EP1614817A1 - Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken - Google Patents

Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken Download PDF

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Publication number
EP1614817A1
EP1614817A1 EP05022491A EP05022491A EP1614817A1 EP 1614817 A1 EP1614817 A1 EP 1614817A1 EP 05022491 A EP05022491 A EP 05022491A EP 05022491 A EP05022491 A EP 05022491A EP 1614817 A1 EP1614817 A1 EP 1614817A1
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EP
European Patent Office
Prior art keywords
dispensing device
active substance
phase
storage containers
holder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05022491A
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German (de)
English (en)
French (fr)
Inventor
Ralph Butter-Jentsch
Roland Menke
Hans-Georg MÜHLHAUSEN
Frank Pessel
Thomas Jungmann
Stefan Hucher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1614817A1 publication Critical patent/EP1614817A1/de
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E03D9/032—Devices connected to or dispensing into the bowl

Definitions

  • the invention relates to a delivery device for delivering active substance fluids into the rinsing liquid in a toilet bowl having the features of the preamble of claim 1.
  • active ingredient fluid means flowable, that is liquid to viscous, possibly gelatinous or pasty or granular or otherwise pourable active substance preparations with cleansing, disinfecting, deodorizing, bleaching and the like. Effect (in particular described in the non-prepublished DE 199 30 362 A1, as well as in EP 0 775 741 A1 and EP 0 960 984 A2).
  • Dispensers of the type in question are known under the keyword “toilet bowl” in different versions.
  • dispensing devices for a single active substance fluid are known.
  • the drug fluid is there in a fixed in a holder or interchangeable used reservoir with a mounted on the holder reservoir bottom outlet opening.
  • the active substance fluid is added via an actuating element (eg made of an open-cell foam) which can be impregnated therewith and acted upon by the rinsing fluid (EP 785 315 A1).
  • an actuating element eg made of an open-cell foam
  • the outlet opening of the reservoir after expulsion of a closure member of the reservoir of a holder fixedly arranged on the sealing member is largely closed, so that only a flow path with a small cross-section for leakage of the active ingredient fluid is available.
  • the device works by utilizing the capillary action of the open cell foam.
  • a similar construction is also known with a distribution ribbed plate.
  • Another dispensing device for a single active substance fluid (DE 299 02 066 U1) realized on the reservoir a valve-like working sealing element, which normally assumes a positive closed closed position in which the outlet opening is closed. This happens under the effect of the weight of a valve ball acting as a sealing element.
  • This sealing element can be adjusted against the biasing force in the outlet opening a little releasing release position.
  • the confirmation element On one side of the axis, the confirmation element has a loading region having a trough-like receptacle for rinsing liquid. The lying on the other side of the axis arm of the confirmation element is applied to the bottom of the sealing element.
  • Each chamber has a dispenser with a dispensing tube, which exits with its one free end over the bottom of the container into the environment and at its other free end fluid leading surrounded by a cover.
  • the two chambers of the container can be filled via slit-like passages of a cover part of overflowing rinse water, which then exits in the manner of a siphon or overflow via the delivery tube with entrainment of the respective active ingredient in the toilet bowl.
  • the separation of the chambers in the container has the advantage that different media can be used, which would otherwise be detrimental to their desired effect in a common storage in only one chamber. The consistency of the media may vary in the different chambers.
  • a two-chamber dispenser for the same or different, gel-like active fluids (WO 92/20876 A1), in which the outlet openings are designed as bottom-side perforations in the reservoirs and permanently open. Due to the viscosity and surface tension of the gel, this normally can not escape by itself under gravitational force. Only by overflowing rinsing liquid, which enters from below into the outlet openings and the outlet openings near gel slightly dissolves, subsets of the drug fluids can be discharged. In this two-chamber system, it is also the case that the outlet openings are in principle open permanently, so even with prolonged non-use of the toilet bowl, the drug fluids either seep out or harden under the influence of the ambient atmosphere and then are no longer activated.
  • the teaching is based on the problem of optimizing the known, previously explained dispensing device for dispensing active fluid from at least two separate reservoir with respect to the control option for the delivery of the drug fluids.
