持体 |
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ES2407655T5 (es) | 2007-11-30 | 2023-02-23 | Speira Gmbh | Banda de aluminio para soportes para planchas de impresión litográfica y su producción |
-
2006
- 2006-10-19 US US12/090,775 patent/US9914318B2/en active Active
- 2006-10-19 ES ES06819101T patent/ES2435404T5/es active Active
- 2006-10-19 CN CN2006800443465A patent/CN101321882B/zh active Active
- 2006-10-19 EP EP06819101.4A patent/EP1937860B2/de active Active
- 2006-10-19 JP JP2008536055A patent/JP4913816B2/ja active Active
- 2006-10-19 BR BRPI0617702A patent/BRPI0617702B8/pt active IP Right Grant
- 2006-10-19 WO PCT/EP2006/067573 patent/WO2007045676A1/de active Application Filing
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---|---|---|---|---|
EP0239995A2 (en) † | 1986-04-01 | 1987-10-07 | Furukawa Aluminum Co., Ltd. | Aluminum alloy supporter for lithographic printing plate |
JPH09111427A (ja) † | 1995-10-19 | 1997-04-28 | Kobe Steel Ltd | 印刷版用アルミニウム合金板及びその製造方法 |
EP1172228A2 (en) † | 2000-07-11 | 2002-01-16 | Fuji Photo Film Co., Ltd. | Support for lithographic printing plate and pre-sensitized plate |
US6555247B2 (en) † | 2000-07-11 | 2003-04-29 | Mitsubishi Aluminum Kabushiki Kaisha | Aluminum alloy plate for planographic printing plate |
EP1293579A2 (en) † | 2001-09-12 | 2003-03-19 | Fuji Photo Film Co., Ltd. | Support for lithographic printing plate and presensitized plate |
WO2003023079A1 (en) † | 2001-09-12 | 2003-03-20 | Alcan International Limited | Ai alloy for lithographic sheet |
EP1516744A2 (en) † | 2003-09-19 | 2005-03-23 | Fuji Photo Film Co., Ltd. | Aluminium alloy blank for lithographic printing plate and support for lithographic printing plate |
EP1820866A1 (de) † | 2006-02-13 | 2007-08-22 | Hydro Aluminium Deutschland GmbH | Aluminiumcarbidfreie Aluminiumlegierung |
EP1880861A1 (de) † | 2006-07-21 | 2008-01-23 | Hydro Aluminium Deutschland GmbH | Aluminiumband für lithografische Druckplattenträger |
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Also Published As
Publication number | Publication date |
---|---|
CN101321882A (zh) | 2008-12-10 |
ES2435404T3 (es) | 2013-12-19 |
CN101321882B (zh) | 2011-09-21 |
EP1937860B1 (de) | 2013-08-14 |
WO2007045676A1 (de) | 2007-04-26 |
EP1937860A1 (de) | 2008-07-02 |
JP4913816B2 (ja) | 2012-04-11 |
US20090016928A1 (en) | 2009-01-15 |
BRPI0617702B1 (pt) | 2018-04-03 |
BRPI0617702A2 (pt) | 2011-08-09 |
ES2435404T5 (es) | 2021-02-22 |
US9914318B2 (en) | 2018-03-13 |
BRPI0617702B8 (pt) | 2023-01-10 |
JP2009512780A (ja) | 2009-03-26 |
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