EP1674589A2 - Pulver zum thermischen Spritzen, Flammspritzverfahren und Verfahren zum Auftragen einer Schicht durch thermischen Spritzen - Google Patents

Pulver zum thermischen Spritzen, Flammspritzverfahren und Verfahren zum Auftragen einer Schicht durch thermischen Spritzen Download PDF

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Publication number
EP1674589A2
EP1674589A2 EP05027976A EP05027976A EP1674589A2 EP 1674589 A2 EP1674589 A2 EP 1674589A2 EP 05027976 A EP05027976 A EP 05027976A EP 05027976 A EP05027976 A EP 05027976A EP 1674589 A2 EP1674589 A2 EP 1674589A2
Authority
EP
European Patent Office
Prior art keywords
thermal spraying
spraying powder
thermal
less
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05027976A
Other languages
English (en)
French (fr)
Inventor
Nobuaki Fujimi Incorporated Kato
Satoru Fujimi Incorporated Osawa
Tsuyoshi Fujimi Incorporated Itsukaichi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujimi Inc
Original Assignee
Fujimi Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujimi Inc filed Critical Fujimi Inc
Publication of EP1674589A2 publication Critical patent/EP1674589A2/de
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying

Definitions

  • Japanese Laid-Open Patent Publication No. 2003-129212 discloses a technique for forming a thermal spray coating from a thermal spraying powder having 90% particle size D 90 of 20 ⁇ m or less.
  • the thermal spraying powder of the above publication since the ratio of particles having a particle size of 1 ⁇ m or less in the thermal spraying powder is not specified, the thermal spraying powder could include a large amount of particles having a particle size of 1 ⁇ m or less. If the thermal spraying powder includes many particles having a particle size of 1 ⁇ m or less, in addition to decreasing the flowability of the thermal spraying powder, flocculation of the thermal spraying powder is likely to occur. If the thermal spraying powder that has been flocculated is mixed in the thermal spray coating, uniformity and density of the thermal spray coating may be decreased, through holes may be formed in the thermal spray coating, or the surface roughness of the thermal spray coating may be increased.
  • the ratio of the total volume of particles having a particle size of 1 ⁇ m or less to the total volume of all particles in the thermal spraying powder is greater than 2% (that is, when 2% particle size D 2 of the thermal spraying powder is less than 1 ⁇ m)
  • the flowability of the thermal spraying powder is significantly decreased since particles having a particle size of 1 ⁇ m or less is included in the thermal spraying powder by a large amount.
  • supply of the thermal spraying powder from the powder feeder to the spray gun during spraying becomes unstable.
  • flocculation of the thermal spraying powder may occur, thereby decreasing the uniformity and the density of the thermal spray coating, generating through holes in the thermal spray coating, or increasing the surface roughness of the thermal spray coating.
  • the granulated and sintered powder generally has sufficient flowability and less risk of contamination by impurities during a manufacturing process as compared to a fused and crushed powder and a sintered and crushed powder. Therefore, the thermal spraying powder of this embodiment consisting of the granulated and sintered powder has the same advantages.
  • the evaluation results are shown in the column entitled "Surface roughness of thermal spray coating before polishing” in table 1.
  • the thermal spraying powders were evaluated according to a three rank scale: excellent (1), good (2), and poor (3). That is, when the standard deviation of the surface roughness Ra was less than 0.3, the thermal spraying powder was ranked excellent, when it was 0.3 or more and less than 0.45, the thermal spraying powder was ranked good, and when it was 0.45 or more, the thermal spraying powder was ranked poor.
  • the evaluation results are shown in the column entitled "Variation of surface roughness" in Table 1.
  • Powder feeder "AM-30” manufactured by Technoserve Co. Ltd.
  • Oxygen flow rate 1900 scfh Kerosene flow rate: 5.1 gph Spraying distance: 250 mm
  • Base material SS400 steel plate (7 cm x 5 cm x 2.3 mm, degreased and surface roughened using an alumina grit #40)
  • Spray gun "JP-5000" manufactured by Praxair/TAFA
  • Powder feeder "AM-30” manufactured by Technoserve Co. Ltd.
  • Oxygen flow rate 1900 scfh Kerosene flow rate: 5.1 gph Spraying distance: 380 mm Barrel length: 101.6 mm
  • Table 3 Surface roughness measuring instrument: "SURFCOM 1400D-12" manufactured by TOKYO SEIMITSU CO. LTD. Measuring length: 10.0 mm Cutoff wavelength: 0.8 mm Measuring speed: 0.30 mm/second Tip: r 5 ⁇ m