  • an embodiment of the dispensing device according to the invention according to claim 16 is particularly appropriate.
  • a positive closure of the outlet openings is useful in this design, in particular for the purpose of the defined dimensioning of the subsets and for the purpose of protecting the active ingredient fluids in the reservoirs with prolonged non-use.
  • the dispenser shown in the drawing is used to deliver at least two active fluids in the rinsing fluid, with which is rinsed in a toilet bowl. What is understood in the meaning of the teaching as drug fluid has already been defined in the general part of the description, it should be pointed out.
  • Such a dispensing device initially has a holder 1 which can be suspended at the edge of the toilet bowl and at least two storage containers 2, 3, which are provided in the holder 1 and are separated from each other, for one active substance fluid in each case.
  • the drug fluids may be matched, different, compatible or incompatible drug fluids.
  • Active substance fluids which are suitable according to the invention are, for example, fragrance phases, in particular perfumed fragrance phases.
  • scent phases usually comprise at least one perfume, preferably perfume oil, at least one surfactant or an emulsifier and water and optionally further ingredients such as preservatives, thickeners, complexing agents, dyes, other surfactants or emulsifiers, stabilizers, lime solubilizer, etc.
  • bleaching phases in particular chlorine-containing bleaching phases, preferably bleaching phases based on hypochlorite, wherein the bleaching phases may optionally contain, in addition to the actual bleaching agent and water, further ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, fragrances, etc.
  • lime-dissolving active substance phases preferably acidic lime-dissolving active substance phases.
  • Such lime-solubilizing active ingredient phases may contain, in addition to the actual lime solubilizer - preferably this is an organic or inorganic acid - and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • surfactant phases so-called “foam boosters”, as active substance fluids.
  • surfactant phases may also contain other customary ingredients.
  • active-ingredient fluids having an antibacterial and / or fungicidal and / or antiviral active phase, wherein the active-substance phase, in addition to the antibacterial and / or fungicidal and / or antiviral active and water, optionally further ingredients, such as, for example, surfactants or emulsifiers, thickeners, fragrances , Preservatives, etc. may contain.
  • the active substance fluids are enzyme-containing active substance phases.
  • enzyme (s) and water such enzyme-containing active substance phases may optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • the active substance fluids used according to the invention are absorbent, in particular odor-absorbing, active-substance phases. These may, in addition to the absorbent, in particular odor absorbent, and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc. included.
  • the dispensing device offers the possibility of using combinations of different active substance fluids in the storage containers 2, 3, wherein according to a preferred embodiment one of the storage containers 2, 3 contains a fragrance phase, in particular as defined above.
  • active substance-fluid combinations to be used are perfumed fragrance phase combined with chlorine bleach (together not storage-stable), perfumed fragrance phase with highly concentrated surfactant phase (foam booster), fragrance phase with lime-dissolving, acidic phase of active substance, fragrance phase with antibacterial active ingredient phase, different acid systems, fragrance phase combined with enzyme-containing active ingredient phase, perfumed acid phase combined with water-coloring phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active ingredient phase, thickened with polyacrylate etc.
  • viscous to gel-like active substance fluids with viscosities in the range of a few thousand mPas, in particular from 2000 to 5000 mPas, preferably 2500 to 3500 mPas (measured with Rotovisko LVT, spindle 2, 6 U / min, 20 ° C).
  • each storage container 2, 3 has its own outlet opening 4, via which the respective active substance fluid can be dispensed into the rinsing liquid.
  • the outlet openings 4 of the reservoir 2, 3 are arranged so that only active fluid exits.
  • the delivery of a subset of the active substance fluid from each of the storage containers 2, 3 takes place in the rinsing liquid.
  • this is realized in that the outlet opening 4 of the respective storage container 2, 3 in the use position, as shown in Fig. 2, is arranged on the bottom side. Overflowing rinse water meets at most laterally on the reservoir 2, 3rd
  • the reservoir 2, 3 are mounted individually replaceable in the holder 1 or attachable.
  • An alternative is to couple the reservoir 2, 3 by means of an adapter o. The like. Together and so coupled in the holder 1 to install.
  • a further alternative is to couple the storage containers 2, 3 directly to one another and to mount them directly coupled in the holder 1.
  • the reservoir 2, 3 in a common, one-piece housing form, for example, as a separate chambers in a contiguous housing, and so then attach to the holder 1.
  • one or the other variant will be chosen.
  • the storage containers 2, 3 as described in the prior art can be individually refillable via a respective refilling opening, optionally equipped with a valve.
  • the illustrated embodiment shows the reservoir 2, 3 as exchangeable disposable containers, which will probably be more common in practice.
  • the illustrated and preferred embodiment shows the reservoir 2, 3 arranged on the holder 1 side by side. The same applies to an arrangement of the reservoir 2, 3 in a row. Alternatively, it could also be provided to arrange the storage containers 2, 3 one above the other for the purpose of a cascaded product delivery.
  • the illustrated and preferred embodiment also shows that the reservoir 2.3, which are here individually interchangeable, in the holder 1 by plugging in from above (in the use position) are attachable.
  • the reservoir 2, 3 attach laterally on the holder 1 and then swing in the position of use about a pivot axis.
  • the reservoir 2, 3 has a flexible wall portion or a total of a flexible wall and an application of the active substance fluid therein by pressurization of the reservoir 2, 3 takes place. This pressurization can be exercised for example via a corresponding mechanism by the overflowing rinsing liquid.
  • the dispensing mechanisms known in principle for dispensers for a single active substance fluid of the prior art can be used.
  • a plate-like distribution element is provided on the holder 1, which has an overflow during the rinsing of the rinsing liquid Beaufschlagungs Scheme, wherein the interior of the storage container. 2 , 3 via the outlet opening 4, possibly with the intermediate arrangement of a free flow of the active substance fluid preventing arrangement, is permanently connected to the distribution element in connection.
  • the plate-like distribution element is assigned to all storage containers 2, 3 together.
  • the illustrated and preferred embodiment shows a solution that operates with an actively closing sealing element.
  • an actively closing sealing element namely, the bottom side arranged outlet opening 4 of the reservoir 2, 3 closed by means of a sealing element 5.
  • the sealing element 5 is biased into the closing position closing the outlet opening 4 and adjustable against the biasing force in a release opening 4 a little releasing release position.
  • actuating element 6 is provided, which is temporarily such a force acted upon in such a way with each flushing by the rinsing liquid, that the sealing element 5 temporarily assumes the release position against the biasing force.
  • an actuating element 6 is acted upon by a flushing process of flushing liquid Beaufschlagungs Scheme 7, so impinges on the rinse during flushing.
  • the actuator 6 is designed as a one-armed, at one end hinged to the holder 1 lever.
  • the sealing element 5 is arranged on the actuating element 6 at a certain distance from the loading area 7.
  • the sealing element 5 is arranged between the hinged to the holder 1 end of the actuating element 6 and the loading area 7.
  • the opening path of the sealing element 5 is thus comparatively low, the opening is as desired only with a very small gap.
  • this gap is opened asymmetrically with a corresponding design of the sealing element 5, namely, more strongly opening in the direction of the loading region 7, so that active substance fluid preferably exits in this direction.
  • This is the direction to the rinsing fluid with which the active fluid then mixes accordingly.
  • the active substance fluid can therefore run on the upper side of the actuating element 6 in the direction of the loading region 7 and already mixes with the overflowing rinsing fluid on this route.
  • the sealing element 5 is integrally formed on the actuating element 6. This is recommended in particular in the design of the actuating element 6 made of a plastic material, in particular of plastic spritzcalledem.
  • the holder 1 may be made of plastic, in particular of plastic, preferably plastic, preferably thermoplastic material in a particularly preferred manner. Overall, it can be provided that the actuating element 6 is integrally formed on the holder 1 and the Biasing force is generated by the inherent elasticity of the confirmation element 6.
  • the illustrated and preferred embodiment is characterized in a special way by the fact that the actuating element 6, the sealing elements 5 for at least two reservoir 2, 3, preferably for all reservoir 2, 3, is assigned together. It can be seen in Fig. 1 in plan view, the wide and plate-like running actuator 6 with the also wide, trough-like Beaufschlagungs Scheme 7 and the recognizable small discharge openings 8, all in the frame-like bottom plate 9 of the holder 1. It is coordinated the arrangement of the outlet 4 These are in fact carried out asymmetrically with respect to the center of the entire dispensing device with the outlet openings 4 offset overall relative to the center of the dispensing device (FIG. 2). This results in a concentration of the active substance leakage to a relatively narrow range regardless of the fact that two reservoirs 2, 3 are provided.