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
EP05027976A 2004-12-21 2005-12-20 Pulver zum thermischen Spritzen, Flammspritzverfahren und Verfahren zum Auftragen einer Schicht durch thermischen Spritzen Withdrawn EP1674589A2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004370262A JP4885445B2 (ja) 2004-12-21 2004-12-21 溶射用粉末

Publications (1)

Publication Number Publication Date
EP1674589A2 true EP1674589A2 (de) 2006-06-28

Family

ID=36123340

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05027976A Withdrawn EP1674589A2 (de) 2004-12-21 2005-12-20 Pulver zum thermischen Spritzen, Flammspritzverfahren und Verfahren zum Auftragen einer Schicht durch thermischen Spritzen

Country Status (5)

Country Link
US (1) US20060134343A1 (de)
EP (1) EP1674589A2 (de)
JP (1) JP4885445B2 (de)
KR (1) KR101241244B1 (de)
CN (1) CN1792469A (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112008001037B4 (de) * 2007-06-21 2018-02-22 Toyota Jidosha Kabushiki Kaisha Verfahren zum Ausbilden einer metallischen Beschichtung, wärmeleitendes Element und dessen Verwendung als Leistungsmodul

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5039346B2 (ja) * 2006-09-12 2012-10-03 株式会社フジミインコーポレーテッド 溶射用粉末及び溶射皮膜
EP1911858B1 (de) * 2006-10-02 2012-07-11 Sulzer Metco AG Verfahren zur Herstellung einer Beschichtung mit kolumnarer Struktur
JP2011017079A (ja) * 2009-06-10 2011-01-27 Fujimi Inc 溶射用粉末及び溶射皮膜の形成方法
US20120308776A1 (en) * 2009-11-27 2012-12-06 Seiji Kuroda Cermet coating, spraying particles for forming same, method for forming cermet coating, and coated article
DE102011052121A1 (de) * 2011-07-25 2013-01-31 Eckart Gmbh Beschichtungsverfahren nutzend spezielle pulverförmige Beschichtungsmaterialien und Verwendung derartiger Beschichtungsmaterialien
FR2999457B1 (fr) * 2012-12-18 2015-01-16 Commissariat Energie Atomique Procede de revetement d'un substrat par un materiau abradable ceramique, et revetement ainsi obtenu.
KR102106486B1 (ko) 2018-07-25 2020-05-07 안동대학교 산학협력단 내열성, 내마모성 및 내부식성이 우수한 용사분말, 이를 이용하여 용사피막을 형성하는 방법 및 용사피막이 형성된 그레이트바
CN112639155B (zh) * 2018-08-27 2023-03-14 东华隆株式会社 热喷涂皮膜的形成方法
CN114226713B (zh) * 2021-12-17 2023-07-25 武汉苏泊尔炊具有限公司 热喷涂粉末及其制备方法、烹饪器具