  • fragrance phase composition FAEOS-Na, C12-14 + 2 EO 24.50%
  • chlorine-containing bleaching phase (about 1% active chlorine) composition Na-hypochlorite (12.5% active chlorine) 8.00% Chlorine bleach Sodium hydroxide (50%) 2.50% Neutalleitersstoff Oxy-Rite® 100 * 1 0.10% Stabilization of rheological properties Polyacrylate polymer * 2 1.00% thickener Cocoalkyldimethylamine oxide * 3 2.00% Surfactant / emulsifier Dest. Water ad.100 * 1 manufacturer BF Goodrich * 2 Manufacturer BF Goodrich, eg Carbopol® 676 * 3 eg Genaminox CS / Fa.
  • fragrance phase with high perfume content composition FAEOS-Na, C12-14 + 2 EO * 24.50%
  • Base surfactant Alkyl (C8-10) -1,5-glucoside ** 2.88% Co.Tensid / Emulagtor 1,2-propanediol 10.00% Emulagtor Ethanol 96%, 1% MEK denatured 5.00% Co.Emulgator hydroxyethyl 0.45% thickener Perfume oil, note Citrus 20.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 * eg Texapon N 70 ** eg Glucopon 220 UP-W 2500 mPas, 20 ° C, Rotovisko LVT, Spindle 2, 6U / min 6.5 pH, undiluted clear solution manufacturing Put warm water at 20-25 ° C.
  • fragrance phase combined with acidic, limescale active ingredient phase a.) fragrance phase composition FAS-Na, C12-14 * 29.50% Base surfactant Alkyl (C12-14) -polyglucoside ** 3.30% Co.Tensid / Emulagtor 1,2-propanediol 5.00% Emulagtor Ethanol 96%, 1% MEK denatured 5.00% Co.Emulgator hydroxyethyl 0.45% thickener Perfume oil, note Aqua 10.00% perfume Trisodium citrate * 2H 2 O 2.00% complexing Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 * eg Texapon LS 35 ** eg Glucopon 600 CS-UP 2500 mPas, 20 ° C, Rotovisko LVT, Spindle 2, 6U / min 8.0 pH, undiluted clear solution manufacturing Put warm water at 20-25 ° C.
  • fragrance phase combined with antibacterial drug phase a.) fragrance phase / foam activated by ABS formulation composition Na alkyl benzene sulfonate * 25.50% Base surfactant C12-15 oxo alcohol + 10 EO ** 10.00% Co.Tensid / Emulagtor 1,2-propanediol 5.00% Emulagtor Ethanol 96%, 1% MEK denatured 5.00% Co.Emulgator hydroxyethyl 0.45% thickener Perfume oil, Lemon Note 10.00% perfume Halbacetate-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 * eg Marlon A 350, Fa.
  • Lactic acid phase composition FAEOS-Na, C12-14 + 2 EO 8.11% Base surfactant Alkyl (C8-10) -1,5-glucoside 5.44% Co.Tensid Lactic acid * 2.50% Kalklöser Polysaccharide / xanthan gum 0.22% thickener Ethanol 96%, 1% MEK denatured 3.00% Co.Emulgator Perfume oil, note orange 8.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 * Purac 80 3500 mPas, 20 ° C, Rotovisko LVT, spindle 2.20 rpm 2.2 pH, undiluted clear solution manufacturing Submit water.
  • citric acid phase / Nio-surfactant base composition FA-C12-C18 + 7 EO * 12.50%
  • fragrance phase combined with enzyme-containing active ingredient phase a.) fragrance phase composition FAEOS-Na, C12-14 + 2 EO 24.50% Base surfactant Na-alkanesulfonate * 8.50% Co.Tensid 1,2-propanediol 5.00% Emulagtor Ethanol 96%, 1% MEK denatured 5.00% Co.Emulgator hydroxyethyl 0.45% thickener Perfume oil, fruit blossoms 9.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 * eg Hostapur SAS 60 / Hoechst 2500 mPas, 20 ° C, Rotovisko LVT, Spindle 2.6U / min 6.8 pH, undiluted clear solution manufacturing Put warm water at 20-25 ° C.
  • fragrance phase combined with odor-absorbing active ingredient phase a.) fragrance phase composition FAEOS-Na, C12-14 + 2 EO 24.50% Base surfactant Alkyl (C8-10) -1,5-glucoside 2.88% Co.Tensid / Emulagtor 1,2-propanediol 10.00% Emulagtor hydroxyethyl 0.50% thickener Perfume oil, willow green 10.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 2500 mPas, 20 ° C, Rotovisko LVT, Spindle 2, 6U / min 6.5 pH, undiluted clear solution manufacturing Put warm water at 20-25 ° C.
  • fragrance phase composition FAEOS-Na, C12-14 + 2 EO 20.10% Base surfactant Alkyl (C8-10) -1,5-glucoside 5.44% Co.Tensid citric acid 2.00% Kalklöser Polysaccharide / xanthan gum 0.22% thickener Ethanol 96%, 1% MEK denatured 6.00% Co.Emulgator Perfume oil, Apple 10.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 3500 mPas, 20 ° C, Rotovisko LVT, spindle 2.20 rpm 2.5 pH, undiluted clear solution manufacturing Submit water.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Epidemiology (AREA)
  • Detergent Compositions (AREA)
  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
EP05022491A 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken Withdrawn EP1614817A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10057325 2000-11-17
DE10113036A DE10113036B4 (de) 2000-11-17 2001-03-17 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
EP01955364A EP1334239B1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP01955364A Division EP1334239B1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken

Publications (1)

Publication Number Publication Date
EP1614817A1 true EP1614817A1 (de) 2006-01-11

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ID=26007712

Family Applications (4)

Application Number Title Priority Date Filing Date
EP05022491A Withdrawn EP1614817A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
EP01955364A Expired - Lifetime EP1334239B1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken
EP09008185A Expired - Lifetime EP2116656B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden
EP09008188A Expired - Lifetime EP2123833B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden

Family Applications After (3)

Application Number Title Priority Date Filing Date
EP01955364A Expired - Lifetime EP1334239B1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken
EP09008185A Expired - Lifetime EP2116656B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden
EP09008188A Expired - Lifetime EP2123833B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden

Country Status (21)

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US (2) US20040068782A1 (es)
EP (4) EP1614817A1 (es)
JP (1) JP2004526075A (es)
CN (1) CN1474901A (es)
AR (1) AR031465A1 (es)
AT (3) ATE315140T1 (es)
AU (1) AU2001277547A1 (es)
CR (1) CR6973A (es)
CZ (4) CZ305459B6 (es)
DE (4) DE10164866B4 (es)
ES (3) ES2206080T3 (es)
HU (1) HU228554B1 (es)
PL (1) PL196974B1 (es)
PT (2) PT2123833E (es)
RO (1) RO120857B1 (es)
RU (1) RU2266372C2 (es)
SI (1) SI21141B (es)
SK (1) SK5812003A3 (es)
TR (1) TR200301652T3 (es)
UA (1) UA74854C2 (es)
WO (1) WO2002040791A1 (es)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10164866B4 (de) * 2000-11-17 2007-06-14 Henkel Kgaa Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
US7511006B2 (en) * 2000-12-14 2009-03-31 The Clorox Company Low residue cleaning solution comprising a C8 to C10 alkylpolyglucoside and glycerol
GB2372046A (en) * 2001-02-09 2002-08-14 Jeyes Group Ltd Liquid dispensing unit for a toilet bowl
DE10204928B4 (de) * 2002-02-07 2004-04-01 Henkel Kgaa Abgabevorrichtung zur Abgabe eines Wirkstofffluids in die Spülflüssigkeit in einem Toilettenbecken
WO2003078747A1 (en) 2002-03-12 2003-09-25 Robert Mcbride Limited Dispenser
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