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003129212A (ja) 2001-10-15 2003-05-08 Fujimi Inc 溶射方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2585540B2 (ja) * 1986-07-15 1997-02-26 バブコツク日立株式会社 溶射方法
JPH01195267A (ja) * 1988-01-29 1989-08-07 Mazda Motor Corp 溶射被覆された物とその物品および溶射用粉末の製造方法
US4865252A (en) * 1988-05-11 1989-09-12 The Perkin-Elmer Corporation High velocity powder thermal spray gun and method
US4925626A (en) * 1989-04-13 1990-05-15 Vidhu Anand Method for producing a Wc-Co-Cr alloy suitable for use as a hard non-corrosive coating
JPH0347957A (ja) * 1989-07-14 1991-02-28 Nippon Steel Corp 低鉄損一方向性珪素鋼板の製造方法
US5075129A (en) * 1989-11-27 1991-12-24 Union Carbide Coatings Service Technology Corporation Method of producing tungsten chromium carbide-nickel coatings having particles containing three times by weight more chromium than tungsten
JPH0586452A (ja) * 1991-09-27 1993-04-06 Kobe Steel Ltd 溶射用粉末材料
JP3203442B2 (ja) * 1992-12-18 2001-08-27 太平洋セメント株式会社 複合溶射材料および溶射皮膜とその製造方法
CA2129874C (en) * 1993-09-03 1999-07-20 Richard M. Douglas Powder for use in thermal spraying
US5419976A (en) * 1993-12-08 1995-05-30 Dulin; Bruce E. Thermal spray powder of tungsten carbide and chromium carbide
US5789077A (en) * 1994-06-27 1998-08-04 Ebara Corporation Method of forming carbide-base composite coatings, the composite coatings formed by that method, and members having thermally sprayed chromium carbide coatings
US5580833A (en) * 1994-10-11 1996-12-03 Industrial Technology Research Institute High performance ceramic composites containing tungsten carbide reinforced chromium carbide matrix
JPH08311635A (ja) * 1995-05-12 1996-11-26 Sumitomo Metal Mining Co Ltd 高速粉末式フレーム溶射用タングステンカーバイト系サーメット粉末
US5763106A (en) * 1996-01-19 1998-06-09 Hino Motors, Ltd. Composite powder and method for forming a self-lubricating composite coating and self-lubricating components formed thereby
JP2990655B2 (ja) * 1996-05-21 1999-12-13 東京タングステン株式会社 複合炭化物粉末及びその製造方法
JPH1088311A (ja) * 1996-09-17 1998-04-07 Showa Denko Kk タングステンカーバイド/コバルト溶射粉末及びその製造方法
JP3172488B2 (ja) * 1998-03-10 2001-06-04 トーカロ株式会社 耐摩耗性に優れる軟質非鉄金属部材および軟質非鉄金属部材の表面改質方法
JP3605281B2 (ja) * 1998-03-18 2004-12-22 ペンタックス株式会社 累進多焦点レンズ
US6004372A (en) * 1999-01-28 1999-12-21 Praxair S.T. Technology, Inc. Thermal spray coating for gates and seats
JP2001234320A (ja) * 2000-02-17 2001-08-31 Fujimi Inc 溶射粉末材、およびそれを使用した溶射方法並びに溶射皮膜
US6410470B1 (en) * 2000-04-24 2002-06-25 Saint-Gobain Industrial Ceramics, Inc. Thermal spray powder process
JP3523216B2 (ja) * 2001-04-06 2004-04-26 信越化学工業株式会社 溶射用希土類含有化合物粒子、これを溶射した溶射部材
JP3672833B2 (ja) 2000-06-29 2005-07-20 信越化学工業株式会社 溶射粉及び溶射被膜
JP3952252B2 (ja) * 2001-01-25 2007-08-01 株式会社フジミインコーポレーテッド 溶射用粉末およびそれを用いた高速フレーム溶射方法
JP4044348B2 (ja) * 2001-03-08 2008-02-06 信越化学工業株式会社 溶射用球状粒子および溶射部材
EP1239055B1 (de) * 2001-03-08 2017-03-01 Shin-Etsu Chemical Co., Ltd. Sphärische Teilchen zum thermischen Spritzen sowie bespritzte Bauteile
JP4273292B2 (ja) * 2001-04-06 2009-06-03 信越化学工業株式会社 溶射用粒子、および該粒子を用いた溶射部材
US6596397B2 (en) * 2001-04-06 2003-07-22 Shin-Etsu Chemical Co., Ltd. Thermal spray particles and sprayed components
JP4628578B2 (ja) * 2001-04-12 2011-02-09 トーカロ株式会社 低温溶射皮膜被覆部材およびその製造方法
US7017677B2 (en) * 2002-07-24 2006-03-28 Smith International, Inc. Coarse carbide substrate cutting elements and method of forming the same
JP4354176B2 (ja) * 2002-11-19 2009-10-28 Jfeスチール株式会社 Wcサーメット溶射ロールおよびその製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003129212A (ja) 2001-10-15 2003-05-08 Fujimi Inc 溶射方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112008001037B4 (de) * 2007-06-21 2018-02-22 Toyota Jidosha Kabushiki Kaisha Verfahren zum Ausbilden einer metallischen Beschichtung, wärmeleitendes Element und dessen Verwendung als Leistungsmodul

Also Published As

Publication number Publication date
KR101241244B1 (ko) 2013-03-14
US20060134343A1 (en) 2006-06-22
JP4885445B2 (ja) 2012-02-29
KR20060071320A (ko) 2006-06-26
CN1792469A (zh) 2006-06-28
JP2006176818A (ja) 2006-07-06

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